{"id":10178,"date":"2016-04-27T17:00:17","date_gmt":"2016-04-27T09:00:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=10178"},"modified":"2016-05-19T20:36:37","modified_gmt":"2016-05-19T12:36:37","slug":"%e9%a1%b6%e5%88%8a%e5%8a%a8%e6%80%81%e4%b8%a8naturejacsangew%e7%ad%89%e8%bf%91%e6%9c%9fmofs%e7%a0%94%e7%a9%b6%e8%bf%9b%e5%b1%95%e6%b1%87%e6%80%bb%e3%80%90160427%e6%9c%9f%e3%80%91","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=10178","title":{"rendered":"\u9876\u520a\u52a8\u6001\u4e28Nature\/JACS\/Angew\u7b49\u8fd1\u671fMOFs\u7814\u7a76\u8fdb\u5c55\u6c47\u603b\u3010160427\u671f\u3011"},"content":{"rendered":"

1\u3001Nature\uff1a\u5177\u6709\u53cd\u5e38\u6c14\u4f53\u5438\u9644\u6027\u80fd\u7684MOF<\/strong><\/p>\n

\u5728\u6c14\u4f53\u5206\u79bb\u8fc7\u7a0b\u4e2d\uff0c\u57fa\u4e8e\u5438\u9644\u73b0\u8c61\u662f\u5f88\u91cd\u8981\u7684\uff0c\u5982\u5bf9\u6e29\u5ba4\u6c14\u4f53\u3001\u6709\u6bd2\u7684\u6c14\u4f53\u6c61\u67d3\u7269\u5206\u79bb\u3002MOFs\u6750\u6599\u7684\u7ed3\u6784\u7075\u6d3b\u6027\u548c\u5ba2\u4f53\u5206\u5b50\u4f5c\u7528\u4f1a\u4f7f\u5176\u5177\u6709\u4ee4\u4eba\u6ee1\u610f\u7684\u6c14\u4f53\u5438\u9644\u6027\u80fd\uff0c\u901a\u5e38\u60c5\u51b5\u4e0b\uff0c\u76f8\u540c\u6e29\u5ea6\uff0c\u5916\u754c\u538b\u529b\u8d8a\u5927\uff0c\u5176\u5438\u9644\u7684\u7269\u8d28\u8d8a\u591a\uff0c\u76f4\u5230\u8fbe\u5230\u9971\u548c\u3002<\/p>\n

\u7136\u800c\uff0c\u6700\u8fd1\u4ee5\u5fb7\u56fd\u5fb7\u7d2f\u65af\u987f\u5de5\u4e1a\u5927\u5b66\u6559\u6388 Stefan Kaskel \u4e3a\u9996\u7684\u5fb7\u56fd\u548c\u6cd5\u56fd\u7814\u7a76\u56e2\u961f\u7814\u53d1\u7684\u4e00\u79cd\u53cd\u5e38\u7684MOF\u6750\u6599\uff0c\u53d6\u540d\u4e3aDUT-49\uff0c\u5b83\u5177\u6709\u5947\u7279\u5438\u9644\u6027\u80fd\uff1a\u5728\u7279\u5b9a\u7684\u538b\u529b\u548c\u6e29\u5ea6\u8303\u56f4\u5185\uff0c\u5f53\u6c14\u4f53\uff08\u7532\u70f7\u548c\u6b63\u4e01\u70f7\uff09\u538b\u529b\u589e\u52a0\u5230\u4e00\u5b9a\u7a0b\u5ea6\u540e\uff0c\u8fd9\u79cd\u6750\u6599\u4f1a\u7a81\u7136\u6536\u7f29\uff0c\u5e76\u91ca\u653e\u4e4b\u524d\u5df2\u7ecf\u5438\u9644\u7684\u6c14\u4f53\u3002\u7ecf\u8fc7\u539f\u4f4dPXRD\u3001\u6c14\u4f53\u5438\u9644\u5b9e\u9a8c\u3001\u7406\u8bba\u6a21\u62df\uff0c\u53d1\u73b0\u8fd9\u79cd\u53cd\u5e38\u7684\u5438\u9644\u884c\u4e3a\u662f\u7531\u7a81\u7136\u8fdf\u6ede\u7ed3\u6784\u53d8\u5f62\u548c\u6536\u7f29\u6bdb\u5b54\u63a7\u5236\u3002<\/p>\n

\u00a0\"\u56fe\u72471\"<\/b><\/strong><\/p>\n

\u56fe1 \u8be5\u79cdMOF\u5438\u9644\u884c\u4e3a\u8868\u5f81<\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1aA pressure-amplifying framework material with negative gas adsorption transitions<\/a><\/p>\n

2\u3001JACS\uff1a\u6676\u79cd\u6cd5\u5408\u6210\u7eaf\u76f8MOFs<\/strong><\/p>\n

\u91d1\u5c5e\u6709\u673a\u5316\u5408\u7269\uff08MOFs\uff09\u662f\u7531\u91d1\u5c5e\u79bb\u5b50\u6216\u56e2\u7c07\u4e0e\u6709\u673a\u914d\u4f53\u901a\u8fc7\u914d\u4f4d\u952e\u7ed3\u5408\u8d77\u6765\u7684\u6709\u673a\u65e0\u673a\u6742\u5316\u591a\u5b54\u6750\u6599\u3002\u7531\u4e8eMOFs\u5177\u6709\u6c38\u4e45\u591a\u5b54\u6027\u3001\u9ad8\u7684\u6bd4\u8868\u9762\u79ef\u3001\u7ed3\u6784\u53ef\u8c03\u6027\u7b49\u7279\u6027\uff0c\u5b83\u5728\u50a8\u6c22\u3001\u591a\u76f8\u50ac\u5316\u3001\u5149\u5b66\u3001\u6c14\u4f53\u8bc6\u522b\u7b49\u9886\u57df\u6709\u7740\u5de8\u5927\u7684\u5e94\u7528\u524d\u666f\u3002\u7136\u800c\u7eaf\u76f8MOFs\u7684\u5408\u6210\u5e38\u5e38\u5b58\u5728\u6311\u6218\uff0c\u8fd9\u6210\u4e3a\u5b83\u5e94\u7528\u7684\u4e00\u4e2a\u74f6\u9888\u3002\u8fd9\u662f\u7531\u4e8e\u91d1\u5c5e\u79bb\u5b50\u6216\u56e2\u7c07\u548c\u6709\u673a\u914d\u4f53\u4e4b\u95f4\u914d\u4f4d\u65b9\u5f0f\u5177\u6709\u7075\u6d3b\u6027\u548c\u548c\u591a\u6837\u6027\uff0c\u5728\u4f20\u7edf\u7684\u201c\u4e00\u9505\u6cd5\u201d\u5408\u6210MOFs\u7684\u65f6\u5019\u53ef\u4ee5\u5f62\u6210\u591a\u79cd\u7ec4\u5206\u4e14\u5206\u79bb\u5e38\u5e38\u9762\u4e34\u5f88\u5927\u7684\u56f0\u96be\u3002<\/p>\n

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\"\u56fe\u72472\"<\/p>\n

\u56fe2 \u6676\u79cd\u6cd5\u4e0e\u4f20\u7edfMOFs\u5408\u6210\u65b9\u6cd5\u6bd4\u8f83<\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1aSeed-Mediated Synthesis of Metal\u2013Organic Frameworks<\/a><\/p>\n

3\u3001Nature Communications\uff1a\u8f6c\u53d8\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u5316\u5408\u7269\u7528\u4e8e\u5206\u5b50\u7b5b\u819c<\/strong><\/p>\n

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\"\u56fe\u72473\"<\/p>\n

\u56fe3 CuBTC \u5230MIL-100\u7684\u8f6c\u53d8 \uff08a\uff09\u6240\u5408\u6210\u7684CuBTC\u516b\u9762\u4f53\u6676\u4f53SEM\u56fe\uff08b\uff09CuBTC \u5230MIL-100\u8f6c\u53d8\u8fc7\u7a0b\uff08c\uff09\u4e0d\u540c\u8f6c\u53d8\u65f6\u95f4CuBTC\/MIL-100\u7684XRD\u56fe\u8c31\uff08d\uff09\u4ece\u4e0d\u540c\u9762\u4e0a\u770b\u5230\u7684CuBTC\u7ed3\u6784\uff08e\uff09\u4e0d\u540c\u8f6c\u53d8\u65f6\u95f4(200)\/(222)\u548c(220)\/(222)\u884d\u5c04\u5cf0\u5f3a\u5ea6\u6bd4\uff08f\uff09\u4e0d\u540c\u8f6c\u53d8\u65f6\u95f4CuBTC\/MIL-100 SEM\u56fe\u8c31<\/p>\n

\u57fa\u4e8e\u591a\u4ef7\u9633\u79bb\u5b50\u53d6\u4ee3\uff0c\u5b9e\u73b0\u4e86\u4e0d\u540c\u7cfb\u5217\u7684MOF\u819c\u548c\u9897\u7c92\u7684\u5b8c\u5168\u8f6c\u5316\u548c\u8fde\u63a5\u3002\u8fd9\u4e2a\u7b56\u7565\u5305\u542b\u4e09\u4e2a\u91cd\u8981\u65b9\u9762\uff1a1\uff09\u5c06\u4e0d\u7a33\u5b9a\u3001\u6613\u5408\u6210\u7684MOF\u9897\u7c92\u6709\u6548\u7684\u8f6c\u5316\u6210\u5b8c\u5168\u4e0d\u540c\u62d3\u6251\u7ed3\u6784\u7684MOF\u819c\uff0c\u5982\u5229\u7528\u5e38\u89c4\u624b\u6bb5\u5408\u6210\u8fd9\u6837\u7684MOFs\u819c\u9700\u8981\u6781\u5176\u82db\u523b\u7684\u53cd\u5e94\u6761\u4ef6\uff1b2\uff09\u5c06\u4e00\u79cd\u5e38\u89c1\u7684MOF\u819c\u539f\u4f4d\u8f6c\u53d8\u6210\u53e6\u4e00\u79cdMOF\u819c\uff0c\u8fd9\u6837\u7684MOF\u819c\u5728\u76ee\u524d\u7684\u6761\u4ef6\u4e0b\u5408\u6210\u662f\u5f88\u96be\u7684\uff1b3\uff09\u901a\u8fc7\u6b8b\u7559\u7a7a\u8154\u7684\u91d1\u5c5e\u76d0\u7684\u56fa\u5b9a\u4f5c\u7528\uff0c\u53ef\u4ee5\u6709\u6548\u7684\u51cf\u5c11\u5b54\u5f84\u3002\u901a\u8fc7MOF\u819c\u7684\u8f6c\u53d8\u66b4\u9732\u9002\u5f53\u6676\u9762\uff0c\u4ee5\u5b9e\u73b0\u5206\u5b50\u7b5b\u7684\u80fd\u529b\u3002\u8fd9\u6837\u7684\u7b56\u7565\u53ef\u7528\u4e8e\u591a\u79cdMOF\u819c\u548c\u9897\u7c92\u3002\u5728\u672c\u6587\u4e2d\uff0c\u63d0\u51fa\u4e86\u4e24\u4e2a\u4f8b\u5b50\u3002\u4e00\u4e2a\u662fCuBTC\u5230MIL-100\u7684\u8f6c\u53d8\uff0c\u53e6\u4e00\u4e2a\u662fCuBTC \u5230CuBTC\/MIL-100\u7684\u8f6c\u53d8\u3002\u8fd9\u4e3a\u5206\u5b50\u7b5bMOF\u819c\u5408\u6210\u63d0\u4f9b\u4e86\u4e00\u6761\u7b80\u4fbf\u7684\u5408\u6210\u8def\u7ebf\u3002<\/p>\n

\u6587\u7ae0\u94fe\u63a5\uff1aTransformation of metal-organic frameworks for molecular sieving membranes<\/a><\/p>\n

4\u3001Angew. Chem\uff1aPd \u7eb3\u7c73\u7acb\u65b9\u4f53@ZIF-8\u6574\u5408\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u6750\u6599\u548c\u5149\u70ed\u8f6c\u6362\u6548\u5e94\u5b9e\u73b0\u9ad8\u6548\u9009\u62e9\u6027\u50ac\u5316<\/strong><\/p>\n

\u7eb3\u7c73\u590d\u5408\u6750\u6599\u7684\u610f\u4e49\u5728\u4e8e\u5229\u7528\u4e0d\u540c\u7ec4\u5206\u7684\u6750\u6599\u6027\u80fd\uff0c\u76f8\u4e92\u534f\u540c\uff0c\u53d6\u957f\u8865\u77ed\uff0c\u4ee5\u5b9e\u73b0\u66f4\u52a0\u5e7f\u6cdb\u7684\u5e94\u7528\u3002\u672c\u6587\uff0c\u5c06Pd \u7eb3\u7c73\u7acb\u65b9\u4f53\uff08NCs\uff09\u5f15\u5165\u5230ZIF-8\uff08\u4e00\u79cd\u5e38\u89c1\u7684MOF\uff09\uff0c\u5236\u5907\u51fa\u4e86Pd NCs@ZIF-8\u6838\u58f3\u7ed3\u6784\u7684\u590d\u5408\u6750\u6599\u3002\u5bf9\u4e8e\u8fd9\u6837\u7684\u590d\u5408\u6750\u6599\uff0c\u5c06Pd NCs\u7684\u7b49\u79bb\u5b50\u5149\u70ed\u8f6c\u6362\u6548\u5e94\u548cZIF-8\u7684\u591a\u79cd\u6027\u80fd\u7ed3\u5408\u5728\u4e00\u8d77\uff0c\u5728\u5e38\u6e29\u5e38\u538b\u7684\u6c22\u6c14\u6c1b\u56f4\u4e0b\uff0c\u901a\u8fc7\u5149\u7167\u53ef\u4ee5\u9009\u62e9\u6027\u6709\u6548\u50ac\u5316\u70ef\u70c3\u7684\u6c22\u5316\u53cd\u5e94\u3002\u8fd9\u79cd\u590d\u5408\u6750\u6599\u53ef\u4ee5\u4f5c\u4e3a\u4e00\u79cd\u201c\u5206\u5b50\u7b5b\u201d\u7b5b\u5b9a\u7279\u5b9a\u5927\u5c0f\u7684\u70ef\u70c3\u5b9e\u73b0\u9009\u62e9\u6027\u50ac\u5316\u7684\u6548\u679c\uff0c\u800c\u591a\u5b54\u7ed3\u6784\u7684MOFs \u58f3\u5c42\u80fd\u7a33\u5b9aPd NCs\uff0c\u9632\u6b62\u56e2\u805a\u3002<\/p>\n

\"\u56fe\u72474\"<\/p>\n

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\"\u56fe\u72475\"<\/p>\n

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\u6587\u7ae0\u94fe\u63a5\uff1aFabrication of Isolated Metal\u2013Organic Polyhedra in Confined Cavities: Adsorbents\/Catalysts with Unusual Dispersity and Activity<\/a><\/p>\n

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