{"id":114108,"date":"2017-11-29T14:00:43","date_gmt":"2017-11-29T06:00:43","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=114108"},"modified":"2017-11-27T21:09:18","modified_gmt":"2017-11-27T13:09:18","slug":"adv-eng-mater-%ef%bc%9a%e5%90%8c%e6%97%b6%e5%af%b9%e9%ab%98%e6%80%a7%e8%83%bd%e7%9a%84%e5%af%8c%e5%8b%92%e7%83%af%e5%92%8c%e9%9d%9e%e5%af%8c%e5%8b%92%e7%83%af%e7%9a%84%e5%a4%aa%e9%98%b3%e8%83%bd","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=114108","title":{"rendered":"Adv.Eng.Mater.\uff1a\u540c\u65f6\u5bf9\u9ad8\u6027\u80fd\u7684\u5bcc\u52d2\u70ef\u548c\u975e\u5bcc\u52d2\u70ef\u7684\u592a\u9633\u80fd\u7535\u6c60\u6709\u4f5c\u7528\u6027\u7684D1-A-D2-A\u968f\u673a\u5171\u805a\u7269"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u5bcc\u52d2\u70ef\u662f\u7531\u82f1\u56fdSussex\u5927\u5b66\u7684H\u00b7W\u00b7Kroto\u4e0e\u7f8e\u56fdRice\u5927\u5b66\u7684R\u00b7E\u00b7Smally\u7b49\u4e8e1985\u5e748\u6708\u4e3a\u4e86\u6a21\u62df\u661f\u9645\u5c18\u57c3\u7684\u7814\u7a76\uff0c\u4ee5\u6fc0\u5149\u7167\u5c04\u77f3\u58a8\u4f7f\u5176\u84b8\u53d1\uff0c\u84b8\u53d1\u7269\u78b3\u70df\u4e2d\u53d1\u73b0\u5404\u79cd\u542b\u6709\u5404\u79cd\u78b3\u539f\u5b50\u7c07\u5206\u5b50\uff0c\u5c06\u84b8\u53d1\u7269\u4ee5\u9ad8\u538b\u6c26\u6c14\u6d41\u9001\u5165\u8d28\u8c31\u4eea\u8fdb\u884c\u68c0\u6d4b\uff0c\u7531\u8d28\u8c31\u56fe\u53d1\u73b0\u5176\u4e2d\u5927\u90e8\u5206\u4e3aC<sub>60<\/sub>\u548c\u767e\u5206\u4e4b\u51e0\u7684C<sub>70<\/sub>\u5206\u5b50\uff0c\u540e\u6765\u53c8\u76f8\u7ee7\u6d4b\u51faC<sub>50<\/sub>\u3001C<sub>76<\/sub>\u3001C<sub>78<\/sub>\u3001C<sub>80<\/sub>\u3001C82\u3001C<sub>84<\/sub>\u3001C<sub>90<\/sub>\u3001C<sub>120<\/sub>\u3001C<sub>180<\/sub>\u3001C<sub>240<\/sub>&#8230;\u7b49\u4e00\u7cfb\u5217\u5c01\u95ed\u62e2\u5f62\u7ed3\u6784\u7684\u5206\u5b50\u3002\u56e0\u53d1\u73b0C<sub>60<\/sub>\u5206\u5b50\u7ed3\u6784\u5177\u6709\u591a\u9762\u5c01\u95ed\u7684\u5916\u5f62\u5f88\u50cf\u8db3\u7403\uff0c\u4e5f\u6210\u4e3a\u8db3\u7403\u70ef\u3002\uff1b\u8be5\u5206\u5b50\u6bd4\u8f83\u7a33\u5b9a\uff0c\u62e5\u670960\u4e2a\u9876\u70b9\u300132\u4e2a\u9762\uff0c\u5176\u4e2d\u670912\u4e2a\u6b63\u4e94\u8fb9\u5f62\u9762\u548c20\u4e2a\u6b63\u516d\u8fb9\u5f62\u9762\uff0c\u88ab\u79f0\u4f5c\u5bcc\u52d2\u70ef\u3002\u975e\u5bcc\u52d2\u70ef\u53d7\u4f53\u5177\u6709\u5438\u6536\u4e0e\u80fd\u7ea7\u53ef\u8c03\u3001\u5408\u6210\u7b80\u4fbf\u3001\u52a0\u5de5\u6210\u672c\u4f4e\u3001\u6eb6\u89e3\u6027\u80fd\u4f18\u5f02\u7b49\u7279\u70b9,\u8fd1\u5e74\u6765\u53d1\u5c55\u8fc5\u901f,\u5e76\u8d8a\u6765\u8d8a\u53d7\u4eba\u4eec\u8ba4\u53ef\u3002\u5bcc\u52d2\u70ef\u53ca\u5176\u884d\u751f\u7269\u5236\u5907\u7684\u7535\u5b50\u53d7\u4f53\u6750\u6599\u4e3a\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u9886\u57df\u7684\u53d1\u5c55\u505a\u51fa\u4e86\u5de8\u5927\u8d21\u732e\uff0c\u4f46\u8fd9\u7c7b\u6750\u6599\u4e5f\u5b58\u5728\u81ea\u8eab\u7f3a\u9677\uff0c\u5982C<sub>60<\/sub>\u3001C<sub>70<\/sub>\u7684\u5408\u6210\u53ca\u5236\u5907\u5bcc\u52d2\u70ef\u884d\u751f\u7269\u7684\u539f\u6750\u6599\u6210\u672c\u8f83\u9ad8\uff0c\u4e14\u5236\u5907\u548c\u63d0\u7eaf\u56f0\u96be\uff1b\u5728\u53ef\u89c1\u5149\u533a\u5438\u6536\u8f83\u5f31\uff0c\u4e14\u5f88\u96be\u62d3\u5bbd\u3002\u56e0\u6b64\uff0c\u7814\u7a76\u8005\u5408\u6210\u4e86\u8bb8\u591a\u975e\u5bcc\u52d2\u70ef\u805a\u5408\u7269\u548c\u5c0f\u5206\u5b50\u53d7\u4f53\u6750\u6599\u5e76\u5c06\u5176\u5e7f\u6cdb\u5e94\u7528\u5728\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\u4e2d\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>PBDB-TTn\u7684\u968f\u673a\u4f9b\u5e94\u5171\u805a\u7269\u662f\u5408\u6210\u7684\uff0c\u7531\u4e00\u79cd\u7f3a\u4e4f\u7535\u5b50\u7684\u82ef\u4e8c\u915a\uff0c1,2-c:4,5-c&#8217;\u4e8c\u786b\u915a-4\uff0c8-\u4e8c\u916e(BDD)2\u4e2a\u7535\u5b50\u7684\u5355\u4f4d\u548c\u4e0d\u540c\u7684\u6bd4\uff0c2-b:4,5-b&#8217;\u4e8c\u567b\u5429(BDT)\u548cthieno 3,2-b\u567b\u5429(TT)\u5355\u4f4d\u7ec4\u6210\uff0c\u610f\u5728\u8c03\u8282\u5185\u94fe\u548c\/\u6216\u8fde\u9501\u53cd\u5e94\uff0c\u6700\u7ec8\u662f\u7403-\u5f02\u8d28\u7ed3\u8fdb\u5316\u5f62\u6001\u3002\u75284 \u00d72\u805a\u5408\u7269\u592a\u9633\u80fd\u7535\u6c60(PSC)\u6027\u80fd\u56fe\u548c6-6-c71-\u4e01\u9178\u9178\u7532\u916f(PC71BM)\u548c\u57fa\u4e8e\u82b3\u9999\u73af\u7684\u5206\u5b50(m-itic)\u63a5\u53d7\u5668\u4e0e\u4e4b\u8fdb\u884c\u6bd4\u8f83\u7814\u7a76\u3002\u8003\u8651\u5230\u5b83\u4eec\u5438\u6536\u7684\u76f8\u4f3c\u4e4b\u5904\u8303\u56f4\u548c\u80fd\u7ea7\uff0cpbdb-ttn\u5171\u805a\u7269\u5f88\u660e\u663e\u5730\u63ed\u793a\u4e86\u4e00\u4e2a\u53d8\u5316\uff0c\u5373\u5728\u5c06BDT\u4f18\u5316\u4e3aTT\u6bd4\u65f6\u5438\u6536\u7cfb\u6570\u7684\u4e3b\u8981\u4f5c\u7528\u3002\u5728\u7ed9\u5b9a\u7684\u53d7\u4f53\u7ec4\u5408\u96c6\u5408\u4e2d\uff0c\u4f18\u8d8a\u7684\u6027\u80fd\u5728pbdb-tt5\u4e0ePC71BM\u6df7\u5408\u7684\u60c5\u51b5\u4e0b\u89c2\u5bdf\u5230(8.34 0.10%)m-itic(11.10 0.08%)\u4ee5\u53ca\u4e3b\u8981\u56e0\u7d20\u9020\u6210\u80fd\u91cf\u8f6c\u6362\u6548\u7387\u5dee\u5f02\u7684\u539f\u56e0\u662f\u622a\u7136\u4e0d\u540c\u7684\u3002\u672c\u7814\u7a76\u63d0\u4f9b\u4e86\u4e00\u79cd\u5bcc\u52d2\u70ef\u548c\u975e\u5bcc\u52d2\u70ef\u7684PSCs\u7ed3\u6784-\u5f62\u6001-\u6027\u80fd\u5173\u7cfb\u7684\u65b0\u8349\u56fe\u3002\u8be5\u6210\u679c\u7531\u851a\u5c71\u56fd\u5bb6\u79d1\u5b66\u6280\u672f\u7814\u7a76\u6240\u7684Changduk Yang\u7b49\u4ee5\u201c<strong>Feasible D1\u2013A\u2013D2\u2013A Random Copolymers for Simultaneous High-Performance Fullerene and Nonfullerene Solar Cells<\/strong>\u201d\u4e3a\u9898\u4e8e2017\u5e7411\u670814\u65e5\u53d1\u8868\u5728<strong>Advanced Engeenering Materials<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe<\/strong><strong>1.<\/strong><strong>\u56db\u79cd<\/strong><strong>PBDB-TTn\u00a0<\/strong><strong>\u805a\u5408\u7269\u901a\u8fc7<\/strong><strong>Stille<\/strong><strong>\u805a\u5408\u4f5c\u7528\u7684\u5408\u6210\u8def\u7ebf\u3002<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-114103\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/1-98.jpg\" alt=\"\" width=\"600\" height=\"619\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/1-98.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/1-98-291x300.jpg 291w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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decoding=\"async\" class=\"aligncenter size-full wp-image-114105\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/3-70.jpg\" alt=\"\" width=\"600\" height=\"456\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/3-70.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/11\/3-70-300x228.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a)4\u4e2apbdb-ttn\u5171\u805a\u7269\u7684\u5316\u5b66\u7ed3\u6784\uff0cPC71BM,m-ITIC\u3002<\/p>\n<p>b)4\u4e2apbdb-ttn\u5171\u805a\u7269\u3001PC71BM\u548cm-itic\u7684\u80fd\u7ea7\u56fe\u3002<\/p>\n<p>c) \u5728\u6c2f\u82ef\u6eb6\u6db2\u4e2dpbdb-ttn\u5171\u805a\u7269\u7684\u7d2b\u5916-vis\u5149\u8c31\u3002<\/p>\n<p>d) 4\u4e2a\u6574\u9f50\u7684\u805a\u5408\u7269\u8584\u819c\u7684uv-vis\u5438\u6536\u5149\u8c31\u3002<\/p>\n<p><strong>\u3010\u5c55\u671b\u3011<\/strong><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u5408\u6210\u5e76\u63cf\u8ff0\u4e86\u4e00\u7cfb\u5217\u7684\u4f5c\u4e3a\u7535\u5b50\u7f3a\u9677\u7684BDD\u7684pbdb-ttn\u5171\u805a\u7269\uff0c\u4e14\u5176\u662f\u4ee5\u7535\u5b50\u4e3a\u5355\u4f4d\u7684\u7535\u5b50\u548c\u7535\u5b50\u7684\u7ed3\u5408\u3002\u4e0d\u540cBDT:\u5171\u805a\u7269\u7684TT\u6210\u5206\u7531\u4e8e\u4e0d\u540c\u7684\u539f\u56e0\u5f71\u54cd\u4e86\u5b83\u4eec\u7684\u5149\u5b66\u5438\u6536\u7cfb\u6570\u5185\u90e8\u548c\/\u6216\u8fde\u9501\u53cd\u5e94\u7684\u7a0b\u5ea6\u7535\u5f71\uff0c\u800c\u4e0d\u662f\u53ea\u5f71\u54cd\u50cf\u5438\u6536\u8303\u56f4\u8fd9\u6837\u7684\u5176\u4ed6\u5c5e\u6027\uff0c\u548c\u524d\u6cbf\u80fd\u7ea7\u3002\u7814\u7a76\u53d1\u73b0\u57fa\u4e8em-itic\u7684\u5668\u4ef6\u663e\u793a\u51fa\u6bd4\u76f8\u5e94\u57fa\u4e8epc71bm1\u7684\u5668\u4ef6\u7684\u66f4\u597d\u7684PCEs\u3002\u589e\u5f3a\u7684\u5149\u4ea7\u751f\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0ePC71BM\u76f8\u6bd4\uff0c\u662f\u7531\u4e8em-itic\u66f4\u5f3a\u7684\u5438\u6536\u7387\u9020\u6210\u7684\u3002\u8fd9\u9879\u7814\u7a76\u4e0d\u4ec5\u4fc3\u8fdb\u4e86\u5bf9\u5bcc\u52d2\u70ef\u4e0e\u975e\u5bcc\u52d2\u70ef\u7684\u64cd\u4f5c\u673a\u7406\u7684\u7406\u89e3\uff0c\u5728PSCs\u4e0a\u5b83\u4e5f\u8bc1\u660e\u4e86\u968f\u673a\u5171\u805a\u7b80\u5355\u7684\u53ef\u80fd\u6027\uff0c\u5e76\u5df2\u7ecf\u6700\u5927\u9650\u5ea6\u5730\u63d0\u9ad8\u8fd9\u4e24\u79cd\u7c7b\u578b\u7684\u6027\u80fd\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/aenm.201702166\/full\" target=\"_blank\" rel=\"noopener\">Feasible D1\u2013A\u2013D2\u2013A Random Copolymers for Simultaneous High-Performance Fullerene and Nonfullerene Solar Cells<\/a><\/strong>\uff08Advanced Engineering Materials,DOI:10.1002\/aenm.201702166\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u4ed8\u94b0\u7f16\u8f91\uff0c\u9ec4\u8d85\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002\u00a0<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong>\u6d4b\u8bd5\u8c37<\/strong><\/a><strong>!<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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