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1\u3001Journal of the Electrochemical Society\uff1a\u78f7\u9178\u94c1\u9502\u4f5c\u4e3a\u9502\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599<\/strong><\/p>\n \u6587\u732e\u94fe\u63a5<\/strong>\uff1aPhospho-olivines as positive-electrode materials for rechargeable lithium batteries<\/a>\uff08J.Electrochem.Soc.,1997,DOI:10.1149\/1.1837571\uff09<\/p>\n 2\u3001Nature\uff1a\u5728\u534a\u5bfc\u4f53\u7535\u6781\u5904\u6c34\u7684\u7535\u5316\u5b66\u5149\u89e3<\/strong><\/p>\n 1972\u5e74\u65e5\u672c\u4e1c\u4eac\u5927\u5b66KENICHI HONDA\u3001\u795e\u5948\u5ddd\u5927\u5b66AKIRA FUJISHIMA\u00a0<\/strong>\u7b49\u4eba\u5728Nature\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cElectrochemical photolysis of water at a semiconductor electrode\u201d\u7684\u7814\u7a76\u8bba\u6587\uff0c\u5f00\u521b\u6027\u7684\u53d1\u73b0\u4e86\u4e00\u79cd\u6c34\u5149\u89e3\u7684\u65b0\u65b9\u6cd5\u3002\u867d\u7136\u5728\u5f53\u65f6\u5df2\u7ecf\u6709\u5f88\u591a\u5de5\u4f5c\u81f4\u529b\u4e8e\u7814\u7a76\u4e86\u6c34\u7684\u5149\u89e3\u7684\u53ef\u80fd\u6027\uff0c\u4f46\u5927\u591a\u662f\u6beb\u65e0\u7a81\u7834\u6027\u8fdb\u5c55\u3002\u56e0\u4e3a\u6c34\u5bf9\u53ef\u89c1\u5149\u662f\u900f\u660e\u7684\uff0c\u6240\u4ee5\u4e0d\u80fd\u76f4\u63a5\u5206\u89e3\uff0c\u800c\u53ea\u80fd\u7528\u6ce2\u957f\u77ed\u4e8e190nm\u7684\u8f90\u5c04\u4ee4\u5176\u5206\u89e3\u3002\u5bf9\u4e8e\u6c34\u7684\u7535\u5316\u5b66\u5206\u89e3\uff0c\u5728\u53d1\u751f\u9633\u6781\u8fc7\u7a0b\u7684\u4e00\u4e2a\u7535\u6781\u548c\u53d1\u751f\u9634\u6781\u53cd\u5e94\u7684\u53e6\u4e00\u4e2a\u7535\u6781\u4e4b\u95f4\u9700\u8981\u5927\u4e8e1.23V\u7684\u7535\u4f4d\u5dee\u3002\u8fd9\u4e2a\u7535\u4f4d\u5dee\u5c31\u76f8\u5f53\u4e8e\u6ce2\u957f\u5927\u7ea6\u4e3a1000nm\u7684\u8f90\u5c04\u80fd\u91cf\u3002\u56e0\u6b64\uff0c\u5982\u679c\u5728\u7535\u5316\u5b66\u7cfb\u7edf\u4e2d\u6709\u6548\u5730\u5229\u7528\u5149\u7684\u80fd\u91cf\uff0c\u5e94\u8be5\u53ef\u4ee5\u7528\u53ef\u89c1\u5149\u5206\u89e3\u6c34\u3002KENICHI HONDA\u7b49\u4eba\u5c31\u662f\u57fa\u4e8e\u6b64\u65b9\u6cd5\u5f00\u521b\u4e86\u5149\u50ac\u5316\u6c34\u5206\u89e3\u65b0\u65f6\u4ee3\u3002<\/p>\n \u6587\u732e\u94fe\u63a5<\/strong>\uff1aElectrochemical Photolysis of Water at a Semiconductor Electrode<\/a>\uff08Nature,1972,DOI:10.1038\/<\/span>238037a0\uff09<\/p>\n 3\u3001Nature\uff1aC60<\/sub>:\u5df4\u514b\u654f\u65af\u7279\u5bcc\u52d2\u70ef \u6587\u732e\u94fe\u63a5<\/strong>\uff1aC60: Buckminsterfullerene<\/a>\uff08Nature,1985,DOI:10.1038\/318162a0\uff09<\/p>\n 4\u3001Nature\uff1a\u87ba\u65cb\u7684\u78b3\u7eb3\u7c73\u7ba1<\/strong><\/p>\n \u6b63\u662f\u57fa\u4e8e\u4e0a\u8ff0\u5bcc\u52d2\u70ef\u7684\u53d1\u73b0\uff0c1991\u5e74\u65e5\u672c\u7535\u5b50\u516c\u53f8Sumio Iijima\u535a\u58eb<\/strong>\u53d1\u73b0\u4e86\u66f4\u52a0\u5947\u7279\u7684\u78b3\u7eb3\u7c73\u7ba1\u7ed3\u6784\uff0c\u5e76\u5728Nature<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cHelical microtubules of graphitic carbon<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u5728Iijima\u5c06\u5176\u547d\u540d\u4e4b\u524d\uff0c\u5df2\u7ecf\u6709\u4eba\u5c06\u5176\u5236\u9020\u51fa\u6765\u4f46\u662f\u6ca1\u6709\u610f\u8bc6\u5230\u8fd9\u79cd\u7ed3\u6784\u4f1a\u662f\u98a0\u8986\u4f20\u7edf\u8ba4\u77e5\uff0c\u6539\u53d8\u4eba\u751f\u8f68\u8ff9\u7684\u798f\u661f\u3002\u8fd9\u79cd\u7ed3\u6784\u4e0e\u7528\u4e8e\u5bcc\u52d2\u70ef\u5408\u6210\u65b9\u6cd5\u7c7b\u4f3c\u7684\u7535\u5f27\u653e\u7535\u84b8\u53d1\u65b9\u6cd5\u751f\u4ea7\uff0c\u9488\u72b6\u7269\u5728\u7528\u4e8e\u7535\u5f27\u653e\u7535\u7684\u7535\u6781\u7684\u8d1f\u6781\u7aef\u751f\u957f\u3002\u7535\u5b50\u663e\u5fae\u955c\u663e\u793a\u6bcf\u6839\u9488\u90fd\u5305\u542b\u77f3\u58a8\u7247\u7684\u540c\u8f74\u7ba1\uff0c\u6570\u91cf\u4ece2\u4e2a\u5230\u7ea650\u4e2a\u3002\u5728\u6bcf\u4e2a\u7ba1\u4e0a\uff0c\u78b3\u539f\u5b50\u516d\u8fb9\u5f62\u56f4\u7ed5\u9488\u72b6\u7269\u8f74\u7ebf\u4ee5\u87ba\u65cb\u65b9\u5f0f\u6392\u5217\uff0c\u7814\u7a76\u53d1\u73b0\u8fd9\u4e2a\u87ba\u65cb\u7ed3\u6784\u6709\u52a9\u4e8e\u751f\u957f\u8fc7\u7a0b\u3002<\/p>\n \u6587\u732e\u94fe\u63a5<\/strong>\uff1aHelical microtubules of graphitic carbon<\/a>\uff08Nature,1991,DOI:10.1038\/354056a0\uff09<\/p>\n 5\u3001Science\uff1a\u539f\u5b50\u7ea7\u8584\u78b3\u819c\u7684\u7535\u573a\u6548\u5e94<\/strong><\/p>\n 2004\u5e74\u66fc\u5f7b\u65af\u7279\u5927\u5b66A. K. Geim<\/strong>\u56e2\u961f\u5728Science<\/strong>\u53d1\u8868\u9898\u4e3a\u201cElectric field effect in atomically thin carbon films<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\uff0c\u62c9\u5f00\u4e86\u77f3\u58a8\u70ef\u7684\u5e8f\u5e55\u3002\u8be5\u56e2\u961f\u5236\u5907\u4e86\u51e0\u4e2a\u539f\u5b50\u7ea7\u539a\u5ea6\u7684\u5355\u6676\u77f3\u58a8\u819c\uff0c\u4f46\u662f\u5728\u6b63\u5e38\u6761\u4ef6\u4e0b\u4ecd\u7136\u5341\u5206\u7a33\u5b9a\u7684\u3002\u53d1\u73b0\u8fd9\u4e9b\u8584\u819c\u662f\u4e8c\u7ef4\u534a\u91d1\u5c5e\uff0c\u5728\u4ef7\u7535\u5b50\u5e26\u548c\u7535\u5bfc\u5e26\u4e4b\u95f4\u6709\u5f88\u5c0f\u7684\u91cd\u53e0\uff0c\u5e76\u4e14\u5b83\u4eec\u8868\u73b0\u51fa\u5f3a\u70c8\u7684\u53cc\u6781\u6027\u7535\u573a\u6548\u5e94\uff0c\u4f7f\u5f97\u7535\u5b50\u548c\u7a7a\u7a74\u6d53\u5ea6\u9ad8\u8fbe\u6bcf\u5e73\u65b9\u5398\u7c731013\u4e2a\uff0c\u5ba4\u6e29\u8fc1\u79fb\u7387\u53ef\u4ee5\u901a\u8fc7\u65bd\u52a0\u6805\u6781\u7535\u538b\u6765\u8bf1\u5bfc\u8fbe\u5230\u6bcf\u4f0f\u79d2\u301c10,000\u5e73\u65b9\u5398\u7c73\u3002\u901a\u8fc7\u8fdb\u4e00\u6b65\u7814\u7a76Geim\u7b49\u4eba\u5236\u5907\u51fa\u4e86\u8d8a\u6765\u8d8a\u8584\u7684\u8584\u7247\uff0c\u6700\u540e\uff0c\u4ed6\u4eec\u5f97\u5230\u4e86\u4ec5\u7531\u4e00\u5c42\u78b3\u539f\u5b50\u6784\u6210\u7684\u8584\u7247\uff0c\u8fd9\u5c31\u662f\u77f3\u58a8\u70ef\u3002<\/p>\n \u6587\u732e\u94fe\u63a5<\/strong>\uff1aElectric field effect in atomically thin carbon films<\/a>\uff08Science,2004,DOI:0.1126\/science.1102896\uff09<\/p>\n 6\u3001Nature\uff1a\u56fa\u5316\u91d1-\u7845\u5408\u91d1\u4e2d\u7684\u975e\u6676\u6001\u7ed3\u6784 \u6587\u732e\u94fe\u63a5<\/strong>\uff1aNon-crystalline structure in solidified gold\u2013silicon all<\/a>oys\uff08Nature,1960,DOI:10.1038\/187869b0\uff09<\/p>\n 7\u3001Nature\uff1a\u4e00\u79cd\u7a33\u5b9a\u548c\u591a\u5b54\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u7684\u8bbe\u8ba1\u4e0e\u5408\u6210 1999\u5e74\u5bc6\u6b47\u6839\u5927\u5b66O. 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Yaghi<\/strong>\u7b49\u4eba\u5728Nature<\/strong>\u4e0a\u53d1\u8868\u9898\u4e3a\u201cDesign and synthesis of an exceptionally stable and highly porous metal-organic 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\u6587\u732e\u94fe\u63a5\uff1aDesign and synthesis of an exceptionally stable and highly porous metal-organic framework<\/a>\uff08Nature,1999,DOI:doi<\/abbr>:10.1038\/46248\uff09<\/p>\n \u66f4\u591a\u7684\u5f00\u5c71\u8bba\u6587\u6b22\u8fce\u7559\u8a00\u8ba8\u8bba\u3002<\/p>\n \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8Allen\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002<\/p>\n \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n 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\u78f7\u9178\u94c1\u9502\u662f1997\u5e74\u7f8e\u56fd\u5fb7\u514b\u8428\u65af\u5dde\u7acb\u5927\u5b66J. B. Goodenough<\/strong>\u7b49\u4eba\u5728Journal of the Electrochemical Society<\/strong>\u4e0a\u53d1\u8868\u7684\u9898\u4e3a\u201cPhospho-olivines as positive-electrode materials for rechargeable lithium batteries<\/strong>\u201d\u7684\u6587\u7ae0\u63d0\u51fa\u7684\u4e00\u79cd\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\uff0c\u4e3a\u6a44\u6984\u77f3\u7ed3\u6784\u6750\u6599\u3002J. B. Goodenough\u7b49\u4eba\u53d1\u73b0\u57283.5 V\u7535\u538b\u4e0b\u8fd9\u79cd\u6a44\u6984\u77f3\u7ed3\u6784\uff08LiFePO4<\/sub>\uff09\u53ef\u9006\u6027\u5730\u8fc1\u5165\u8131\u51fa\u9502\u7684\u7279\u6027\uff0c\u8bc1\u660e\u5176\u4f5c\u4e3a\u9502\u7535\u6c60\u6b63\u6781\u6750\u6599\u5177\u6709\u4f18\u5f02\u7684\u6027\u80fd\u3002\u8fdb\u4e00\u6b65\u7814\u7a76\u53d1\u73b0\uff0c\u5176\u6bd4\u5bb9\u91cf\u8fbe\u5230100\u5230110mAh\/g\u3002\u8fc1\u5165\u6216\u8131\u51fa\u53cd\u5e94\u901a\u8fc7\u4e24\u76f8\u8fc7\u7a0b\u8fdb\u884c\uff0c\u968f\u7740\u7535\u6d41\u5bc6\u5ea6\u589e\u52a0\uff0c\u5bb9\u91cf\u7684\u53ef\u9006\u635f\u5931\u4f3c\u4e4e\u4e0e\u9502\u5728\u6574\u4e2a\u4e24\u76f8\u754c\u9762\u4e0a\u7684\u6269\u6563\u9650\u5236\u8f6c\u79fb\u6709\u5173\u3002\u78f7\u9178\u94c1\u9502\u4e5f\u662f\u662f\u76ee\u524d\u6700\u5b89\u5168\u7684\u9502\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\uff0c\u4e0d\u542b\u4efb\u4f55\u5bf9\u4eba\u4f53\u6709\u5bb3\u7684\u91cd\u91d1\u5c5e\u5143\u7d20\u3002\u5176\u7406\u8bba\u6bd4\u5bb9\u91cf\u4e3a170 mAh\/g\uff0c\u4ea7\u54c1\u5b9e\u9645\u6bd4\u5bb9\u91cf\u53ef\u8d85\u8fc7140 mAh\/g\uff080.2C,25\u00b0C\uff09\u3002<\/p>\n![\"\"](\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/\u56fe\u72474-10.png\")
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<\/strong>1985\u5e74\u83b1\u65af\u5927\u5b66H. W. Kroto\u56e2\u961f<\/strong>\u5728Nature<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cC60<\/sub>: Buckminsterfullerene<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u4e00\u4e3e\u6210\u540d\u3002Kroto\u4e3b\u8981\u7814\u7a76\u68c0\u6d4b\u5916\u592a\u7a7a\u63a2\u6d4b\u5230\u7684\u957f\u94fe\u7ebf\u5f62\u78b3\u94fe\u5206\u5b50\uff0c\u6b63\u662f\u5728\u8fd9\u4e9b\u5b9e\u9a8c\u4e2d\uff0c\u4ed6\u4eec\u53d1\u73b0\u4e86\u78b3\u7684\u4e00\u79cd\u65b0\u7684\u540c\u7d20\u5f02\u5f62\u4f53\uff1a\u8db3\u7403\u5f62\u72b6\u7684C60<\/sub>\uff0c\u53ef\u80fd\u662f\u78b3\u84b8\u6c7d\u88ab\u538b\u7f29\u540e\u5f62\u6210\u7684\u3002\u5173\u4e8e\u4ec0\u4e48\u6837\u768460\u78b3\u539f\u5b50\u7ed3\u6784\u53ef\u80fd\u4f1a\u662f\u4e00\u4e2a\u8d85\u7ea7\u7a33\u5b9a\u7684\u7ed3\u6784\u95ee\u9898\uff0cKroto\u63d0\u51fa\u4e00\u4e2a\u622a\u9876\u7684\u4e8c\u5341\u9762\u4f53\uff0c\u4e00\u4e2a\u670960\u4e2a\u9876\u70b9\u548c32\u4e2a\u9762\u7684\u591a\u8fb9\u5f62\uff0c\u5176\u4e2d12\u4e2a\u662f\u4e94\u89d2\u5f62\u7684\uff0c20\u4e2a\u662f\u516d\u89d2\u5f62\u7684\u3002\u4e3a\u4e86\u5411\u7f8e\u56fd\u5efa\u7b51\u5e08Buckminster Fuller\u81f4\u656c\uff0cKroto\u63d0\u8bae\u5c06\u8fd9\u79cd\u65b0\u7684\u540c\u7d20\u5f02\u5f62\u4f53\u547d\u540d\u4e3a\u5df4\u514b\u654f\u65af\u7279\u5bcc\u52d2\u70ef\u3002\u4e5f\u6b63\u662f\u56e0\u4e3a\u8fd9\u9879\u5de5\u4f5c\uff0cKroto\u4e0eRobert Curl\u3001Richard Smalley\u4e00\u540c\u83b7\u5f97\u4e861996\u5e74\u7684\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\uff0c\u5e76\u5728\u540c\u5e74\u88ab\u6388\u4e88\u7235\u4f4d\u3002<\/p>\n![\"\"](\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/\u56fe\u72476-7.png\")
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<\/strong>1960\u5e74\u4f2f\u660e\u7ff0<\/strong>\u5927\u5b66POL DUWEZ<\/strong>\u7b49\u4eba\u5728Nature\u4e0a\u53d1\u8868\u9898\u4e3a\u201cNon-crystalline structure in solidified gold\u2013silicon alloys<\/strong>\u201d\u7684\u6587\u7ae0\uff0c\u7528\u5feb\u6dec\u5de5\u827a\u5236\u5907\u51fa\u4e86\u975e\u6676\u6001\u5408\u91d1\u3002\u9664\u4e86\u5728\u975e\u5e38\u4f4e\u7684\u6e29\u5ea6\u4e0b\u6c89\u79ef\u7684\u8584\u819c\u4ee5\u5916\uff0c\u5728\u56fa\u4f53\u91d1\u5c5e\u548c\u5408\u91d1\u4e2d\u4ece\u672a\u89c2\u5bdf\u5230\u7c7b\u4f3c\u4e8e\u6db2\u6001\u7684\u9ad8\u5ea6\u65e0\u5e8f\u7684\u539f\u5b50\u6392\u5217\u3002\u5bf9\u4e8e\u4e00\u4e9b\u975e\u91d1\u5c5e\u800c\u8a00\uff0c\u5176\u952e\u5408\u5b9e\u9645\u4e0a\u53ef\u80fd\u6bd4\u91d1\u5c5e\u66f4\u6613\u5f62\u6210\u5171\u4ef7\u952e\uff0c\u8fd9\u79cd\u65e0\u5b9a\u5f62\u7ed3\u6784\u901a\u8fc7\u4ee5\u8db3\u591f\u5feb\u7684\u901f\u5ea6\u4ece\u7194\u4f53\u51b7\u5374\u800c\u4fdd\u6301\u56fa\u6001\uff0c\u4ece\u800c\u9632\u6b62\u5f62\u6210\u5e73\u8861\u7ed3\u6676\u7ed3\u6784\u3002\u8fd9\u79cd\u56fa\u6001\u5408\u91d1\u662f\u957f\u7a0b\u65e0\u5e8f\u7ed3\u6784\uff0c\u6ca1\u6709\u6676\u6001\u5408\u91d1\u7684\u6676\u7c92\u3001\u6676\u754c\u5b58\u5728\uff0c\u79f0\u4e4b\u4e3a\u975e\u6676\u5408\u91d1\u3002\u8fd9\u79cd\u975e\u6676\u5408\u91d1\u5177\u6709\u8bb8\u591a\u72ec\u7279\u7684\u6027\u80fd\uff0c\u5982\u4f18\u5f02\u7684\u78c1\u6027\u3001\u8010\u8680\u6027\u3001\u8010\u78e8\u6027\u3001\u9ad8\u7684\u5f3a\u5ea6\u3001\u786c\u5ea6\u548c\u97e7\u6027\uff0c\u9ad8\u7684\u7535\u963b\u7387\u548c\u673a\u7535\u8026\u5408\u6027\u80fd\u7b49\u3002<\/p>\n![\"\"](\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/\u56fe\u72479-3.png\")
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