{"id":115398,"date":"2017-12-11T06:30:16","date_gmt":"2017-12-10T22:30:16","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=115398"},"modified":"2017-12-11T11:30:22","modified_gmt":"2017-12-11T03:30:22","slug":"macromolecules%ef%bc%9a%e9%80%9a%e8%bf%87%e5%8e%9f%e4%bd%8d%e5%bc%95%e5%8f%91%e4%b8%99%e4%ba%a4%e9%85%af%e5%92%8c%ce%b5-%e5%b7%b1%e5%86%85%e9%85%af%e8%81%9a%e5%90%88%e7%9a%84%e7%ab%8b%e4%bd%93","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=115398","title":{"rendered":"Macromolecules\uff1a\u901a\u8fc7\u539f\u4f4d\u5f15\u53d1\u4e19\u4ea4\u916f\u548c\u03b5-\u5df1\u5185\u916f\u805a\u5408\u7684\u7acb\u4f53\u9009\u62e9\u6027\u50ac\u5316\u5242"},"content":{"rendered":"<p><strong>\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u73af\u5883\u95ee\u9898\u662f\u73b0\u5982\u4eca\u6700\u503c\u5f97\u4eba\u4eec\u5173\u6ce8\u7684\u95ee\u9898\uff0c\u9488\u5bf9\u73af\u5883\u95ee\u9898\u7279\u522b\u662f\u201c\u767d\u8272\u6c61\u67d3\u201d\uff0c\u4eba\u4eec\u628a\u76ee\u5149\u6295\u5411\u4e86\u805a\u4e73\u9178\uff08PLA\uff09\u548c\u805a\u03b5-\u5df1\u5185\u916f\uff08PCL\uff09\uff0c\u8fd9\u4e24\u79cd\u805a\u5408\u7269\u5c06\u6210\u4e3a\u6700\u5177\u524d\u666f\u7684\u751f\u7269\u5851\u6599\u4ee5\u53ca\u4f20\u7edf\u5851\u6599\u7684\u53ef\u6301\u7eed\u548c\u751f\u6001\u9ad8\u6548\u7684\u66ff\u4ee3\u54c1\u3002\u5b83\u4eec\u7684\u5e94\u7528\u9886\u57df\u53ca\u5176\u5e7f\u6cdb\uff0c\u4ece\u519c\u4e1a\u5230\u533b\u836f\u884c\u4e1a\u90fd\u80fd\u770b\u89c1\u5b83\u4eec\u7684\u8eab\u5f71\u3002PLA\u548cPCL\u53ef\u4ee5\u901a\u8fc7\u4e19\u4ea4\u916f\uff08LA\uff09\u548c\u03b5-\u5df1\u5185\u916f\uff08\u03b5-CL\uff09\u7684\u5f00\u73af\u805a\u5408\uff08ROP\uff09\u6765\u5236\u5907\uff0c\u8be5\u8fc7\u7a0b\u4e3b\u8981\u53d7\u73af\u5e94\u53d8\u7684\u9a71\u52a8\u3002<\/p>\n<p>\u800c\u91d1\u5c5e\u7edc\u5408\u7269\u662f\u4e19\u4ea4\u916f\u548c\u03b5-\u5df1\u5185\u916f\u5f00\u73af\u805a\u5408\u6700\u6709\u6548\u7684\u50ac\u5316\u5242\u4e4b\u4e00\u3002\u5404\u79cd\u91d1\u5c5e\u7edc\u5408\u7269\u5728\u6b64\u524d\u7684\u6587\u732e\u4e2d\u5747\u6709\u62a5\u9053\uff0c\u5982\uff1a\u78b1\u91d1\u5c5e\uff0c\u78b1\u571f\u91d1\u5c5e\uff0c\u8fc7\u6e21\u91d1\u5c5e\u548c\u9567\u7cfb\u5143\u7d20\u7b49\u3002\u5176\u4e2d\u94c1\u7edc\u5408\u7269\u542b\u91cf\u4e30\u5bcc\uff0c\u6bd2\u6027\u4f4e\uff0c\u751f\u7269\u76f8\u5bb9\u6027\u597d\uff0c\u662f\u5f00\u73af\u805a\u5408\u50ac\u5316\u5242\u7684\u6700\u4f73\u9009\u62e9\u3002\u5728\u6b64\u57fa\u7840\u4e4b\u4e0a\uff0c\u7814\u7a76\u4eba\u5458\u5f00\u53d1\u51fa\u4e86\u4e00\u7cfb\u5217Salen-\u6c2f\u5316\u94c1\uff08III\uff09\u7edc\u5408\u7269\u7528\u4e8e\u5236\u5907\u7a33\u5b9a\uff0c\u6d3b\u6027\u9ad8\u4ee5\u53ca\u73af\u5883\u53cb\u597d\u7684\u5185\u916f\u5f00\u73af\u805a\u5408\u7684\u5f15\u53d1\u5242\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5\uff0c\u6765\u81ea<strong>\u4e2d\u79d1\u9662\u957f\u6625\u5e94\u7528\u5316\u5b66\u7814\u7a76\u6240<\/strong>\u7684<strong>\u5e9e\u70dc\u526f\u7814\u7a76\u5458\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7b49\u4eba\u5728\u8fd1\u671f\u7684<strong>Macromolecules<\/strong>\u671f\u520a\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201c<strong>Air-Stable Salen\u2212Iron Complexes: Stereoselective Catalysts for Lactide and \u03b5\u2011Caprolactone Polymerization through in Situ Initiation<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u6587\u7ae0\u4e3b\u8981\u4ecb\u7ecd\u4e86\u4e00\u79cd\u901a\u8fc7\u539f\u4f4d\u5f15\u53d1\u4e19\u4ea4\u916f\u548c\u03b5-\u5df1\u5185\u916f\u805a\u5408\u7684\u7acb\u4f53\u9009\u62e9\u6027\u50ac\u5316\u5242\u7684\u5236\u5907\u65b9\u6cd5\u3002\u7814\u7a76\u4eba\u5458\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u57fa\u4e8e\u5e2d\u592b\u78b1\u9aa8\u67b6\u7684\u6c2f\u5316\u94c1\uff08III\uff09\u914d\u5408\u7269\uff0c\u8fd9\u79cd\u914d\u5408\u7269\u80fd\u591f\u5728\u6c27\u5316\u4e19\u70ef\uff08PO\uff09\u7684\u5b58\u5728\u4e0b\u9ad8\u6548\u50ac\u5316\u4e19\u4ea4\u916f\u548c\u03b5-\u5df1\u5185\u916f\u7684\u805a\u5408\uff0c\u5176\u50ac\u5316\u6548\u7387\u8fdc\u8fdc\u8d85\u8fc7\u4e86\u4f20\u7edf\u7684\u94dd\u7c7b\u4f3c\u7269\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1 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\/><\/a><\/p>\n<p>\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u901a\u8fc7\u5904\u7406\u6c2f\u5316\u94c1\u548c\u5316\u5b66\u8ba1\u91cf\u76f8\u5e94\u7684\u914d\u4f53\u5728\u7532\u9187\u4e2d\u5236\u5907\u4e86\u914d\u5408\u72691-8a\u3002X\u5c04\u7ebf\u7ed3\u6784\u5206\u6790\u8868\u660e\u914d\u5408\u72692a\u548c3a\u5728Fe\u4e2d\u5fc3\u5468\u56f4\u6709\u4e94\u4e2a\u914d\u4f4d\uff0c\u800c\u4e94\u914d\u4f4d\u91d1\u5c5e\u7edc\u5408\u7269\u7ed3\u6784\u7684\u5f62\u6210\u901a\u5e38\u5f52\u56e0\u4e8e\u4e24\u7c7b\u51e0\u4f55\u6784\u578b\uff1a\u56db\u65b9\u9525(sqp)\u6216\u4e09\u89d2\u53cc\u9525(tbp)\u6784\u578b\u4ee5\u53ca\u7528\u6765\u63cf\u8ff0\u4e24\u7c7b\u6784\u578b\u590d\u6742\u7a0b\u5ea6\u7684\u53c2\u6570\u03c4\u3002\u5f53\u03c4\u4e3a0\u65f6\uff0c\u7edc\u5408\u7269\u53d6sqp\u6784\u578b\uff0c\u800c\u5f53\u03c4\u4e3a1\u65f6\u5219\u53d6tbp\u6784\u578b\u3002\u4e3a\u4e86\u6e05\u695a\u8d77\u89c1\uff0c\u4e0a\u56fe\u7701\u7565\u4e86\u65e0\u5e8f\u5206\u5b50\u548c\u6c22\u539f\u5b50\u3002<\/p>\n<p><strong>\u56fe2 \u914d\u5408\u72695a\u7684X\u5c04\u7ebf\u7ed3\u6784\u5206\u6790<\/strong><\/p>\n<p style=\"text-align: center;\"><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/2-0.png\"><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-116616 size-full\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/2-0.png\" alt=\"\" width=\"700\" height=\"387\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/2-0.png 700w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/2-0-300x166.png 300w\" sizes=\"(max-width: 700px) 100vw, 700px\" 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wp-image-115401\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/3.bmp\" alt=\"\" width=\"700\" height=\"530\" \/><\/a><\/p>\n<p>\u5728\u5355\u4e59\u4e8c\u80fa\u6865\u8fde\u7edc\u5408\u7269\uff084a\uff0c5a\u548c7a\uff09\u4e2d\uff0c\u672a\u53d6\u4ee3\u7684\u914d\u5408\u72694a\u663e\u793a\u51fa\u6700\u4f4e\u7684\u6d3b\u6027\uff0c\u800c\u572860 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src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/4.bmp\" alt=\"\" width=\"700\" height=\"179\" \/><\/a><\/p>\n<p>\u4e3a\u4e86\u8bf4\u660e\u5b9e\u9a8c\u4e2d\u6d89\u53ca\u7684\u9009\u62e9\u6027\u805a\u5408\uff0c\u5c06LA\u7684\u8f6c\u5316\u7387\u4f5c\u4e3a\u805a\u5408\u65f6\u95f4\u7684\u51fd\u6570\u5e76\u5bf9\u5176\u8fdb\u884c\u76d1\u6d4b\uff0c\u6700\u540e\u5c06\u7ed3\u679c\u7ed8\u5236\u6210\u52a8\u529b\u5b66\u66f2\u7ebf\uff08\u4ece\u5de6\u81f3\u53f3\u4f9d\u6b21\u4e3a\u6dfb\u52a0\u4e86\u914d\u5408\u72691a\uff0c2a\u548c3a\u7684\u52a8\u529b\u5b66\u66f2\u7ebf\uff09\u3002\u7ed3\u679c\u53d1\u73b0\uff0c\u6dfb\u52a0\u4e861a\u548c2a\u7684rac-LA\u7684\u805a\u5408\u53cd\u5e94\u901f\u7387\u76f8\u540c\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u8bc1\u5b9e\u8fd9\u4e00\u7ed3\u679c\uff0c\u7814\u7a76\u4eba\u5458\u5728\u76f8\u540c\u7684\u6761\u4ef6\u4e0b\u5206\u522b\u8fdb\u884c\u4e86\u6dfb\u52a0\u4e86\u914d\u5408\u72691a\u7684 L-LA\uff0c L-LA\u548c\u6dfb\u52a0\u4e86\u914d\u5408\u72692a\u7684 D-LA\u805a\u5408\u53cd\u5e94\u7684\u7814\u7a76\u3002\u6700\u7ec8\u7ed3\u679c\u8868\u660e\uff0cL-LA\u7684\u805a\u5408\u901f\u7387\u9ad8\u4e8e\u4f7f\u75281a\u7684rac-LA\uff1b\u540c\u6837\u7684\uff0c\u4f7f\u75282a\u7684D-LA\u548cL-LA\u7684\u805a\u5408\u51e0\u4e4e\u4ee5\u76f8\u540c\u7684\u901f\u5ea6\u53cd\u5e94\uff0c\u4f46\u4e24\u8005\u7684\u901f\u7387\u5747\u6bd4rac-LA\u7684\u9ad8\u3002<\/p>\n<p><strong>\u56fe5 \u4ece\u5916\u6d88\u65cb\u4e73\u9178\u805a\u5408\u6240\u5f97\u76841a\u590d\u5408\u7269\u4e2d\u5206\u79bb\u5f97\u5230\u7684\u805a\u5408\u7269\u7684MALDI-TOF\u8d28\u8c31<\/strong><\/p>\n<p style=\"text-align: center;\"><a href=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/5.bmp\"><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-115403 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/5.bmp\" alt=\"\" width=\"700\" height=\"668\" \/><\/a><\/p>\n<p>\u4e3a\u4e86\u8fdb\u4e00\u6b65\u4e86\u89e3\u4e19\u4ea4\u916f\u7684\u805a\u5408\u673a\u7406\uff0c\u7528MALDI-TOF\u8d28\u8c31\u6765\u8bb0\u5f55PLA\u4f4e\u805a\u7269\u7684\u53cd\u5e94\u60c5\u51b5\u3002\u53ef\u5728 144m + 94.5 +23 (\u621639)\u5904\u89c2\u5bdf\u5230\u4e00\u7cfb\u5217\u5cf0\u3002<\/p>\n<p><strong>\u56fe6 \u94c1\u7edc\u5408\u7269\u548c\u6c27\u5316\u4e19\u70ef\u5f15\u53d1LA\u5f00\u73af\u805a\u5408\u7684\u673a\u7406<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-115404 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/6-1.png\" alt=\"\" width=\"600\" height=\"359\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/6-1.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/6-1-300x180.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.macromol.7b01766\" target=\"_blank\" rel=\"noopener\">Air-Stable Salen\u2212Iron Complexes: Stereoselective Catalysts for Lactide and \u03b5\u2011Caprolactone Polymerization through in Situ Initiation<\/a><\/strong>.\uff08Macromolecules\uff0c2017\uff0cDOI: 10.1021\/acs.macromol.7b01766\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u5b66\u672f\u7ec4Andy\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u5ba1\u6838\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n<p>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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