{"id":112371,"date":"2017-11-18T14:00:40","date_gmt":"2017-11-18T06:00:40","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=112371"},"modified":"2017-11-16T23:14:00","modified_gmt":"2017-11-16T15:14:00","slug":"donald-r-sadoway%e6%95%99%e6%8e%88adv-funct-mater-%e6%b6%b2%e6%80%81%e9%94%a1%e8%be%85%e5%8a%a9%e7%86%94%e7%9b%90%e7%94%b5%e6%b2%89%e7%a7%af%e5%88%b6%e5%a4%87%e5%85%89%e6%95%8fn%e5%9e%8b%e7%a1%85","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=112371","title":{"rendered":"Donald R. Sadoway\u6559\u6388Adv Funct Mater : \u6db2\u6001\u9521\u8f85\u52a9\u7194\u76d0\u7535\u6c89\u79ef\u5236\u5907\u5149\u654fn\u578b\u7845\u819c"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u7531\u7194\u76d0\u7535\u6c89\u79ef\u6cd5\u76f4\u63a5\u751f\u4ea7\u7845\u819c\uff0c\u5de5\u827a\u7b80\u5355\uff0c\u751f\u4ea7\u6210\u672c\u4f4e\uff0c\u5728\u5236\u9020\u5149\u4f0f\u548c\u5149\u7535\u5b50\u5668\u4ef6\u65b9\u9762\u5177\u6709\u5b9e\u7528\u6027\u3002\u5df2\u7ecf\u8bc1\u660e\u5728650\u2103\u7684\u7194\u878dKCl-KF-1mol\uff05K<sub>2<\/sub>SiF<sub>6<\/sub>\u76d0\u4e2d\uff0c\u80fd\u591f\u5728\u77f3\u58a8\u7247\u57fa\u6750\u4e0a\u7535\u6c89\u79ef\u81f4\u5bc6\u4e14\u5149\u654f\u7684\u7845\u819c\u3002\u4e0e\u5148\u524d\u5728\u4e0d\u63ba\u6742\u9521\u7684\u8be5\u4f53\u7cfb\u4e2d\u751f\u6210\u7684\u7845\u7eb3\u7c73\u7ebf\u76f8\u6bd4\uff0c\u9521\u4f5c\u4e3a\u6d78\u5165\u7194\u878d\u76d0\u4e2d\u7684\u6db2\u6001\u91d1\u5c5e\uff0c\u5f71\u54cd\u751f\u6210\u7845\u7684\u5f62\u6001\uff0c\u53ef\u4ee5\u5236\u5907\u81f4\u5bc6\u7684\u3001\u539a\u800c\u5747\u5300\u7684\u7845\u819c\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u9ebb\u7701\u7406\u5de5\u5b66\u9662Donald R. Sadoway\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5728<strong>Adv.Funct.Mater.<\/strong>\u4e0a\u53d1\u5e03\u4e86\u4e00\u7bc7\u5173\u4e8e\u7194\u76d0\u7535\u6c89\u79ef\u6cd5\u5236\u5907\u591a\u6676\u7845\u819c\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201c<strong>Liquid-Tin-Assisted Molten Salt Electrodeposition of Photoresponsive n-Type Silicon Films<\/strong>\u201d\u3002\u672c\u6587\u4f5c\u8005\u5728650\u2103\u542b\u67090.020-0.035%\u9521\u7684\u7194\u878dKCl-KF-1mol\uff05K<sub>2<\/sub>SiF<sub>6<\/sub>\u76d0\u4e2d\uff0c\u5728\u77f3\u58a8\u7247\u57fa\u6750\u4e0a\u7535\u6c89\u79ef\u5236\u5907\u81f4\u5bc6\u5747\u5300\u7684\u591a\u6676\u7845\u819c\uff08\u539a\u5ea6\u9ad8\u8fbe60\u03bcm\uff09\uff0c\u4e14\u8868\u73b0\u51fan\u578b\u534a\u5bfc\u4f53\u884c\u4e3a\u3002\u89e3\u91ca\u4e86\u8fd9\u79cd\u9ad8\u8d28\u91cf\u7684\u63ba\u9521\u7845\u819c\u7684\u751f\u957f\u662f\u7531\u4e8e\u7194\u76d0\u7535\u89e3\u8d28\u4e2d\u9521\u7684\u4f5c\u7528\u3002\u63d0\u51fa\u4e86\u6210\u819c\u7684\u56db\u6b65\u673a\u5236\uff1a\u6210\u6838\uff0c\u5c9b\u5f62\u6210\uff0c\u5c9b\u805a\u96c6\u548c\u6210\u819c\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 \u5b9e\u9a8c\u539f\u7406\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-112373\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/1-35.png\" alt=\"\" width=\"600\" height=\"386\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/1-35.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/1-35-300x193.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08<strong>a<\/strong>\uff09\u6765\u81ea\u65e0\u9521\u7194\u76d0<\/p>\n<p>\uff08<strong>b<\/strong>\uff09\u6765\u81ea\u542b\u9521\u7194\u76d0<\/p>\n<p><strong>\u56fe2 \u7535\u6c89\u79ef\u4ea7\u7269\u7684SEM\u56fe\u50cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-112374\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/2-29.png\" alt=\"\" width=\"520\" height=\"585\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/2-29.png 520w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/2-29-267x300.png 267w\" sizes=\"(max-width: 520px) 100vw, 520px\" \/><\/p>\n<p>\uff08<strong>a<\/strong>\uff095 mA cm <sup>-2<\/sup> \uff0c\u6301\u7eed4 h\uff0c\u65e0Sn\u7535\u89e3\u8d28<\/p>\n<p>\uff08<strong>b<\/strong>\uff0920 mA cm<sup>-2<\/sup>\uff0c\u6301\u7eed4 h\uff0c\u65e0Sn\u7535\u89e3\u8d28<\/p>\n<p>(<strong>c,d<\/strong>\uff09\u77f3\u58a8\u7b94\u57fa\u6750\uff0c5mA\/ cm<sup> 2<\/sup>\uff0c\u6301\u7eed4 h\uff0c\u542b0.02wt\uff05Sn\u7535\u89e3\u8d28<\/p>\n<p>(<strong>e,f<\/strong>\uff09\u521a\u6027\u77f3\u58a8\u677f\u57fa\u6750\uff0c20mA\/ cm<sup>2<\/sup>\uff0c\u6301\u7eed4 h\uff0c\u542b0.035wt\uff05Sn\u7535\u89e3\u8d28<\/p>\n<p><strong>\u56fe3 \u521a\u6027\u77f3\u58a8\u57fa\u5e95\u4e0a\u7535\u6c89\u79ef\u4ea7\u7269\u7684XRD\u56fe\u8c31<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-112375\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/3-22.png\" alt=\"\" width=\"600\" height=\"337\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/3-22.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/3-22-300x169.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\u542bSn\u7194\u76d0\u7535\u6c89\u79ef\u4ea7\u7269\u5f62\u6001\u4e3a\u7845\u819c\uff0c\u4e0e\u65e0Sn\u7194\u76d0\u7535\u6c89\u79ef\u4ea7\u7269\u76f8\u6bd4\uff0c\u5176\u5cf0\u66f4\u5f3a\u3001\u66f4\u5c16\u9510\uff0c\u7ed3\u6676\u6027\u8f83\u597d\u3002<\/p>\n<p><strong>\u56fe4 \u4e0d\u540c\u5de5\u4f5c\u7535\u6781\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-112376\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/4-21.png\" alt=\"\" width=\"600\" height=\"240\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/4-21.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/4-21-300x120.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08<strong>a<\/strong>\uff09\u5728650\u2103\u4e0b,\u542b\u4e0e\u4e0d\u542b0.02 \uff05Sn\u7684KCl-KF-1 mol\uff05 K<sub>2<\/sub>SiF<sub>6<\/sub>\u7194\u76d0\u4e2d\u7684\u77f3\u58a8\u68d2\u5de5\u4f5c\u7535\u6781<\/p>\n<p>\uff08<strong>b<\/strong>\uff09\u5728KCl-KF-1 \uff05 K<sub>2<\/sub>SiF<sub>6<\/sub>\u76d0\u4e2d,Sn\u4f5c\u4e3a\u5de5\u4f5c\u7535\u6781<\/p>\n<p><strong>\u56fe5 \u5728\u77f3\u58a8\u7b94\u57fa\u5e95\u4e0a\u7535\u6c89\u79efSn\u63ba\u6742\u7845\u819c\u7684\u751f\u957f\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-112377\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/5-17.png\" alt=\"\" width=\"600\" height=\"246\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/5-17.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/5-17-300x123.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>650\u2103\uff0c\u542b\u67090.02\uff05Sn\u7684KCl-KF-1mol\uff05K<sub>2<\/sub>SiF<sub>6<\/sub>\u76d0\u4e2d\uff0c5 mA cm<sup>-2<\/sup>\uff0c\u4e0d\u540c\u65f6\u95f4\u4e0b\u7684\u6837\u54c1\u7684\u76f8\u5e94\u5f62\u6001<\/p>\n<p>\uff08<strong>a<\/strong>\uff09\u6210\u6838\uff0c5min<\/p>\n<p>\uff08<strong>b<\/strong>\uff09\u5c9b\u5f62\u6210\uff0c15min<\/p>\n<p>\uff08<strong>c<\/strong>\uff09\u5c9b\u805a\u96c6\uff0c30min<\/p>\n<p>\uff08<strong>d<\/strong>\uff09\u6210\u819c\uff0c\u8d85\u8fc790min<\/p>\n<p><strong>\u56fe6 \u5177\u6709\u4e0d\u540c\u539a\u5ea6\u7684Sn\u63ba\u6742\u7845\u8584\u819c\u7684\u5149\u54cd\u5e94<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-112378\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/6-12.png\" alt=\"\" width=\"600\" height=\"245\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/6-12.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/6-12-300x123.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08<strong>a<\/strong>\uff098.3\u03bcm<\/p>\n<p>\uff08<strong>b<\/strong>\uff0961\u03bcm<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u5728650\u2103\uff0c\u5728\u542b\u6709Sn\u7684K<sub>2<\/sub>SiF<sub>6<\/sub>\u7194\u878d\u76d0\u4e2d\uff0c\u4e8e\u77f3\u58a8\u7247\u57fa\u6750\u4e0a\u901a\u8fc7\u7535\u6c89\u79ef\u5f97\u5230\u7684Sn\u63ba\u6742\u7845\u819c\u81f4\u5bc6\u5747\u5300\u3002\u7194\u76d0\u4e2d\u7684Sn\u4fc3\u8fdb\u7845\u819c\u751f\u957f\u3002\u4f5c\u8005\u63d0\u51fa\u4e86\u5305\u62ec\u6210\u6838\uff0c\u5c9b\u5f62\u6210\uff0c\u5c9b\u805a\u96c6\u548c\u6210\u819c\u7684\u56db\u6b65\u751f\u957f\u673a\u5236\u3002\u63ba\u6742Sn\u7684\u7845\u819c\u5177\u6709\u5149\u6d3b\u6027\uff0c\u6d4b\u5f97\u7684PEC\u5149\u7535\u6d41\u7ea6\u4e3a\u5546\u7528n\u578b\u591a\u6676\u7845\u6676\u7247\u768438\u301c44\uff05\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5<\/strong>\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/adfm.201703551\/full\" target=\"_blank\" rel=\"noopener\">Liquid-Tin-Assisted Molten Salt Electrodeposition of Photoresponsive n-Type Silicon Films<\/a> (Adv.Funct.Mater., 2017, DOI: 10.1002\/adfm.201703551)<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u4eba\u7ec4\u8521\u51a0\u5b87\u7f16\u8bd1\uff0c\u9648\u70b3\u65ed\u5ba1\u6838\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u7531\u7194\u76d0\u7535\u6c89\u79ef\u6cd5\u76f4\u63a5\u751f\u4ea7\u7845\u819c\uff0c\u5de5\u827a\u7b80\u5355\uff0c\u751f\u4ea7\u6210\u672c\u4f4e\uff0c\u5728\u5236\u9020\u5149\u4f0f\u548c\u5149\u7535\u5b50\u5668\u4ef6\u65b9\u9762\u5177\u6709\u5b9e\u7528\u6027\u3002\u5df2\u7ecf\u8bc1\u660e\u5728650\u2103\u7684\u7194\u878dKCl-KF-1mol\uff05K2SiF6\u76d0&#8230;<\/p>\n","protected":false},"author":230,"featured_media":112377,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2560],"class_list":["post-112371","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-2560"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/112371"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=112371"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/112371\/revisions"}],"predecessor-version":[{"id":112435,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/112371\/revisions\/112435"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/112377"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=112371"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=112371"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=112371"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}