{"id":115958,"date":"2017-12-11T06:30:29","date_gmt":"2017-12-10T22:30:29","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=115958"},"modified":"2017-12-07T23:24:00","modified_gmt":"2017-12-07T15:24:00","slug":"%e6%b5%99%e5%a4%a7%e9%82%a2%e5%8d%8e%e6%96%8c%e5%9b%a2%e9%98%9fangew-chem-int-ed-%ef%bc%9a%e5%8f%af%e5%ae%9e%e7%8e%b0%e5%88%86%e5%ad%90%e8%af%86%e5%88%ab%e5%92%8c%e7%ad%9b%e5%88%86%e7%9b%b8","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=115958","title":{"rendered":"\u6d59\u5927\u90a2\u534e\u658c\u56e2\u961fAngew. Chem. Int. Ed.\uff1a\u53ef\u5b9e\u73b0\u5206\u5b50\u8bc6\u522b\u548c\u7b5b\u5206\u76f8\u7ed3\u5408\u7684\u4e92\u7a7f\u6742\u5316\u8d85\u5fae\u5b54\u6750\u6599"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

C4\u70ef\u70c3\u4f5c\u4e3a\u91cd\u8981\u7684\u5316\u5de5\u57fa\u7840\u539f\u6599\uff0c\u5728\u5de5\u4e1a\u4e0aC4\u70ef\u70c3\u7ec4\u5206\u4e2d\uff1a\u7ea650%\u4e3a1\uff0c3-\u4e01\u4e8c\u70ef\uff0c\u662f\u5408\u6210\u6a61\u80f6\u7684\u91cd\u8981\u539f\u6599\uff1b\u7ea640%\u4e3a\u6b63\u4e01\u70ef\u548c\u5f02\u4e01\u70ef\uff0c\u4e3b\u8981\u7528\u4e8e\u751f\u4ea7MTBE\u3001\u4ef2\u4e01\u9187\u548c\u7532\u4e59\u916e\u7b49\u91cd\u8981\u5316\u5de5\u4ea7\u54c1\u3002\u7136\u800c1\uff0c3-\u4e01\u4e8c\u70ef\u3001\u6b63\u4e01\u70ef\u548c\u5f02\u4e01\u70ef\u7b49\u78b3\u6c22\u5316\u5408\u7269\u7ed3\u6784\u9ad8\u5ea6\u76f8\u4f3c\uff0c\u5f7c\u6b64\u5206\u5b50\u5f62\u72b6\u548c\u5c3a\u5bf8\u76f8\u4f3c\uff0c\u6cb8\u70b9\u76f8\u8fd1\u3002\u56e0\u6b64C4\u70ef\u70c3\u7684\u5206\u79bb\u6210\u4e3a\u70c3\u7c7b\u7eaf\u5316\u7684\u91cd\u5927\u6311\u6218\u4e4b\u4e00\u3002\u5229\u7528\u591a\u5b54\u6750\u6599\u8fdb\u884c\u7269\u7406\u5438\u9644\u5b9e\u73b0\u78b3\u6c22\u5316\u5408\u7269\u7684\u5206\u79bb\u662f\u5341\u5206\u5177\u6709\u8282\u80fd\u524d\u666f\u7684\u4e00\u79cd\u5206\u79bb\u6280\u672f\u3002\u5e38\u89c1\u7684\u591a\u5b54\u6750\u6599\u4e3b\u8981\u6709\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\uff08MOFs\uff09\u548c\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\uff08PCPs\uff09\u3002\u800c\u5e38\u89c4\u5206\u5b50\u7b5b\u6750\u6599\u548c\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u6750\u6599\u5b58\u5728\u5bb9\u91cf\u4f4e\u3001\u9009\u62e9\u6027\u4e0d\u9ad8\u7b49\u4e0d\u8db3\u3002<\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6d59\u6c5f\u5927\u5b66\u4f4e\u78b3\u70c3\u548c\u836f\u7269\u5206\u79bb\u8bfe\u9898\u7ec4\u90a2\u534e\u658c\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u56e2\u961f\u9488\u5bf9\u4e0a\u8ff0\u95ee\u9898\uff0c\u8bbe\u8ba1\u5236\u5907\u4e86\u591a\u7c7b\u7a7f\u63d2\u7ed3\u6784\u7684GeF62- \u6216NbF6-\u9634\u79bb\u5b50\u67f1\u6491\u6742\u5316\u8d85\u5fae\u5b54\u6750\u6599\uff0c\u5728Angewandte Chemie International Edition<\/strong>\u53d1\u8868\u4e86\u9898\u4e3a\u201cSorting of C4 Olefins with Interpenetrated Hybrid Ultramicroporous Materials by Combining Molecular Recognition and Size-Sieving \u201d<\/strong>\u7684\u6587\u7ae0\u3002\u901a\u8fc7\u5bf9\u767e\u5206\u4e4b\u4e00\u7eb3\u7c73\u5c3a\u5ea6\u4e0a\u5b54\u7a74\u548c\u6c1f\u529f\u80fd\u4f4d\u70b9\u7a7a\u95f4\u5206\u5e03\u7684\u7cbe\u51c6\u8c03\u63a7\uff0c\u5b9e\u73b0\u5b54\u9053\u8868\u9762\u5316\u5b66\u6027\u8d28\u548c\u5b54\u7a74\u5c3a\u5bf8\u7684\u8c03\u63a7\uff0c\u4ee5\u9002\u5e94\u4e0d\u540cC4\u70ef\u70c3\u7684\u5206\u5b50\u5f62\u72b6\uff0c\u5b9e\u73b0\u7279\u5b9aC4\u70ef\u70c3\u5206\u5b50\u7684\u9ad8\u5bb9\u91cf\u5206\u5b50\u8bc6\u522b\uff1b\u540c\u65f6\u901a\u8fc7\u8c03\u8282\u65e0\u673a\u9634\u79bb\u5b50\u79cd\u7c7b\u63a7\u5236\u6709\u673a\u914d\u4f53\u7684\u65cb\u8f6c\u89d2\u5ea6\uff0c\u5f97\u5230\u53ef\u6536\u7f29\u7684\u5b54\u7a97\u53e3\uff0c\u8be5\u6536\u7f29\u7684\u5b54\u7a97\u53e3\u5728\u5916\u6765\u6c14\u4f53\u5206\u5b50\u523a\u6fc0\u54cd\u5e94\u65f6\u5448\u73b0\u4e0d\u540c\u7a0b\u5ea6\u7684\u547c\u5438\u6548\u5e94\uff0c\u5b9e\u73b0\u4e0d\u540cC4\u70ef\u70c3\u5206\u5b50\u7684\u5c3a\u5bf8\u7b5b\u5206\u3002\u901a\u8fc7\u5206\u5b50\u8bc6\u522b\u548c\u5c3a\u5bf8\u7b5b\u5206\u673a\u7406\u7684\u534f\u540c\uff0c\u8be5\u7c7b\u6750\u6599\u517c\u5177\u9ad8\u7684\u5438\u9644\u5bb9\u91cf\u548c\u4f18\u5f02\u7684\u9009\u62e9\u6027\uff1b\u5e76\u91c7\u7528\u5206\u5b50\u6a21\u62df\u6280\u672f\u63a2\u8ba8\u4e86\u9634\u79bb\u5b50\u67f1\u6491\u8d85\u5fae\u5b54\u4e0eC4\u70ef\u70c3\u7684\u4f5c\u7528\u65b9\u5f0f\uff0c\u8fdb\u4e00\u6b65\u901a\u8fc7\u6df7\u5408\u6c14\u4f53\u56fa\u5b9a\u5e8a\u7a7f\u900f\u5b9e\u9a8c\u8bc1\u5b9e\u4e86\u8be5\u7cfb\u5217\u6750\u6599\u7684\u6781\u4f73\u7684C4\u70ef\u70c3\u5206\u79bb\u548c\u5faa\u73af\u4f7f\u7528\u6027\u80fd\u3002\u8fd9\u4e00\u6750\u6599\u7684\u53d1\u660e\u4e3aC4\u70ef\u70c3\u7684\u5206\u79bb\u7814\u7a76\u63d0\u4f9b\u4e86\u65b0\u7684\u7814\u7a76\u601d\u8def\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1.\u7a7f\u63d2\u7ed3\u6784\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

A. \u7701\u7565\u5421\u5576H\u539f\u5b50\u7684\u900f\u89c6\u56fe\u3002<\/p>\n

B. TIFSIX \u9634\u79bb\u5b50\u3001SIFSIX \u9634\u79bb\u5b50\u548cNbFSIX-2-Cu-i \u7b49\u4ee3\u66ffGeFSIX\u9634\u79bb\u5b50\u7684\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

C. GeFSIX-14-Cu-i\u4ee3\u66ffGeFSIX\u9634\u79bb\u5b50\u7684\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

D. C\u4e2d\u7ed3\u6784\u6cbf\u7740c\u8f74\u89c2\u5bdf\u5f97\u5230\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\uff08C\u56fe\u4e2d\u4e3a\u4e86\u6e05\u695a\u800c\u5c06F \u79bb\u5b50\u5ffd\u7565\u6389; F \u7ea2\u8272; H \u7070\u8272; Cu \u7c89\u8272; Nb \u84dd\u7eff\u8272; Ge \u6df1\u9752\u8272; C \u5728\u4e0d\u540c\u7f51\u72b6\u7ed3\u6784\u4e2d\u78b3\u539f\u5b50\u7528\u84dd\u8272\u548c\u7eff\u8272\u6765\u7a81\u51fa\u3002\uff09<\/p>\n

\u56fe2. C4<\/sub>H6<\/sub>\uff0cn-C4<\/sub>H8<\/sub>\u548ciso-C4<\/sub>H8<\/sub> \u5728TIFSIX-2-Cu-i\u6750\u6599\u4e0a\u7684\u5438\u9644\u7b49\u6e29\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

A. \u5728298K\uff0c1.01bar\u6761\u4ef6\u4e0bSIFSIX-2-Cu-i\u7ed3\u6784\u5bf9C4<\/sub>H6<\/sub>\uff0cn-C4<\/sub>H8<\/sub>\u548ciso-C4<\/sub>H8<\/sub>\u4e09\u79cd\u5206\u5b50\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

B. \u5728298K\uff0c1.01bar\u6761\u4ef6\u4e0b GeFSIX-2-Cu-i\u7ed3\u6784\u5bf9C4<\/sub>H6<\/sub>\uff0cn-C4<\/sub>H8<\/sub>\u548ciso-C4<\/sub>H8<\/sub>\u4e09\u79cd\u5206\u5b50\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

C. \u5728298K\uff0c1.01bar\u6761\u4ef6\u4e0b NbFSIX-2-Cu-i\u7ed3\u6784\u5bf9C4<\/sub>H6<\/sub>\uff0cn-C4<\/sub>H8<\/sub>\u548ciso-C4<\/sub>H8<\/sub>\u4e09\u79cd\u5206\u5b50\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

D. \u5728298K\uff0c1.01bar\u6761\u4ef6\u4e0bGeFSIX-14-Cu-i\u7ed3\u6784\u5bf9C4<\/sub>H6<\/sub>\uff0cn-C4<\/sub>H8<\/sub>\u548ciso-C4<\/sub>H8<\/sub>\u4e09\u79cd\u5206\u5b50\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

E. \u5728298K\uff0c1.01bar\u6761\u4ef6\u4e0bSIFSIX-1-Cu\u7ed3\u6784\u5bf9C4<\/sub>H6<\/sub>\uff0cn-C4<\/sub>H8<\/sub>\u548ciso-C4<\/sub>H8<\/sub>\u4e09\u79cd\u5206\u5b50\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

F. \u5728298K\uff0c1.01bar\u6761\u4ef6\u4e0bSIFSIX-3-Ni\u7ed3\u6784\u5bf9C4<\/sub>H6<\/sub>\uff0cn-C4<\/sub>H8<\/sub>\u548ciso-C4<\/sub>H8<\/sub>\u4e09\u79cd\u5206\u5b50\u7684\u5438\u9644\u7b49\u6e29\u7ebf\u3002<\/p>\n

\u56fe3.\u79bb\u6563\u5085\u91cc\u53f6\u53d8\u6362\u5bf9C4\u70ef\u70c3\u5728\u6750\u6599\u4e0a\u7ed3\u5408\u4f4d\u70b9\u7684\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/p>\n

A.C4<\/sub>H6<\/sub> (C \u6a59\u8272, H \u7070\u8272)\u5728SIFSIX-2-Cu-i\u6750\u6599\u4e0a\u7ed3\u5408\u4f4d\u70b9\u8ba1\u7b97\u7ed3\u679c\u3002<\/p>\n

B.n-C4<\/sub>H8<\/sub>\u5728SIFSIX-2-Cu-i\u6750\u6599\u4e0a\u7ed3\u5408\u4f4d\u70b9\u8ba1\u7b97\u7ed3\u679c\u3002<\/p>\n

C.n-C4<\/sub>H8<\/sub>\u5728TIFSIX-2-Cu-i\u6750\u6599\u4e0a\u7ed3\u5408\u4f4d\u70b9\u8ba1\u7b97\u7ed3\u679c\u3002<\/p>\n

D.C4<\/sub>H6<\/sub>\u5728GeFSIX-14-Cu-i\u6750\u6599\u4e0a\u7ed3\u5408\u4f4d\u70b9\u8ba1\u7b97\u7ed3\u679c\u3002<\/p>\n

(\u56fe\u4e2d\uff1aF \u7ea2\u8272\uff0cSi, Ti, \u6216 Ge \u84dd\u8272\uff0c \u6c22\u952e \u9ec4\u8272\u7684\u865a\u7ebf\u3002 )<\/p>\n

\u56fe4.\u4e0d\u540c\u7ec4\u5206\u6df7\u5408\u6c14\u5728\u4e0d\u540c\u7ed3\u6784\u6750\u6599\u4e0a\u7684\u7a7f\u900f\u66f2\u7ebf\u5b9e\u9a8c\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

A. \u6df7\u5408\u7ec4\u5206C4<\/sub>H6<\/sub> \/n-C4<\/sub>H8<\/sub>\/iso-C4<\/sub>H8<\/sub>\/He\uff0850\/15\/30\/5\uff09\u5728GeFSIX-2-Cu-i\u6750\u6599\u5185\u7684\u7a7f\u900f\u66f2\u7ebf\u3002<\/p>\n

B. \u6df7\u5408\u7ec4\u5206 C4<\/sub>H6<\/sub> \/n-C4<\/sub>H8<\/sub>\uff0850\/50\uff09\u5728GeFSIX-14-Cu-i\u6750\u6599\u5185\u7684\u7a7f\u900f\u66f2\u7ebf\u3002<\/p>\n

C. \u6df7\u5408\u7ec4\u5206n-C4<\/sub>H8<\/sub>\/iso-C4<\/sub>H8<\/sub>\uff0850\/50\uff09\u5728NbFSIX-2-Cu-i\u6750\u6599\u5185\u7684\u7a7f\u900f\u66f2\u7ebf\u3002<\/p>\n

D. NbFSIX-2-Cu-i\u6750\u6599\u5206\u79bbn-C4<\/sub>H8<\/sub>\/iso-C4<\/sub>H8<\/sub>\uff0850\/50\uff09\u6df7\u5408\u7ec4\u5206\u7a7f\u900f\u66f2\u7ebf\u5faa\u73af\u6027\u80fd\u6d4b\u8bd5\uff08298K,1.01bar,\u6c14\u4f53\u6d41\u901f\uff0c0.5mL\/min\uff09\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u591a\u5b54\u7a7f\u63d2\u6750\u6599\uff0c\u4e0d\u4ec5\u53ef\u4ee5\u8c03\u63a7\u5b54\u9053\u8868\u9762\u5316\u5b66\u6027\u8d28\u548c\u63a7\u5230\u5c3a\u5bf8\uff0c\u540c\u65f6\u53ef\u4ee5\u5728\u5916\u6765\u6c14\u4f53\u5206\u5b50\u523a\u6fc0\u4e0b\u5b9e\u73b0\u5206\u79bb\u7a97\u53e3\u7684\u7075\u6d3b\u6536\u7f29\uff0c\u5b9e\u73b0\u4e0d\u540cC4\u70ef\u70c3\u5206\u5b50\u7684\u5c3a\u5bf8\u7b5b\u5206\u3002\u901a\u8fc7\u5206\u5b50\u8bc6\u522b\u548c\u5c3a\u5bf8\u7b5b\u5206\u673a\u7406\u7684\u534f\u540c\uff0c\u8be5\u7c7b\u6750\u6599\u5728\u5e38\u6e29\u5e38\u538b\u4e0b\u5bf9\u70ef\u70c3\u6c14\u4f53\u5206\u5b50\u5177\u6709\u5f88\u9ad8\u7684\u5438\u9644\u5bb9\u91cf\u548c\u9009\u62e9\u6027\uff0c\u4e14\u5176\u6027\u80fd\u5747\u4f18\u4e8e\u73b0\u6709\u5206\u5b50\u7b5b\u548c\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u6750\u6599\u3002\u91c7\u7528\u5206\u5b50\u6a21\u62df\u6280\u672f\u63a2\u8ba8\u4e86\u9634\u79bb\u5b50\u67f1\u6491\u8d85\u5fae\u5b54\u4e0eC4\u70ef\u70c3\u7684\u4f5c\u7528\u65b9\u5f0f\uff0c\u8fdb\u4e00\u6b65\u901a\u8fc7\u6df7\u5408\u6c14\u4f53\u56fa\u5b9a\u5e8a\u7a7f\u900f\u5b9e\u9a8c\u8bc1\u5b9e\u4e86\u8be5\u7cfb\u5217\u6750\u6599\u7684\u6781\u4f73\u7684C4\u70ef\u70c3\u5206\u79bb\u548c\u5faa\u73af\u4f7f\u7528\u6027\u80fd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Zhang Z, Yang Q, Cui X, et al. Sorting of C4 Olefins with Interpenetrated Hybrid Ultramicroporous Materials by Combining Molecular Recognition and Size\u2010Sieving[J]. Angewandte Chemie, 2017.<\/p>\n

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\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/span>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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