{"id":109625,"date":"2017-11-04T06:30:56","date_gmt":"2017-11-03T22:30:56","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=109625"},"modified":"2017-11-01T19:16:58","modified_gmt":"2017-11-01T11:16:58","slug":"jacs%ef%bc%9a%e4%b8%89%e4%bb%b7%e9%94%86%e5%92%8c%e9%93%aa%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e7%94%a8%e4%ba%8e%e8%b5%b7%e5%82%ac%e5%8c%96%e4%bd%9c%e7%94%a8%e7%9a%84%e5%90%a1","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=109625","title":{"rendered":"JACS\uff1a\u4e09\u4ef7\u9506\u548c\u94ea\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u7528\u4e8e\u8d77\u50ac\u5316\u4f5c\u7528\u7684\u5421\u5576\u548c\u55b9\u55491,4-\u8131\u6eb4\u6dfb\u52a0\u5242"},"content":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

TiIII<\/sup>\u5316\u5b66\u5df2\u7ecf\u6210\u4e3a\u7814\u7a76\u70ed\u70b9\uff0c\u5df2\u7ecf\u5728\u5149\u50ac\u5316\uff0c\u6709\u673a\u5408\u6210\u548c\u6709\u673a\u91d1\u5c5e\u50ac\u5316\u7b49\u9886\u57df\u5f97\u5230\u7684\u91cd\u8981\u5e94\u7528\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u56e0\u4e3a\u56fa\u6709\u7684\u5316\u5b66\u4e0d\u7a33\u5b9a\u6027\u548c\u9700\u8981\u51cf\u5c11ZrIV\u548cHfIV\u524d\u4f53\u7684\u9ad8\u8d1f\u7535\u4f4d\uff0cZrIII<\/sup>\u548cHfIII<\/sup>\u7edc\u5408\u7269\u7684\u5b9e\u4f8b\u662f\u4e0d\u5e38\u89c1\u5230\u7684\u3002\u57fa\u4e8e\u7535\u5b50\u987a\u78c1\u5171\u632f\uff08EPR\uff09\u5149\u8c31\u7684\u4f4e\u5f3a\u5ea6\u7279\u5f81\uff0c\u6700\u8fd1\u6709\u5b66\u8005\u63d0\u51fa\u4f4e\u6d53\u5ea6\u7684\u77ac\u6001ZrIII<\/sup>\u7269\u8d28\u5b58\u5728\u4e8eMOFs\u7684Zr6<\/sub> SBUs\u4e2d\uff0c\u5e76\u8d1f\u8d23\u5149\u50ac\u5316\u548c\u4e8c\u6c27\u5316\u78b3\u6c22\u5316\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u829d\u52a0\u54e5\u5927\u5b66\u6797\u6587\u658c\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u901a\u8fc7\u4ece\u5047\u5b9a\u7684[MIV<\/sup>6<\/sub>\uff08\u03bc3<\/sub>-O\uff094<\/sub>\uff08\u03bc3<\/sub>-OH\uff094<\/sub>H12<\/sub>] 6-<\/sup>\u8282\u70b9\u4e2dH2<\/sub>\u7684\u53cc\u91d1\u5c5e\u8fd8\u539f\u6d88\u9664\u53cd\u5e94\u5b9e\u73b0\u4e86MCl2<\/sub>-BTC\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u4e2d\u7684[MIV<\/sup>6<\/sub>\uff08\u03bc3<\/sub>-O\uff094<\/sub>\uff08\u03bc3<\/sub>-OH\uff094<\/sub>Cl12<\/sub>] 6-<\/sup>\u8282\u70b9\u5230MIII<\/sup>H-BTC\uff08M=Zr\uff0cHf; BTC\u662f1,3,5-\u82ef\u4e09\u7fa7\u9178\u76d0\uff09\u4e2d[MIV<\/sup>6<\/sub>\uff08\u03bc3<\/sub>-O\uff094<\/sub>\uff08\u03bc3<\/sub>-ONa\uff094<\/sub>H6<\/sub>] 6-<\/sup>\u8282\u70b9\u7684\u5b9a\u91cf\u8f6c\u5316\u3002MIII<\/sup>H-BTC\u4e2d\u7684\u914d\u4f4d\u4e0d\u9971\u548cMIII<\/sup>H\u4e2d\u5fc3\u5bf9\u5421\u5576\u548c\u55b9\u5549\u76841,4-\u8131\u6eb4\u6c22\u5316\u548c\u6c22\u5316\u7845\u70f7\u5316\u5177\u6709\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cTrivalent Zirconium and Hafnium Metal\u2013Organic Frameworks for Catalytic 1,4-Dearomative Additions of Pyridines and Quinolines<\/strong>\u201d\u53d1\u8868\u5728\u4e86Journal of the American Chemical Society<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u5c06MIVCl2<\/sub>-BTC\u8fd8\u539f\u6210MIIIH-BTC<\/strong><\/p>\n

\"\"<\/p>\n

\u8fd9\u79cd\u65b9\u6cd5\u63d0\u4f9b\u4e86\u7814\u7a76\u4ee5\u524d\u96be\u4ee5\u6349\u6478\u7684ZrIII<\/sup>\u7269\u8d28\u7684\u7535\u5b50\u6027\u8d28\u548c\u50ac\u5316\u6d3b\u6027\u7684\u72ec\u7279\u673a\u4f1a\u3002<\/p>\n

\u56fe2 ZrIII<\/sup>H-BTC\u5408\u6210\u53ca\u6a21\u62df<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u901a\u8fc7ZrIVCl2<\/sub>-BTC\u7684\u6c2f\u5316\u7269\/\u6c22\u5316\u7269\u5206\u89e3\uff0c\u4ee5\u53ca\u968f\u540eH2<\/sub>\u7684\u53cc\u91d1\u5c5e\u8fd8\u539f\u6d88\u9664\u5408\u6210ZrIII<\/sup>H-BTC<\/p>\n

\uff08b\uff09\u6a21\u62dfZr-BTC\uff08\u9ed1\u8272\uff09\uff0cZrIII<\/sup>H-BTC\uff08\u7ea2\u8272\uff09\u7684PXRD\u56fe\uff0cZrIII<\/sup>H-BTC\u7ecf\u8fc7\u5421\u5576\u787c\u6c22\u5316\uff08\u84dd\u8272\uff09\u548c\u6c22\u5316\u7845\u70f7\u5316\uff08\u7c89\u7ea2\u8272\uff09\u548cZrIVH-BTC\uff08\u7eff\u8272\uff09\u5904\u7406<\/p>\n

\uff08c\uff09ZrVCl2<\/sub>-BTC\uff08\u5e95\u90e8\uff09\u548cZrIII<\/sup>H-BTC\uff08\u9876\u90e8\uff09\u7684Zr 3d XPS\u5149\u8c31<\/p>\n

\uff08d\uff09\u5bf9ZrIVCl2<\/sub>-BTC\uff08\u9ed1\u8272\uff09\uff0cZrIII<\/sup>H-BTC\uff08\u7ea2\u8272\uff09\u548cZrIV<\/sup>H-BTC\uff08\u84dd\u8272\uff09\u7684XANES\u5206\u6790<\/p>\n

\uff08e\uff09ZrIII<\/sup>H-BTC\u7684EXAFS\u62df\u5408<\/p>\n

\u56fe3 EPR\u8c31\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4eceZrIII<\/sup>H-BTC\u5411FcPF6<\/sub>\uff0cO2<\/sub>\u548c\u7532\u8418\u918c\u7684\u7535\u5b50\u8f6c\u79fb<\/p>\n

\uff08b\uff09Zr\uff08O2<\/sub>\u00b7\uff09-BTC\u7684EPR\u8c31<\/p>\n

\uff08c\uff09ZrIV<\/sup>H-BTC\u7ed3\u5408\u534a\u918c\u7684EPR\u8c31<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u6865\u8054\u6c27\u4ee3\/\u7fa7\u9178\u76d0\u914d\u4f53\u548cMOF\u6846\u67b6\u7684\u4f4d\u70b9\u5206\u79bb\u4f5c\u7528\u7a33\u5b9a\u4e86\u914d\u4f4d\u4e0d\u9971\u548cMIIIH\u4e2d\u5fc3\uff0c\u4e3a\u5421\u5576\u548c\u55b9\u5549\u76841,4-\u52a0\u6c22\u8131\u6c22\u548c1,4-\u6c22\u5316\u7845\u70f7\u5316\u63d0\u4f9b\u4e86\u9ad8\u6d3b\u6027\u548c\u9009\u62e9\u6027\u7684\u50ac\u5316\u5242\uff0c\u8fd9\u9879\u5de5\u4f5c\u8868\u660eSBU\u8f6c\u5316\u662f\u4e00\u79cd\u901a\u7528\u548c\u5f3a\u5927\u7684\u7b56\u7565\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1aTrivalent Zirconium and Hafnium Metal\u2013Organic Frameworks for Catalytic 1,4-Dearomative Additions of Pyridines and Quinolines<\/a>\uff08JACS,2017,DOI:10.1021\/ jacs.7b09093\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u751f\u7269\u6750\u6599\u7ec4Allen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/b><\/strong><\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c<\/b><\/strong>\u4e0a<\/b><\/strong>\u6d4b\u8bd5\u8c37<\/b><\/strong><\/a>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u80cc\u666f\u4ecb\u7ecd\u3011 TiIII\u5316\u5b66\u5df2\u7ecf\u6210\u4e3a\u7814\u7a76\u70ed\u70b9\uff0c\u5df2\u7ecf\u5728\u5149\u50ac\u5316\uff0c\u6709\u673a\u5408\u6210\u548c\u6709\u673a\u91d1\u5c5e\u50ac\u5316\u7b49\u9886\u57df\u5f97\u5230\u7684\u91cd\u8981\u5e94\u7528\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u56e0\u4e3a\u56fa\u6709\u7684\u5316\u5b66\u4e0d\u7a33\u5b9a\u6027\u548c\u9700\u8981\u51cf\u5c11ZrIV\u548cHf…<\/p>\n","protected":false},"author":349,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[245],"class_list":["post-109625","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-mof"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/109625"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/349"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=109625"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/109625\/revisions"}],"predecessor-version":[{"id":109716,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/109625\/revisions\/109716"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=109625"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=109625"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=109625"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}