{"id":113305,"date":"2017-11-23T06:30:03","date_gmt":"2017-11-22T22:30:03","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=113305"},"modified":"2017-11-21T21:50:16","modified_gmt":"2017-11-21T13:50:16","slug":"%e6%a5%bc%e9%9b%84%e6%96%87angew-chem-int-ed-%e4%bb%8b%e5%ad%94%e7%a2%b3%e6%b0%ae%e5%8c%96%e9%92%9b%e7%a9%ba%e5%bf%83%e7%90%83%e4%bd%9c%e4%b8%ba%e9%ab%98%e6%95%88ses2%e8%bd%bd%e4%bd%93%e7%94%a8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=113305","title":{"rendered":"\u697c\u96c4\u6587Angew. Chem. Int. Ed. : \u4ecb\u5b54\u78b3@\u6c2e\u5316\u949b\u7a7a\u5fc3\u7403\u4f5c\u4e3a\u9ad8\u6548SeS2\u8f7d\u4f53\u7528\u4e8e\u5148\u8fdbLi-SeS2 \u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u4f5c\u4e3a\u65b0\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\uff0c\u786b\u53d7\u5230\u4e86\u4e1a\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5176\u8f83\u4f4e\u7535\u5bfc\u7387\u4ee5\u53caS\u548cLi2<\/sub>S\u8f83\u5dee\u7684\u53cd\u5e94\u6d3b\u6027\u9650\u5236\u4e86\u5176\u8fdb\u4e00\u6b65\u63d0\u9ad8\u7535\u6c60\u7684\u6027\u80fd\u3002\u76f8\u6bd4\u4e8e\u786b\uff0c\u7852\u5177\u6709\u66f4\u9ad8\u7684\u7535\u5bfc\u7387\u4ee5\u53ca\u4e0e\u78b3\u9178\u916f\u57fa\u7535\u89e3\u8d28\u66f4\u597d\u7684\u76f8\u5bb9\u6027\uff0c\u4e00\u7cfb\u5217\u7852\u57fa\u6b63\u6781\u7684\u5bff\u547d\u5f97\u5230\u663e\u8457\u5ef6\u957f\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u4e0eLi-S\u7535\u6c60\u76f8\u6bd4\uff0cLi-Se\u7535\u6c60\u53c8\u5b58\u5728\u4e00\u4e9b\u4e0d\u53ef\u907f\u514d\u7684\u65b0\u95ee\u9898\u3002\u7531\u4e8e\u7852\u7684\u6469\u5c14\u8d28\u91cf\u8f83\u5927\uff0c Li-Se\u7535\u6c60\u7684\u91cd\u91cf\u80fd\u91cf\u5bc6\u5ea6\u6bd4Li-S\u7535\u6c60\u7684\u4e00\u534a\u8fd8\u5c0f\u3002\u6b64\u5916\uff0c\u7852\u7684\u6210\u672c\u8f83\u9ad8\uff0c\u9650\u5236\u5176\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u7684\u5927\u89c4\u6a21\u5e94\u7528\u3002\u5411\u542b\u786b\u6b63\u6781\u5f15\u5165\u4e00\u5b9a\u6bd4\u4f8b\u7684\u7852\u662f\u4e00\u79cd\u63d0\u9ad8\u7535\u6c60\u7efc\u5408\u6027\u80fd\u7684\u6709\u6548\u7b56\u7565\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u697c\u96c4\u6587\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u626cSeS2<\/sub>\u4e4b\u957f\uff0c\u907fSeS2<\/sub>\u4e4b\u77ed\uff0c\u8bbe\u8ba1\u5e76\u5408\u6210\u4e86\u4e00\u79cd\u4e2d\u7a7a\u4ecb\u5b54\u78b3@\u6c2e\u5316\u949b(HMC@TiN)\u4f5c\u4e3aSeS2<\/sub>\u8f7d\u4f53\u7528\u4e8eLi-SeS2<\/sub>\u7535\u6c60\u8d1f\u6781\u6750\u6599\uff0c\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cMesoporous Carbon@Titanium Nitride Hollow Spheres as an Efficient SeS2<\/sub> Host for Advanced Li-SeS2<\/sub> Batteries<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u8bba\u6587\u88ab\u9009\u4e3a\u70ed\u70b9\u8bba\u6587\u3002<\/strong>\u53d7\u76ca\u4e8e\u7a7a\u5fc3\u4ecb\u5b54\u78b3\u548cTiN\u7684\u7269\u7406\u548c\u5316\u5b66\u53cc\u91cd\u8bf1\u6355\uff0cHMC@TiN\/SeS2<\/sub>\u6b63\u6781\u6d3b\u6027\u7269\u8d28\u7684\u5229\u7528\u7387\u8f83\u9ad8\uff0c\u5faa\u73af\u7a33\u5b9a\u6027\u826f\u597d\u3002\u6b64\u5916\uff0c\u5728\u9ad8\u8d1f\u8f7d\u91cf\u7535\u6781\u7684\u60c5\u51b5\u4e0b\uff0c\u5176\u9762\u79ef\u5bb9\u91cf\u8f83\u9ad8(4 mAh\u00b7cm-2<\/sup>)\u4e14\u7535\u6c60\u6027\u80fd\u7a33\u5b9a\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 HMC@TiN\u7684\u5408\u6210\u4e0e\u5bf9\u591a\u786b\/\u7852\u5316\u7269\u6d41\u5931\u7684\u63a7\u5236<\/strong><\/p>\n

\"\"<\/p>\n

a) HMC@TiN \u7684\u5408\u6210\u8fc7\u7a0b\uff1b<\/p>\n

b) \u5728\u6709TiN\u58f3\u5c42\u65f6\uff0c\u5faa\u73af\u65f6\u53ef\u6eb6\u6027\u7684\u591a\u786b\/\u7852\u5316\u7269\u88ab\u6709\u6548\u7684\u9650\u5236\u4e8e\u8f7d\u4f53\u4e2d\uff1b<\/p>\n

c) \u5728\u7eaf\u7684HMC\/SeS2<\/sub>\u590d\u5408\u7269\u4e2d\uff0c\u5faa\u73af\u65f6\u4e2d\u95f4\u4ea7\u7269\u4f1a\u4ece\u78b3\u57fa\u8f7d\u4f53\u9038\u51fa\u3002<\/p>\n

\u56fe2 HMC@TiN\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a,b) HMC@TiN\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

c,e,f) HMC@TiN\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

d) HMC@TiN\u7684EDX\u80fd\u8c31\uff1b<\/p>\n

g) HMC@TiN\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

h) HMC@TiN\u7684XRD\u56fe\u8c31\uff1b<\/p>\n

i,j) HMC\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

k,l) HMC\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe3 HMC@TiN\/SeS2<\/sub>\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a,b) HMC@TiN\/SeS2<\/sub>\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

c,d) HMC@TiN\/SeS2<\/sub>\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

e) HMC@TiN\/SeS2<\/sub>\u7684EDX\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

f) HMC@TiN\/SeS2<\/sub>\u7684\u7ebf\u6027EDX\u626b\u63cf\u3002<\/p>\n

g) HMC\/SeS2<\/sub>\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

h,i) HMC\/SeS2<\/sub>\u7684TEM\u56fe\u50cf\u3002<\/p>\n

\u56fe4 HMC@TiN\/SeS2<\/sub>\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) 0.2 C\u4e0bHMC\/SeS2<\/sub>\u548cHMC@TiN\/SeS2<\/sub>\u5faa\u73af\u6027\u80fd\u6bd4\u8f83\uff1b<\/p>\n

b) 0.2 C\u4e0bHMC@TiN\/SeS2<\/sub>\u7684\u5145-\u653e\u7535\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n

c) \u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0bHMC@TiN\/SeS2<\/sub>\u7684\u500d\u7387\u6027\u80fd\uff1b<\/p>\n

d) \u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0bHMC@TiN\/SeS2<\/sub>\u7684\u7535\u538b\u66f2\u7ebf\uff1b<\/p>\n

e) \u9ad8SeS2<\/sub>\u8d1f\u8f7d\u91cf(5 mg\u00b7cm-2<\/sup>)\u4e0b\uff0cHMC@TiN\/SeS2<\/sub>\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

f) \u9ad8SeS2<\/sub>\u8d1f\u8f7d\u91cf(5 mg\u00b7cm-2<\/sup>)\u4e0b\uff0cHMC@TiN\/SeS2<\/sub>\u7684\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u5408\u6210\u4e86HMC@TiN\/SeS2<\/sub>\u5e76\u5c06\u5176\u4f5c\u4e3a\u65b0\u7684\u6b63\u6781\u6750\u6599\u7528\u4e8eLi-SeS2<\/sub>\u7535\u6c60\u3002\u53d7\u76ca\u4e8eSeS2<\/sub>\u7684\u56fa\u6709\u4f18\u52bf\u548c\u8f7d\u4f53\u6750\u6599\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0cHMC@TiN\/SeS2<\/sub>\u6b63\u6781\u663e\u793a\u51fa\u826f\u597d\u7684\u5faa\u73af\u5bff\u547d\u548c\u500d\u7387\u6027\u80fd\uff0c\u5728\u9ad8\u8d1f\u8f7d\u91cf\u7535\u6781\u4e0b\u9762\u79ef\u5bb9\u91cf\u8f83\u5927\u3002\u867d\u7136\u5728\u8be5\u6587\u4e2d\u7684\u9762\u79ef\u5bb9\u91cf\u76f8\u6bd4\u5176\u4ed6\u62a5\u9053\u4ecd\u6709\u4e0d\u8db3\uff0c\u4f46\u76ee\u524d\u7684\u7ed3\u679c\u8868\u660e\u4e0a\u8ff0\u65b0\u578bSex<\/sub>Sy<\/sub>\u57fa\u6b63\u6781\u5728\u4e0b\u4e00\u4ee3\u53ef\u5145\u7535\u7535\u6c60\u4e2d\u663e\u793a\u51fa\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u76f8\u4fe1\u901a\u8fc7\u5bf9\u7535\u6781\/\u7535\u6c60\u7684\u7ed3\u6784\u548c\u6210\u5206\u8fdb\u4e00\u6b65\u4f18\u5316\uff0c\u5982\u9009\u62e9\u9002\u5f53\u7684\u7c98\u7ed3\u5242\u3001\u91c7\u7528\u63d2\u5c42\u7ed3\u6784\u4ee5\u53ca\u5e94\u7528\u56fa\u6001\u7535\u89e3\u8d28\uff0c\u5728\u4e0d\u4e45\u7684\u5c06\u6765Sex<\/sub>Sy<\/sub>\u57fa\u6b63\u6781\u5c06\u5177\u6709\u66f4\u4f18\u5f02\u7684\u6027\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Mesoporous Carbon@Titanium Nitride Hollow Spheres as an Efficient SeS2<\/sub> Host for Advanced Li\u2013SeS2<\/sub> Batteries<\/a>\u00a0<\/strong>(Angew. Chem. Int. Ed., 2017, DOI: 10.1002\/anie.201709176)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/a><\/strong>\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u4f5c\u4e3a\u65b0\u4e00\u4ee3\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u7535\u6c60\u7684\u6b63\u6781\u6750\u6599\uff0c\u786b\u53d7\u5230\u4e86\u4e1a\u754c\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u7136\u800c\uff0c\u5176\u8f83\u4f4e\u7535\u5bfc\u7387\u4ee5\u53caS\u548cLi2S\u8f83\u5dee\u7684\u53cd\u5e94\u6d3b\u6027\u9650\u5236\u4e86\u5176\u8fdb\u4e00\u6b65\u63d0\u9ad8\u7535\u6c60\u7684\u6027\u80fd\u3002\u76f8\u6bd4\u4e8e\u786b\uff0c\u7852…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-113305","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/113305"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=113305"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/113305\/revisions"}],"predecessor-version":[{"id":113424,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/113305\/revisions\/113424"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=113305"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=113305"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=113305"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}