{"id":113123,"date":"2017-11-22T06:30:43","date_gmt":"2017-11-21T22:30:43","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=113123"},"modified":"2017-11-21T21:50:45","modified_gmt":"2017-11-21T13:50:45","slug":"%e5%8c%97%e4%ba%ac%e5%b7%a5%e4%b8%9a%e5%a4%a7%e5%ad%a6%e5%b0%89%e6%b5%b7%e5%86%9bnano-energy%ef%bc%9a%e5%8f%af%e5%85%85%e7%94%b5%e9%92%a0%e7%a6%bb%e5%ad%90%e7%94%b5%e6%b1%a0%e7%9a%84%e4%b8%89%e7%9b%b8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=113123","title":{"rendered":"\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u5c09\u6d77\u519bNano Energy\uff1a\u53ef\u5145\u7535\u94a0\u79bb\u5b50\u7535\u6c60\u7684\u4e09\u76f8\u7535\u6781\u6027\u80fd\u8c03\u6574"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u76ee\u524d\uff0c\u5546\u4e1a\u5316\u7684LIBs\u7684\u80fd\u91cf\u5bc6\u5ea6\u4ecd\u7136\u4e0d\u8db3\u4ee5\u6ee1\u8db3\u73b0\u4ee3\u793e\u4f1a\u4e0d\u65ad\u589e\u957f\u7684\u9700\u6c42\u3002\u5f53\u4e0b\u7684\u7535\u6781\u4e3b\u8981\u662f\u5177\u6709\u5355\u4e00\u7ed3\u6784\u7684\u4f20\u7edf\u6c27\u5316\u7269\uff0c\u8868\u73b0\u51fa\u6709\u9650\u7684\u53ef\u9006\u5bb9\u91cf\u3002\u8fd1\u5e74\u6765\uff0c\u590d\u5408\u7ed3\u6784\u6750\u6599\u7531\u4e8e\u63d0\u9ad8\u4e86\u7535\u5316\u5b66\u6027\u80fd\uff0c\u590d\u5408\u7ed3\u6784\u6750\u6599\u53d7\u5230\u4e86\u66f4\u591a\u7684\u5173\u6ce8\u3002\u4e0e\u5355\u7ed3\u6784\u6750\u6599\u76f8\u6bd4\uff0c\u590d\u5408\u7ed3\u6784\u6750\u6599\u5177\u6709\u4f18\u4e8e\u5c01\u95ed\u7ed3\u6784\u7684\u4f18\u70b9\uff0c\u4f7f\u5176\u6210\u4e3a\u5145\u7535\u7535\u6c60\u6709\u524d\u666f\u7684\u7535\u6781\u7cfb\u7edf\u3002\u7136\u800c\uff0c\u7531\u4e8e\u590d\u5408\u7ed3\u6784\u6750\u6599\u5408\u6210\u8fc7\u7a0b\u7684\u590d\u6742\u6027\u4ee5\u53ca\u96be\u4ee5\u8868\u5f81\uff0c\u5728\u6b64\u65b9\u9762\u7684\u5de5\u4f5c\u8fd8\u5f88\u5c11\u3002<\/p>\n

\u00a0<\/strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5728\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u5c09\u6d77\u519b\u6559\u6388\u7684\u5e26\u9886\u4e0b\uff0c\u7f8e\u56fd\u963f\u8d21\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u548c\u4e2d\u56fd\u79d1\u5b66\u9662\u7269\u7406\u7814\u7a76\u6240\u5408\u4f5c\uff0c\u9009\u62e9P2-Na2\/3<\/sub>Ni1\/3<\/sub>Ti2\/3<\/sub>O2<\/sub>\u4f5c\u4e3a\u6a21\u578b\u6750\u6599\u6765\u7cfb\u7edf\u5730\u7814\u7a76\u590d\u5408\u7ed3\u6784\u6750\u6599\uff0c\u9996\u6b21\u6210\u529f\u8bbe\u8ba1\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u4e09\u76f8\u7279\u6027\u7684\u590d\u5408\u7ed3\u6784\u7535\u6781\u6750\u6599\uff1aNa2\/3<\/sub>Ni1\/3-x<\/sub> Fex<\/sub>Ti2\/3<\/sub>O2<\/sub>\uff080\u2264x\u22641\/ 3\uff09\u901a\u8fc7\u539f\u4f4d\u9ad8\u6e29X\u5c04\u7ebf\u884d\u5c04\uff08\u539f\u4f4dHTXRD\uff09\u5206\u6790\u3002\u540c\u65f6\u4e5f\u901a\u8fc7\u539f\u4f4d\u7535\u5316\u5b66X\u5c04\u7ebf\u884d\u5c04\uff08\u539f\u4f4d EXRD\uff09\u7814\u7a76\u4e86Na+<\/sup>\u5728\u4e0d\u540c\u7ed3\u6784\u4e2d\u7684\u5d4c\u5165\/\u8131\u5d4c\u673a\u5236\u3002\u4f5c\u4e3aNIB\u7684\u7535\u6781\u6750\u6599\uff0c\u4e24\u79cd\u6d3b\u6027\u7ed3\u6784\uff08P2-Na2\/3<\/sub>Ni1\/3<\/sub>Ti2\/3<\/sub>O2<\/sub>\u548ctunnel-\u96a7\u9053Na2.65<\/sub>Ti3.35<\/sub>Fe0.65<\/sub>O9<\/sub>\uff09\u63d0\u4f9b\u53ef\u9006\u5bb9\u91cf\u548c\u975e\u6d3b\u6027\u7ed3\u6784\uff08tunnel-\u96a7\u9053NaFeTiO4<\/sub>\uff09\u88ab\u8ba4\u4e3a\u662f\u7f13\u89e3Na+<\/sup>\u5d4c\u5165\/\u8131\u5d4c\u8fc7\u7a0b\u4e2d\u7684\u5185\u90e8\u5e94\u529b\u3002\u4e09\u79cd\u7ed3\u6784\u76f8\u4e92\u5e73\u8861\u4ee5\u63d0\u9ad8\u7535\u5316\u5b66\u6027\u80fd\u3002\u57281C\u500d\u7387\u4e0b\uff0c\u7ecf\u8fc71500\u5708\u5faa\u73af\u540e\uff0c\u4f18\u5316\u7684\u590d\u5408\u6750\u6599\u7ed3\u6784\u6750\u6599\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u4ecd\u8fbe\u5230\u4e8686.5\uff05\uff0c\u5177\u6709\u826f\u597d\u7684\u6027\u80fd\u8868\u73b0\u3002\u8fd9\u9879\u5de5\u4f5c\u4e0d\u4ec5\u5c55\u793a\u4e86\u5177\u6709\u826f\u597d\u7efc\u5408\u6027\u80fd\u7684NIB\u4e09\u76f8\u590d\u5408\u7ed3\u6784\u6750\u6599\uff0c\u800c\u4e14\u4e3a\u672a\u6765\u9ad8\u7ea7\u7535\u6c60\u7cfb\u7edf\u4e2d\u7684\u9ad8\u6027\u80fd\u7535\u6781\u6750\u6599\u7684\u590d\u5408\u7ed3\u6784\u7684\u8bbe\u8ba1\u548c\u8c03\u6574\u5f00\u8f9f\u4e86\u65b0\u7684\u9886\u57df\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cTriphase electrode performance adjustment for rechargeable ion batteries\u201d\u53d1\u8868\u5728\u4e86Nano Energy\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1.<\/strong>\u539f\u4f4d<\/strong>HTXRD<\/strong>\u5206\u6790\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u539f\u4f4dHTXRD\u4ece\u5ba4\u6e29\u52301000\u2103\u76842D XRD\u56fe\u7684\u7b49\u503c\u7ebf\u56fe\uff1b<\/p>\n

\uff08b\uff09HTXRD\u6a21\u5f0f\u7684\u4e8c\u7ef4\u534f\u65b9\u5dee\u5206\u6790\u7684\u7b49\u503c\u7ebf\u56fe\uff1b<\/p>\n

\uff08c\uff09HTXRD\u6a21\u5f0f\u7684\u4e00\u7ef4\u534f\u65b9\u5dee\u5206\u6790\u7684\u7b49\u503c\u7ebf\u56fe\uff1b<\/p>\n

\uff08d\uff09Na2<\/sub>CO3<\/sub>\u6d88\u5931\u548cNa4<\/sub>Ti5<\/sub>O12<\/sub>\u751f\u6210\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

\uff08e\uff09P2\u7ed3\u6784\u751f\u6210\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

\uff08f\uff09Na4<\/sub>Ti5<\/sub>O12<\/sub>\u7ed3\u6784\u6d88\u5931\u4ee5\u53caT1\u7ed3\u6784\u751f\u6210\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

\uff08g\uff09Na4<\/sub>Ti5<\/sub>O12<\/sub>\u7ed3\u6784\u6d88\u5931\u4ee5\u53caT2\u7ed3\u6784\u751f\u6210\u7684XRD\u56fe\u8c31\u3002<\/p>\n

\u56fe<\/strong>2.<\/strong>\u6837\u54c1\u7684\u7ed3\u6784\u548c\u5fae\u89c2\u5f62\u6001<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u572810\u00b0\u81f390\u00b0\u76842\u03b8\u503c\u7684\u8303\u56f4\uff0c10\u00b0min-1<\/sup>\u7684\u626b\u63cf\u901f\u7387\u5185\u6536\u96c6\u7684NNFT\u6750\u6599\uff08x = 0,1\/12,1\/6,1\/4\u548c1\/3\uff09\uff1b<\/p>\n

\uff08b\uff09\u6240\u6709\u6837\u54c1\u7684\u76f8\u5e94SEM\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong>3. NNFT<\/strong>\u6750\u6599\u4e2d\u5305\u542b\u7684\u7ed3\u6784\u548c\u7cbe\u4fee\u7ed3\u679c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-c\uff09P2\uff08a\uff09\u7ed3\u6784\uff0cT1\uff08b\uff09\u7ed3\u6784\u548cT2\uff08c\uff09\u7ed3\u6784\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08d-f\uff09P2\uff08d\uff09\u7ed3\u6784\uff0cT1\uff08e\uff09\u7ed3\u6784\u548cT2\uff08f\uff09\u7ed3\u6784\u7684TEM\u56fe\uff0c\u63d2\u56fe\uff1aP2\uff0cT1\u548cT2\u7ed3\u6784\u7684\u5085\u7acb\u53f6\u53d8\u6362\u56fe\u50cf\uff1b<\/p>\n

\uff08g\uff09NNFT\uff08x = 1\/6\uff09\u6750\u6599\u7684Rietveld\u7cbe\u4fee\u7ed3\u679c\u56fe\uff1b<\/p>\n

\uff08h\uff09\u4f5c\u4e3aFe\u542b\u91cf\u51fd\u6570\u7684NNFT\u6750\u6599\u4e2d\u5305\u542b\u7684\u4e09\u79cd\u7ed3\u6784\u7684\u6bd4\u4f8b\u3002\u6837\u54c1\u88ab\u8bc6\u522b\u4e3aS\uff08<\/sub>P2 \/ T1 \/ T2<\/sub>\uff09<\/sub>\uff0c\u5176\u4e2d\u201cS\u201d\u4ee3\u8868\u201c\u6837\u54c1\u201d\uff0c\u4e0b\u6807P2\uff0cT1\u548cT2\u4ee3\u8868\u6837\u54c1\u7ed3\u6784\u7684\u767e\u5206\u6570\u3002<\/p>\n

\u56fe<\/strong>4.<\/strong>\u94a0\u50a8\u5b58\u6027\u80fd<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u4e0d\u540c\u6837\u54c1\u7684\u4e09\u76f8\uff08S\uff08<\/sub>100\/0\/0<\/sub>\uff09<\/sub>\uff0cS\uff08<\/sub>75\/11\/14<\/sub>\uff09<\/sub>\uff0cS\uff08<\/sub>46\/21\/33<\/sub>\uff09<\/sub>\uff0cS\uff08<\/sub>23\/35\/42<\/sub>\uff09<\/sub>\u548cS\uff08<\/sub>4\/46\/50<\/sub>\uff09<\/sub>\uff09\u7684\u7b2c\u4e00\u5708\u653e\u7535\u66f2\u7ebf\u56fe\u3002\u6bcf\u4e2a\u6837\u54c1\u90fd\u6709\u4e24\u4e2a\u660e\u663e\u7684\u7535\u538b\u5e73\u53f0\uff1b<\/p>\n

\uff08b\uff09\u6240\u6709\u6837\u54c1\u4e2d\u6bcf\u4e2a\u7535\u538b\u5e73\u53f0\u7684\u76f8\u5e94\u5bb9\u91cf\uff1b<\/p>\n

\uff08c\uff09\u6240\u6709\u6837\u54c1\u7684\u5faa\u73af\u4f0f\u5b89\u66f2\u7ebf\u3002\u6bcf\u4e2a\u6837\u54c1\u4e2d\u6709\u4e24\u4e2a\u660e\u663e\u7684\u5cf0\uff0c\u5bf9\u5e94\u4e8ea\u4e2d\u7684\u4e24\u4e2a\u7535\u538b\u5e73\u53f0\u3002<\/p>\n

\u56fe<\/strong>5. Na +<\/sup><\/strong>\u5d4c\u5165<\/strong>\/<\/strong>\u8131\u5d4c\u8fc7\u7a0b\u4e2d\u7684\u7ed3\u6784\u6f14\u53d8\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09\u5bf9\u4e8eS\uff0846\/21\/33\uff09\uff0c\u524d\u4e09\u5708\u5faa\u73af\u76842D\u539f\u4f4dXRD\u56fe\uff08a\uff09\u548c\u5bf9\u5e94\u7684\u5145\u7535\/\u653e\u7535\u66f2\u7ebf\uff08b\uff09\u7684\u7b49\u503c\u7ebf\u56fe\uff1b<\/p>\n

\uff08c-e\uff09\u524d\u4e09\u5708\u5faa\u73af\uff08c\uff09\u548c\u7b2c\u4e8c\u5708\u5faa\u73af\uff08d\uff09\u4e2d\u663e\u793aT1\uff08004\uff09\u548cP2\uff08002\uff09\u5cf0\u7684XRD\u56fe\u3002T2\uff08102\uff09\uff0c\uff08200\uff09\u5cf0\uff08e\uff09\u7684XRD\u56fe\uff1b<\/p>\n

\uff08f-h\uff09T1\uff08f\uff09\u7ed3\u6784\uff0cP2\uff08g\uff09\u7ed3\u6784\u548cT2\uff08h\uff09\u7ed3\u6784\u7684a\u548cc\u8f74\u7684\u6676\u683c\u53c2\u6570\uff1b<\/p>\n

\uff08i\uff09\u524d\u4e09\u5708\u5faa\u73af\u4e09\u79cd\u7ed3\u6784\u7684\u603b\u4f53\u79ef\u53d8\u5316\u3002<\/p>\n

\u56fe<\/strong>6.<\/strong>\u94a0\u50a8\u5b58\u673a\u5236\u548c\u8c03\u6574<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09Na+<\/sup>\u50a8\u5b58\u673a\u5236\u7684\u793a\u610f\u56fe\u3002\u5728\u653e\u7535\u8fc7\u7a0b\u4e2d\uff0cNa+<\/sup>\u4f1a\u5d4c\u5165\u5230T1\u7ed3\u6784\u4e2d\uff0c\u7136\u540e\u518d\u5d4c\u5165\u5230P2\u7ed3\u6784\u4e2d\uff0c\u8fd9\u4e2a\u8fc7\u7a0b\u5728\u63a5\u4e0b\u6765\u7684\u5145\u7535\u8fc7\u7a0b\u4e2d\u53ef\u4ee5\u9006\u8f6c\u3002<\/p>\n

\uff08b\uff09\u901a\u8fc7\u6539\u53d8T1\uff0cP2\u548cT2\u7ed3\u6784\u7684\u767e\u5206\u6570\u6765\u8c03\u8282\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n

\uff08c\uff09\u4f18\u5316S\uff0846\/21\/33\uff09\u7684\u957f\u5468\u671f\u6027\u80fd\u3002<\/p>\n

\u3010\u5c0f\u7ed3<\/strong>\u3011<\/p>\n

\u8be5\u5de5\u4f5c\u7684\u521b\u65b0\u4e4b\u5904\u5728\u4e8e\u63d0\u51fa\u4e86\u4e00\u79cd\u8bbe\u8ba1\u590d\u5408\u7535\u6781\u6750\u6599\u7ed3\u6784\u7684\u6709\u6548\u9014\u5f84\u3002\u8fd9\u4e9b\u6750\u6599\u901a\u8fc7\u63a7\u5236\u5176\u6676\u4f53\u7ed3\u6784\u548c\u8c03\u6574\u5176\u7ed3\u6784\u6bd4\u4f8b\u53ef\u4ee5\u5b9e\u73b0\u826f\u597d\u7684\u957f\u671f\u7535\u5316\u5b66\u6027\u80fd\u3002\u672c\u6587\u5408\u6210\u5e76\u7814\u7a76\u4e86\u4e00\u7cfb\u5217NIBs\u9633\u6781\u6750\u6599\u53ef\u63a7\u7ed3\u6784\u7684\u8fc7\u6e21\u91d1\u5c5e\u6c27\u5316\u7269\u590d\u5408\u6750\u6599\u3002\u5728\u5145\u7535\/\u653e\u7535\u66f2\u7ebf\u4e2d\u53ef\u89c1\u4e24\u4e2a\u660e\u663e\u7684\u7535\u538b\u5e73\u53f0\uff0c\u5bf9\u5e94\u4e8eT1\u548cP2\u7ed3\u6784\u3002\u8be5\u539f\u4f4dEXRD\u6570\u636e\u8868\u660eNa+<\/sup>\u5728\u653e\u7535\u671f\u95f4\u5148\u5d4c\u5165T1\u7ed3\u6784\uff0c\u7136\u540e\u518d\u5d4c\u5165P2\u7ed3\u6784\uff0c\u5e76\u4e14\u5728\u540e\u9762\u5145\u7535\u65f6\u53ef\u4ee5\u88ab\u9006\u8f6c\u3002\u975e\u7535\u5316\u5b66\u7684T2\u7ed3\u6784\u5bf9\u4e8e\u5728\u5faa\u73af\u671f\u95f4\u7a33\u5b9a\u6574\u4e2a\u7ed3\u6676\u6846\u67b6\u662f\u91cd\u8981\u7684\u3002S\uff08<\/sub>46\/21\/33<\/sub>\uff09<\/sub>\u6750\u6599\uff0846\uff05P2\uff09\u7684\u5bb9\u91cf\u4fdd\u6301\u7387\u662f\u6700\u4f73\u7684\uff0c\u5e76\u4e14\u57281C\u500d\u7387\u4e0b\u5faa\u73af1500\u5708\u540e\u4e3a86.5\uff05\u3002\u8fd9\u9879\u5de5\u4f5c\u5f00\u8f9f\u4e86\u4e00\u4e2a\u65b0\u7684\u65b9\u6cd5\u6765\u8c03\u6574\u7535\u5316\u5b66\u6027\u80fd\u8bbe\u8ba1\u590d\u5408\u7ed3\u6784\u7535\u6781\u6750\u6599\u7684NIBs\u4ee5\u53ca\u672a\u6765\u7684\u5148\u8fdb\u7535\u6c60\u7cfb\u7edf\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5<\/strong>\uff1a<\/strong>Triphase electrode performance adjustment for rechargeable ion batteries <\/a>\uff08Nano Energy, 2017, DOI\uff1a10.1016\/j.nanoen.2017.11.006\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u4eba\u7ec4\u6728\u6587\u97ec\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1a<\/strong>RDD-2011-CHERISH<\/strong>\uff0c<\/strong>\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

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