{"id":102563,"date":"2017-09-23T14:00:33","date_gmt":"2017-09-23T06:00:33","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=102563"},"modified":"2017-09-19T15:52:16","modified_gmt":"2017-09-19T07:52:16","slug":"%e5%ae%8b%e5%bb%b6%e6%9e%97adv-mater-%e9%80%9a%e8%bf%87%e7%ba%b3%e7%b1%b3%e5%ad%94%e9%aa%a8%e6%9e%b6%e5%ae%9e%e7%8e%b0%e5%8f%af%e7%a9%bf%e6%88%b4%e5%a4%a7%e5%b0%ba%e5%af%b8%e7%9a%84%e9%92%99","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=102563","title":{"rendered":"\u5b8b\u5ef6\u6797Adv. Mater. : \u901a\u8fc7\u7eb3\u7c73\u5b54\u9aa8\u67b6\u5b9e\u73b0\u53ef\u7a7f\u6234\u5927\u5c3a\u5bf8\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"

\u3010\u524d\u8a00\u3011<\/strong><\/p>\n

\u53ef\u7a7f\u6234\u7535\u5b50\u5668\u4ef6\u4f5c\u4e3a\u4e0b\u4e00\u4ee3\u4eba\u5de5\u667a\u80fd\u8bbe\u5907\u5438\u5f15\u4e86\u8db3\u591f\u591a\u7684\u5173\u6ce8\u3002\u6b64\u5916\uff0c\u7535\u6e90\u4f5c\u4e3a\u53ef\u7a7f\u6234\u7535\u5b50\u5668\u4ef6\u7684\u6838\u5fc3\u90e8\u5206\uff0c\u5bf9\u4e8e\u672a\u6765\u5668\u4ef6\u7684\u8bbe\u8ba1\u548c\u529f\u80fd\u5177\u6709\u5341\u5206\u91cd\u8981\u7684\u610f\u4e49\u3002\u5bf9\u6bd4\u4e8e\u4f20\u7edf\u7535\u6e90\uff0c\u6709\u673a-\u65e0\u673a\u91d1\u5c5e\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSCs\uff09\u5177\u6709\u67d4\u6027\u3001\u8d28\u8f7b\u4ee5\u53ca\u5149\u4f0f\u6548\u7387\u9ad8\u7684\u4f18\u70b9\uff0c\u6709\u671b\u6210\u4e3a\u7406\u60f3\u7684\u7535\u6e90\u3002\u67d4\u6027\u7535\u6e90\u6bd4\u7845\u57fa\u592a\u9633\u80fd\u7535\u6c60\u66f4\u9002\u5408\u5546\u4e1a\u5e94\u7528\u3002<\/p>\n

PSCs\u8f83\u9ad8\u7684\u70e7\u7ed3\u6e29\u5ea6\uff08300\u2103\uff09\u548c\u9000\u706b\u6e29\u5ea6\uff0c\u6210\u4e3a\u5668\u4ef6\u5e94\u7528\u4e8e\u67d4\u6027\u57fa\u8d28\u4e2d\u7684\u91cd\u8981\u74f6\u9888\u3002\u6b64\u5916\u9499\u949b\u77ff\uff08PVK\uff09\u8584\u819c\u7684\u5149\u5229\u7528\u7387\u548c\u6676\u4f53\u8d28\u91cf\u5bf9\u4e8e\u63d0\u9ad8\u5668\u4ef6\u7684\u6548\u7387\u8d77\u5230\u81f3\u5173\u91cd\u8981\u7684\u4f5c\u7528\u3002\u4e3a\u4e86\u514b\u670d\u8fd9\u4e9b\u5c40\u9650\u6027\uff0c\u7814\u7a76\u4eba\u5458\u4e3a\u4f4e\u6e29\u5408\u6210\u4f20\u8f93\u5c42\u505a\u4e86\u5f88\u591a\u8d21\u732e\u3002\u91d1\u5c5e\u6c27\u5316\u7269\uff08TiO2\u3001ZnO\u3001MoO3\u3001 NiO\u548cCu2O\u7b49\uff09\u548c\u805a\u5408\u7269\uff08PEDOT:PSS\uff09\u7b49\u7528\u6765\u4f5c\u4e3aPSCs\u7684\u4f20\u8f93\u5c42\u3002\u6700\u8fd1\u7814\u7a76\u7684\u67d4\u6027\u3001\u5c0f\u9762\u79ef\u7684PSCs\u7684\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u53ef\u8fbe15%\u3002\u4e0d\u8fc7\uff0c\u7531\u4e8e\u8584\u819c\u4e2d\u5b58\u5728\u4e0d\u53ef\u907f\u514d\u7684\u65ad\u88c2\uff0c\u4e00\u822c\u62a5\u9053\u7684\u9ad8\u6548\u3001\u67d4\u6027\u7684PSCs\u5c3a\u5bf8\u8f83\u5c0f\uff0c\u5927\u9762\u79ef\u751f\u4ea7\u7684\u91cd\u590d\u6027\u5dee\u3002\u6b64\u5916\uff0c\u5668\u4ef6\u7684\u529b\u5b66\u7a33\u5b9a\u6027\u548c\u8010\u5f2f\u6298\u6027\u5747\u672a\u5b9e\u73b0\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u5b8b\u5ef6\u6797\u6559\u6388\u4e8e9\u67088\u65e5\u5728Avd. Mater.\u671f\u520a\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cWearable Large-Scale Perovskite Solar-Power Source via Nanocellular Scaffold\u201d\u7684\u7814\u7a76\u8bba\u6587\uff0c\u62a5\u9053\u4e86\u901a\u8fc7\u5f15\u5165\u7eb3\u7c73\u5b54\u9aa8\u67b6\u7684\u7a7a\u7a74\u8f93\u8fd0\u5c42\u6765\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\u3002\u7eb3\u7c73\u5b54\u9aa8\u67b6\u7a7a\u7a74\u8f93\u8fd0\u5c42\u53ef\u4ee5\u6709\u6548\u6539\u5584\u9499\u949b\u77ff\u592a\u9633\u80fd\u5668\u4ef6\u7684\u5149\u80fd\u6536\u96c6\u3001\u7ed3\u6676\u8d28\u91cf\u4ee5\u53ca\u7535\u8377\u4f20\u8f93\u6027\u80fd\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8fd9\u79cd\u521b\u65b0\u6027\u7684\u7eb3\u7c73\u5b54\u7ed3\u6784\u53ef\u4ee5\u91ca\u653e\u5f2f\u66f2\u65f6\u7684\u673a\u68b0\u5e94\u529b\uff0c\u589e\u5927\u4e86\u5927\u5c3a\u5bf8\u67d4\u6027\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5b9e\u73b0\u7684\u53ef\u884c\u6027\u3002\u5177\u6709\u8d85\u5f3a\u5f2f\u66f2\u75b2\u52b3\u7684\u9499\u949b\u77ff\u57fa\u592a\u9633\u80fd\u7535\u6c60\u57281.01 cm2\u7684\u9762\u79ef\u4e0b\u5b9e\u73b0\u4e8612.32%\u7684\u6548\u7387\u3002\u5728\u5b9e\u9645\u5e94\u7528\u4e2d\uff0c\u67d4\u6027\u9499\u949b\u77ff\u592a\u9633\u80fd\u6a21\u5757\u53ef\u4ee5\u4f5c\u4e3a\u53ef\u7a7f\u6234\u5668\u4ef6\u4f9b\u7535\u7535\u6e90\uff0c\u4e3a\u672a\u6765\u7684\u53ef\u7a7f\u6234\u7535\u5b50\u5668\u4ef6\u7684\u4f9b\u7535\u63d0\u4f9b\u4e86\u5e7f\u9614\u7684\u524d\u666f\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1\uff1a\u5236\u5907\u4e0e\u5f62\u6001\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a)NC-PEDOT:PSS\u9aa8\u67b6\u548cPVK\u592a\u9633\u80fd\u7535\u6c60\u7684\u5236\u5907\u6d41\u7a0b\u3002<\/p>\n

(b)NC-PEDOT:PSS\u9aa8\u67b6\u91ca\u653e\u5e94\u529b\u56fe\u89e3\u3002<\/p>\n

(c d)\u67d4\u6027PVK\u592a\u9633\u80fd\u7535\u6c60\u4f5c\u4e3a\u53ef\u7a7f\u6234\u7535\u5b50\u5668\u4ef6\u7535\u538b\u6e90\u7684\u7167\u7247\u3002<\/p>\n

(e)NC-PEDOT:PSS\u5c42\u7684\u626b\u63cf\u7535\u5b50\u663e\u5fae\u56fe\u50cf\u3002<\/p>\n

(f)NC-PEDOT:PSS\/PVK\u592a\u9633\u80fd\u7535\u6c60\u622a\u9762\u7684\u626b\u63cf\u7535\u5b50\u663e\u5fae\u56fe\u50cf\u3002<\/p>\n

\u56fe2\uff1a\u5149\u80fd\u6536\u96c6\u7279\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(a)ITO\/PEDOT:PSS\u548cNC-ITO\/PEDOT:PSS\u8584\u819c\u7684\u900f\u8fc7\u7387\u4e0e\u906e\u5149\u7387\u3002\u63d2\u56fe\u8868\u793a\u5229\u7528\u79ef\u5206\u7403\u5149\u5b66\u6d4b\u91cf\u7684\u56fe\u89e3\u3002<\/p>\n

(b)ITO\/PEDOT:PSS\/PVK\u548cNC-ITO\/PEDOT:PSS\/PVK\u8584\u819c\u7684\u5438\u6536\u6bd4\uff0c\u63d2\u56fe\u8868\u793a\u4e86\u6d4b\u8bd5\u7684\u5668\u4ef6\u7ed3\u6784\u3002<\/p>\n

(c)ITO\/PEDOT:PSS\u548cNC-ITO\/PEDOT:PSS\u8584\u819c\u7684\u5438\u6536\u7387\u3002<\/p>\n

(d)PEDOT:PSS\uff0cNC-PEDOT:PSS\u4ee5\u53ca\u8ba1\u7b97\u7684NC-ITO\/PEDOT:PSS\/PVK\u8584\u819c\u7684\u6298\u5c04\u7387\u3002<\/p>\n

(e)\u5229\u7528\u4f20\u8f93\u77e9\u9635\u6cd5\u8ba1\u7b97\u5177\u6709PEDOT\/PSS HTL \u5668\u4ef6\u7684\u5149\u7535\u573a\u5206\u5e03\uff0c\u5176\u4e2d\u5149\u7535\u573a\u5206\u5e03\u4f5c\u4e3a360-740nm\u6ce2\u957f\u7684\u51fd\u6570\u3002<\/p>\n

(f)\u5229\u7528\u4f20\u8f93\u77e9\u9635\u6cd5\u8ba1\u7b97\u5177\u6709NC-PEDOT\/PSS HTL\u5668\u4ef6\u7684\u5149\u7535\u573a\u5206\u5e03\uff0c\u5176\u4e2d\u5149\u7535\u573a\u5206\u5e03\u4f5c\u4e3a360-740nm\u6ce2\u957f\u7684\u51fd\u6570\u3002<\/p>\n

\u56fe3\uff1a\u7ed3\u6676\u6027\u4ee5\u53ca\u7535\u8377\u8f6c\u79fb\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a)PEDOT:PSS\/PVK\u8584\u819c\u4ee5\u53caNC-PEDOT:PSS\/PVK\u8584\u819c\u7684X\u5c04\u7ebf\u56fe\u8c31\u3002<\/p>\n

(b)NC-PEDOT:PSS\/PVK\u5c42\u7684\u626b\u63cf\u7535\u955c\u56fe\u50cf\u3002<\/p>\n

(c)PEDOT:PSS\u4ee5\u53caNC-PEDOT:PSS\u7684C 1S\u5cf0\u7684XPS\u68c0\u6d4b\u3002<\/p>\n

(d)PEDOT:PSS\u548cNC-PEDOT:PSS\u7a7a\u7a74\u5668\u4ef6\u7684\u7a7a\u95f4\u7535\u8377\u9650\u5236\u7535\u6d41\u6a21\u91cf\u3002<\/p>\n

(e)PEDOT:PSS\/PVK\u548cNC-PEDOT:PSS\/PVK\u8584\u819c\u7684\u65f6\u95f4\u5206\u8fa8\u5149\u81f4\u53d1\u5149\u5149\u8c31\u3002<\/p>\n

(f)\u9499\u949b\u77ff\u7535\u6c60\u7684\u80fd\u7ea7\u56fe\u3002<\/p>\n

\u56fe4\uff1a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u5206\u522b\u57fa\u4e8ePEDOT:PSS\u4ee5\u53caNC-PEDOT:PSSHTL\u7684PSCs\u7684\u6b63\u5411\u4e0e\u53cd\u5411J-V\u66f2\u7ebf\u3002<\/p>\n

(b)\u5206\u522b\u57fa\u4e8ePEDOT:PSS\u4ee5\u53caNC-PEDOT:PSSHTL\u7684\u67d4\u6027PVK\u7535\u6c60\u7684J-V\u66f2\u7ebf\u3002<\/p>\n

(c)\u5728\u5f2f\u66f2\u66f2\u7387\u76f4\u5f84500-2mm\u4e0b\u6d4b\u91cf\u5f52\u4e00\u5316\u7684PCE\u3002\u63d2\u56fe\u6240\u793a\u4e3a\u67d4\u6027\u9499\u949b\u77ff\u5668\u4ef6\u7684\u7684\u7167\u7247\u3002<\/p>\n

(d)\u67d4\u6027PVK\u7535\u6c60\u7684\u5e73\u5747PCE\u4f5c\u4e3a\u5f2f\u66f2\u6b21\u6570\u7684\u51fd\u6570\uff0c\u5176\u4e2d\u5f2f\u66f2\u534a\u5f84\u4e3a2mm\u3002\u7a7a\u5fc3\u548c\u5b9e\u5fc3\u6807\u8bb0\u5206\u522b\u4ee3\u8868\u4e86\u57fa\u4e8ePEDOT:PSS HTL\u548cNC-PEDOT:PSS HTL \u7684PSCs\u3002<\/p>\n

(e, f)\u5728\u5f2f\u66f2\u60c5\u51b5\u4e0b\uff0c\u57fa\u4e8ePEDOT:PSS\u548cNC-PEDOT:PSS\u7684PVK\u8584\u819c\u7684 SEM\u56fe\u50cf\u4ee5\u53caFEM\u6a21\u62df\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u901a\u8fc7\u5f15\u5165\u7eb3\u7c73\u5b54\u9aa8\u67b6\u7684\u7a7a\u7a74\u8f93\u8fd0\u5c42\u6765\u63d0\u9ad8\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd\u3002\u7eb3\u7c73\u5b54\u9aa8\u67b6\u7a7a\u7a74\u8f93\u8fd0\u5c42\u53ef\u4ee5\u6709\u6548\u6539\u5584\u9499\u949b\u77ff\u592a\u9633\u80fd\u5668\u4ef6\u7684\u5149\u80fd\u6536\u96c6\u3001\u7ed3\u6676\u8d28\u91cf\u4ee5\u53ca\u7535\u8377\u4f20\u8f93\u6027\u80fd\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8fd9\u79cd\u521b\u65b0\u6027\u7684\u7eb3\u7c73\u5b54\u7ed3\u6784\u53ef\u4ee5\u91ca\u653e\u5f2f\u66f2\u65f6\u7684\u673a\u68b0\u5e94\u529b\uff0c\u589e\u5927\u4e86\u5927\u5c3a\u5bf8\u67d4\u6027\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5b9e\u73b0\u7684\u53ef\u884c\u6027\uff0c\u4e3a\u672a\u6765\u7684\u53ef\u7a7f\u6234\u7535\u5b50\u5668\u4ef6\u7684\u4f9b\u7535\u63d0\u4f9b\u4e86\u5e7f\u9614\u7684\u524d\u666f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aWearable Large-Scale Perovskite Solar-Power Source via Nanocellular Scaffold<\/a><\/strong>\u00a0(Adv. Mater. 2017, Doi:10.1002\/adma.201703236)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u8d75\u6625\u6797\u7f16\u8bd1\uff0c\u6731\u6653\u79c0\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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