{"id":110885,"date":"2017-11-11T06:30:58","date_gmt":"2017-11-10T22:30:58","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=110885"},"modified":"2017-11-09T20:54:22","modified_gmt":"2017-11-09T12:54:22","slug":"macromolecules%ef%bc%9a%e5%9c%a8%e7%94%b1%e5%a4%9a%e4%b8%aa%e6%b0%a2%e9%94%ae%e9%94%ae%e5%90%88%e7%9a%84%e8%b6%85%e5%88%86%e5%ad%90%e8%81%9a%ef%bc%881-%e4%b9%b3%e9%85%b8%ef%bc%89%e4%b8%ad%ce%b2","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=110885","title":{"rendered":"Macromolecules\uff1a\u5728\u7531\u591a\u4e2a\u6c22\u952e\u952e\u5408\u7684\u8d85\u5206\u5b50\u805a\uff081-\u4e73\u9178\uff09\u4e2d\u03b2\u6676\u4f18\u5148\u6210\u5f62\u53ca\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u591a\u6676\u7ed3\u6784"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8d85\u5206\u5b50\u805a\u5408\u7269\uff08SMPs\uff09\u7684\u5355\u4f53\u5355\u5143\u6216\u805a\u5408\u7269\u90e8\u5206\u901a\u8fc7\u53ef\u9006\u7684\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u8fde\u63a5\uff0c\u5df2\u7ecf\u5728\u79d1\u5b66\u754c\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u8d85\u5206\u5b50\u57fa\u56e2\u7684\u5f15\u5165\u4e3a\u5e38\u89c4\u805a\u5408\u7269\u5e26\u6765\u4e86\u6709\u7528\u7684\u4e14\u53ef\u8c03\u7684\u6027\u80fd\u548c\u529f\u80fd\uff0c\u5e76\u4e14\u4e5f\u662f\u5236\u5907\u9ad8\u5206\u5b50\u91cf\u805a\u5408\u7269\u548c\u5d4c\u6bb5\u5171\u805a\u7269\u7684\u5b9e\u7528\u9014\u5f84\u3002\u591a\u91cd\u6c22\u952e\uff08MHBs\uff09\u88ab\u5e7f\u6cdb\u7528\u4f5c\u6784\u5efaSMPs\uff0c\u56e0\u4e3a\u5b83\u5177\u6709\u5f3a\u5927\u7684\u7ed3\u5408\u529b\u548c\u5bf9\u5916\u90e8\u523a\u6fc0\u7684\u9ad8\u5ea6\u654f\u611f\u6027\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6d59\u6c5f\u5927\u5b66\u6f58\u9e4f\u4e3e\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u56e2\u961f\u9009\u62e9\u4e862-\u8132\u57fa-4 [1H] – \u5627\u5576\u916e\uff08UPy\uff09\u952e\u5408\u805aL-\u4e73\u9178\uff08PLLA\uff09\u4f5c\u4e3a\u6a21\u578bSMP\uff0c\u7814\u7a76\u4e86\u8d85\u5206\u5b50PLLA(SM-PLLAs)\u7684\u7ed3\u6676\u52a8\u529b\u5b66\uff0c\u591a\u6676\u578b\u7ed3\u6784\u548c\u76f8\u53d8\u3002\u901a\u8fc7\u5177\u6709\u4e0d\u540c\u5206\u5b50\u91cf\u7684\u7f9f\u57fa\u5c01\u7aef\u76842-\u548c3-\u81c2PLLA\u524d\u4f53\u7684\u672b\u7aef\u5b98\u80fd\u5316\u6765\u5408\u6210SM-PLLAs\u3002\u4e0e\u672a\u5b98\u80fd\u5316\u7684PLLA\u524d\u4f53\u76f8\u6bd4\uff0cSM-PLLA\u7684\u7ed3\u6676\u901f\u7387\u548c\u7ed3\u6676\u5ea6\u5728\u975e\u7b49\u6e29\u548c\u7b49\u6e29\u7ed3\u6676\u4e2d\u90fd\u88ab\u5f3a\u70c8\u6291\u5236\u3002SM-PLLA\u7684\u6676\u4f53\u7ed3\u6784\u5bf9\u7ed3\u6676\u6e29\u5ea6\uff08Tc<\/sub>\uff09\u654f\u611f\uff0c\u4f4eTc<\/sub>\uff0875-95\u2103\uff09\u6709\u52a9\u4e8e\u5728SM-PLLA\u4e2d\u5f62\u6210PLLA\u7684\u4e9a\u7a33\u6001\u03b2\u6676\u4f53; \u800c\u9ad8Tc<\/sub>\uff08100-130\u2103\uff09\u6709\u5229\u4e8e\u03b1\uff08\u6216\u03b1’\uff09\u6676\u4f53\u7684\u751f\u6210\u3002\u5728\u968f\u540e\u7684\u52a0\u70ed\u8fc7\u7a0b\u4e2d\uff0c\u5728SM-PLLA\u4e2d\u5f62\u6210\u7684\u03b2\u6676\u4f53\u8f6c\u5316\u6210\u66f4\u7a33\u5b9a\u7684\u03b1\u6676\u4f53\u3002\u7ecf\u8fc7\u5b9e\u9a8c\u7814\u7a76\u8ba4\u4e3a\u03b2\u6676\u4f53\u7684\u4f18\u5148\u5f62\u6210\u5f52\u56e0\u4e8eUPy\u57fa\u5143\u548cUPy-UPy\u76f8\u4e92\u4f5c\u7528\u7684\u201c\u5f3a\u201d\u9650\u5236\uff0c\u53ef\u80fd\u5728\u7ed3\u6676\u8fc7\u7a0b\u4e2d\u5bf9\u8fde\u63a5\u7684PLLA\u94fe\u4ea7\u751f\u53d6\u5411\u548c\u4f38\u5c55\u6548\u5e94\u3002\u4e0a\u8ff0\u6210\u679c\u4ee5\u9898\u4e3a\u201cPreferential Formation of \u03b2-Form Crystals and Temperature-Dependent Polymorphic Structure in Supramolecular Poly(l-lactic acid) Bonded by Multiple Hydrogen Bonds<\/strong>\u201d\u53d1\u8868\u5728\u4e86Macromolecules<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u6e29\u5ea6\u4f9d\u8d56\u6027\u5206\u6790<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\uff08A\uff09\u6ce2\u6570\u8303\u56f4\u5185\u7684\u6e29\u5ea6\u4f9d\u8d56\u6027FTIR\u5149\u8c31<\/p>\n

\uff08B\uff09\u9891\u5e26\u5f3a\u5ea6\u968f\u6e29\u5ea6\u7684\u53d8\u5316<\/p>\n

\u56fe2 \u70ed\u5206\u6790\u56fe<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\uff08A,B\uff09\u8bb0\u5f55\u5728\u7194\u5316\u7684SM-PLLA\u548cPLLA\u524d\u4f53\u7684\u52a0\u70ed\u8fc7\u7a0b\u4e2d\u7684DSC\u70ed\u5206\u6790\u56fe\uff1a\uff08A\uff09SM-PLLA; \uff08B\uff09PLLA\u524d\u4f53<\/p>\n

\u56fe3 \u5728\u5404\u79cdTc<\/sub>\u4e0b\u7b49\u6e29\u51b7\u7ed3\u6676\u4e2d\u8bb0\u5f55\u7684SM-PLLA\u548cPLLA\u524d\u4f53\u7684DSC\u7ed3\u679c<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\uff08A\uff09SMPLLA\u7684DSC\u66f2\u7ebf;<\/p>\n

\uff08B\uff09PLLA\u524d\u4f53\u7684DSC\u66f2\u7ebf;<\/p>\n

\uff08C\uff09t1\/2<\/sub>\u301cTc<\/sub>\u56fe<\/p>\n

\u56fe4 SM-PLLA\u548cPLLA\u524d\u4f53\u5728120\u2103\u7194\u878d\u7ed3\u6676\u671f\u95f4\u7684POM\u7ed3\u679c<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\uff08A\uff09\u4ee3\u8868\u6027POM\u663e\u5fae\u7167\u7247<\/p>\n

\uff08B\uff09\u7403\u6676\u534a\u5f84\u76f8\u5bf9\u4e8e\u6676\u4f53\u751f\u957f\u65f6\u95f4\u7684\u56fe<\/p>\n

\u56fe5 \u572890\u2103\u4e0b\uff0c2L-4.4k-U SM-PLLA<\/strong>\u51b7\u7ed3\u6676<\/strong>\u7684\u653e\u5927WAXD\u5206\u5e03\u56fe<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\u5728\u8fd9\u4e2a\u56fe\u4e2d\u6676\u683c\u95f4\u8ddd\u5bf9\u5e94\u4e8e\u7279\u5f81\u884d\u5c04\u9762<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

UPy\u952e\u5408\u7684SM-PLLA\u4e0e\u4f20\u7edf\u5171\u4ef7\u952e\u5408PLLA\u76f8\u6bd4\u8868\u73b0\u51fa\u72ec\u7279\u548c\u4e0d\u540c\u7684\u7ed3\u6676\u52a8\u529b\u5b66\uff0c\u591a\u6676\u578b\u6676\u4f53\u7ed3\u6784\u548c\u76f8\u53d8\u884c\u4e3a\u3002SM-PLLA\u6bd4\u76f8\u5e94\u7684\u5171\u4ef7\u952e\u5408\u7684PLLA\u524d\u4f53\u5177\u6709\u66f4\u6162\u7684\u7ed3\u6676\u901f\u7387\u548c\u66f4\u4f4e\u7684\u7ed3\u6676\u5ea6\uff0c\u8fd9\u662f\u7531\u4e8eH\u952eUPy\u57fa\u5143\u7684\u9650\u5236\u4f5c\u7528\u6240\u5f15\u8d77\u7684\u3002\u8fd9\u9879\u7814\u7a76\u53ef\u4ee5\u4f7f\u6211\u4eec\u8fdb\u4e00\u6b65\u4e86\u89e3SMPs\u72ec\u7279\u7684\u7ed3\u6676\u52a8\u529b\u5b66\u548c\u591a\u6676\u578b\u6676\u4f53\u7ed3\u6784\uff0c\u4e5f\u4e3aSMPs\u5728\u52a0\u5de5\u8fc7\u7a0b\u4e2d\u7684\u7269\u7406\u6027\u80fd\u548c\u529f\u80fd\u5b9a\u5236\u63d0\u4f9b\u4e86\u53ef\u80fd\u7684\u9014\u5f84\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Preferential Formation of \u03b2-Form Crystals and Temperature-Dependent Polymorphic Structure in Supramolecular Poly(l-lactic acid) Bonded by Multiple Hydrogen Bonds<\/a>\uff08Macromolecules, 2017, DOI:10.1021\/acs.macromol.7b01705\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4Allen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/b><\/strong><\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c<\/b><\/strong>\u4e0a<\/b><\/strong>\u6d4b\u8bd5\u8c37<\/b><\/strong><\/a>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8d85\u5206\u5b50\u805a\u5408\u7269\uff08SMPs\uff09\u7684\u5355\u4f53\u5355\u5143\u6216\u805a\u5408\u7269\u90e8\u5206\u901a\u8fc7\u53ef\u9006\u7684\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u8fde\u63a5\uff0c\u5df2\u7ecf\u5728\u79d1\u5b66\u754c\u53d7\u5230\u8d8a\u6765\u8d8a\u591a\u7684\u5173\u6ce8\u3002\u8d85\u5206\u5b50\u57fa\u56e2\u7684\u5f15\u5165\u4e3a\u5e38\u89c4\u805a\u5408\u7269\u5e26\u6765\u4e86\u6709\u7528\u7684\u4e14…<\/p>\n","protected":false},"author":349,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2521],"class_list":["post-110885","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2521"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/110885"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/349"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=110885"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/110885\/revisions"}],"predecessor-version":[{"id":111120,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/110885\/revisions\/111120"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=110885"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=110885"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=110885"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}