{"id":119693,"date":"2018-01-05T06:30:31","date_gmt":"2018-01-04T22:30:31","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=119693"},"modified":"2018-01-04T23:27:00","modified_gmt":"2018-01-04T15:27:00","slug":"angew-chem-int-ed-%ef%bc%9a%e5%88%86%e5%ad%90%e6%94%af%e6%9f%b1%e6%b3%95%e5%ae%9e%e7%8e%b0cof%e5%9c%a8go%e4%b8%8a%e7%9a%84%e5%9e%82%e7%9b%b4%e7%94%9f%e9%95%bf","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=119693","title":{"rendered":"Angew.Chem.Int.Ed.\uff1a\u5206\u5b50\u652f\u67f1\u6cd5\u5b9e\u73b0COF\u5728GO\u4e0a\u7684\u5782\u76f4\u751f\u957f"},"content":{"rendered":"<p><strong style=\"line-height: inherit;\">\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n<p>\u8fd1\u5e74\u6765\uff0c\u4ee5\u77f3\u58a8\u70ef\u57fa\u590d\u5408\u6750\u6599\u6765\u4f5c\u4e3a\u50a8\u80fd\u6750\u6599\u7684\u80fd\u6e90\u5668\u4ef6\u5f97\u5230\u4e86\u8fc5\u731b\u53d1\u5c55\u3002\u5171\u4ef7\u6709\u673a\u6846\u67b6\u6750\u6599\uff08Covalent organic frameworks\uff0cCOFs\uff09\u662f\u4e00\u79cd\u53ef\u7cbe\u786e\u8c03\u63a7\u5b54\u5c3a\u5bf8\u7684\u4e8c\u7ef4\u591a\u5b54\u6750\u6599\uff0c\u5177\u6709\u5927\u7684\u6bd4\u8868\u9762\u79ef\u53ca\u79bb\u5b50\u4f20\u8f93\u901a\u9053\u3002\u901a\u8fc7\u4e0e\u77f3\u58a8\u70ef\u590d\u5408\uff0c\u501f\u52a9\u4e8e\u77f3\u58a8\u70ef\u7684\u9ad8\u7535\u6027\uff0c\u77f3\u58a8\u70ef\/COF\u6750\u6599\u5728\u50a8\u80fd\u9886\u57df\u4e2d\u5d2d\u9732\u5934\u89d2\u3002\u76ee\u524d\u6240\u62a5\u9053\u7684\u5173\u4e8e\u77f3\u58a8\u70ef\/COF\u6750\u6599\u7684\u5236\u5907\u65b9\u5f0f\u591a\u4e3a\u5c06COF\u7247\u5c42\u6c89\u79ef\u5728\u77f3\u58a8\u70ef\u4e0a\uff0c\u6216\u5c06COF\u819c\u5e73\u884c\u6392\u5217\u5728\u57fa\u5e95\u4e0a\u3002\u7136\u800c\u8fd9\u79cd\u5e73\u884c\u5806\u53e0\u7684\u65b9\u5f0f\u5e76\u4e0d\u80fd\u4f7fCOF\u6750\u6599\u7684\u5b54\u7ed3\u6784\u5f97\u5230\u5145\u5206\u5229\u7528\uff0c\u8fdb\u800c\u963b\u788d\u4e86\u6750\u6599\u79bb\u5b50\u4f20\u8f93\u6027\u80fd\u3002<\/p>\n<p><strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n<p>\u8fd1\u65e5<strong>\uff0c\u4e8e\u9ed8\u5965\u5927\u5b66<\/strong><strong>Alexandr V. Talyzin<\/strong><strong>\u6559\u6388<\/strong><strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u5e26\u9886\u7684\u56e2\u961f\u63d0\u51fa\u4e00\u79cd\u5236\u5907\u5177\u6709\u9ad8\u50a8\u80fd\u6027\u80fdCOF\/\u77f3\u58a8\u70ef\u590d\u5408\u6750\u6599\u7684\u65b0\u7b56\u7565\u3002\u5728\u8be5\u5de5\u4f5c\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u5f15\u5165\u5206\u5b50\u652f\u67f1\u7684\u65b9\u6cd5\uff0c\u5b9e\u73b0\u4e86COF-1\u6750\u6599\u4e8e\u6c27\u5316\u77f3\u58a8\u70ef\uff08GO\uff09\u4e0a\u7684\u5782\u76f4\u751f\u957f\u3002\u5728\u5236\u5907\u8fc7\u7a0b\u4e2d\uff0c\u7814\u7a76\u4eba\u5458\u9996\u5148\u5c061,4-\u82ef\u4e8c\u787c\u9178\u5206\u5b50\uff08DBA\uff09\u5171\u4ef7\u63a5\u679d\u4e8eGO\u4e0a\uff0c\u518d\u5c06\u4e4b\u4f5c\u4e3aCOF-1\u751f\u957f\u7684\u6210\u6838\u4f4d\u70b9\uff0c\u5f97\u5230\u5782\u76f4\u4e8e\u57fa\u5e95\u751f\u957f\u7684COF\u6750\u6599\u3002\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u82e5\u6ca1\u6709DBA\u4f5c\u4e3a\u5206\u5b50\u652f\u67f1\uff0cCOF\u6750\u6599\u65e0\u6cd5\u5b9e\u73b0\u5728GO\u4e0a\u7684\u5782\u76f4\u751f\u957f\uff0c\u800c\u662f\u5e73\u884c\u6392\u5217\u4e8e\u57fa\u5e95\u4e4b\u4e0a\u3002\u6b64\u5916\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0\u901a\u8fc7\u8c03\u63a7COF-1\u5408\u6210\u8fc7\u7a0b\u4e2dDBA\u7684\u7528\u91cf\uff0c\u53ef\u5b9e\u73b0\u5bf9COF-1\u7eb3\u7c73\u7247\u5c42\u539a\u5ea6\u7684\u7cbe\u786e\u8c03\u63a7\uff0c\u8fdb\u800c\u83b7\u5f97\u539a\u5ea6\u57283~15nm\u7684\u7eb3\u7c73\u7247\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u78b3\u5316\u540e\u7684\u590d\u5408\u6750\u6599\u4f9d\u7136\u53ef\u4ee5\u4fdd\u6301\u5176\u72ec\u7279\u7684\u4e09\u7ef4\u7ed3\u6784\uff0c\u5e76\u5728\u8d85\u7ea7\u7535\u5bb9\u5668\u6d4b\u8bd5\u4e2d\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c1A\u00b7g<sup>-1<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u6bd4\u5bb9\u91cf\u4e3a160F\u00b7g<sup>-1<\/sup>\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a\u201c<strong>A Molecular Pillar Approach to Grow Vertical Covalent Organic Framework Nanosheets on Graphene: Hybrid Materials for Energy Storage<\/strong>\u201d\u53d1\u8868\u5728<strong>Angew.Chem.Int.Ed.<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe1.<\/strong><strong>GO<\/strong><strong>\u4e0a\u5782\u76f4\u751f\u957f<\/strong><strong>COF-1<\/strong><strong>\u7eb3\u7c73\u7247\u793a\u610f\u56fe<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-119697 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/1-36.png\" alt=\"\" width=\"600\" height=\"609\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/1-36.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/1-36-296x300.png 296w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a)DBA\u5171\u4ef7\u63a5\u679d\u5728GO\u4e0a<\/p>\n<p>b)\u5229\u7528DBA\u4f5c\u4e3a\u5206\u5b50\u652f\u67f1\u5b9e\u73b0COF\u4e8eGO\u4e0a\u7684\u5782\u76f4\u751f\u957f(v-COF-GO)<\/p>\n<p>c)\u6ca1\u6709DBA\u4f5c\u4e3a\u5206\u5b50\u652f\u67f1\u65f6\uff0c\u76f8\u540c\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0cCOF\u5e73\u884c\u751f\u957f\u4e8eGO\u4e0a(COF\/GO)<\/p>\n<p>\u7ecf\u8fc7\u78b3\u5316\u540ec)v-COF-GO\u53cae)COF\/GO\u5f62\u6210\u5782\u76f4\/\u6c34\u5e73\u4e8eRGO\u7684\u78b3\u7eb3\u7c73\u7247<\/p>\n<p><strong>\u56fe<\/strong><strong>2.DBA<\/strong><strong>\u7528\u91cf\u5bf9<\/strong><strong>COF<\/strong><strong>\u7eb3\u7c73\u7247\u751f\u957f\u7684\u5f71\u54cd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-119698 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/2-34.png\" alt=\"\" width=\"600\" height=\"605\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/2-34.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/2-34-150x150.png 150w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/2-34-298x300.png 298w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a)DBA:DBA-GO=1:2,\u53ea\u6709\u5c11\u91cf\u7eb3\u7c73\u7247\u751f\u957f\u4e8eGO\u8868\u9762<\/p>\n<p>b)DBA:DBA-GO=1:1,c)2:1,d)3:1,\u968f\u7740DBA\u7528\u91cf\u7684\u63d0\u9ad8\uff0c\u7eb3\u7c73\u7247\u81f4\u5bc6\u5730\u6392\u5217\u5728GO\u4e0a<\/p>\n<p>e)DBA:DBA-GO=1:4,\u5927\u91cf\u7684\u7eb3\u7c73\u7247\u751f\u6210\uff0c\u5b8c\u5168\u8986\u76d6\u4f4fGO\u8868\u9762<\/p>\n<p>h)\u4e0d\u540cDBA\u7528\u91cf\u4e0b\uff0cCOF-1\u7eb3\u7c73\u7247\u5177\u6709\u4e0d\u540c\u7684\u539a\u5ea6<\/p>\n<p>i)\u82e5\u6ca1\u6709DBA\u4f5c\u4e3a\u5206\u5b50\u652f\u67f1\uff0c\u76f8\u540c\u53cd\u5e94\u6761\u4ef6\u4e0b\uff0cCOF-1\u5e73\u884c\u4e8eGO\u751f\u957f\u5f62\u6210\u5fae\u7c73\u7ea7\u76d8\u72b6\u5f62\u8c8c<\/p>\n<p><strong>\u56fe<\/strong><strong>3.<\/strong><strong>\u6750\u6599\u7ed3\u6784\u76f8\u5173\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-119699 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/3-29.png\" alt=\"\" width=\"600\" height=\"1173\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/3-29.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/3-29-153x300.png 153w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/3-29-524x1024.png 524w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a)\u4e0d\u540cDBA\u7528\u91cf\u4e0b\uff0cv-COF-GO\u6750\u6599XRD\u8c31\u56fe<\/p>\n<p>b)COF-1\u3001v-COF-GO-3\u53caCOF-GO-3 XRD\u8c31\u56fe<\/p>\n<p>c)\u4e0d\u540cDBA\u7528\u91cf\u4e0b\uff0cv-COF-GO\u6750\u6599\u5177\u6709\u4e0d\u540c\u6bd4\u8868\u9762\u79ef<\/p>\n<p>d)v-COF-GO-3\u53ca COF-1\u7684\u5b54\u5f84\u5206\u5e03\u53ca\u5b54\u4f53\u79ef<\/p>\n<p><strong>\u56fe<\/strong><strong>4.<\/strong><strong>\u78b3\u5316\u540e\u6750\u6599\u5f62\u8c8c\u53ca<\/strong><strong>BET<\/strong><strong>\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-119700 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/4-27.png\" alt=\"\" width=\"600\" height=\"723\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/4-27.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/4-27-249x300.png 249w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a,b)v-CNS-RGO-2 SEM\u5f62\u8c8c<\/p>\n<p>c,d)v-CNS-RGO-3 TEM\u5f62\u8c8c<\/p>\n<p>e)CNP\/RGO SEM\u5f62\u8c8c<\/p>\n<p>f)v-CNS-RGO-3\u53caCNP\/RGO-3\u7684N<sub>2<\/sub>\u5438\/\u8131\u9644\u7b49\u6e29\u7ebf<\/p>\n<p><strong>\u56fe<\/strong><strong>5.<\/strong><strong>\u6750\u6599\u8d85\u7ea7\u7535\u5bb9\u5668\u6027\u80fd\u6d4b\u8bd5<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-119701 aligncenter\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/5-21.png\" alt=\"\" width=\"600\" height=\"453\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/5-21.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2017\/12\/5-21-300x227.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>a)\u4e0d\u540cDBA\u7528\u91cf\u4e0b\u5236\u5907\u7684v-CNS-RGO\u4f5c\u4e3a\u7535\u6781\u6750\u6599\u5728100mv\/s\u4e0b\u7684CV\u66f2\u7ebf<\/p>\n<p>b)\u4e0d\u540cDBA\u7528\u91cf\u4e0b\u5236\u5907\u7684v-CNS-RGO\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u7535\u5bb9<\/p>\n<p>c)\u5782\u76f4\u751f\u957f\u6837\u54c1v-CNS-RGO-3\u548c\u6c34\u5e73\u751f\u957f\u6837\u54c1CNP\/RGO-3\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u6bd4\u7535\u5bb9\u53ca1A\u00b7g<sup>-1<\/sup>\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n<p>d)v-CNS-RGO-3\u7684\u5faa\u73af\u6027\u80fd<\/p>\n<p><strong>\u3010\u7ed3\u8bba\u3011<\/strong><\/p>\n<p>\u7814\u7a76\u4eba\u5458\u5229\u7528\u5f15\u5165\u5206\u5b50\u652f\u67f1\u7684\u624b\u6bb5\uff0c\u5b9e\u73b0\u4e86\u8d85\u8584COF\u7eb3\u7c73\u7247\u4e8eGO\u4e0a\u7684\u5782\u76f4\u751f\u957f\u3002\u5171\u4ef7\u63a5\u679d\u4e8eGO\u4e0a\u7684DBA\u5206\u5b50\u652f\u67f1\u4f5c\u4e3a\u6210\u6838\u4f4d\u70b9\u8bf1\u5bfcCOF\u6750\u6599\u5782\u76f4\u751f\u957f\u3002\u901a\u8fc7\u5bf9DBA\u7528\u91cf\u7684\u8c03\u63a7\u53ef\u83b7\u5f97\u539a\u5ea6\u57283~15nm\u7684COF\u7eb3\u7c73\u7247\u3002\u6b64\u5916\uff0c\u78b3\u5316\u540e\u7684COF\/GO\u6750\u6599\u4ecd\u80fd\u591f\u4fdd\u6301\u72ec\u7279\u7684\u7eb3\u7c73\u7ed3\u6784\uff0c\u591a\u5b54COF\u6750\u6599\u548c\u9ad8\u5bfc\u7535RGO\u534f\u540c\u4f5c\u7528\uff0c\u8d4b\u4e88\u4e86\u590d\u5408\u6750\u6599\u5feb\u901f\u7684\u7535\u5b50\u4f20\u8f93\u901f\u7387\uff0c\u4f7f\u5176\u5728\u8d85\u7535\u6d4b\u8bd5\u4e2d\u5c55\u73b0\u51fa\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002\u8be5\u5de5\u4f5c\u6240\u63d0\u51fa\u7684\u6750\u6599\u7ed3\u6784\u8bbe\u8ba1\u7406\u5ff5\u4e3a\u65b0\u578b\u6742\u5316\u6750\u6599\u7684\u5236\u5907\u63d0\u4f9b\u4e86\u601d\u8def\u3002<\/p>\n<p><strong>\u3010\u6587\u732e\u4fe1\u606f\u3011<\/strong><\/p>\n<p>\u6587\u732e\u94fe\u63a5\uff1a<strong><a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201710502\/full\" target=\"_blank\" rel=\"noopener\">A Molecular Pillar Approach to Grow Vertical Covalent Organic Framework Nanosheets on Graphene: Hybrid Materials for Energy Storage<\/a> <\/strong>(Angew.Chem.Int.Ed.,2017,DOI: 10.1002\/anie.201710502<strong>)<\/strong><\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u7ec4\u725b\u8d8a\u6574\u7406\u7f16\u8bd1\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong>\u6d4b\u8bd5\u8c37<\/strong><\/a><strong>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u8fd1\u5e74\u6765\uff0c\u4ee5\u77f3\u58a8\u70ef\u57fa\u590d\u5408\u6750\u6599\u6765\u4f5c\u4e3a\u50a8\u80fd\u6750\u6599\u7684\u80fd\u6e90\u5668\u4ef6\u5f97\u5230\u4e86\u8fc5\u731b\u53d1\u5c55\u3002\u5171\u4ef7\u6709\u673a\u6846\u67b6\u6750\u6599\uff08Covalent organic frameworks\uff0cCOFs\uff09&#8230;<\/p>\n","protected":false},"author":6277,"featured_media":119697,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[43,46,386],"class_list":["post-119693","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-composite","tag-graphene","tag-superccapacitor"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/119693"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/6277"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=119693"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/119693\/revisions"}],"predecessor-version":[{"id":120209,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/119693\/revisions\/120209"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/119697"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=119693"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=119693"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=119693"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}