{"id":107282,"date":"2017-10-20T06:30:51","date_gmt":"2017-10-19T22:30:51","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=107282"},"modified":"2017-10-19T17:32:54","modified_gmt":"2017-10-19T09:32:54","slug":"%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e5%82%ac%e5%8c%96%e8%bd%ac%e5%8c%96%e8%bf%9b%e5%b1%95%ef%bc%9a%e8%bf%87%e6%b8%a1%e9%87%91%e5%b1%9e-%e6%b0%ae-%e5%85%b1%e6%8e%ba%e6%9d%82%e5%9e%8b%e5%a4%9a%e5%ad%94","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=107282","title":{"rendered":"\u4e8c\u6c27\u5316\u78b3\u50ac\u5316\u8f6c\u5316\u8fdb\u5c55\uff1a\u8fc7\u6e21\u91d1\u5c5e-\u6c2e-\u5171\u63ba\u6742\u578b\u591a\u5b54\u78b3\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u7684\u6d3b\u6027\u53ca\u9009\u62e9\u6027\u89c4\u5f8b\u63ed\u793a"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u00a0\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u4ea7\u7269\u5305\u62ec\u4e00\u6c27\u5316\u78b3\uff08CO\uff09\u3001\u7532\u9178\u3001\u7532\u9187\u3001\u4e59\u9187\u7b49\u78b3\u6c22\u5316\u5408\u7269\u71c3\u6599\u53ca\u5316\u5b66\u54c1\u3002\u4e0e\u78b3\u6c22\u5316\u5408\u7269\uff08\u7532\u70f7\u3001\u7532\u9187\u7b49\uff09\u4ea7\u7269\u76f8\u6bd4\uff0c\u4e8c\u6c27\u5316\u78b3\u8f6c\u5316\u4e3a\u4e00\u6c27\u5316\u78b3\u4ec5\u9700\u8981\u4e24\u4e2a\u7535\u5b50\u8f6c\u79fb\uff0c\u5176\u5b9e\u73b0\u66f4\u4e3a\u5bb9\u6613\u3002\u6240\u5f97\u4e00\u6c27\u5316\u78b3\u4e0e\u4f34\u968f\u6790\u6c22\u53cd\u5e94\u4ea7\u751f\u7684\u6c22\u6c14\u53ef\u4f5c\u4e3a\u539f\u6599\u8fdb\u4e00\u6b65\u901a\u8fc7\u8d39\u6258\u5408\u6210\u83b7\u5f97\u78b3\u6c22\u71c3\u6599\u3002\u4f20\u7edf\u7535\u50ac\u5316CO2<\/sub>\u8fd8\u539f\u5e38\u7528\u7684\u50ac\u5316\u5242\u4e3aAg\u3001Au\u3001Cu\u53ca\u5176\u5408\u91d1\u3002\u8fd1\u5e74\u6765\u63ba\u6742\u578b\uff08\u5982\u6c2e\u63ba\u6742\u3001\u91d1\u5c5e\u63ba\u6742\uff09\u591a\u5b54\u78b3\u6750\u6599\u4f5c\u4e3a\u4e8c\u6c27\u5316\u78b3\u7535\u50ac\u5316\u8fd8\u539f\u50ac\u5316\u5242\u5f15\u8d77\u4e86\u7814\u7a76\u4eba\u5458\u7684\u5e7f\u6cdb\u5174\u8da3\u3002\u867d\u7136\u5355\u7eaf\u6c2e\u63ba\u6742\u591a\u5b54\u78b3\u8868\u73b0\u51fa\u4e00\u5b9a\u7684\u6d3b\u6027\uff0c\u4f46\u662f\u7814\u7a76\u4eba\u5458\u53d1\u73b0\u5728\u6c2e\u63ba\u6742\u7684\u57fa\u7840\u4e0a\u52a0\u5165\u8fc7\u6e21\u91d1\u5c5e\u540e\uff0c\u6d3b\u6027\u660e\u663e\u63d0\u9ad8\u3002\u4f46\u662f\u5bf9\u4e8e\u8be5\u8fc7\u6e21\u91d1\u5c5e-\u6c2e-\u78b3(M-N-C)\u7c7b\u578b\u5bf9\u4e8c\u6c27\u5316\u78b3\u50ac\u5316\u6d3b\u6027\u53ca\u9009\u62e9\u6027\u7684\u673a\u7406\u6027\u8ba4\u8bc6\u5c1a\u4e0d\u660e\u786e\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u57fa\u4e8e\u6b64\uff0c\u5fb7\u7d2f\u65af\u987f\u5de5\u4e1a\u5927\u5b66\u90dd\u5e7f\u5e73\u535a\u58eb\uff08\u5171\u540c\u901a\u8baf\uff09\u3001\u67cf\u6797\u5de5\u4e1a\u5927\u5b66Peter Strasser\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09\u3001\u4e39\u9ea6\u54e5\u672c\u54c8\u6839\u5927\u5b66Jan Rossmeisl\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09\u7814\u7a76\u7ec4\u5408\u4f5c\uff0c\u4ee5\u4e00\u7cfb\u5217\u8fc7\u6e21\u91d1\u5c5e-\u6c2e-\u78b3(M-N-C\uff0cM=Mn, Fe, Co, Ni, Cu)\u6750\u6599\u4e3a\u6a21\u578b\u50ac\u5316\u5242\uff0c\u901a\u8fc7\u5b9e\u9a8c\u4e0e\u8ba1\u7b97\u7cfb\u7edf\u7814\u7a76\u4e86\u8be5M-N-C\u7c7b\u578b\u50ac\u5316\u5242\u5728\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u6210\u4e00\u6c27\u5316\u78b3\u8fc7\u7a0b\u4e2d\u7684\u6d3b\u6027\u4e0e\u9009\u62e9\u6027\uff0c\u53d1\u73b0\u9ad8\u5206\u6563\u7684\u91d1\u5c5e-\u6c2e\u914d\u4f4d\u4e2d\u5fc3\u4e3a\u6d3b\u6027\u4f4d\uff0c\u5bf9\u8be5\u7c7b\u578b\u6750\u6599\u7684\u5f00\u53d1\u5177\u6709\u6307\u5bfc\u6027\u610f\u4e49\u3002\u8be5\u5de5\u4f5c\u8fd1\u671f\u53d1\u8868\u4e8eNature Communications\uff0c\u7b2c\u4e00\u4f5c\u8005\u4e3aWen Ju\uff0cAlexander Bagger\uff08\u5171\u540c\u4e00\u4f5c\uff09\u3002<\/p>\n

\u56fe<\/strong>1.<\/strong> \u4e00\u7cfb\u5217\u8fc7\u6e21\u91d1\u5c5e-\u6c2e-\u78b3(M-N-C, M=Mn, Fe, Co, Ni, Cu)\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u50ac\u5316\u5242\u7684\u5f62\u8c8c\u3001\u591a\u5b54\u7ed3\u6784\u8868\u5f81\u53ca\u5fae\u533a\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2.<\/strong> \u4e00\u7cfb\u5217\u8fc7\u6e21\u91d1\u5c5e-\u6c2e-\u78b3(M-N-C, M=Mn, Fe, Co, Ni, Cu) \u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u50ac\u5316\u5242\u7684XPS\u8868\u5f81<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>3.<\/strong> \u8be5M-N-C (M=Mn, Fe, Co, Ni, Cu)\u7cfb\u5217\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u50ac\u5316\u5242\u7684\u6d3b\u6027\u5206\u6790<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>4.<\/strong> M-N-C (M=Mn, Fe, Co, Ni, Cu)\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u50ac\u5316\u5242\u7684\u9009\u62e9\u6027\u7814\u7a76<\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>5.<\/strong> \u5b9e\u9a8c\u4e0e\u7406\u8bba\u8ba1\u7b97\u7ed3\u5408\u89e3\u6790M-N-C (M=Mn, Fe, Co, Ni, Cu)\u7535\u50ac\u5316\u4e8c\u6c27\u5316\u78b3\u8fd8\u539f\u50ac\u5316\u5242\u7684\u6d3b\u6027\u4e0e\u9009\u62e9\u6027\u89c4\u5f8b<\/p>\n

\"\"<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aWen Ju*, Alexander Bagger*, Guang-Ping Hao, et al. Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2<\/sub><\/a>. Nature Communications, 2017, 8, 944.<\/p>\n

\u672c\u6587\u7531\u90dd\u5e7f\u5e73\u535a\u58eb\u6295\u7a3f\uff0c\u6750\u6599\u4eba\u7f16\u8f91\u90e8 \u80cc\u9006\u65f6\u5149 \u7f16\u8f91\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong>RDD-2011-CHERISH<\/strong>\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

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