{"id":111786,"date":"2017-11-19T14:00:04","date_gmt":"2017-11-19T06:00:04","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=111786"},"modified":"2017-11-19T21:29:01","modified_gmt":"2017-11-19T13:29:01","slug":"adv-energy-mater-%ef%bc%9a%e5%ae%9e%e9%aa%8c%e8%ae%a1%e7%ae%97%e4%b8%a4%e9%87%8d%e5%a5%8f-na2pdc%e7%94%a8%e4%ba%8e%e9%92%a0%e7%94%b5%e6%9c%89%e6%9c%ba%e8%b4%9f%e6%9e%81%e5%8f%8a%e5%85%b6%e5%85%85","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=111786","title":{"rendered":"Adv. Energy. Mater. \uff1a\u5b9e\u9a8c\u8ba1\u7b97\u4e24\u91cd\u594f-Na2PDC\u7528\u4e8e\u94a0\u7535\u6709\u673a\u8d1f\u6781\u53ca\u5176\u5145\u653e\u7535\u539f\u7406"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u53ef\u5145\u7535\u94a0\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u5176\u4ef7\u683c\u66f4\u4fbf\u5b9c\u548c\u94a0\u57fa\u6750\u6599\u50a8\u91cf\u4e30\u5bcc\uff0c\u662f\u4e0b\u4e00\u4ee3\u7535\u5316\u5b66\u50a8\u80fd\u9886\u57df\u7684\u65b0\u661f\u3002\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u4e3b\u8981\u5305\u62ec\u65e0\u673a\u548c\u6709\u673a\u6750\u6599\uff0c\u4e0e\u65e0\u673a\u6750\u6599\u76f8\u6bd4\uff0c\u6709\u673a\u7535\u6781\u6750\u6599\u6709\u66f4\u4f4e\u5ec9\u7684\u4ef7\u683c\u3001\u66f4\u7a33\u5b9a\u7684\u7ed3\u6784\u548c\u66f4\u4f18\u5f02\u7684\u73af\u5883\u53cb\u597d\u6027\u3002<\/p>\n

\u5176\u4e2d\uff0c\u57fa\u4e8e\u7fa7\u9178\u76d0\u53ca\u5176\u5316\u5408\u7269\u7684\u6709\u673a\u7535\u6781\u6750\u6599\u6709\u7740\u9ad8\u7535\u5316\u5b66\u6d3b\u6027\u5229\u4e8e\u9502\u79bb\u5b50\u548c\u94a0\u79bb\u5b50\u7684\u53ef\u9006\u5b58\u50a8\u3002\u800c\u4e14\uff0c\u4ece\u7fa7\u9178\u76d0\u4e2d\u5f62\u6210\u7684\u6709\u673a\u76d0\u6709\u66f4\u9ad8\u7684\u6781\u6027\uff0c\u56e0\u800c\u80fd\u9632\u6b62\u7535\u6781\u6750\u6599\u5728\u7535\u89e3\u6db2\u4e2d\u7684\u5206\u89e3\uff0c\u63d0\u9ad8\u4e86\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u9664\u6b64\u4ee5\u5916\uff0c\u4e0e\u9502\u79bb\u5b50\u7535\u6c60\u4e2d\u76f8\u6bd4\uff0c\u7fa7\u9178\u94a0\u76d0\u5e94\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u5177\u6709\u66f4\u4f4e\u7684\u653e\u7535\u7535\u538b\u3002\u7136\u800c\uff0c\u66f4\u4f4e\u7684\u5de5\u4f5c\u7535\u538b\u4e5f\u5bfc\u81f4\u4e86SEI\u819c\u7b49\u5404\u79cd\u8584\u819c\u7684\u5f62\u6210\uff0c\u964d\u4f4e\u4e86\u9996\u6b21\u5e93\u4f26\u6548\u7387\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u65b0\u52a0\u5761\u56fd\u7acb\u5927\u5b66\u7684<\/strong>Sergei Manzhos<\/strong>\u6559\u6388\u548c<\/strong>Palani Balaya<\/strong>\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728\u8457\u540d\u671f\u520aAdvanced Energy Materials<\/strong>\u4e0a\u53d1\u8868\u9898\u4e3a\u201cCharge and Discharge Processes and Sodium Storage in Disodium Pyridine-2,5-Dicarboxylate Anode\u2014Insights from Experiments and Theory<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u62a5\u9053\u4e86\u4e00\u79cd\u5236\u59072,5-\u5421\u5576\u4e8c\u7532\u9178\u4e8c\u94a0\u76d0(Na2<\/sub>C7<\/sub>H3<\/sub>NO4<\/sub>, Na2<\/sub>PDC)\u7684\u65b9\u6cd5\u9996\u6b21\u7528\u4e8e\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\uff0c\u540c\u65f6\u7ed3\u5408\u4e86\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u9610\u8ff0\u4e86\u6709\u673a\u8d1f\u6781\u7684\u7ed3\u6784\u5f62\u5f0f\u548c\u7535\u5316\u5b66\u6027\u80fd\u4e4b\u95f4\u7684\u5173\u7cfb\u3002\u800c\u4e14\uff0c\u8be5Na2<\/sub>PDC\u80fd\u591f\u53ef\u9006\u5730\u50a8\u5b58\u4e24\u4e2aNa+<\/sup>\u4e8e\u4e00\u4e2a\u5316\u5b66\u5355\u5143\u4e2d\uff0c\u5f97\u5230\u4e86270mAh g-1<\/sup>\u7684\u53ef\u9006\u5bb9\u91cf\uff0c\u4ee5\u53ca\u4f18\u5f02\u7684\u5faa\u73af\u7279\u6027\u548c\u500d\u7387\u6027\u80fd\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\uff1a<\/strong>Na2<\/sub>PDC<\/strong>\u7684\u5408\u6210\u793a\u610f\u56fe\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\uff1a<\/strong>Na2<\/sub>PDC<\/strong>\u7684\u8868\u5f81\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a) \u524d\u9a71\u6db2\uff08\u9876\u90e8\uff09\u548cNa2<\/sub>PDC\uff08\u5e95\u90e8\uff09\u7684\u7ea2\u5916\u5149\u8c31\u56fe\uff1b<\/p>\n

b) \u524d\u9a71\u6db2\u548cNa2<\/sub>PDC\u7684TGA\u56fe\uff1b<\/p>\n

c) \u5b9e\u9a8c\u548c\u6a21\u62df\u7684Na2<\/sub>PDC\u7684XRD\u56fe\uff1b<\/p>\n

d) Na2<\/sub>PDC\u7684FESEM\u56fe\u3002<\/p>\n

\u56fe\u4e09\uff1a<\/strong>Na2<\/sub>PDC\/Na<\/strong>\u534a\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u6d4b\u8bd5\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a) CGD\u66f2\u7ebf\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 b) CV\u66f2\u7ebf\uff1b<\/p>\n

c) \u957f\u5faa\u73af\u66f2\u7ebf\uff1b \u00a0 \u00a0 \u00a0 \u00a0 \u00a0 \u00a0d) \u500d\u7387\u7279\u6027\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u56db\uff1a\u539f\u4f4d<\/strong>XRD<\/strong>\u56fe\u5206\u6790\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a) \u9996\u6b21CGD\u66f2\u7ebf\uff1b<\/p>\n

b) \u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0bNa\u00ad2<\/sub>PDC\u7535\u6781\u7684XRD\u56fe\u3002<\/p>\n

\u56fe\u4e94\uff1a\u4e09\u7535\u6781\u4f53\u7cfb\u4e0b<\/strong>Na2<\/sub>PDC<\/strong>\u7535\u6781\u7684\u6027\u80fd\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a) \u521d\u59cb\u5145\/\u653e\u7535\u56fe\uff1b<\/p>\n

b) \u4e0a\u56fe\u5404\u4e2a\u72b6\u6001\u4e0b\u7684EIS\u56fe\u3002<\/p>\n

\u56fe\u516d\uff1a\u8ba1\u7b97\u7684<\/strong>Na2<\/sub>PDC<\/strong>\u6676\u4f53\u7ed3\u6784\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a) \u975e\u5e73\u9762\u5f62\u6001\uff1b<\/p>\n

b) \u5e73\u9762\u5f62\u6001\u3002<\/p>\n

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\"\"<\/p>\n

a)-h) \u5206\u522b\u8868\u793aNa2+x<\/sub>PDC\u4e2d\uff0cx=0.25, 0.5, 0.75, 1.0, 1.25,1.5, 1.75, \u548c2.0\u516b\u79cd\u4e0d\u540c\u7684\u5d4c\u94a0\u72b6\u6001\u3002<\/p>\n

\u56fe\u516b\uff1a\u6a21\u62df\u8ba1\u7b97\u7684\u6027\u80fd\u548c\u8868\u5f81\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a) \u8ba1\u7b97\u7684\u7535\u538b\u66f2\u7ebf\uff1a<\/p>\n

b) \u6a21\u62df\u7684XRD\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7ed3\u5408\u4e86\u5b9e\u9a8c\u548c\u8ba1\u7b97\u65b9\u6cd5\u7814\u7a76\u4e86Na2<\/sub>PDC\u4f5c\u4e3a\u94a0\u79bb\u5b50\u7535\u6c60\u6709\u673a\u8d1f\u6781\u7684\u5d4c\u94a0\u539f\u7406\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u5176\u5177\u6709\u9ad8\u8fbe270mAh g-1<\/sup>\u7684\u53ef\u9006\u5bb9\u91cf\uff0c5C\u7535\u6d41\u5bc6\u5ea6\u4e0b\u53ef\u9006\u5bb9\u91cf\u8fbe\u5230138mAh g-1<\/sup>\uff0c\u5177\u6709\u4f18\u5f02\u7684\u500d\u7387\u7279\u6027\u3002\u9ad8\u500d\u7387\u7279\u6027\u5f52\u56e0\u4e8e\u826f\u597d\u7684\u7eb3\u7c73\u5f62\u8c8c\u3001\u8f83\u5c0f\u7684\u94a0\u79bb\u5b50\u6269\u6563\u58c1\u5792\u4ee5\u53ca\u76f8\u6bd4\u5176\u4ed6\u5bf9\u82ef\u4e8c\u9178\u76d0\u800c\u8a00\u8f83\u9ad8\u7684\u5bfc\u7535\u6027\u3002Na2<\/sub>PDC\u6709\u4e24\u4e2a\u7535\u538b\u5e73\u53f0\uff0c\u5206\u522b\u662f0.6V\u5f62\u6210Na2+1<\/sub>PDC\u548c0.4V\u5b8c\u6210\u5168\u8131\u94a0\u5f62\u6210Na2+2<\/sub>PDC\uff0c\u7ecf\u7531\u7406\u8bba\u5206\u6790\uff0c\u8be5\u6750\u6599\u6bd4\u5148\u524d\u62a5\u9053\u7684\u5bf9\u82ef\u4e8c\u9178\u4e8c\u94a0\u76d0\u90fd\u8981\u9ad8\u3002\u8ba1\u7b97\u7ed3\u679c\u8868\u660e\uff0c\u7b2c\u4e00\u4e2a\u7535\u538b\u5e73\u53f0\u7684\u5f62\u6210\u662f\u7531\u4e8eNa\u539f\u5b50\u5d4c\u5165\u5230N\u539f\u5b50\u4e2d\uff0c\u7b2c\u4e8c\u4e2a\u5e73\u53f0\u662f\u7531\u4e8eNa\u539f\u5b50\u5d4c\u5165\u5230\u7fa7\u57fa\u5b98\u80fd\u56e2\u4e2d\uff0c\u56e0\u6b64N\u539f\u5b50\u66ff\u4ee3CH\uff0c\u5177\u6709\u4e0d\u540c\u7684\u5d4c\u94a0\u539f\u7406\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5:<\/strong> Charge and Discharge Processes and Sodium Storage in Disodium Pyridine-2,5-Dicarboxylate Anode\u2014Insights from Experiments and Theory<\/a>(Adv. Energy.Mater.: 10.1002\/aenm.201701572)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u7ec4Jespen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong>RDD-2011-CHERISH<\/strong>\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u4eba\u91cd\u78c5\u63a8\u51fa\u6750\u6599\u8ba1\u7b97\u89e3\u51b3\u65b9\u6848\uff0c\u63d0\u4f9b\u8ba1\u7b97\u6a21\u62df\u5206\u6790\u670d\u52a1\u3002\u5982\u6709\u9700\u6c42\uff0c\u8bf7\u70b9\u51fb\u94fe\u63a5\u63d0\u4ea4<\/a>\u3002\u5fae\u4fe1\u7528\u6237\u53ef\u626b\u4ee5\u4e0b\u4e8c\u7ef4\u7801\u63d0\u4ea4\u3002<\/p>\n

\"\"<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u53ef\u5145\u7535\u94a0\u79bb\u5b50\u7535\u6c60\u7531\u4e8e\u5176\u4ef7\u683c\u66f4\u4fbf\u5b9c\u548c\u94a0\u57fa\u6750\u6599\u50a8\u91cf\u4e30\u5bcc\uff0c\u662f\u4e0b\u4e00\u4ee3\u7535\u5316\u5b66\u50a8\u80fd\u9886\u57df\u7684\u65b0\u661f\u3002\u94a0\u79bb\u5b50\u7535\u6c60\u8d1f\u6781\u6750\u6599\u4e3b\u8981\u5305\u62ec\u65e0\u673a\u548c\u6709\u673a\u6750\u6599\uff0c\u4e0e\u65e0\u673a\u6750\u6599\u76f8\u6bd4\uff0c\u6709\u673a\u7535\u6781\u6750…<\/p>\n","protected":false},"author":1182,"featured_media":111788,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-111786","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/111786"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/1182"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=111786"}],"version-history":[{"count":10,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/111786\/revisions"}],"predecessor-version":[{"id":111796,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/111786\/revisions\/111796"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/111788"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=111786"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=111786"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=111786"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}