{"id":101054,"date":"2017-09-13T06:30:27","date_gmt":"2017-09-12T22:30:27","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=101054"},"modified":"2017-09-11T23:09:38","modified_gmt":"2017-09-11T15:09:38","slug":"%e6%9a%a8%e5%a4%a7%e6%b5%99%e5%b7%a5%e5%a4%a7nature%e5%ad%90%e5%88%8a-%e5%87%9d%e8%83%b6-%e6%b0%94%e7%9b%b8%e6%b2%89%e7%a7%af%e6%b3%95%e5%88%b6%e5%a4%87%e8%b6%85%e8%96%84%e9%87%91%e5%b1%9e","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=101054","title":{"rendered":"\u66a8\u5927&\u6d59\u5de5\u5927Nature\u5b50\u520a: \u51dd\u80f6-\u6c14\u76f8\u6c89\u79ef\u6cd5\u5236\u5907\u8d85\u8584\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u5206\u79bb\u819c"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u819c\u5206\u79bb\u6280\u672f\uff0c\u7531\u4e8e\u5176\u9ad8\u6548\u3001\u8282\u80fd\u3001\u73af\u4fdd\u7b49\u7279\u70b9\uff0c\u5df2\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u73af\u5883\u6c61\u67d3\u6cbb\u7406\u3001\u5316\u5de5\u5206\u79bb\u7b49\u9886\u57df\uff0c\u5176\u4e2d\u5206\u5b50\u7b5b\u5206\u819c\u5728\u6c22\u6c14\u7eaf\u5316\u3001\u4e8c\u6c27\u5316\u78b3\u6355\u96c6\u3001\u70c3\u7c7b\u7684\u5206\u79bb\u4e2d\u5c55\u73b0\u51fa\u4e86\u4f18\u5f02\u7684\u9009\u62e9\u5206\u79bb\u6027\u80fd\u3002\u819c\u5206\u79bb\u4e2d\u901a\u5e38\u5b58\u5728\u6b64\u6d88\u5f7c\u957f\u7684\u4e0a\u9650\u7ebf\uff0c\u5373\u4e3a\u83b7\u5f97\u66f4\u9ad8\u7684\u9009\u62e9\u6027\/\u901a\u91cf\uff0c\u8d8b\u5411\u4e8e\u5236\u5907\u8f83\u539a\/\u66f4\u8584\u7684\u819c\uff0c\u5bf9\u5e94\u7684\u901a\u91cf\/\u9009\u62e9\u6027\u4f1a\u4e0b\u964d\u3002\u540c\u65f6\uff0c\u5206\u5b50\u7b5b\u5206\u819c\u7684\u89c4\u6a21\u5316\u5236\u5907\u4e5f\u662f\u5176\u5de5\u4e1a\u5316\u5e94\u7528\u7684\u74f6\u9888\u3002\u5982\u4f55\u80fd\u89c4\u6a21\u5316\u5730\u5236\u5907\u8d85\u8584\u4e14\u9ad8\u901a\u91cf\u9ad8\u9009\u62e9\u6027\u7684\u5206\u5b50\u7b5b\u5206\u819c\uff0c\u662f\u819c\u5206\u79bb\u9886\u57df\u7684\u91cd\u70b9\u548c\u96be\u70b9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe<\/strong>1 GVD<\/strong>\u5236\u5907\u8d85\u8584<\/strong>ZIF-8<\/strong>\u5206\u79bb\u819c<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6(MOF)\u5206\u79bb\u819c\u5f62\u6210\u6d41\u7a0b\u793a\u610f\u56fe\uff1b<\/p>\n

(b)Zn\u57fa\u51dd\u80f6\u7684\u793a\u610f\u56fe\u3001\u5316\u5b66\u7ed3\u6784\u4ee5\u53caZIF-8\u7684\u6676\u4f53\u7ed3\u6784\u3002Zn\u3001O\u3001C\u548cN\u539f\u5b50\u5206\u522b\u63cf\u7ed8\u4e3a\u9ec4\u3001\u7ea2\u3001\u7070\u548c\u84dd\u8272\uff0c\u4e3a\u4e86\u7b80\u5316\uff0cH\u539f\u5b50\u672a\u663e\u793a\uff1b<\/p>\n

(c-d)\u805a\u504f\u6c1f\u4e59\u70ef(PVDF)\u4e2d\u7a7a\u7ea4\u7ef4(c)\u548cZn\u57fa\u51dd\u80f6\u5c42(d)\u7684\u4fef\u89c6SEM\u56fe\uff1b<\/p>\n

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\u56fe<\/strong>2 ZIF-8<\/strong>\u5206\u79bb\u819c\u7684\u8868\u5f81\u548c\u539a\u5ea6<\/strong><\/p>\n

\"\"<\/p>\n

(a)Zn\u57fa\u51dd\u80f6\u548cZIF-8\u7c89\u672b\u7684\u5149\u5b66\u7167\u7247\uff1b<\/p>\n

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(c)ZnO\u3001Zn\u57fa\u51dd\u80f6\u5c42\u548c\u5728PVDF\u4e2d\u7a7a\u7ea4\u7ef4\u4e0a\u7ecf\u8fc7\u7145\u70e7\u7684Zn\u57fa\u51dd\u80f6\u5c42\u7684XRD\u8c31\u56fe\uff1b<\/p>\n

(d)ZIF-8\u3001ZIF-8\u5206\u79bb\u819c\u548c\u7ecf\u8fc7\u7145\u70e7\u7684ZIF-8\u5206\u79bb\u819c\u7684XRD\u8c31\u56fe\u3002\u6837\u54c1\u5236\u5907\u6761\u4ef6\uff1a\u6eb6\u80f6\u6d53\u5ea61U\u3001\u6d82\u819c\u65f6\u95f42s\u3001\u6c89\u79ef\u65f6\u95f42h\uff1b<\/p>\n

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(g-h)ZIF-8\u5206\u79bb\u819c\u7684\u4fef\u89c6\u548c\u622a\u9762SEM\u56fe\u3002\u6807\u5c3a\uff1a200nm\uff1b<\/p>\n

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\u56fe<\/strong>3 ZIF-8<\/strong>\u5206\u79bb\u819c\u7684\u6c14\u4f53\u8f93\u8fd0\u884c\u4e3a<\/strong><\/p>\n

\"\"<\/p>\n

(a)ZIF-8\u5206\u79bb\u819c(\u5236\u5907\u6761\u4ef6\uff1a\u6eb6\u80f6\u6d53\u5ea61U\u3001\u6d82\u819c\u65f6\u95f42s\u3001\u6c14\u76f8\u6c89\u79ef\u65f6\u95f42h)\u7684\u5355\u4e00\u6c14\u4f53\u8f93\u8fd0\u884c\u4e3a\u3002Xn<\/sub>\u4ee3\u8868\u4e0d\u540c\u7684\u6c14\u4f53\u3002\u900f\u8fc7\u6570\u636e\u662f\u7ecf\u5386\u65f6274h\u76842\u4e2a\u5faa\u73af\u6536\u96c6\u7684\uff0c\u4ece\u6700\u5c0f\u7684H2<\/sub>(\u52a8\u529b\u5b66\u76f4\u5f840.289nm)\u5230\u6700\u5927\u7684C3<\/sub>H8<\/sub>(\u52a8\u529b\u5b66\u76f4\u5f840.43nm)\uff0c\u7136\u540e\u53cd\u5e8f\uff1b<\/p>\n

(b)\u6bd4\u8f83ZIF-8\u5206\u79bb\u819c\u4e0e\u6587\u732e\u4e2d\u5176\u5b83\u5206\u79bb\u819c(\u9ad8\u5206\u5b50\u819c\u3001\u78b3\u819c\u3001\u5176\u5b83MOF\u819c)\u5bf9C3<\/sub>H6<\/sub>\/C3<\/sub>H8<\/sub>\u4f53\u7cfb\u7684\u5206\u79bb\u6027\u80fd\uff1b<\/p>\n

(c)\u4e0d\u540c\u6eb6\u80f6\u6d53\u5ea6(0.1\u30011\u30011.5\u548c2U)\u5236\u5f97\u7684ZIF-8\u5206\u79bb\u819c(\u5236\u5907\u6761\u4ef6\uff1a\u6d82\u819c\u65f6\u95f42s\u3001\u6c89\u79ef\u65f6\u95f42h)\u5bf9\u4e0d\u540c\u5355\u4e00\u6c14\u4f53\u7684\u900f\u8fc7\u884c\u4e3a\u3002<\/p>\n

\u56fe<\/strong>4 ZIF-8<\/strong>\u4e2d\u7a7a\u7ea4\u7ef4\u7ec4\u4ef6<\/strong><\/p>\n

\"\"<\/p>\n

(a)ZIF-8\u4e2d\u7a7a\u7ea4\u7ef4\u5206\u79bb\u819c\u7ec4\u4ef6\u7684\u5149\u5b66\u7167\u7247\uff1b<\/p>\n

(b-c)\u7ec4\u4ef6\u4e2dZIF-8\u5206\u79bb\u819c\u7684\u4fef\u89c6\u548c\u622a\u9762SEM\u56fe\u3002\u6807\u5c3a\uff1a400nm(b)\u30012\u03bcm(c)\uff1b<\/p>\n

(d)ZIF-8\u4e2d\u7a7a\u7ea4\u7ef4\u5206\u79bb\u819c\u7ec4\u4ef6\u5bf9\u4e0d\u540c\u6c14\u4f53\u7684\u900f\u8fc7\u884c\u4e3a\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n

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\u3010\u901a\u8baf\u4f5c\u8005<\/strong>\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

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\u539f\u6587\u94fe\u63a5\uff1a<\/strong>\u73af\u5883\u5b66\u9662\u674e\u4e07\u658c\u8bfe\u9898\u7ec4\u5728Nature Communications\u53d1\u8868\u819c\u5206\u79bb\u9886\u57df\u91cd\u8981\u8fdb\u5c55<\/a><\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Ultrathin metal\u2013organic framework membrane production by gel-vapour deposition<\/a>\u00a0(Nat. Commun., 2017, DOI: 10.1038\/s41467-017-00544-1)<\/p>\n

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