{"id":117256,"date":"2017-12-19T06:30:05","date_gmt":"2017-12-18T22:30:05","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=117256"},"modified":"2017-12-15T17:36:42","modified_gmt":"2017-12-15T09:36:42","slug":"%e7%a6%8f%e5%b7%9e%e5%a4%a7%e5%ad%a6%e7%8e%8b%e5%bf%83%e6%99%a8angew-chem-int-ed-%e5%85%b7%e6%9c%89%e5%8f%af%e8%b0%83%e8%83%bd%e5%b8%a6%e7%bb%93%e6%9e%84%e7%9a%84%e5%8a%9f%e8%83%bd%e5%8c%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=117256","title":{"rendered":"\u798f\u5dde\u5927\u5b66\u738b\u5fc3\u6668Angew. Chem. Int. Ed. : \u5177\u6709\u53ef\u8c03\u80fd\u5e26\u7ed3\u6784\u7684\u529f\u80fd\u5316\u4e09\u55ea\u57fa\u805a\u5408\u7269\u7528\u4e8e\u5149\u50ac\u5316\u4ea7\u6c27"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5149\u5408\u4f5c\u7528\u4ee5\u8fd8\u539f\u78b3\u7684\u5f62\u5f0f\u5c06\u592a\u9633\u80fd\u8f6c\u5316\u4e3a\u5316\u5b66\u80fd\uff0c\u4f7f\u5f97\u5927\u6c14\u4e2d\u6c27\u6c14\u542b\u91cf\u589e\u52a0\uff0c\u8fd9\u4e5f\u6fc0\u52b1\u7740\u7814\u7a76\u4eba\u5458\u5bf9\u4e8e\u4eba\u5de5\u5149\u5408\u6210\u7684\u5b5c\u5b5c\u6c42\u7d22\u3002\u4e3a\u4e86\u5b9e\u73b0\u4eba\u5de5\u5149\u5408\u6210\u8fd9\u4e00\u76ee\u6807\uff0c\u6700\u8fd1\u7814\u7a76\u4eba\u5458\u5c06\u5177\u6709\u534a\u5bfc\u4f53\u7279\u6027\u7684\u5171\u8f6d\u805a\u5408\u7269\u5f15\u5165\u5149\u50ac\u5316\u5206\u89e3\u6c34\uff0c\u4ee5\u5f25\u8865\u5df2\u6df1\u5165\u7814\u7a76\u4e8640\u5e74\u7684\u65e0\u673a\u534a\u5bfc\u4f53\u7684\u4e0d\u8db3\u3002\u5171\u8f6d\u805a\u5408\u7269\u5728\u53ef\u6301\u7eed\u6027\u3001\u6210\u672c\u6548\u76ca\u3001\u53ef\u52a0\u5de5\u6027\u548c\u53ef\u8c03\u8282\u6027\u65b9\u9762\u5b58\u5728\u4e00\u5b9a\u4f18\u52bf\u3002\u4e8b\u5b9e\u4e0a\uff0c\u5171\u8f6d\u805a\u5408\u7269\u7531\u4e8e\u5176\u5149\u7535\u6027\u80fd\u4ee5\u53ca\u5728\u67d4\u6027\u7535\u5b50\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u83b7\u5f97\u4e86\u8f83\u591a\u5173\u6ce8\uff0c\u800c\u5728\u4eba\u5de5\u5149\u5408\u4f5c\u7528\u4e2d\u5e94\u7528\u4ecd\u8f83\u5c11\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u798f\u5dde\u5927\u5b66\u738b\u5fc3\u6668\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u6e29\u548c\u7684\u5236\u5907\u4e86\u4e09\u79cd\u5177\u6709\u4e0d\u540c\u94fe\u957f\u5ea6\u7684\u5171\u8f6d\u4e09\u55ea\u57fa\u805a\u5408\u7269(CTPs) \uff0c\u5e76\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cPhotocatalytic Oxygen Evolution from Functional Triazine-Based Polymers with Tunable Band Structures<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u8be5\u8bba\u6587\u88ab\u9009\u4e3a\u91cd\u70b9(<\/strong>VIP<\/strong>)\u8bba\u6587<\/strong>\u3002\u901a\u8fc7\u589e\u52a0\u9aa8\u67b6\u4e2d\u4f9b\u7535\u5b50\u82c4\u57fa\u7684\u6570\u91cf\uff0c\u8c03\u63a7CTPs\u7684\u94fe\u957f\u5ea6\uff0c\u8fdb\u800c\u8c03\u8282\u5176\u7535\u5b50\u3001\u5149\u5b66\u548c\u6c27\u5316\u8fd8\u539f\u6027\u8d28\uff0c\u5149\u50ac\u5316\u4ea7\u6c27\u6027\u80fd\u589e\u5f3a\uff0c\u4e0a\u8ff0\u5206\u89e3\u6c34\u534a\u53cd\u5e94\u7531\u4e8e\u7f13\u6162\u7684\u53cd\u5e94\u52a8\u529b\u5b66\u66f4\u5177\u6709\u6311\u6218\u6027\u3002\u8be5\u7814\u7a76\u6210\u679c\u6709\u671b\u5f15\u53d1\u5173\u4e8e\u529f\u80fd\u6027\u805a\u5408\u7269\u7684\u5174\u8da3\uff0c\u4ee5\u53ca\u5229\u7528\u5206\u5b50\u5de5\u7a0b\u7b56\u7565\u6784\u7b51\u7528\u4e8e\u5149\u5408\u4f5c\u7528\u7684\u5177\u6709\u9002\u5b9c\u6c27\u5316\u8fd8\u539f\u80fd\u7ea7\u7684\u534a\u5bfc\u4f53\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 CTPs\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

CTPs\u5408\u6210\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2 CTPs\u7684\u5316\u5b66\u7ed3\u6784\u3001\u5149\u5438\u6536\u548c\u80fd\u5e26\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

a) CTPs\u7684\u56fa\u4f5313<\/sup>C NMR\u8c31\uff1b<\/p>\n

b) CTPs\u548cCN\u7684UV\/Vis DRS\u5149\u8c31\uff1b<\/p>\n

c) CTPs\u548cCN\u7684\u80fd\u5e26\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe3 CTP-2\u548cCo\/CTP-2\u7684\u5f62\u8c8c\u548c\u5149\u7535\u6027\u8d28\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a) Co\/CTP-2\u7684TEM\u56fe\u50cf\u4ee5\u53caC\u3001N\u548cCo\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

b) CTP-2\u548cCo\/CTP-2\u7684PL\u66f2\u7ebf(\u03bbex<\/sub>=340 nm)\uff1b<\/p>\n

c) CTP-2\u548cCo\/CTP-2\u7684\u6781\u5316\u66f2\u7ebf\u4ee5\u53ca\u5149\u7535\u6d41\u54cd\u5e94\u3002<\/p>\n

\u56fe4 CTPs\u548cCN\u7684\u5149\u50ac\u5316\u6d4b\u8bd5<\/strong><\/p>\n

\"\"<\/p>\n

a) \u94b4\u8d1f\u8f7d\u91cf\u5bf9\u4e8eCTP-2\u4ea7\u6c27\u901f\u7387\u7684\u5f71\u54cd(\u03bb>300 nm)\uff1b<\/p>\n

b) CTPs\u548cCN\u5728\u7d2b\u5916\/\u53ef\u89c1\u5149\u4e0b\u7684\u4ea7\u6c27\u901f\u7387(\u03bb>300 nm)\uff1b<\/p>\n

c) CTP-2\u548cCN\u4ea7\u6c27\u91cf\u968f\u65f6\u95f4\u7684\u53d8\u5316\uff1b<\/p>\n

d) CTP-2\u548cCN\u4ea7\u6c22\u91cf\u968f\u65f6\u95f4\u7684\u53d8\u5316\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u5df2\u7ecf\u5f00\u53d1\u51fa\u4e00\u7cfb\u5217CTPs\u4f5c\u4e3a\u6709\u673a\u5149\u50ac\u5316\u5242\u5206\u89e3\u6c34\u4ea7\u6c27\u3002\u8c03\u8282\u524d\u9a71\u4f53\u7684\u8fde\u63a5\u7ed3\u6784\u548c\u7535\u5b50\u6027\u8d28\u5bf9\u4e8eCTPs\u7684\u5149\u50ac\u5316\u4ea7\u6c27\u6d3b\u6027\u5177\u6709\u91cd\u5927\u5f71\u54cd\u3002\u4e0e\u5176\u4ed6CTPs\u548cCN\u805a\u5408\u7269\u76f8\u6bd4\uff0cCTP-2\u5177\u6709\u6700\u4f18\u5149\u50ac\u5316\u6d3b\u6027\u3002CTP-2\u805a\u5408\u7269\u4e5f\u5c55\u73b0\u51fa\u4f18\u8d8a\u7684\u53ef\u89c1\u5149\u50ac\u5316\u5236\u6c22\u6d3b\u6027\uff0c\u7ea6\u662fCN\u805a\u5408\u7269\u76845\u500d\u3002CTP-2\u4f18\u8d8a\u7684\u50ac\u5316\u6548\u7387\u5e94\u5f52\u56e0\u4e8e\u5149\u5438\u6536\u589e\u5f3a\u548c\u7a7a\u7a74\u7684\u6c27\u5316\u80fd\u529b\u589e\u5f3a\u7684\u534f\u540c\u4f5c\u7528\u3002\u8c03\u8282CTPs\u9aa8\u67b6\u8fdb\u884c\u5149\u50ac\u5316\u4ea7\u6c27\u4e3a\u5b9e\u73b0\u5168\u5206\u89e3\u6c34\u63d0\u4f9b\u4e86\u65b0\u7684\u673a\u9047\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aPhotocatalytic Oxygen Evolution from Functional Triazine-Based Polymers with Tunable Band Structures<\/a><\/strong>\u00a0(Angew. Chem. Int. Ed., 2017, DOI: 10.1002\/anie.201711155)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

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