{"id":110256,"date":"2017-11-09T14:00:21","date_gmt":"2017-11-09T06:00:21","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=110256"},"modified":"2017-11-05T20:56:21","modified_gmt":"2017-11-05T12:56:21","slug":"adv-funct-mater%ef%bc%9amose2-bi2se3%e5%85%ad%e6%96%b9%e7%ba%b3%e7%b1%b3%e7%89%87%e5%87%86%e5%b9%b3%e9%9d%a2%e6%9d%82%e5%8c%96%e7%bb%93%e6%9e%84%e7%9a%84%e7%a0%94%e7%a9%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=110256","title":{"rendered":"Adv Funct Mater\uff1aMoSe2\/Bi2Se3\u516d\u65b9\u7eb3\u7c73\u7247\u51c6\u5e73\u9762\u6742\u5316\u7ed3\u6784\u7684\u7814\u7a76"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/strong>\u3011<\/p>\n

\u53ef\u6301\u7eed\u6e05\u6d01\u80fd\u6e90\u548c\u9ad8\u6548\u50a8\u80fd\u6280\u672f\u7684\u53d1\u5c55\u8fd1\u5e74\u6765\u53d7\u5230\u79d1\u5b66\u5bb6\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5206\u5b50\u6c22\u7531\u4e8e\u9ad8\u91cd\u529b\u80fd\u91cf\u5bc6\u5ea6\u548c\u73af\u5883\u53cb\u597d\u7684\u7279\u6027\uff0c\u88ab\u8ba4\u4e3a\u662f\u672a\u6765\u80fd\u591f\u6ee1\u8db3\u80fd\u6e90\u9700\u6c42\u7684\u6709\u6548\u65b9\u6848\u3002\u901a\u8fc7\u7535\u5316\u5b66\u8fd8\u539f\u6cd5\u5206\u89e3\u6c34\u6765\u4ea7\u751f\u6c22\u6c14\uff0c\u5177\u6709\u9ad8\u6548\u6027\u548c\u53ef\u884c\u6027\uff0c\u56e0\u800c\u901a\u5e38\u9700\u8981\u9ad8\u6548\u548c\u8010\u7528\u7684\u7535\u50ac\u5316\u5242\u6765\u4f7f\u8fc7\u7535\u52bf\u6700\u5c0f\u5316\u5e76\u51cf\u5c11\u88ab\u5438\u9644\u6c22\u5206\u5b50\u7684\u81ea\u7531\u80fd\u5792\uff08\u5373\u0394GH\uff09\uff0c\u4ece\u800c\u4f7f\u6790\u6c22\u8fc7\u7a0b(HER)\u66f4\u5bb9\u6613\u5728\u70ed\u529b\u5b66\u548c\u52a8\u529b\u5b66\u65b9\u9762\u8fdb\u884c\u3002\u6700\u8fd1\uff0c\u6709\u62a5\u9053\u79f0\u7814\u53d1\u4e86\u4e00\u79cd\u65b0\u578b\u9ad8\u6548\u7535\u50ac\u5316\u5242\u2014\u2014MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u516d\u65b9\u7eb3\u7c73\u7247\uff0c\u663e\u8457\u63d0\u9ad8\u4e86MoSe2<\/sub>\u7535\u6781\u7684HER\u6d3b\u6027\u548c\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6027\u80fd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u6280\u672f\u5927\u5b66\u6768\u6674\u6559\u6388<\/strong>(\u901a\u8baf\u4f5c\u8005<\/strong>)\u56e2\u961f\u5728Adv Funct Mater<\/strong>\u4e0a\u53d1\u5e03\u4e86\u4e00\u7bc7\u5173\u4e8e\u7535\u50ac\u5316\u5242\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201cIntegrated Quasiplane Heteronanostructures of MoSe2<\/sub>\/Bi2<\/sub>Se3<\/sub>Hexagonal Nanosheets: Synergetic Electrocatalytic Water Splitting and Enhanced Supercapacitor Performance<\/strong>\u201d\u3002\u4f5c\u8005\u8bbe\u8ba1\u51faMoSe2<\/sub>\/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u7684\u4e00\u4f53\u5316\u51c6\u5e73\u9762\u7ed3\u6784\uff0c\u5176\u5177\u6709\u4f4e\u8d77\u59cb\u7535\u4f4d\u3001\u5c0f\u7684Tafel\u659c\u7387\u3001\u9ad8\u7535\u6d41\u5bc6\u5ea6\u548c\u957f\u671f\u7a33\u5b9a\u6027\uff0c\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6790\u6c22\u53cd\u5e94\u6d3b\u6027\uff1b\u540c\u65f6\u9ad8\u7684\u6bd4\u7535\u5bb9\u3001\u4f18\u5f02\u7684\u500d\u7387\u6027\u80fd\u548c\u5feb\u901f\u7684\u79bb\u5b50\u6269\u6563\u663e\u8457\u589e\u5f3a\u4e86\u8d85\u7ea7\u7535\u5bb9\u5668\u7684\u6027\u80fd\u3002<\/p>\n

\u3010\u56fe\u7247\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u7684\u5f62\u6001\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"
\n (a-b<\/strong>) \u4f4e\u500d\u548c\u9ad8\u500d\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

(c-d<\/strong>) \u6837\u54c1TEM\u56fe\u50cf;<\/p>\n

(e-f<\/strong>) MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u7684\u9ad8\u5206\u8fa8\u7387\u900f\u5c04\u7535\u955c\u56fe\u50cf\uff1b<\/p>\n

(g<\/strong>) \u6837\u54c1\u7684\u9009\u533a\u7535\u5b50\u884d\u5c04(SAED)\u56fe\u50cf\uff1b<\/p>\n

(h<\/strong>) HAADF-STEM\u56fe\u50cf\u548c\u5355\u4e2aMoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u7684\u76f8\u5e94EDX\u6620\u5c04\u56fe\u50cf\u3002<\/p>\n

\u56fe2 \u6837\u54c1\u7684X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31(XPS)\u548c\u62c9\u66fc\u5149\u8c31\u68c0\u6d4b<\/strong><\/p>\n

\"\"
\n (a<\/strong>) MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u548c\u7eafMoSe2<\/sub>\u7684XPS\u56fe\uff1b<\/p>\n

(b<\/strong>) MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u548c\u7eafBi2<\/sub>Se3<\/sub>\u7684XPS\u56fe;<\/p>\n

(c<\/strong>) MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u3001\u7eafMoSe2<\/sub>\u548c\u7eafBi2<\/sub>Se3<\/sub>\u7684\u62c9\u66fc\u5149\u8c31\u56fe\u3002<\/p>\n

\u56fe3 MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u7d2b\u5916\u5149\u7535\u5b50\u80fd\u8c31\u56fe<\/strong><\/p>\n

\"\"
\n (a<\/strong>) MoSe2<\/sub>\u7684UPS\u8c31\u56fe\uff0c\u63a5\u8fd1\u8d39\u7c73\u80fd\u7ea7\u548c\u4ef7\u5e26\u6700\u5927\u503c\uff1b<\/p>\n

(b-c<\/strong>) Bi2<\/sub>Se3<\/sub>\u548cMoSe2<\/sub> UPS\u8c31\u56fe\u7684\u8d77\u59cb\u6c34\u5e73;<\/p>\n

(d<\/strong>) Bi2<\/sub>Se3<\/sub>\u548cMoSe2<\/sub>\u7684\u80fd\u5e26\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe4 MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u7684HER\u6d3b\u6027<\/strong><\/p>\n

\"\"
\n (a<\/strong>) \u6781\u5316\u66f2\u7ebf\uff1b<\/p>\n

(b<\/strong>) Tafel\u659c\u7387;<\/p>\n

(c<\/strong>) MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u7684\u5c3c\u594e\u65af\u7279\u56fe\uff1b<\/p>\n

(d<\/strong>) MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u5728\u6052\u5b9a\u8fc7\u7535\u4f4d\u4e0b\u7684\u8ba1\u65f6\u7535\u6d41\u66f2\u7ebf\u3002<\/p>\n

\u56fe5 MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u7684\u8d85\u7ea7\u7535\u5bb9\u5668\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a<\/strong>) \u6837\u54c1\u7684\u5faa\u73af\u4f0f\u5b89\u6cd5(CV)\u66f2\u7ebf\uff1b<\/p>\n

(b-c<\/strong>) \u6837\u54c1\u7684\u6052\u7535\u6d41\u5145\u653e\u7535(GCD)\u66f2\u7ebf;<\/p>\n

(d<\/strong>) MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u3001\u7eafMoSe2<\/sub>\u548c\u7eafBi2<\/sub>Se3<\/sub>\u653e\u7535\u7535\u5bb9\u4e0e\u7535\u6d41\u5bc6\u5ea6\uff1b<\/p>\n

(e<\/strong>) \u7eafBi2<\/sub>Se3<\/sub>\uff0cMoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u548c\u7eafMoSe2<\/sub>\u7535\u6781\u7684EIS\u8c31\uff1b<\/p>\n

(f<\/strong>) MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u5faa\u73af\u6027\u80fd\u548cGCD\u66f2\u7ebf\u3002<\/p>\n

\u3010\u5c0f\u7ed3<\/strong>\u3011<\/p>\n

\u8fd9\u7bc7\u6587\u7ae0\u901a\u8fc7\u70ed\u6ce8\u5165\u5de5\u827a\u8bbe\u8ba1\u5e76\u5f00\u53d1\u4e86\u4e00\u79cd\u5177\u6709\u5f02\u8d28\u7ed3\u6784\u7684\u65b0\u578bMoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u6750\u6599\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0cXRD\u56fe\u8c31\u3001EDX\u8c31\u56fe\u3001TEM\u3001SEM\u548cHRTEM\u56fe\u50cf\u786e\u5b9a\u4e86MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u7684\u7ed3\u6784\u3001\u7ec4\u6210\u548c\u5f62\u6001\uff0c\u800cHAADF-STEM\u56fe\u50cf\u548c\u76f8\u5e94\u7684EDX\u56fe\u63ed\u793a\u4e86MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u4e2d\u5143\u7d20\u7684\u5206\u5e03\u5e76\u4e14\u8bc1\u5b9e\u4e86MoSe2<\/sub>\u7eb3\u7c73\u7247\u5747\u5300\u5730\u751f\u957f\u5728\u516d\u65b9\u6676Bi2Se3\u7eb3\u7c73\u7247\u57fa\u5e95\u7684\u6574\u4e2a\u8868\u9762\u4e0a\u3002\u6b64\u5916\uff0cXPS\u548cUPS\u8c31\u663e\u793a\u4e86\u5728\u6742\u4ea4\u4f53\u7cfb\u4e2d\u5b58\u5728\u7535\u5b50\u8c03\u63a7\uff0c\u8fd9\u8bc1\u5b9e\u4e86MoSe2<\/sub> \/ Bi2<\/sub>Se3<\/sub>\u6742\u5316\u4f53\u5177\u6709\u66f4\u6613\u4e8e\u83b7\u5f97\u7684\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u4f4d\u70b9\uff0c\u76f8\u5bf9\u8f83\u5927\u7684\u6709\u6548\u8868\u9762\u79ef\u548c\u66f4\u597d\u7684\u7535\u5b50\u4f20\u8f93\u80fd\u529b\uff0c\u56e0\u6b64\u5448\u73b0\u66f4\u5f3a\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Integrated Quasiplane Heteronanostructures of MoSe2<\/sub>\/Bi2<\/sub>Se3<\/sub> Hexagonal Nanosheets: Synergetic Electrocatalytic Water Splitting and Enhanced Supercapacitor Performance<\/a>\u00a0 \u00a0(Adv. Funct. Mater, 2 November, 2017 , DOI: 10.1002\/adfm.201703864\uff09
\n \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u5b66\u672f\u7ec4jcfxs01\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u53ef\u6301\u7eed\u6e05\u6d01\u80fd\u6e90\u548c\u9ad8\u6548\u50a8\u80fd\u6280\u672f\u7684\u53d1\u5c55\u8fd1\u5e74\u6765\u53d7\u5230\u79d1\u5b66\u5bb6\u4eec\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5206\u5b50\u6c22\u7531\u4e8e\u9ad8\u91cd\u529b\u80fd\u91cf\u5bc6\u5ea6\u548c\u73af\u5883\u53cb\u597d\u7684\u7279\u6027\uff0c\u88ab\u8ba4\u4e3a\u662f\u672a\u6765\u80fd\u591f\u6ee1\u8db3\u80fd\u6e90\u9700\u6c42\u7684\u6709\u6548\u65b9\u6848\u3002\u901a\u8fc7…<\/p>\n","protected":false},"author":4915,"featured_media":110268,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116,33],"class_list":["post-110256","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-catalyst","tag-nano"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/110256"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/4915"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=110256"}],"version-history":[{"count":8,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/110256\/revisions"}],"predecessor-version":[{"id":110360,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/110256\/revisions\/110360"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/110268"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=110256"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=110256"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=110256"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}