{"id":112243,"date":"2017-11-18T06:30:36","date_gmt":"2017-11-17T22:30:36","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=112243"},"modified":"2017-11-17T18:58:54","modified_gmt":"2017-11-17T10:58:54","slug":"%e9%95%bf%e6%98%a5%e5%ba%94%e5%8c%96%e6%89%80%e5%8d%8e%e4%b8%ad%e7%a7%91%e5%a4%a7adv-mater-%e4%b8%80%e7%a7%8d%e6%94%b9%e5%96%84%e9%94%82%e7%a9%ba%e7%94%b5%e6%b1%a0%e9%87%91%e5%b1%9e%e9%94%82","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=112243","title":{"rendered":"\u957f\u6625\u5e94\u5316\u6240&\u534e\u4e2d\u79d1\u5927Adv. Mater.: \u4e00\u79cd\u6539\u5584\u9502\u7a7a\u7535\u6c60\u91d1\u5c5e\u9502\u8d1f\u6781\u7a33\u5b9a\u6027\u7684\u65b0\u578b\u9502\u76d0\uff1aLiTNFSI"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u9502\u7a7a\u6c14\u7535\u6c60\uff0c\u66f4\u51c6\u786e\u5730\u8bf4\uff0c\u9502\u6c27\u7535\u6c60\uff0c\u7531\u4e8e\u5176\u9ad8\u6bd4\u80fd\u91cf\u5bc6\u5ea6\u800c\u53d7\u5e7f\u6cdb\u5173\u6ce8\u3002\u5728\u8fc7\u53bb\u4e00\u6bb5\u65f6\u95f4\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u628a\u6ce8\u610f\u529b\u4e3b\u8981\u653e\u5728\u6b63\u6781\uff0c\u800c\u8f83\u5c11\u5173\u6ce8\u9502\u6c27\u7535\u6c60\u8fd9\u4e00\u7279\u6b8a\u73af\u5883\u4e0b\u91d1\u5c5e\u9502\u8d1f\u6781\u7684\u7a33\u5b9a\u6027\u3002\u5728\u9502\u6c27\u7535\u6c60\u4e2d\uff0c\u6eb6\u89e3\u4e8e\u7535\u89e3\u6db2\u4e2d\u7684\u6c27\u6c14\u5206\u5b50\u53ef\u80fd\u4ece\u6b63\u6781\u7a7f\u68ad\u81f3\u8d1f\u6781\uff0c\u4ece\u800c\u52a0\u5267\u91d1\u5c5e\u9502\u8d1f\u6781\u7684\u4e0d\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u63d0\u9ad8\u91d1\u5c5e\u9502\u8d1f\u6781\u5728\u6c27\u6c14\u6c1b\u56f4\u4e2d\u7684\u7a33\u5b9a\u6027\u662f\u9502\u6c27\u7535\u6c60\u9762\u4e34\u7684\u5927\u6311\u6218\uff0c\u4ece\u5e7f\u6cdb\u7684\u610f\u4e49\u4e0a\u6765\u8bf4\uff0c\u4e5f\u662f\u4e5f\u662f\u9502\u91d1\u5c5e\u8d1f\u6781\u7814\u7a76\u7684\u65b0\u8bfe\u9898\u3002\u8fd9\u7bc7\u63a8\u9001\uff0c\u5c06\u4ecb\u7ecd\u4e00\u79cd\u901a\u8fc7\u9502\u76d0\u7684\u8bbe\u8ba1\u5e94\u5bf9\u8fd9\u4e00\u6311\u6218\u7684\u65b0\u601d\u8def\u3002<\/p>\n

\u300a\u5148\u8fdb\u6750\u6599\u300b\uff08Advanced Materials<\/strong>\uff09\u6700\u8fd1\u520a\u767b\u4e86\u6765\u81ea\u4e2d\u56fd\u79d1\u5b66\u9662\u957f\u6625\u5e94\u7528\u5316\u5b66\u7814\u7a76\u6240\u5f6d\u7ae0\u6cc9\u8bfe\u9898\u7ec4\u548c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5468\u5fd7\u5f6c\u8bfe\u9898\u7ec4<\/strong>\u7684\u5408\u4f5c\u7814\u7a76\uff0c\u9898\u4e3a\u201cThe Salt Matters: Enhanced Reversibility of Li\u2013O2<\/sub> Batteries with a Li[(CF3<\/sub>SO2<\/sub>)(n-C4<\/sub>F9<\/sub>SO2<\/sub>)N]-Based Electrolyte\u201d\u3002\u8be5\u8bba\u6587\u91c7\u7528\u4e00\u79cd\u65b0\u578b\u78fa\u9170\u4e9a\u80fa\u9502\u76d0{Li[(CF3<\/sub>SO2<\/sub>)(n<\/em>-C4<\/sub>F9<\/sub>SO2<\/sub>)N], LiTNFSI}\uff0c\u5e76\u4ee5\u56db\u4e59\u4e8c\u9187\u4e8c\u7532\u919a\uff08TEGDME\uff09\u4e3a\u6eb6\u5242\u5236\u5907\u6210\u7535\u89e3\u6db2\u3002\u901a\u8fc7\u4e00\u7cfb\u5217\u5148\u8fdb\u8868\u5f81\u624b\u6bb5\uff0c\u8be5\u8bba\u6587\u53d1\u73b0\u8fd9\u79cd\u65b0\u7535\u89e3\u6db2\u5f15\u5bfc\u5728\u91d1\u5c5e\u9502\u8d1f\u6781\u8868\u9762\u539f\u4f4d\u751f\u6210\u4e86\u4e00\u5c42\u81f4\u5bc6\u3001\u591a\u6c1f\u3001\u758f\u6c27\u7684\u56fa\u6001\u7535\u89e3\u8d28\u754c\u9762\uff08SEI\uff09\u819c\uff0c\u660e\u663e\u589e\u5f3a\u4e86\u9502\u91d1\u5c5e\u5728\u6c27\u6c14\u6c1b\u56f4\u4e2d\u7684\u7a33\u5b9a\u6027\u3002\u4e0e\u5546\u4e1a\u5316\u7684\u9502\u76d0{Li[(CF3<\/sub>SO2<\/sub>)2<\/sub>], LiTFSI}\u5bf9\u6bd4\uff0c\u5e94\u7528\u8fd9\u79cd\u65b0\u578b\u9502\u76d0\u80fd\u591f\u4f7f\u9502\u6c27\u7535\u6c60\u5bff\u547d\u63d0\u9ad8\u4e00\u500d\u3002<\/p>\n

\u5f6d\u7ae0\u6cc9\u7814\u7a76\u5458\u548c\u5468\u5fd7\u5f6c\u6559\u6388\u4e3a\u8bba\u6587\u7684\u5171\u540c\u901a\u8baf\u4f5c\u8005\u3002\u534e\u4e2d\u79d1\u6280\u5927\u5b662015\u7ea7\u535a\u58eb\u751f\u4edd\u535a\u4e3a\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u3002\u4e2d\u5357\u5927\u5b66\u9ec4\u4fca\u526f\u6559\u6388\u4e3a\u8bba\u6587\u7b2c\u4e8c\u4f5c\u8005\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1 \u5bfc\u7535\u9502\u76d0\u7ed3\u6784<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe2 O2<\/sub>\u6c1b\u56f4\u4e0b\u9502\u91d1\u5c5e\u8d1f\u6781\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09Li|1.0 M LiTNFSI TEGDME|Li0.5<\/sub>FePO4<\/sub><\/p>\n

b\uff09Li|1.0 M LiTFSI TEGDME|Li0.5<\/sub>FePO4<\/sub><\/p>\n

\u6c27\u6c14\u6c1b\u56f4\u4e0b\uff0c\u9502\u91d1\u5c5e\u57281.0 M LiTNFSI TEGDME\u4e2d\u53ef\u4ee5\u4fdd\u6301\u826f\u597d\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe3 \u5728Ar (\u6216O2<\/sub>)\u6761\u4ef6\u4e0bLi|Li\u7535\u6c60\u5faa\u73af\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a\uff091.0 M LiTFSI TEGDME Ar<\/p>\n

b\uff091.0 M LiTFSI TEGDME O2<\/sub><\/p>\n

c\uff091.0 M LiTNFSI TEGDME Ar<\/p>\n

d\uff091.0 M LiTNFSI TEGDME O2<\/sub><\/p>\n

\u00a0<\/strong>Li|Li \u7535\u6c60\u5faa\u73af\u8868\u660e\u65e0\u8bba\u5728\u6c27\u6c14\u8fd8\u662f\u6c29\u6c14\u6761\u4ef6\uff0c\u9502\u91d1\u5c5e\u57281.0 M LiTNFSI TEGDME\u4e2d\u5747\u80fd\u4fdd\u6301\u826f\u597d\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe4 O2<\/sub> \u6c1b\u56f4\u4e0b\uff0cLi|Li\u7535\u6c60\u5faa\u73af100\u5468\u540e\u9502\u91d1\u5c5e\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

a, b, c) \u65b0\u9c9c\u9502\u91d1\u5c5e<\/p>\n

d, e, f) 1.0 M LiTNFSI TEGDME<\/p>\n

g, h, i) 1.0 M LiTFSI TEGDME<\/p>\n

\u57281.0 M LiTNFSI TEGDME\u4f53\u7cfb\u4e2d\uff0c\u91d1\u5c5e\u9502\u8868\u9762\u4fdd\u6301\u826f\u597d\u7684\u5e73\u6574\u6027\uff0c\u526f\u53cd\u5e94\u5f97\u5230\u6709\u6548\u6291\u5236\u3002<\/p>\n

\u56fe5\u00a0Li-O2<\/sub> \u7535\u6c60\u5faa\u73af\u66f2\u7ebf\u53caDEMS\u6d4b\u8bd5\u7ed3\u679c<\/strong><\/p>\n

\"\"<\/p>\n

a,b,c) 1.0 M LiTNFSI TEGDME<\/p>\n

d,e,f) 1.0 M LiTFSI TEGDME<\/p>\n

\u57fa\u4e8e1.0 M LiTNFSI TEGDME\u7535\u89e3\u6db2\u7684\u9502\u6c27\u7535\u6c60\u5faa\u73af\u6027\u80fd\u53ca\u53ef\u9006\u6027\u5f97\u5230\u660e\u663e\u63d0\u9ad8\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u5de5\u4f5c\u901a\u8fc7\u8c03\u8282\u9502\u76d0\u7ed3\u6784\uff08LiTNFSI vs LiTFSI\uff09\uff0c\u8fdb\u800c\u6539\u5584\u91d1\u5c5e\u9502\u754c\u9762\u7ec4\u6210\u3001\u63d0\u9ad8\u5176\u5728O2<\/sub>\u6761\u4ef6\u4e0b\u7684\u7a33\u5b9a\u6027\u3002\u7814\u7a76\u53d1\u73b0LiTNFSI\u5728\u91d1\u5c5e\u9502\u8868\u9762\u4f18\u5148\u8fd8\u539f\uff0c\u751f\u6210\u4e86\u4e00\u5c42\u81f4\u5bc6\u3001\u591a\u6c1f\u7684SEI\u819c\uff0c\u8be5SEI\u819c\u660e\u663e\u63d0\u9ad8\u4e86O2<\/sub>\u6c1b\u56f4\u4e0b\u91d1\u5c5e\u9502\u754c\u9762\u7a33\u5b9a\u6027\uff0c \u589e\u5f3a\u4e86Li-O2<\/sub> \u7535\u6c60\u5faa\u73af\u6027\u80fd\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u4e3a\u63d0\u9ad8\u91d1\u5c5e\u9502\u754c\u9762\u7a33\u5b9a\u6027\u63d0\u4f9b\u4e86\u65b0\u7684\u89e3\u51b3\u65b9\u6848\u3002<\/p>\n

\u539f\u6587\u94fe\u63a5\uff1aThe Salt Matters: Enhanced Reversibility of Li\u2013O2<\/sub> Batteries with a Li[(CF3<\/sub>SO2<\/sub>)(n-C4<\/sub>F9<\/sub>SO2<\/sub>)N]-Based Electrolyte<\/a>\uff08Adv<\/span>.<\/span> Mater<\/span>.<\/span> 2017<\/span>,DOI: 10.1002\/adma.201704841<\/span><\/span><\/span><\/span><\/span><\/span>\uff09<\/p>\n

\u672c\u6587\u7531\u4edd\u535a\u63d0\u4f9b\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u9502\u7a7a\u6c14\u7535\u6c60\uff0c\u66f4\u51c6\u786e\u5730\u8bf4\uff0c\u9502\u6c27\u7535\u6c60\uff0c\u7531\u4e8e\u5176\u9ad8\u6bd4\u80fd\u91cf\u5bc6\u5ea6\u800c\u53d7\u5e7f\u6cdb\u5173\u6ce8\u3002\u5728\u8fc7\u53bb\u4e00\u6bb5\u65f6\u95f4\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u628a\u6ce8\u610f\u529b\u4e3b\u8981\u653e\u5728\u6b63\u6781\uff0c\u800c\u8f83\u5c11\u5173\u6ce8\u9502\u6c27\u7535\u6c60\u8fd9\u4e00\u7279\u6b8a\u73af\u5883\u4e0b\u91d1\u5c5e…<\/p>\n","protected":false},"author":272,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2558],"class_list":["post-112243","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-2558"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/112243"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/272"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=112243"}],"version-history":[{"count":7,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/112243\/revisions"}],"predecessor-version":[{"id":112509,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/112243\/revisions\/112509"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=112243"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=112243"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=112243"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}