{"id":102870,"date":"2017-09-26T06:30:40","date_gmt":"2017-09-25T22:30:40","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=102870"},"modified":"2017-09-24T18:18:38","modified_gmt":"2017-09-24T10:18:38","slug":"%e5%8e%a6%e9%97%a8%e5%a4%a7%e5%ad%a6%e5%8c%96%e5%ad%a6%e5%8c%96%e5%b7%a5%e5%ad%a6%e9%99%a2%ef%bc%9a%e5%8f%af%e6%8e%a7%e5%88%86%e5%ad%90%e7%bb%84%e8%a3%85%e7%a0%94%e7%a9%b6%e5%86%8d%e6%ac%a1%e5%8f%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=102870","title":{"rendered":"\u53a6\u95e8\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\uff1a\u53ef\u63a7\u5206\u5b50\u7ec4\u88c5\u7814\u7a76\u518d\u6b21\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55"},"content":{"rendered":"<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u53a6\u95e8\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u66f9\u6653\u5b87\u8bfe\u9898\u7ec4\u5728\u53ef\u63a7\u5206\u5b50\u7ec4\u88c5\u9886\u57df\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\uff0c\u6210\u679c\u4ee5\u201cMolecular Face-Rotating Cube with Emergent Chiral and Fluorescence Properties\u201d\u4e3a\u9898\u53d1\u8868\u4e8eJ. Am. Chem. Soc.\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1 <\/strong><strong>\u7acb\u65b9\u4f53<\/strong><strong>1<\/strong><strong>\u548c<\/strong><strong>2<\/strong><strong>\u7684<\/strong><strong>Chiral-HPLC<\/strong><strong>\u548c<\/strong><strong>CD<\/strong><strong>\u5206\u6790\u56fe\u8c31<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-102876 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/1-87.jpg\" alt=\"\" width=\"600\" height=\"271\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/1-87.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/1-87-300x136.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>A\uff0cChiral HPLC\u5149\u8c31\u5305\u542b\u56db\u4e2a\u5cf0\uff0c\u5206\u522b\u5bf9\u5e94\u4e8e\uff086M\uff09-1\uff0c\uff082P4M\uff09-2\uff0c\uff086P\uff09-1\u548c\uff084P2M\uff09-2\uff0c\u6bd4\u4f8b\u4e3a3\uff1a1\uff1a3\uff1a1\uff0c\u6240\u6709\u7acb\u65b9\u4f53\u7684\u5438\u5149\u5ea6\u5747\u4e3a300 nm\uff1b<\/p>\n<p>B\uff0c\u4e8c\u6c2f\u7532\u70f7\u548c\u7532\u9187\u7684\u6df7\u5408\u6eb6\u5242\uff08v:v = 1:1\uff09\u4e2d\u5206\u79bb\u51fa\u7684\u7acb\u65b9\u4f53\uff086M\uff09-1\uff0c\uff082P4M\uff09-2\uff0c\uff086P\uff09-1\u548c\uff084P2M\uff09-2\u7684CD\u5149\u8c31\uff1b<\/p>\n<p><strong>\u56fe<\/strong><strong>2 <\/strong><strong>\uff08<\/strong><strong>6M<\/strong><strong>\uff09<\/strong><strong>-1<\/strong><strong>\u548c\uff08<\/strong><strong>2P4M<\/strong><strong>\uff09<\/strong><strong>-2<\/strong><strong>\u7684\u5355\u6676\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-102879 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/2-66.jpg\" alt=\"\" width=\"600\" height=\"500\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/2-66.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/09\/2-66-300x250.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>A\uff0c\uff086M\uff09-1\u7684\u7acb\u65b9\u7ed3\u6784\u7684\u6b63\u89c6\u56fe\uff1b<\/p>\n<p>B\uff0c\uff086M\uff09-1\u7684\u7acb\u65b9\u7ed3\u6784\u7684\u659c\u89c6\u56fe\uff1b<\/p>\n<p>C\uff0c\uff082P4M\uff09-2\u7684\u7acb\u65b9\u7ed3\u6784\u7684\u6b63\u89c6\u56fe\uff1b<\/p>\n<p>D\uff0c\uff082P4M\uff09-2\u7684\u7acb\u65b9\u7ed3\u6784\u7684\u659c\u89c6\u56fe\u3002<\/p>\n<p>\u7070\u8272\uff0c\u7eff\u8272\u6216\u7c89\u7ea2\u8272\u4e3a\u78b3\u539f\u5b50\uff0c\u84dd\u8272\u4e3a\u6c2e\u539f\u5b50\uff0c\u4e3a\u6e05\u695a\u8d77\u89c1\uff0c\u7701\u7565\u4e86\u6c22\u539f\u5b50\u3002<\/p>\n<p><strong>\u3010\u7814\u7a76\u5185\u5bb9\u3011<\/strong><\/p>\n<p>\u5206\u5b50\u591a\u9762\u4f53\u5728\u5206\u5b50\u8bc6\u522b\u3001\u5206\u79bb\u3001\u50ac\u5316\u9886\u57df\u6709\u91cd\u8981\u5e94\u7528\uff0c\u800c\u5c06\u624b\u6027\u5f15\u5165\u5206\u5b50\u591a\u9762\u4f53\uff0c\u5728\u589e\u52a0\u4f53\u7cfb\u590d\u6742\u5ea6\u7684\u540c\u65f6\uff0c\u529f\u80fd\u5316\u5206\u5b50\u591a\u9762\u4f53\uff0c\u4f7f\u5176\u5177\u5907\u624b\u6027\u5206\u79bb\u4e0e\u4e0d\u5bf9\u79f0\u50ac\u5316\u7684\u6f5c\u5728\u5e94\u7528\u3002\u624b\u6027\u5206\u5b50\u591a\u9762\u4f53\u591a\u91c7\u7528\u624b\u6027\u524d\u4f53\u6216\u624b\u6027\u91d1\u5c5e\u4e2d\u5fc3\u6784\u7b51\uff0c\u800c\u5229\u7528\u6f5c\u624b\u6027\u57fa\u5143\u6784\u7b51\u9762\u65b9\u5411\u6027\u5206\u5b50\u591a\u9762\u4f53\u7684\u65b9\u6cd5\u9c9c\u6709\u62a5\u9053\uff08\u66f9\u6653\u5b87\u8bfe\u9898\u7ec4\u5728\u53bb\u5e74\u53d1\u8868\u57fa\u4e8e\u4e09\u805a\u831a\u7684\u9762\u65b9\u5411\u6027\u591a\u9762\u4f53Nat.Commun. 2016, 7, 12469\uff09\u3002<\/p>\n<p>\u56db\u82ef\u4e59\u70ef\u662f\u5e38\u89c1\u7684\u805a\u96c6\u8bf1\u5bfc\u53d1\u5149\u57fa\u5143\uff0c\u5728\u7a7a\u95f4\u4f4d\u963b\u53d7\u9650\u65f6\u5177\u6709P\u6216M\u4e24\u79cd\u6784\u8c61\uff0c\u7ed3\u5408\u5176\u53cc\u952e\u53d6\u5411\u6784\u6210\u56db\u79cd\u4e0d\u540c\u7684\u9762\u624b\u6027\u56fe\u6848\u3002\u5c06\u56db\u82ef\u4e59\u70ef\u57fa\u5143\u7f6e\u4e8e\u5206\u5b50\u7acb\u65b9\u4f53\u9762\u4e0a\uff0c\u7ed3\u5408\u6570\u5b66\u56fe\u8bba\u5206\u6790\uff0c\u53ef\u5f97\u5230224\u79cd\u53ef\u80fd\u7ec4\u88c5\u4f53\u3002\u8be5\u6570\u5b66\u65b9\u6cd5\u9002\u7528\u4e8e\u5206\u6790\u5176\u4ed6\u590d\u6742\u5206\u5b50\u591a\u9762\u4f53\u3002\u672c\u5de5\u4f5c\u4ee5\u56db\u82ef\u4e59\u70ef\u884d\u751f\u7269\u4e3a\u7ec4\u88c5\u57fa\u5143\uff0c\u901a\u8fc7\u52a8\u6001\u5171\u4ef7\u5316\u5b66\uff0c\u6784\u7b51\u5206\u5b50\u9762\u65b9\u5411\u6027\u7acb\u65b9\u4f53\u3002\u5b9e\u9a8c\u4e0a\u4ec5\u53d1\u73b0\u56db\u79cd\u7ec4\u88c5\u4f53\uff0c\u5e76\u901a\u8fc7\u624b\u6027\u5206\u79bb\u5206\u6790\uff0c\u53d1\u73b0\u968f\u7740\u7ec4\u88c5\u4f53\u7684\u884c\u6210\u201c\u6d8c\u73b0\u201d\u51fa\u624b\u6027\u4e0e\u8367\u5149\u6027\u8d28\u3002\u7406\u8bba\u8ba1\u7b97\u89e3\u91ca\u5206\u5b50\u7acb\u65b9\u4f53\u624b\u6027\u6d8c\u73b0\u53ca\u624b\u6027\u7a33\u5b9a\u5b58\u5728\u7684\u539f\u56e0\u3002\u8be5\u7c7b\u591a\u9762\u4f53\u5728\u624b\u6027\u4f20\u611f\u53ca\u624b\u6027\u8367\u5149\u6750\u6599\u65b9\u9762\u6709\u5e94\u7528\u524d\u666f\u3002<\/p>\n<p>\u7814\u7a76\u5de5\u4f5c\u7531\u738b\u5b87\u535a\u58eb\u3001\u66f9\u6653\u5b87\u526f\u6559\u6388\u548c\u7530\u4e2d\u7fa4\u6559\u6388\u5171\u540c\u6307\u5bfc\uff0c\u535a\u58eb\u751f\u77bf\u822a\u4e3a\u7b2c\u4e00\u4f5c\u8005\uff0c\u535a\u58eb\u751f\u674e\u4e4b\u8c6a\u3001\u738b\u5ffb\u660c\u535a\u58eb\u3001\u535a\u58eb\u751f\u623f\u6d2a\u52cb\u534f\u52a9\u5b8c\u6210\u3002\u6b64\u5de5\u4f5c\u5f97\u5230\u9662\u5185\u6c5f\u4e91\u5b9d\u6559\u6388\u3001\u7ae0\u6167\u6559\u6388\u3001\u6c6a\u9a8b\u6559\u6388\u7b49\u79ef\u6781\u5e2e\u52a9\u4e0e\u652f\u6301\uff0c\u5e76\u5f97\u5230\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u59d4\uff08\u6279\u51c6\u53f7\uff1a91427304, 21573181, 91227111\u548c21102120\uff09\uff0c\u79d1\u6280\u90e8973\u8ba1\u5212\uff08\u6279\u51c6\u53f7\uff1a2015CB856500\uff09\uff0c\u4e2d\u592e\u9ad8\u6821\u57fa\u7840\u7814\u7a76\u7ecf\u8d39\uff08\u6279\u51c6\u53f7\uff1a20720160050\uff09\u7b49\u9879\u76ee\u652f\u6301\u3002<\/p>\n<p>\u539f\u6587\u94fe\u63a5\uff1a<a href=\"http:\/\/chem.xmu.edu.cn\/show.asp?id=2277\" target=\"_blank\" rel=\"noopener\">http:\/\/chem.xmu.edu.cn\/show.asp?id=2277<\/a>\u3002<\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/pubs.acs.org\/doi\/10.1021\/jacs.7b07657\" target=\"_blank\" rel=\"noopener\">Molecular Face-Rotating Cube with Emergent Chiral and Fluorescence Properties<\/a>\uff08J. Am. Chem. Soc., 2017, DOI: 10.1021\/jacs.7b07657\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u738b\u51b0\u7f16\u8f91\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener noreferrer\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener noreferrer\">\u6d4b\u8bd5\u8c37<\/a>\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u6210\u679c\u7b80\u4ecb\u3011 \u8fd1\u65e5\uff0c\u53a6\u95e8\u5927\u5b66\u5316\u5b66\u5316\u5de5\u5b66\u9662\u66f9\u6653\u5b87\u8bfe\u9898\u7ec4\u5728\u53ef\u63a7\u5206\u5b50\u7ec4\u88c5\u9886\u57df\u53d6\u5f97\u91cd\u8981\u8fdb\u5c55\uff0c\u6210\u679c\u4ee5\u201cMolecular Face-Rotating Cube with &#8230;<\/p>\n","protected":false},"author":53,"featured_media":102879,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-102870","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/102870"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/53"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=102870"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/102870\/revisions"}],"predecessor-version":[{"id":102889,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/102870\/revisions\/102889"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/102879"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=102870"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=102870"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=102870"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}