{"id":109517,"date":"2017-11-04T14:00:17","date_gmt":"2017-11-04T06:00:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=109517"},"modified":"2017-11-01T19:30:03","modified_gmt":"2017-11-01T11:30:03","slug":"adv-funct-mater-%ef%bc%9a%e7%ba%b3%e7%b1%b3%e5%b0%ba%e5%af%b8%e7%9a%84%e7%ba%a2%e7%a3%b7%e4%bf%ae%e9%a5%b0g-c3n4%e6%9c%89%e6%95%88%e9%99%8d%e4%bd%8e%e4%ba%86%e7%94%b5%e8%8d%b7%e5%a4%8d%e5%90%88","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=109517","title":{"rendered":"Adv. Funct. Mater.\uff1a\u7eb3\u7c73\u5c3a\u5bf8\u7684\u7ea2\u78f7\u4fee\u9970g-C3N4\u6709\u6548\u964d\u4f4e\u4e86\u7535\u8377\u590d\u5408\u5e76\u5e94\u7528\u4e0e\u5149\uff08\u7535\uff09\u50ac\u5316"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7531\u592a\u9633\u80fd\u9a71\u52a8\u7684\u5149\u50ac\u5316\u4ea7\u6c22\u662f\u4e00\u9879\u5177\u6709\u5f88\u5927\u6f5c\u529b\u7684\u7eff\u8272\u6280\u672f\u3002\u4e3a\u4e86\u4f7f\u8fd9\u9879\u6280\u672f\u53ef\u6301\u7eed\u53d1\u5c55\uff0c\u4eba\u4eec\u9700\u8981\u5f00\u53d1\u4f4e\u6210\u672c\u548c\u9ad8\u6548\u7684\u975e\u91d1\u5c5e\u5149\u50ac\u5316\u5242\u3002 g-C3<\/sub>N4<\/sub>\u56e0\u5176\u5408\u9002\u7684\u5e26\u9699\uff0c\u9ad8\u6e29\u548c\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u6bd2\u6027\u76f8\u5bf9\u8f83\u4f4e\u7b49\u4f18\u70b9\u5df2\u7ecf\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u6781\u5177\u524d\u666f\u7684\u7528\u4e8e\u8bb8\u591a\u5149\u50ac\u5316\u5e94\u7528\u7684\u975e\u91d1\u5c5e\u57fa\u5149\u50ac\u5316\u5242\u3002\u7136\u800c\uff0c\u539f\u59cb\u7684g-C3<\/sub>N4<\/sub>\u5149\u50ac\u5316\u5242\u7684\u6574\u4f53\u6027\u80fd\u4ecd\u7136\u53d7\u5230\u9650\u5236\uff0c\u56e0\u4e3a\u5b83\u7684\u8868\u9762\u9762\u79ef\u8f83\u4f4e(\u7531\u805a\u96c6\u5f15\u8d77)\uff0c\u53ef\u89c1\u5149\u5438\u6536\u5dee\uff0c\u4ee5\u53ca\u5feb\u901f\u7684\u7535\u8377\u590d\u5408\u3002\u6700\u8fd1\uff0c\u6709\u62a5\u9053\u79f0\uff0c\u7531\u4e8e\u5316\u5b66\u7f3a\u9677\u5f15\u8d77\u7684\u7535\u8377\u8f7d\u4f53\u6355\u83b7\u5728\u51b3\u5b9ag-C3<\/sub>N4<\/sub>\u5149\u50ac\u5316\u6d3b\u6027\u65b9\u9762\u662f\u81f3\u5173\u91cd\u8981\u7684\u3002<\/p>\n

\u4e3a\u4e86\u63d0\u9ad8g-C3<\/sub>N4<\/sub>\u7684\u5149\u6d3b\u6027\uff0c\u7814\u7a76\u4eba\u5458\u91c7\u7528\u4e86\u4e09\u79cd\u4e3b\u8981\u7b56\u7565\uff0c\u5305\u62ec\u5f62\u8c8c\u6539\u5584\uff0c\u91d1\u5c5e\/\u975e\u91d1\u5c5e\u63ba\u6742\uff0c\u4ee5\u53ca\u5f02\u8d28\u7ed3\u6784\u5efa\u3002\u5143\u7d20\u78f7\u5177\u6709\u4e0d\u540c\u7684\u5316\u5b66\u76f8\u548c\u7ed3\u6784\u3002\u975e\u6676\u76f8\uff0c\u5e0c\u6258\u592b\u4ee5\u53ca\u7ea4\u7ef4\u7ea2\u78f7\u5df2\u7ecf\u88ab\u53d1\u73b0\uff0c\u5c55\u73b0\u51fa\u4e86\u5149\u50ac\u5316\u6d3b\u6027\u3002\u6b64\u5916\uff0c\u636e\u62a5\u9053\uff0c\u7ea4\u7ef4\u7ea2\u78f7\u5728\u5143\u7d20\u5149\u50ac\u5316\u5242\u5bb6\u65cf\u4e2d\u62e5\u6709\u6700\u9ad8\u7684\u5149\u50ac\u5316\u4ea7\u6c22\u8bb0\u5f55\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u9999\u6e2f\u4e2d\u6587\u5927\u5b66\u7684\u4f59\u6d4e\u7f8e\u6559\u6388<\/strong>\u7b49\u4eba\u5728Advanced Functional Materials<\/strong>\u4e0a\u53d1\u6587\uff0c\u9898\u4e3a\uff1a\u201cEffective Prevention of Charge Trapping in Graphitic Carbon Nitride with Nanosized Red Phosphorus Modification for Superior Photo(electro)catalysis\u201d<\/strong>\u3002\u7814\u7a76\u4eba\u5458\u53d1\u73b0\u63ba\u6742\u8d85\u5c0f\u7ea2\u78f7\u6676\u4f53\u5728g-C3N4\u7eb3\u7c73\u7247\u4e0a\u80fd\u591f\u51cf\u5c11g-C3N4\u7ed3\u6784\u7684\u7f3a\u9677\uff0c\u800c\u4e14\u901a\u8fc7\u5f62\u6210\u65b0\u7684\u5316\u5b66\u952e\u6765\u4ea7\u751f\u66f4\u591a\u7684\u6709\u6548\u7684\u7535\u8377\u5206\u79bb\uff0c\u63d0\u9ad8\u5149\u50ac\u5316\u4ea7\u6c22\u6d3b\u6027\u3002\u5230\u76ee\u524d\u4e3a\u6b62\uff0c\u8fd9\u4e00\u6742\u5316\u4f53\u7cfb\u4e2d\u6240\u83b7\u5f97\u7684\u4ea7\u6c22\u901f\u7387\u662f\u8fc4\u4eca\u4e3a\u6b62\u6240\u62a5\u544a\u7684\u6240\u6709\u78f7\u63ba\u6742g-C3N4\u5149\u50ac\u5316\u5242\u4e2d\u6700\u9ad8\u7684\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1. \u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) \u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>\u5408\u6210\u5de5\u827a\uff1b<\/p>\n

b) \u6837\u54c1\u6eb6\u6db2\u7684\u6570\u7801\u7167\u7247\u4ee5\u53ca\u76f8\u5e94\u7684TEM\u56fe\uff1a<\/p>\n

c) CVD\u5904\u7406\u540e\u7684\u88f8\u9732\u7684\u5265\u79bb\u7684g-C3<\/sub>N4<\/sub>\uff1b<\/p>\n

d) CVD\u5904\u7406\u540e\u88f8\u9732\u7684\u7ea2\u78f7\uff1b<\/p>\n

e\u2013h) \u4e0d\u540c\u7ea2\u78f7\u542b\u91cf\uff081, 5, 10, 20 wt%\uff09\u7684\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>\u590d\u5408\u7269\uff1b<\/p>\n

\u56fe2. \u00a0\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>\u5f62\u8c8c\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

SEM\u548c\u76f8\u5e94\u7684HRTEM\u56fe\uff1a<\/strong><\/p>\n

a,b) CVD\u5904\u7406\u540e\u7684\u88f8\u9732\u7684\u5265\u79bb\u7684g-C3<\/sub>N4<\/sub>\uff1b<\/p>\n

e,f,i) CVD\u5904\u7406\u540e\u7684\u88f8\u9732\u7684\u5265\u79bb\u7684\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>\uff1b<\/p>\n

\u5178\u578b\u7684\u5f00\u5b54\u6a21\u5f0fAFM\u56fe\uff1a<\/strong><\/p>\n

c) CVD\u5904\u7406\u540e\u7684\u88f8\u9732\u7684\u5265\u79bb\u7684g-C3<\/sub>N4<\/sub>\u548c<\/p>\n

g) CVD\u5904\u7406\u540e\u7684\u88f8\u9732\u7684\u5265\u79bb\u7684\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>\u4ee5\u53ca\u5b83\u4eec\u76f8\u5e94\u7684\u622a\u9762\u9ad8\u5ea6\u56fe\uff1a<\/strong><\/p>\n

d) \u5904\u7406\u540e\u7684\u88f8\u9732\u7684\u5265\u79bb\u7684g-C3<\/sub>N4<\/sub>\uff1b<\/p>\n

h) \u5904\u7406\u540e\u7684\u88f8\u9732\u7684\u5265\u79bb\u7684\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>;<\/p>\n

j) STEM\uff1b<\/p>\n

k\u2013m) \u76f8\u5e94\u7684\u7ea2\u78f7\/g-C3<\/sub>N4 <\/sub>EDS\u5143\u7d20\u80fd\u8c31\u56fe\uff1b<\/p>\n

\u56fe3. \u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>\u590d\u5408\u7269\u5143\u7d20\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\u7ea2\u78f7\u7684XPS\u56fe\u8c31\uff1a a) P 2p\uff1b \u00a0 b) C1s\uff1b \u00a0 \u00a0c) N1s\uff1b<\/p>\n

\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>\u590d\u5408\u7269\uff1a<\/p>\n

d) XRD\u56fe\u8c31\uff1b \u00a0 \u00a0e) \u7d2b\u5916\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

f) \u6837\u54c1TGA\uff1b \u00a0 \u00a0 g) CVD\u8fc7\u7a0b\u4e2d\u7684\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>\u590d\u5408\u7269\u539f\u5b50\u7ed3\u6784\u6f14\u5316\uff1b<\/p>\n

\u56fe4. \u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

a) \u5265\u79bb\u7684g-C3<\/sub>N4<\/sub>\u548c\u7ea2\u78f7\u57281M Na2<\/sub>SO4<\/sub>\u5149\u7167\u4e0b\u7684\u7ebf\u6027\u626b\u63cf\uff0c\u63d2\u56fe\u662f\u5265\u79bb\u7684g-C3<\/sub>N4<\/sub>\u548c\u7ea2\u78f7\/ g-C3<\/sub>N4<\/sub>\u7535\u6781\u7167\u7247\uff1b<\/p>\n

b) g-C3<\/sub>N4<\/sub>\u548c\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>\u5149\u7535\u6d41\u54cd\u5e94\uff1b<\/p>\n

c) g-C3<\/sub>N4<\/sub>\u548c\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>EIS\u80fd\u65af\u7279\u66f2\u7ebf\uff1b<\/p>\n

d) Comparison of \u88f8\u9732\u7684\u7ea2\u78f7\uff0c\u539f\u59cb\u7684g-C3<\/sub>N4<\/sub>\uff0c\u5265\u79bb\u7684g-C3<\/sub>N4<\/sub>\uff0c<\/sub>\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>\u4ee5\u53ca\u7ea2\u78f7\u548cg-C3<\/sub>N4<\/sub>\u7684\u5149\u50ac\u5316\u4ea7\u6c22\u6d3b\u6027\u7684\u6bd4\u8f83\uff1b<\/p>\n

e)\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub>.\u4ea7\u6c22\u5faa\u73af\u6d4b\u8bd5\uff1b<\/p>\n

\u56fe5. \u7406\u8bba\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

a) g-C3<\/sub>N4<\/sub> (\u5de6)\uff0c\u7ea2\u78f7\/g-C3<\/sub>N4<\/sub> (\u53f3)\u7684\u7535\u8377\u4fd8\u83b7\u6a21\u578b\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

b) \u77ed\u65f6\u95f4\u5c3a\u5ea6\uff1b<\/p>\n

c) \u957f\u65f6\u95f4\u5c3a\u5ea6\uff1b<\/p>\n

d) \u7eb3\u79d2\u2014\u2014TA \u5ef6\u8fdf\u52a8\u529b\u5b66\uff1b<\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u5728g-C3<\/sub>N4<\/sub>\u7eb3\u7c73\u7247\u4e0a\u91c7\u7528CVD\u6cd5\u4e00\u6b65\u5408\u6210\u4e86\u7ed3\u6676\u7684\u7ea2\u78f7\u7eb3\u7c73\u7c92\u5b50\u3002\u5728g-C3<\/sub>N4<\/sub>\u4e0a\u63ba\u6742\u78f7\u539f\u5b50\u80fd\u591f\u4fee\u590dg-C3<\/sub>N4<\/sub>\u7684\u5316\u5b66\u7f3a\u9677\u3002\u8fd9\u53ef\u4ee5\u6291\u5236g-C3<\/sub>N4<\/sub>\u5728\u6df1\u5c42\u6b21\u7684\u7535\u8377\u4fd8\u83b7\u4ee5\u53ca\u51cf\u5c11\u4e0d\u6d3b\u8dc3\u7684\u9677\u9631\u6001\u3002\u901a\u8fc7\u4f18\u5316\u63ba\u6742\u7684\u7ea2\u78f7\u7eb3\u7c73\u7c92\u5b50\u7684g-C3<\/sub>N4<\/sub>\u5ef6\u957f\u4e86\u6d3b\u6027\u7535\u8377\u7684\u5bff\u547d\uff0c\u5728\u53ef\u89c1\u5149\u8303\u56f4\u5185\u5f97\u5230\u4e86\u4f18\u5f02\u7684\u7a33\u5b9a\u4e86\u5149\u50ac\u5316\u4ea7\u6c22\u6d3b\u6027\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Effective Prevention of Charge Trapping in Graphitic Carbon Nitride with Nanosized Red Phosphorus Modification for Superior Photo(electro)catalysis<\/a> (Adv. Funct. Mater. 2017., DOI: 10.1002\/adfm.201703484)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4Z. Chen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1\uff1atougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7531\u592a\u9633\u80fd\u9a71\u52a8\u7684\u5149\u50ac\u5316\u4ea7\u6c22\u662f\u4e00\u9879\u5177\u6709\u5f88\u5927\u6f5c\u529b\u7684\u7eff\u8272\u6280\u672f\u3002\u4e3a\u4e86\u4f7f\u8fd9\u9879\u6280\u672f\u53ef\u6301\u7eed\u53d1\u5c55\uff0c\u4eba\u4eec\u9700\u8981\u5f00\u53d1\u4f4e\u6210\u672c\u548c\u9ad8\u6548\u7684\u975e\u91d1\u5c5e\u5149\u50ac\u5316\u5242\u3002 g-C3N4\u56e0\u5176\u5408\u9002\u7684\u5e26\u9699…<\/p>\n","protected":false},"author":3029,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-109517","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/109517"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/3029"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=109517"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/109517\/revisions"}],"predecessor-version":[{"id":109719,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/109517\/revisions\/109719"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=109517"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=109517"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=109517"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}