{"id":110287,"date":"2017-11-08T14:00:21","date_gmt":"2017-11-08T06:00:21","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=110287"},"modified":"2017-11-05T20:52:00","modified_gmt":"2017-11-05T12:52:00","slug":"%e5%8c%97%e4%ba%ac%e5%a4%a7%e5%ad%a6adv-mater-%ef%bc%9a%e5%8f%af%e6%8f%90%e9%ab%98%e6%8a%97%e8%85%90%e8%9a%80%e6%80%a7%e8%83%bd%e7%9a%84%e7%9f%b3%e5%a2%a8%e7%83%af%e5%8c%85%e8%a6%86%e9%93%9d%e7%ae%94","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=110287","title":{"rendered":"\u5317\u4eac\u5927\u5b66Adv. Mater.\uff1a\u53ef\u63d0\u9ad8\u6297\u8150\u8680\u6027\u80fd\u7684\u77f3\u58a8\u70ef\u5305\u8986\u94dd\u7b94\u4f5c\u4e3a\u9502\u79bb\u5b50\u7535\u6c60\u96c6\u6d41\u4f53"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u96c6\u6d41\u4f53\u662f\u53ef\u5145\u7535\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u7684\u91cd\u8981\u7ec4\u6210\u90e8\u5206\uff0c\u5b83\u662f\u5185\u5916\u7535\u8def\u7684\u6865\u6881\u3002\u5c3d\u7ba1\u6b63\u8d1f\u6781\u7535\u6781\u6750\u6599\u5343\u53d8\u4e07\u5316\uff0cAl\u7b94\u548cCu\u7b94\u7531\u4e8e\u5177\u6709\u9ad8\u5bfc\u7535\u6027\uff0c\u9002\u5f53\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u4f4e\u6210\u672c\u7b49\u4f18\u70b9\uff0c\u5728LIBs\u4e2d\u4f9d\u7136\u5206\u522b\u662f\u6700\u53d7\u6b22\u8fce\u7684\u6b63\u6781\u548c\u8d1f\u6781\u96c6\u6d41\u4f53\u3002\u7136\u800c\uff0cAl\u7b94\u5728\u957f\u671f\u7684\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u6613\u53d7\u5230\u5c40\u90e8\u7535\u5316\u5b66\u9633\u6781\u8150\u8680\uff0c\u9020\u6210\u7535\u963b\u589e\u52a0\u3001\u77ed\u8def\u548c\u5bc4\u751f\u526f\u53cd\u5e94\u7b49\u3002\u4e3a\u89e3\u51b3\u8fd9\u4e2a\u95ee\u9898\uff0c\u7814\u7a76\u4eba\u5458\u5229\u7528\u77f3\u58a8\u70ef\u8584\u819c\u4f5c\u4e3a\u5bfc\u7535\u6d82\u5c42\u548c\u754c\u9762\u9694\u79bb\u5c42\u63d0\u9ad8\u94dd\u7b94\u7684\u6297\u7535\u5316\u5b66\u8150\u8680\u6027\u80fd\u3002\u901a\u8fc7\u7b49\u79bb\u5b50\u4f53\u5316\u5b66\u6c14\u76f8\u6c89\u79ef\u6cd5\u5728\u5546\u4e1a\u96c6\u6d41\u4f53\u7528\u7684\u94dd\u7b94\u4e0a\u76f4\u63a5\u751f\u957f\u591a\u5c42\u7684\u77f3\u58a8\u70ef\u819c\uff0c\u5229\u7528\u4e0e\u94dd\u7b94\u7d27\u5bc6\u8d34\u5408\u7684\u591a\u5c42\u77f3\u58a8\u70ef\u8584\u819c\u5177\u6709\u79bb\u5b50\/\u5206\u5b50\u4e0d\u901a\u900f\u6027\uff0c\u53ef\u4ee5\u6709\u6548\u963b\u6b62\u9633\u6781\u6781\u5316\u4ea7\u751f\u7684Al3+<\/sup>\u548c\u7535\u89e3\u6db2\u4e2d\u7684\u9634\u79bb\u5b50\u3001\u6eb6\u5242\u5206\u5b50\u7b49\u914d\u4f4d\u7edc\u5408\u3002\u56e0\u6b64\uff0c\u77f3\u58a8\u70ef\u5305\u8986\u94dd\u7b94\u53ef\u4ee5\u663e\u8457\u63d0\u9ad8\u5176\u6297\u7535\u5316\u5b66\u8150\u8680\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66\u5316\u5b66\u4e0e\u5206\u5b50\u5de5\u7a0b\u5b66\u9662\u5f6d\u6d77\u7433\u6559\u6388\u548c\u5218\u5fe0\u8303\u9662\u58eb\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7814\u7a76\u5c0f\u7ec4\u7528\u4f4e\u6e29\u751f\u957f\u7684\u77f3\u58a8\u70ef\u8584\u819c\u5305\u8986\u94dd\u7b94\u589e\u5f3a\u4e86\u5176\u5728LiPF6<\/sub>\u548cLiTFSI\u7535\u89e3\u6db2\u4e2d\u7684\u6297\u8150\u8680\u6027\u3002\u6b64\u5916\uff0c\u76f8\u6bd4\u521d\u59cb\u7684\u94dd\u7b94\uff08LMO\/PA\uff09\uff0cLiMn2<\/sub>O4<\/sub>\u7535\u6c60\u4f7f\u7528\u77f3\u58a8\u70ef\u5305\u8986\u94dd\u7b94\u4f5c\u4e3a\u96c6\u6d41\u4f53\uff08LMO\/GA\uff09\u663e\u793a\u51fa\u66f4\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002LMO\/GA\u7684\u957f\u671f\u653e\u7535\u5bb9\u91cf\u4fdd\u6301\u7387\uff0c\u5728950h\u540e\uff0c\u4f9d\u7136\u80fd\u8fbe\u5230\u521d\u59cb\u768491%\uff0c\u660e\u663e\u9ad8\u4e8eLMO\/PA \u7535\u6c60\u768475%\uff0c\u4e14\u81ea\u653e\u7535\u7387\u66f4\u4f4e\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cGraphene-Armored Aluminum Foil with Enhanced Anticorrosion Performance as Current Collectors for Lithium-Ion Battery<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Adv. Mater.<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1.<\/strong>\u77f3\u58a8\u70ef\u5305\u8986\u94dd\u7b94<\/strong>\u96c6\u6d41\u4f53\u7684\u6297\u7535\u5316\u5b66\u8150\u8680\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>2. <\/strong>\u901a\u8fc7<\/strong>PECVD<\/strong>\u6cd5\u5236\u5907\u77f3\u58a8\u70ef\u5305\u8986\u94dd\u7b94\u7684\u5408\u6210\u4e0e\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u00a0 \u6240\u5408\u6210GA\u7684\u5b9e\u7269\u7167\u7247\uff1b<\/p>\n

\uff08b\uff09\u00a0 GA\u7684\u62c9\u66fc\u8c31\uff1b<\/p>\n

\uff08c\uff09\u00a0 GA\u4e2dC1s\u7684XPS\uff1b<\/p>\n

\uff08d\uff09\u00a0 GA\u7684\u622a\u9762\u900f\u5c04\u7535\u955c\u56fe\uff1b<\/p>\n

\uff08e\uff09 GA\u7684\u5143\u7d20\u5206\u5e03\u56fe\uff1b<\/p>\n

\uff08f\uff09\u6240\u5236\u591a\u5c42\u77f3\u58a8\u70ef\u7684\u4f4e\u500d\u900f\u5c04\u7535\u955c\u56fe\uff1b\u63d2\u56fe\u591a\u5c42\u77f3\u58a8\u70ef\u7684\u9ad8\u500d\u900f\u5c04\u7535\u955c\u56fe\uff0c\u6bd4\u4f8b\u5c3a\u4e3a5nm\u3002<\/p>\n

\u56fe<\/strong>3. GA<\/strong>\u63d0\u9ad8\u6297\u7535\u5316\u5b66\u8150\u8680\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u00a0 GA\u5728LPF6<\/sub>\u7535\u89e3\u6db2\u4e2d\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08b\uff09\u00a0 PA\u5728LPF6<\/sub>\u7535\u89e3\u6db2\u4e2d\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09\u00a0 CV\u6d4b\u8bd5\u540e\uff0cGA\u7684\u626b\u63cf\u7535\u955c\u56fe\uff1b<\/p>\n

\uff08d\uff09\u00a0 PA\u6d4b\u8bd5\u540e\uff0cGA\u7684\u626b\u63cf\u7535\u955c\u56fe\uff0c\u63d2\u56fe\u7684\u6bd4\u4f8b\u5c3a\u4e3a2\u03bcm\u3002<\/p>\n

\u56fe<\/strong>4. GA<\/strong>\u96c6\u6d41\u4f53\u63d0\u9ad8\u7535\u6c60\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u00a0 LMO\/PA \u548c LMO\/GA \u7535\u6c60\u7684\u957f\u65f6\u95f4\u4f4e\u500d\u7387\u5faa\u73af\u6027\u80fd\uff0c\u5b9e\u5fc3\u548c\u5706\u5708\u5206\u522b\u662fCcha<\/sub> \u548c Cdis<\/sub>\uff1b<\/p>\n

\uff08b\uff09\u00a0 LMO\/PA \u548cLMO\/GA\u7535\u6c60\u7684\u81ea\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09\u00a0 LMO\/PA \u548cLMO\/GA\u7535\u6c60\u7684\u500d\u7387\/\u529f\u7387\u6027\u80fd\uff1b<\/p>\n

\uff08d\uff09\u00a0 LMO\/PA \u548cLMO\/GA\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff0c\u5b9e\u7ebf\u548c\u5706\u5708\u5206\u522b\u662fLMO\/PA \u548cLMO\/GA\u7535\u6c60\uff1b<\/p>\n

\uff08e\uff09\u00a0 LMO\/PA \u548cLMO\/GA\u7535\u6c60\u7684\u7535\u5316\u5b66\u963b\u6297\u5206\u6790\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u5145\u5206\u5229\u7528\u5bf9\u79bb\u5b50\u5206\u5b50\u4e0d\u901a\u900f\u7684\u77f3\u58a8\u70ef\u8584\u819c\uff0c\u5728\u4f4e\u6e29\u6761\u4ef6\u4e0b\u76f4\u63a5\u5728\u94dd\u7b94\u8868\u9762\u751f\u957f\u591a\u5c42\u77f3\u58a8\u70ef\u8584\u819c\uff0c\u53ef\u4ee5\u63d0\u9ad8\u96c6\u6d41\u4f53\u5728LiPF6<\/sub>\u548c\u9170\u4e9a\u80fa\u57fa\u7535\u89e3\u6db2\u4e2d\u7684\u6297\u8150\u8680\u6027\u3002\u540c\u65f6\uff0c\u7814\u7a76\u8005\u7684\u7814\u7a76\u8868\u660e LiMn2<\/sub>O4<\/sub>\u7535\u6c60\u7528\u77f3\u58a8\u70ef\u5305\u8986\u94dd\u7b94\u4f5c\u4e3a\u96c6\u6d41\u4f53\u62e5\u6709\u4f18\u8d8a\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5305\u62ec\u66f4\u597d\u7684\u957f\u671f\u5faa\u73af\u6027\u548c\u500d\u7387\u6027\u80fd\uff0c\u5e76\u4e14\u6539\u5584\u4e86\u81ea\u653e\u7535\u6027\u80fd\u3002\u8fd9\u4e5f\u4e3a\u672a\u67655V \u9ad8\u538b\u9502\u79bb\u5b50\u7535\u6c60\u7684\u8bbe\u8ba1\u5960\u5b9a\u4e86\u57fa\u7840\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Graphene-Armored Aluminum Foil with Enhanced Anticorrosion Performance as Current Collectors for Lithium-Ion Battery<\/a>\uff08Adv. Mater.\uff0c2017\uff0cDOI: 10.1002\/adma.201703882\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4\u5bfb\u5e38\u7f16\u8bd1\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065952\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u96c6\u6d41\u4f53\u662f\u53ef\u5145\u7535\u9502\u79bb\u5b50\u7535\u6c60\uff08LIBs\uff09\u7684\u91cd\u8981\u7ec4\u6210\u90e8\u5206\uff0c\u5b83\u662f\u5185\u5916\u7535\u8def\u7684\u6865\u6881\u3002\u5c3d\u7ba1\u6b63\u8d1f\u6781\u7535\u6781\u6750\u6599\u5343\u53d8\u4e07\u5316\uff0cAl\u7b94\u548cCu\u7b94\u7531\u4e8e\u5177\u6709\u9ad8\u5bfc\u7535\u6027\uff0c\u9002\u5f53\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u548c…<\/p>\n","protected":false},"author":4974,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2465],"class_list":["post-110287","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2465"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/110287"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/4974"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=110287"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/110287\/revisions"}],"predecessor-version":[{"id":110357,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/110287\/revisions\/110357"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=110287"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=110287"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=110287"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}