{"id":103325,"date":"2017-09-25T06:30:19","date_gmt":"2017-09-24T22:30:19","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=103325"},"modified":"2017-09-24T20:53:06","modified_gmt":"2017-09-24T12:53:06","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2%e5%8c%96%e5%ad%a6%e6%89%80jacs-%e5%8d%95%e4%b8%aa%e7%ba%b3%e7%b1%b3%e9%a2%97%e7%b2%92%e5%86%85%e9%83%a8%e5%8c%96%e5%ad%a6%e7%bb%84%e5%88%86%e7%9a%84%e8%b0%83%e6%8e%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=103325","title":{"rendered":"\u4e2d\u79d1\u9662\u5316\u5b66\u6240JACS: \u5355\u4e2a\u7eb3\u7c73\u9897\u7c92\u5185\u90e8\u5316\u5b66\u7ec4\u5206\u7684\u8c03\u63a7\u53ca\u7a7a\u5fc3\u78b3\u7403\u7684\u591a\u5c3a\u5ea6\u6784\u7b51"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u56fe<\/strong>1 \u57fa\u4e8e\u5185\u90e8\u5316\u5b66\u7ec4\u6210\u7684\u975e\u5747\u5300\u6027\u5236\u5907\u548c\u8c03\u63a7\u76843-AF\u6811\u8102\u7403\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

(a-b)\u56fa\u60013-AF\u7eb3\u7c73\u7403\u7684SEM\u548cTEM\u56fe\uff1b<\/p>\n

(c)3-AF\u7eb3\u7c73\u7403\u7ecf\u5185\u90e8\u9009\u62e9\u6027\u6eb6\u89e3\u540e\u7684TEM\u56fe\uff1b<\/p>\n

(d-i)\u7ecf\u8fde\u7eed\u751f\u957f\u5faa\u73af\u5236\u5907\u7684\u591a\u5c42(\u53cc\u5c42\u52307\u5c42)3-AF\u4e2d\u7a7a\u7eb3\u7c73\u7403\uff1b<\/p>\n

(j)\u4e2d\u7a7a3-AF\u7ed3\u6784\u7684\u5408\u6210\u8def\u5f84\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong>2 \u00a03-AF\u6811\u8102\u7eb3\u7c73\u7403\u5185\u90e8\u975e\u5747\u5300\u6027\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

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\u56fe<\/strong>3 \u915a\u7c7b\u5355\u4f53\u7684\u5206\u5b50\u8bbe\u8ba1\u53ca\u5176\u5bf9\u6811\u8102\u7403\u5185\u90e8\u5316\u5b66\u7ec4\u5206\u5747\u4e00\u6027\u7684\u5f71\u54cd<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

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(c, g, k)\u5206\u522b\u4f7f\u7528(c)3-AP\u3001(g)4-AP\u548c(k)\u82ef\u915a\u4f5c\u4e3a\u5355\u4f53\u5236\u5907\u7684\u6811\u8102\u7eb3\u7c73\u7403\u7684TEM\u56fe\uff1b<\/p>\n

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\u56fe\u4e2d\uff1a\u25cf=C\uff0c\u25cf<\/span>=O\uff0c\u25cf<\/span>=N\u3002<\/p>\n

\u56fe<\/strong>4 3-AF\u7eb3\u7c73\u7403\u7ed3\u6784\u3001\u5b54\u5f84\u548c\u7ec4\u6210\u7684\u63a7\u5236\u53ca\u6269\u5145<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u5728\u9ad8\u53cd\u5e94\u7269\u6d53\u5ea6\u5f62\u6210\u786c\u6838\u83b7\u5f97Yolk\u58f3\u7ed3\u6784\uff1b<\/p>\n

(b)\u4f7f\u7528\u4e59\u9187\/\u6c34(v\/v=1:2)\u6df7\u5408\u6eb6\u5242\u4f5c\u4e3a\u53cd\u5e94\u4ecb\u8d28\u83b7\u5f97\u4ecb\u5b54\u7684\u4e2d\u7a7a3-AF\u6811\u8102\u7eb3\u7c73\u7403\uff1b<\/p>\n

(c)\u6309\u7167\u56fe(b)\u4e2d\u5408\u6210\u8def\u5f84\u91cd\u590d\u4e00\u4e2a\u751f\u957f\u5faa\u73af\u4ee5\u5305\u57cb\u4ecb\u5b54\u83b7\u5f97\u4e09\u5c42\u7684\u4e2d\u7a7a3-AF\u6811\u8102\u7eb3\u7c73\u7403\uff1b<\/p>\n

(d)\u5728\u4e2d\u7a7a\u6811\u8102\u7eb3\u7c73\u7403\u4e2d\u539f\u4f4d\u5e76\u5165Ag\u7eb3\u7c73\u9897\u7c92\u5f62\u6210\u5177\u6709\u590d\u5408\u7ed3\u6784\u7684Ag\/\u6811\u8102\u7eb3\u7c73\u7403\u3002<\/p>\n

\u56fe<\/strong>5 <\/strong>\u52a8\u529b\u5b66\u63a7\u5236\u751f\u957f\u83b7\u5f97\u4e0d\u540c\u5f62\u72b6\u4e2d\u7a7a\u7ed3\u6784\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u5236\u5907HCNs\u7684\u4e0d\u540c\u751f\u957f\u6b65\u9aa4\u5305\u62ec\uff1a(\u6b65\u9aa41)\u65b0\u5f62\u62103-AF\u6811\u8102\u7eb3\u7c73\u7403\u7684\u8fde\u7eed\u751f\u957f\u548c\u8868\u9762\u786c\u5316\uff1b(\u6b65\u9aa42)\u9009\u62e9\u6027\u9664\u53bb\u53ef\u6eb6\u89e3\u90e8\u5206\uff1b(\u6b65\u9aa43)\u591a\u5c42\u7ed3\u6784\u7684\u91cd\u590d\u5236\u5907\u8fc7\u7a0b\uff1b(\u6b65\u9aa44)\u591a\u5c42\u7a7a\u5fc3\u78b3\u7403(MS-HCNs)\u548c\u4ecb\u5b54MS-HCNs\u7684\u9ad8\u6e29\u78b3\u5316\u8fc7\u7a0b\u3002<\/p>\n

\u56fe<\/strong>6 \u7a7a\u5fc3\u78b3\u7403\u5728KIBs\u4e2d\u7684\u5e94\u7528<\/strong>
\n \"\"
\n <\/strong><\/p>\n

(a) 0.1C\u4e0b\uff0c\u4e09\u5c42\u7a7a\u5fc3\u78b3\u7403(3S-HCNs)\u7b2c\u4e00\u6b21\u548c\u7b2c\u4e8c\u6b21\u5faa\u73af\u4e2d\uff0cK+<\/sup>\u7684\u5145\/\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

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\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n

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\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong>\u3011<\/strong><\/span><\/p>\n

\u66f9\u5b89\u6c11<\/strong>\uff0c\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u7814\u7a76\u5458\u30022006\u5e74\u4e8e\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u83b7\u535a\u58eb\u5b66\u4f4d\uff0c2007\u5e74\u81f32012\u5e74\u5206\u522b\u4e8e\u7f8e\u56fd\u5339\u5179\u5821\u5927\u5b66\u53ca\u5fb7\u5dde\u5927\u5b66\u5965\u65af\u6c40\u5206\u6821\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\u5de5\u4f5c\u30022012\u5e744\u6708\u52a0\u5165\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u5206\u5b50\u7eb3\u7c73\u7ed3\u6784\u4e0e\u7eb3\u7c73\u6280\u672f\u9662\u91cd\u70b9\u5b9e\u9a8c\u5ba4\uff1b\u76ee\u524d\u4ece\u4e8b\u7535\u6781\u6750\u6599\u7ed3\u6784\u8bbe\u8ba1\u53ca\u6027\u80fd\u4f18\u5316\u65b9\u9762\u7684\u7814\u7a76\uff0c\u4e3b\u8981\u6d89\u53ca\u6b63\u6781\u6750\u6599\u8868\u754c\u9762\u7ed3\u6784\u7684\u63a7\u5236\u53ca\u8d1f\u6781\u7a7a\u5fc3\u7ed3\u6784\u7684\u6784\u7b51\u7b49\uff0c\u4ee5\u7b2c\u4e00\u4f5c\u8005\u6216\u901a\u8baf\u4f5c\u8005\u5728J. Am. Chem. Soc., Angew. Chem. Int. Ed.<\/em>, Nature Mater.<\/em>\u7b49\u671f\u520a\u53d1\u8868\u4e86\u4e00\u7cfb\u5217\u4ee3\u8868\u6027\u6210\u679c\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Controlling the Compositional Chemistry in Single Nanoparticles for Functional Hollow Carbon Nanospheres<\/a>\u00a0(J. Am. Chem. Soc., 2017, DOI: 10.1021\/jacs.7b07027)<\/p>\n

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