{"id":116348,"date":"2017-12-13T06:30:23","date_gmt":"2017-12-12T22:30:23","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=116348"},"modified":"2017-12-11T09:24:02","modified_gmt":"2017-12-11T01:24:02","slug":"%e5%a4%8d%e6%97%a6%e5%a4%a7%e5%ad%a6%e5%bd%ad%e6%85%a7%e8%83%9cadv-mater-%ef%bc%9a%e9%94%82%e7%a9%ba%e6%b0%94%e7%94%b5%e6%b1%a0%e5%be%aa%e7%8e%af%e5%af%bf%e5%91%bd%e5%a4%a7%e5%b9%85%e6%8f%90%e9%ab%98","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=116348","title":{"rendered":"\u590d\u65e6\u5927\u5b66\u5f6d\u6167\u80dcAdv.Mater.\uff1a\u9502\u7a7a\u6c14\u7535\u6c60\u5faa\u73af\u5bff\u547d\u5927\u5e45\u63d0\u9ad8\u81f3610\u5708"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u5177\u6709\u9ad8\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\uff083500Wh\u00b7kg-1<\/sup>\uff09\u7684\u53ef\u5145\u7535Li-Air\u7535\u6c60\u5907\u53d7\u5173\u6ce8\u3002\u7136\u800c\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u5176\u53ef\u9006\u653e\u7535\u4ea7\u7269\u8fc7\u6c27\u5316\u9502\uff08Li2<\/sub>O2<\/sub>\uff09\u4e0e\u7a7a\u6c14\u4e2d\u7684\u6c34\u5206\u5b50\u548cCO2<\/sub>\u53d1\u751f\u526f\u53cd\u5e94\uff0c\u9020\u6210\u4e0d\u53ef\u9006\u4ea7\u7269\u7684\u751f\u6210\u548c\u81ea\u8eab\u7684\u6d88\u8017\uff0c\u4e25\u91cd\u9650\u5236\u4e86\u5176\u5faa\u73af\u5bff\u547d\u3002\u56e0\u6b64\uff0c\u76ee\u524d\u5173\u4e8eLi-Air\u7535\u6c60\u7684\u62a5\u9053\u5927\u591a\u662f\u5728\u7eaf\u6c27\u6c14\u6c1b\u4e0b\u8fdb\u884c\u6d4b\u8bd5\u7814\u7a76\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u9488\u5bf9\u76ee\u524dLi-Air\u7535\u6c60\u5728\u7a7a\u6c14\u4e2d\u7a33\u5b9a\u6027\u5dee\u7684\u95ee\u9898\uff0c\u590d\u65e6\u5927\u5b66\u5f6d\u6167\u80dc\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5e26\u9886\u7684\u56e2\u961f\u63d0\u51fa\u4e00\u79cd\u63d0\u9ad8\u5176\u5faa\u73af\u5bff\u547d\u7684\u65b0\u7b56\u7565\u3002\u5728\u8be5\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u5f15\u5165LDPE\uff08\u4f4e\u5bc6\u5ea6\u805a\u4e59\u70ef\uff09\u819c\u6765\u963b\u9694\u6c34\u6c7d\uff0c\u5e76\u7ed3\u5408\u542b\u6709LiI\u6c27\u5316\u8fd8\u539f\u5a92\u4ecb\u7684\u51dd\u80f6\u7535\u89e3\u8d28\uff0c\u5f00\u53d1\u4e86\u4e00\u79cd\u5168\u65b0\u7684\u5177\u6709\u8d85\u957f\u5faa\u73af\u5bff\u547d\u7684\u67d4\u6027Li-Air\u7535\u6c60\u3002LDPE\u7684\u5f15\u5165\u53ef\u6709\u6548\u5730\u6291\u5236\u653e\u7535\u8fc7\u7a0b\u4e2dLi2<\/sub>O2<\/sub>\u4e0e\u7a7a\u6c14\u4e2d\u7684H2<\/sub>O\u548cCO2<\/sub>\u751f\u6210Li2<\/sub>CO3<\/sub>\u7684\u526f\u53cd\u5e94\u53d1\u751f\uff0c\u540c\u65f6LiI\u7684\u5b58\u5728\u4fc3\u8fdb\u4e86\u5145\u7535\u8fc7\u7a0b\u4e2dLi2<\/sub>O2<\/sub>\u7684\u5206\u89e3\uff0c\u8fdb\u800c\u5c06Li-Air\u7535\u6c60\u5faa\u73af\u5bff\u547d\u5927\u5e45\u63d0\u9ad8\u81f3610\u5708\u3002\u6b64\u5916\uff0c\u8003\u8651\u5230\u5404\u9879\u7ec4\u88c5\u57fa\u5143\u5177\u6709\u826f\u597d\u7684\u67d4\u6027\uff0c\u7814\u7a76\u4eba\u5458\u5b9e\u73b0\u4e86\u5177\u6709\u826f\u597d\u8010\u5f2f\u6298\u6027\u80fd\u67d4\u6027Li-Air\u7535\u6c60\u7684\u7ec4\u88c5\uff0c\u5f97\u5230\u7684\u67d4\u6027Li-Air\u7535\u6c60\u6d78\u6ca1\u5728\u6c34\u4e2d\u65f6\u4f9d\u7136\u4fdd\u6301\u7740\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201cA Li\u2013Air Battery with Ultralong Cycle Life in Ambient Air\u201d<\/strong>\u53d1\u8868\u5728Advanced Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe1.LDPE\u7684\u5f15\u5165\u6291\u5236Li2<\/sub>O2<\/sub>\u751f\u6210Li2<\/sub>CO3<\/sub>\u7684\u526f\u53cd\u5e94<\/strong><\/p>\n

\"\"<\/p>\n

a)\u7a7a\u6c14\u6c1b\u56f4\u4e0b\uff0cLi-Air\u7535\u6c60\u6c27\u5316\u8fd8\u539f\u5a92\u4ecb\u5728i)\u65e0ii)\u6709LDPE\u819c\u5b58\u5728\u4e0b\u7684\u5de5\u4f5c\u673a\u5236<\/p>\n

b)LDPE\u819c\u7684H2<\/sub>O\u3001O2<\/sub>\u6e17\u900f\u7387\u4e0e\u62a5\u9053\u7684\u6c27\u6c14\u9009\u62e9\u6027\u819c\u5bf9\u6bd4<\/p>\n

c)\u672c\u5f81Li2<\/sub>O2<\/sub>\u3001\u6709\/\u65e0LDPE\u819c\u4fdd\u62a4\u4e0b\u7684Li2<\/sub>O2<\/sub>\u5728\u7a7a\u6c14\u6c1b\u56f4\u4e0b\u5de5\u4f5c\u4e00\u6bb5\u65f6\u95f4\u540e\u7684XRD\u5bf9\u6bd4<\/p>\n

\u56fe2.LDPE\u548cLiI\u7684\u5b58\u5728\u5927\u5e45\u63d0\u9ad8Li-Air\u7535\u6c60\u5faa\u73af\u5bff\u547d<\/strong><\/p>\n

\"\"<\/p>\n

a)\u4e0d\u540c\u7c7b\u578bLi-Air\u7535\u6c60\u57282000mA\u00b7g-1<\/sup>\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\u53cab)\u5faa\u73af\u6027\u80fd\uff08\u7a7a\u6c14\u6c1b\u56f4\u4e0b\uff0c\u76f8\u5bf9\u6e7f\u5ea6~50%\uff09<\/p>\n

c)LDPE\u548cLiI\u5b58\u5728\u65f6Li-Air\u7535\u6c60\u4e0d\u540c\u5faa\u73af\u6b21\u6570\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\u53cad)\u76f8\u5e94\u7684\u5faa\u73af\u6027\u80fd\uff08\u7535\u6d41\u5bc6\u5ea62000mA\u00b7g-1<\/sup>\uff0c\u7a7a\u6c14\u6c1b\u56f4\u4e0b\uff0c\u76f8\u5bf9\u6e7f\u5ea6~5%\uff09<\/p>\n

e)\u672c\u5de5\u4f5c\u4e2dLi-Air\u7535\u6c60\u4e0e\u4e4b\u524d\u6587\u732e\u62a5\u9053\u7684Li-Air\u7535\u6c60\u5faa\u73af\u5bff\u547d\u5bf9\u6bd4<\/p>\n

\u56fe3.\u4e0d\u540c\u7c7b\u578bLi-Air\u7535\u6c60\u653e\/\u518d\u5145\u7535\u540e\u7535\u6781\u5f62\u8c8c\u53ca\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a,d,g)LDPE\u548cLiI\u5b58\u5728\u4e0b\u7535\u6781\u653e\/\u518d\u5145\u7535\u540eSEM\u5f62\u8c8c\u53caXRD\u8c31\u56fe<\/p>\n

b,e,h)\u53ea\u6709LiI\u5b58\u5728\u4e0b\u7535\u6781\u653e\/\u518d\u5145\u7535\u540eSEM\u5f62\u8c8c\u53caXRD\u8c31\u56fe<\/p>\n

c,f,i)\u53ea\u6709LDPE\u5b58\u5728\u4e0b\u7535\u6781\u653e\/\u518d\u5145\u7535\u540eSEM\u5f62\u8c8c\u53caXRD\u8c31\u56fe<\/p>\n

\u56fe4.\u67d4\u6027Li-Air\u7535\u6c60\u7684\u5236\u5907\u53ca\u5176\u4f18\u5f02\u7684\u67d4\u6027\u548c\u9632\u6c34\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a)\u7ea4\u7ef4\u72b6\u67d4\u6027Li-Air\u7535\u6c60\u7684\u5236\u5907\u793a\u610f\u56fe<\/p>\n

b)500\u30011000\u6b21\u5f2f\u6298\u540e\u67d4\u6027Li-Air\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

c)\u67d4\u6027Li-Air\u7535\u6c60\u6d78\u6ca1\u5230\u6c34\u4e2d\u4f9d\u7136\u53ef\u4ee5\u5de5\u4f5c<\/p>\n

d)\u6709\/\u65e0LDPE\u819c\u4fdd\u62a4\u4e0b\u7684\u67d4\u6027Li-Air\u7535\u6c60\u6d78\u5165\u6c34\u4e2d\u524d\u540e\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

e,f)\u67d4\u6027Li-Air\u7535\u6c60\u53ef\u88ab\u7f16\u7ec7\u5230\u8863\u7269\u4e2d\u5e76\u4e3a\u667a\u80fd\u624b\u673a\u5145\u7535<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u5de5\u4f5c\u5229\u7528LDPE\uff08\u4f4e\u5bc6\u5ea6\u805a\u4e59\u70ef\uff09\u819c\u963b\u9694\u6c34\u6c7d\u7684\u7279\u6027\uff0c\u7ed3\u5408\u542b\u6709LiI\u6c27\u5316\u8fd8\u539f\u5a92\u4ecb\u7684\u51dd\u80f6\u7535\u89e3\u8d28\uff0c\u5b9e\u73b0\u4e86Li-Air\u7535\u6c60\u5728\u7a7a\u6c14\u6c1b\u56f4\u4e2d\u9ad8\u8fbe610\u6b21\u7684\u8d85\u957f\u5faa\u73af\u5bff\u547d\u3002\u540c\u65f6\uff0c\u57fa\u4e8e\u5404\u7ec4\u88c5\u57fa\u5143\u826f\u597d\u7684\u67d4\u6027\uff0c\u7ec4\u88c5\u5f97\u5230\u7684\u67d4\u6027Li-Air\u7535\u6c60\u5c55\u51fa\u4e86\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u8fd9\u9879\u5de5\u4f5c\u4e3a\u9ad8\u6027\u80fd\u7535\u6c60\u7684\u53d1\u5c55\u5f00\u8f9f\u4e86\u65b0\u7684\u65b9\u5411\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>A Li\u2013Air Battery with Ultralong Cycle Life in Ambient Air<\/a>\uff08Adv.Mater. ,2017, DOI: 10.1002\/adma.201704378\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u725b\u8d8a\u7f16\u8bd1\uff0c \u5468\u68a6\u9752\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/span>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8fd1\u5e74\u6765\uff0c\u5177\u6709\u9ad8\u7406\u8bba\u80fd\u91cf\u5bc6\u5ea6\uff083500Wh\u00b7kg-1\uff09\u7684\u53ef\u5145\u7535Li-Air\u7535\u6c60\u5907\u53d7\u5173\u6ce8\u3002\u7136\u800c\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\uff0c\u5176\u53ef\u9006\u653e\u7535\u4ea7\u7269\u8fc7\u6c27\u5316\u9502\uff08Li2O2\uff09\u4e0e\u7a7a\u6c14\u4e2d\u7684…<\/p>\n","protected":false},"author":230,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[],"class_list":["post-116348","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/116348"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=116348"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/116348\/revisions"}],"predecessor-version":[{"id":116596,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/116348\/revisions\/116596"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=116348"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=116348"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=116348"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}