{"id":100194,"date":"2017-09-06T06:30:09","date_gmt":"2017-09-05T22:30:09","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=100194"},"modified":"2017-09-05T15:42:29","modified_gmt":"2017-09-05T07:42:29","slug":"%e4%b8%ad%e5%9b%bd%e7%a7%91%e5%ad%a6%e9%99%a2%e7%90%86%e5%8c%96%e6%8a%80%e6%9c%af%e7%a0%94%e7%a9%b6%e6%89%80%ef%bc%9a%e9%87%91%e5%b1%9e%e7%a3%b7%e5%8c%96%e7%89%a9%e5%82%ac%e5%8c%96%e6%b0%a8%e7%a1%bc","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=100194","title":{"rendered":"\u4e2d\u56fd\u79d1\u5b66\u9662\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\uff1a\u91d1\u5c5e\u78f7\u5316\u7269\u50ac\u5316\u6c28\u787c\u70f7\u6c34\u89e3\u653e\u6c22\u7814\u7a76\u83b7\u8fdb\u5c55"},"content":{"rendered":"<p><strong><b>\u3010<\/b><\/strong><strong><b>\u6210\u679c\u7b80\u4ecb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p>\u8fd1\u671f\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\u5149\u5316\u5b66\u8f6c\u6362\u4e0e\u5408\u6210\u7814\u7a76\u4e2d\u5fc3\u91d1\u5c5e\u6709\u673a\u5149\u5316\u5b66\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u5f15\u5165\u4e0d\u540c\u542b\u91cf\u7684\u91d1\u5c5e\u94b4\uff0c\u7cfb\u7edf\u8c03\u63a7\u4e09\u7ec4\u5206\u91d1\u5c5e\u78f7\u5316\u7269Co-Ni-P\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u4fc3\u8fdb\u91d1\u5c5e\u4e2d\u5fc3\u5230\u78f7\u5143\u7d20\u7684\u7535\u8377\u8f6c\u79fb\uff0c\u589e\u5f3a\u50ac\u5316\u5242\u4e0e\u6c28\u787c\u70f7\u5206\u5b50\u4f5c\u7528\uff0c\u540c\u65f6\u8c03\u63a7\u6c34\u5206\u5b50\u4e2d\u7f9f\u57fa\u5bf9\u6c28\u787c\u70f7\u5206\u5b50\u4eb2\u6838\u8fdb\u653b\uff0c\u4f7f\u6c28\u787c\u70f7\u6c34\u89e3\u653e\u6c22\u901f\u7387\u5927\u5e45\u63d0\u5347\u3002\u7814\u7a76\u4eba\u5458\u4e0e\u897f\u73ed\u7259\u52a0\u6cf0\u7f57\u5c3c\u4e9a\u5316\u5b66\u7814\u7a76\u6240\u6559\u6388Nuria L\u00f3pez\u5408\u4f5c\uff0c\u4ece\u7406\u8bba\u4e0a\u5bf9\u50ac\u5316\u53cd\u5e94\u673a\u7406\u8fdb\u884c\u4e86\u8be6\u7ec6\u7814\u7a76\u3002\u76f8\u5173\u7814\u7a76\u7ed3\u679c\u4ee5\u9898\u4e3a\u201cTernary Ni-Co-P nanoparticles as noble-metal-free catalysts to boost the hydrolytic dehydrogenation of ammonia-borane\u201d\u53d1\u8868\u5728\u56fd\u9645\u80fd\u6e90\u73af\u5883\u9886\u57df\u671f\u520aEnergy &amp; Environmental Science\u4e0a\u3002<\/p>\n<p><strong><b>\u3010<\/b><\/strong><strong><b>\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><strong><b>\u3011<\/b><\/strong><\/p>\n<p><strong><b>\u56fe<\/b><\/strong><strong><b>1 <\/b><\/strong><strong><b>\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-100195\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/1-5.png\" alt=\"\" width=\"600\" height=\"407\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/1-5.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/1-5-300x204.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>\uff08a\uff09\u5236\u5907\u7684Ni<sub>7<\/sub>Co<sub>1.3<\/sub>P\u7eb3\u7c73\u7c92\u5b50\u7684TEM\u56fe\u3002<\/p>\n<p>\uff08b\uff09\u5236\u5907\u7684Ni<sub>0.7<\/sub>Co<sub>1.3<\/sub>P\u7eb3\u7c73\u7c92\u5b50\u7684\u653e\u5927TEM\u56fe\u3002<\/p>\n<p>\uff08c\uff09\u5c3a\u5bf8\u5206\u5e03\u56fe\u3002<\/p>\n<p>\uff08d\uff09Ni<sub>0.7<\/sub>Co<sub>1.3<\/sub>P\u7684HRTEM\u56fe\u50cf\u3002<\/p>\n<p>\uff08e\uff09Ni<sub>0.7<\/sub>Co<sub>1.3<\/sub>P\u7684\u6676\u683c\u95f4\u8ddd\u3002<\/p>\n<p>\uff08f\uff09\uff08d\uff09\u4e2d\u76f8\u5e94\u533a\u57df\u7684FFT\u56fe\u6848\u3002<\/p>\n<p>\uff08g\uff09Ni<sub>0.7<\/sub>Co<sub>1.3<\/sub>P\u4e2dCo\uff0cNi\u548cP\u5bf9\u5e94\u7684EDX\u5143\u7d20\u6620\u5c04<\/p>\n<p><strong><b>\u56fe2 <\/b><\/strong><strong><b>\u6027\u80fd\u8868\u5f81<\/b><\/strong><\/p>\n<p><strong><b><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-100196\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/2-6.png\" alt=\"\" width=\"600\" height=\"476\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/2-6.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/2-6-300x238.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/b><\/strong><\/p>\n<p>\uff08a\uff09Ni<sub>7<\/sub>Co<sub>1.3<\/sub>P \/ GO\u5206\u6563\u5728\u6c34\u4e2d\u7684\u7167\u7247\u3002<\/p>\n<p>\uff08b\uff09XRD\u3002<\/p>\n<p>\uff08c\uff09GO\u548c\uff08d\uff09Ni<sub>0.7<\/sub>Co<sub>1.3<\/sub>P \/ GO\u7eb3\u7c73\u6df7\u5408\u7269\u7684TEM\u56fe\u50cf\u3002<\/p>\n<p>\uff08e\uff09Ni<sub>0.7<\/sub>Co<sub>1.3<\/sub>P \/ GO\u7684\u653e\u5927TEM\u56fe\u3002<\/p>\n<p>\uff08g\uff09Ni<sub>0.7<\/sub>Co<sub>1.3<\/sub>P \/ GO\u7684HRTEM\u56fe\u3002<\/p>\n<p>\uff08f\uff09\u5c3a\u5bf8\u5206\u5e03\u3002<\/p>\n<p>\uff08h\uff09\u5355\u4e2aNPs\u3002<\/p>\n<p>\uff08i\uff09\uff08h\uff09\u4e2d\u76f8\u5e94\u533a\u57df\u7684FFT\u6a21\u5f0f\u3002<\/p>\n<p>\uff08j\uff09\u6676\u683c\u95f4\u8ddd\u3002<\/p>\n<p><strong><b>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/b><\/strong><\/p>\n<p>\u8fc7\u6e21\u91d1\u5c5e\u78f7\u5316\u7269\u5177\u6709\u534a\u91d1\u5c5e\u7279\u6027\uff0c\u5728\u9178\u78b1\u73af\u5883\u4e2d\u7a33\u5b9a\uff0c\u540c\u65f6\u4e5f\u6709\u5f88\u597d\u7684\u5149\u3001\u70ed\u7a33\u5b9a\u6027\uff0c\u662f\u7ee7\u8fc7\u6e21\u91d1\u5c5e\u78b3\u5316\u7269\u548c\u8fc7\u6e21\u91d1\u5c5e\u6c2e\u5316\u7269\u4e4b\u540e\u51fa\u73b0\u7684\u4e00\u7c7b\u65b0\u578b\u50ac\u5316\u6750\u6599\uff0c\u5728\u5149\/\u7535\u50ac\u5316\u5206\u89e3\u6c34\u4ea7\u6c22\u3001\u50ac\u5316\u52a0\u6c22\u548c\u8131\u6c22\u7b49\u53cd\u5e94\u4e2d\u8868\u73b0\u51fa\u4e0e\u8d35\u91d1\u5c5e\u94c2\u5ab2\u7f8e\u7684\u50ac\u5316\u6d3b\u6027\uff0c\u88ab\u8a89\u4e3a\u201c\u51c6\u94c2\u50ac\u5316\u5242\u201d\u3002<\/p>\n<p>\u4e2d\u56fd\u79d1\u5b66\u9662\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\u5149\u5316\u5b66\u8f6c\u6362\u4e0e\u5408\u6210\u7814\u7a76\u4e2d\u5fc3\u91d1\u5c5e\u6709\u673a\u5149\u5316\u5b66\u7814\u7a76\u7ec4\u591a\u5e74\u6765\u81f4\u529b\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u5316\u5408\u7269\u7684\u5236\u5907\u4e0e\u5149\/\u7535\u50ac\u5316\u6027\u8d28\u7814\u7a76\u3002\u7814\u7a76\u4eba\u5458\u5c1d\u8bd5\u5c06\u8fc7\u6e21\u91d1\u5c5e\u78f7\u5316\u7269\u4f5c\u4e3a\u52a9\u50ac\u5316\u5242\u5f15\u5165\u5149\u50ac\u5316\u53cd\u5e94\u4f53\u7cfb\u4e2d\uff0c\u6784\u5efa\u4e86\u9ad8\u6548\u7684\u786b\u5316\u9549\/\u78f7\u5316\u7269\u5149\u50ac\u5316\u5206\u89e3\u6c34\u4ea7\u6c22\u4f53\u7cfb\uff0c\u4ea7\u6c22\u901f\u7387\u6700\u9ad8\u8fbe\u5230200 mmol\u00b7h<sup>-1<\/sup>\u00b7g<sup>-1<\/sup>\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0c\u5229\u7528\u8fc7\u6e21\u91d1\u5c5e\u78f7\u5316\u7269\u4f5c\u4e3a\u524d\u4f53\uff0c\u8868\u9762\u539f\u4f4d\u6c27\u5316\u751f\u6210\u7684\u91d1\u5c5e\u6c27\u5316\u7269\/\u6c22\u6c27\u5316\u7269\u4f5c\u4e3a\u50ac\u5316\u4e2d\u5fc3\uff0c\u5b9e\u73b0\u4e86\u9ad8\u6548\u7684\u7535\u50ac\u5316\u5206\u89e3\u6c34\u4ea7\u6c27\u3002\u81f3\u4eca\uff0c\u5df2\u5728Chem. Commun.\u3001ACS Appl. Mater. Interfaces\u3001Appl. Catal. B: Environ.\u3001J. Mater. Chem. A\u00a0\u7b49\u671f\u520a\u53d1\u8868\u78f7\u5316\u7269\u50ac\u5316\u6c34\u5206\u89e3\u5b66\u672f\u8bba\u65878\u7bc7\u3002\u7814\u7a76\u8fd8\u8868\u660e\uff0c\u8fc7\u6e21\u91d1\u5c5e\u78f7\u5316\u7269\u4e5f\u80fd\u7528\u4e8e\u50ac\u5316\u5316\u5b66\u50a8\u6c22\u6750\u6599\u6c28\u787c\u70f7\u7684\u6c34\u89e3\u53cd\u5e94\uff0c\u5feb\u901f\u5c06\u6c28\u787c\u70f7\u4e2d\u7684\u6c22\u6c14\u91ca\u653e\u51fa\u6765\uff0c\u5ba4\u6e29\u4e0b\u653e\u6c22\u901f\u7387\u8fbe\u5230TOF=40.2 mol(H<sub>2<\/sub>)\u00a0mol(Ni<sub>2<\/sub>P)<sup>\u00a0-1<\/sup>min<sup>-1<\/sup>\u3002<\/p>\n<p>\u8be5\u5de5\u4f5c\u5f97\u5230\u79d1\u6280\u90e8\u56fd\u5bb6\u91cd\u70b9\u57fa\u7840\u7814\u7a76\u8ba1\u5212\uff08973\u8ba1\u5212\uff09\u3001\u4e2d\u79d1\u9662\u6218\u7565\u6027\u5148\u5bfc\u79d1\u6280\u4e13\u9879\uff08B\u7c7b\uff09\u548c\u767e\u4eba\u8ba1\u5212\uff08A\u7c7b\uff09\u4ee5\u53ca\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\u7684\u5927\u529b\u652f\u6301\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/paper.sciencenet.cn\/htmlpaper\/2017911521953844756.shtm\" target=\"_blank\" rel=\"noopener\">http:\/\/paper.sciencenet.cn\/\/htmlpaper\/2017911521953844756.shtm<\/a><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.rsc.org\/en\/content\/articlelanding\/2017\/ee\/c7ee01553d#!divAbstract\" target=\"_blank\" rel=\"noopener\">Ternary Ni-Co-P nanoparticles as noble-metal-free catalysts to boost the hydrolytic dehydrogenation of ammonia-borane<\/a>\u00a0(Energy Environ. Sci., 2017, DOI:10.1039\/C7EE01553D)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u77f3\u5c0f\u6885\u7f16\u8f91\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u8fd1\u671f\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u7406\u5316\u6280\u672f\u7814\u7a76\u6240\u5149\u5316\u5b66\u8f6c\u6362\u4e0e\u5408\u6210\u7814\u7a76\u4e2d\u5fc3\u91d1\u5c5e\u6709\u673a\u5149\u5316\u5b66\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u5f15\u5165\u4e0d\u540c\u542b\u91cf\u7684\u91d1\u5c5e\u94b4\uff0c\u7cfb\u7edf\u8c03\u63a7\u4e09\u7ec4\u5206\u91d1\u5c5e\u78f7\u5316\u7269Co-Ni-P\u7684\u7535\u5b50&#8230;<\/p>\n","protected":false},"author":2832,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[2247],"class_list":["post-100194","post","type-post","status-publish","format-standard","hentry","category-keji","tag-2247"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/100194"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2832"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=100194"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/100194\/revisions"}],"predecessor-version":[{"id":100244,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/100194\/revisions\/100244"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=100194"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=100194"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=100194"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}