{"id":120047,"date":"2018-01-05T06:30:23","date_gmt":"2018-01-04T22:30:23","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=120047"},"modified":"2018-01-03T22:54:05","modified_gmt":"2018-01-03T14:54:05","slug":"%e5%bc%a0%e6%9d%b0%e9%b9%8f%e9%99%88%e5%b0%8f%e6%98%8enatl-sci-rev-%ef%bc%9a%e9%87%91%e5%b1%9e-%e6%9c%89%e6%9c%ba%e6%a1%86%e6%9e%b6%e6%9d%90%e6%96%99%ef%bc%88mof%ef%bc%89%e7%9a%84%e6%9f%94","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=120047","title":{"rendered":"\u5f20\u6770\u9e4f&\u9648\u5c0f\u660eNatl. Sci. Rev.\uff1a\u91d1\u5c5e-\u6709\u673a\u6846\u67b6\u6750\u6599\uff08MOF\uff09\u7684\u67d4\u6027\u63a7\u5236"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u591a\u5b54\u914d\u4f4d\u805a\u5408\u7269\uff08Porous Coordination Polymer, PCP\uff09\uff0c\u53c8\u79f0\u91d1\u5c5e\u2014\u6709\u673a\u6846\u67b6\uff08Metal-Organic Framework, MOF\uff09\uff0c\u56e0\u5177\u6709\u4e30\u5bcc\u591a\u6837\u3001\u53ef\u8bbe\u8ba1\u526a\u88c1\u7684\u6846\u67b6\u548c\u5b54\u7ed3\u6784\u800c\u5438\u5f15\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u548c\u5e38\u89c4\u591a\u5b54\u6750\u6599\u76f8\u6bd4\uff0cMOF\u7684\u6846\u67b6\u67d4\u6027\u7279\u522b\u663e\u8457\uff0c\u53ef\u4ee5\u5bf9\u5916\u754c\u523a\u6fc0\u4ea7\u751f\u4e30\u5bcc\u591a\u6837\u7684\u7ed3\u6784\u54cd\u5e94\u548c\u52a8\u6001\u884c\u4e3a\uff0c\u5e76\u53ef\u7528\u4e8e\u6709\u6548\u63d0\u9ad8\u5438\u9644\u50a8\u5b58\u3001\u5206\u79bb\u3001\u4f20\u611f\u7b49\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u8bbe\u8ba1\u5408\u6210\u5177\u6709\u7279\u5b9a\u67d4\u6027\u548c\u52a8\u6001\u884c\u4e3a\u7684MOF\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u4e0d\u8fc7\uff0c\u5f71\u54cd\u67d4\u6027\u548c\u52a8\u6001\u884c\u4e3a\u7684\u56e0\u7d20\u975e\u5e38\u591a\u800c\u4e14\u590d\u6742\uff0c\u4f7f\u5176\u76f8\u6bd4\u4e8e\u9759\u6001\u7684\u6846\u67b6\u548c\u5b54\u7ed3\u6784\u66f4\u96be\u8bbe\u8ba1\u6216\u63a7\u5236\u3002<\/p>\n

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1\u3001\u7b80\u4ecb<\/strong><\/p>\n

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2\u3001\u901a\u8fc7\u8bbe\u8ba1\u6846\u67b6\u7ed3\u6784\uff0c\u8c03\u63a7MOF\u67d4\u6027<\/strong><\/p>\n

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2.1 \u5408\u7406\u9009\u62e9\u6709\u673a\u914d\u4f53\u548c\u91d1\u5c5e\u79bb\u5b50\/\u56e2\u7c07<\/strong><\/p>\n

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\u5b9e\u9645\u4e0a\uff0c\u6846\u67b6\u67d4\u6027\u5bf9\u7ed3\u6784\u5dee\u5f02\u975e\u5e38\u654f\u611f\uff0c\u6240\u4ee5\u6539\u53d8\u540c\u6784\u6216\u540c\u7f51MOF\u7684\u7ec4\u5206\uff0c\u8fdb\u800c\u6539\u53d8MOF\u7684\u7ed3\u6784\uff0c\u662f\u63a7\u5236\u6846\u67b6\u67d4\u6027\u7684\u4e00\u79cd\u5e38\u7528\u7b56\u7565\u3002MOF\u53ef\u4ee5\u91c7\u7528\u4e24\u79cd\u6216\u4ee5\u4e0a\u7684\u76f8\u4f3c\u6784\u5efa\u6a21\u5757\uff0c\u5728\u4e0d\u540c\u5355\u5143\u7684\u76f8\u540c\u7ed3\u6676\u4f4d\u7f6e\u968f\u610f\u5206\u5e03\uff0c\u5f62\u6210\u5177\u6709\u53ef\u53d8\u5316\u5b66\u8ba1\u91cf\u6570\u7684\u56fa\u6eb6\u4f53\u7ed3\u6784\uff0c\u8fdb\u800c\u5b9e\u73b0\u7ed3\u6784\u548c\u6027\u80fd\u7684\u8fde\u7eed\u8c03\u8282\u3002Kitagawa\u7b49\u4eba\u7814\u7a76\u4e86\u540c\u6784\u578b\u7684CID-5\uff08\u53d6\u4ee3\u57fa\u8f83\u5c0f\uff09\u548cCID-6\uff08\u53d6\u4ee3\u57fa\u8f83\u5c0f\uff09\u7684CO2<\/sub>\u5438\u9644\u6027\u80fd\uff0c\u8bc1\u660e\u4e86\u56fa\u6eb6\u4f53\u7b56\u7565\u6709\u52a9\u4e8e\u8c03\u8282\u6846\u67b6\u67d4\u6027\u3002\u56fa\u6eb6\u4f53\u6846\u67b6\u6784\u6210\u7684\u7cbe\u786e\u63a7\u5236\uff0c\u53ef\u4ee5\u901a\u8fc7\u5408\u6210\u540e\u4fee\u9970\u53cd\u5e94\u5b9e\u73b0\uff0c\u4f46\u662f\u5927\u90e8\u5206\u8fd9\u4e9b\u53cd\u5e94\u5e38\u7528\u6db2\u4f53\u53cd\u5e94\u7269\/\u8bd5\u5242\uff0c\u4e0d\u5229\u4e8e\u56fa\u6eb6\u4f53\u6210\u5206\u7684\u7cbe\u786e\u8c03\u63a7\u3002\u8fd9\u4e2a\u95ee\u9898\u53ef\u4ee5\u5229\u7528\u65e0\u6eb6\u5242\u7684\u56fa\u6c14\u53cd\u5e94\u89e3\u51b3\u3002\u5f20\u6770\u9e4f\u3001\u9648\u5c0f\u660e\u56e2\u961f\u5236\u5907\u4e86\u67d4\u6027\u7684[Cu4<\/sub>(btm)2<\/sub>] (MAF-42)\uff0c\u5176\u4e2d\u542b\u6709Cu+<\/sup>\u548c\u4e9a\u7532\u57fa\u6865\u8fde\u7684\u53cc\u4e09\u6c2e\u5511\u914d\u4f53\uff0c\u5728\u5ba4\u6e29\u4e0b\u6c27\u6c14\u6216\u8005\u7a7a\u6c14\u4e2d\u4e9a\u7532\u57fa\u4f1a\u88ab\u6c27\u5316\u6210\u7fb0\u57fa\u3002\u7531\u4e8e\u7fb0\u57fa\u6bd4\u4e9a\u7532\u57fa\u521a\u6027\u5927\uff0c\u4eb2\u6c34\u6027\u66f4\u5f3a\uff0c\u6240\u4ee5MAF-42\u6c27\u5316\u540e\u8868\u73b0\u51fa\u66f4\u9ad8\u7684\u5f00\u542f\u538b\u529b\u3001\u66f4\u5927\u7684\u6c14\u4f53\u5438\u9644\u6ede\u56de\u4ee5\u53ca\u66f4\u5927\u7684\u5b54\u4f53\u79ef\u3002<\/p>\n

\"\"<\/p>\n

\u56fe3 MAF-42\u7684\u5408\u6210\u540e\u6539\u9020\u548c\u67d4\u6027\u8c03\u63a7\u3002\uff08a\uff09\u5ba2\u4f53\u8bf1\u5bfcMAF-42\u7684\u6846\u67b6\u547c\u5438\uff1b\uff08b\uff09\u65e0\u6eb6\u5242\u7684\u56fa\u6c14\u53cd\u5e94\u673a\u5236\uff1b\uff08c\uff09\u67d4\u6027\u4e9a\u7532\u57fa\u57fa\u56e2\u53d8\u4e3a\u521a\u6027\u7fb0\u57fa\u57fa\u56e2\uff0c\u5bfc\u81f4\u6846\u67b6\u521a\u6027\u589e\u52a0\u3002<\/strong><\/p>\n

2.2 \u6539\u53d8\u6709\u673a\u914d\u4f53\u7684\u6865\u8fde\u957f\u5ea6\u548c\u975e\u914d\u4f4d\u7684\u4fa7\u57fa\u56e2<\/strong><\/p>\n

\u8d8a\u957f\u7684\u914d\u4f53\uff0c\u8d8a\u5bb9\u6613\u5f2f\u66f2\uff0c\u5f62\u6210\u66f4\u52a0\u67d4\u6027\u7684MOF\u3002MOF-74\u662f\u4e00\u79cd\u5177\u67093D\u8702\u7a9d\u72b6\u914d\u4f4d\u7f51\u7edc\u548c1D\u901a\u9053\u7684\u5178\u578b\u521a\u6027\u7ed3\u6784\u3002\u800c\u5408\u7406\u5ef6\u957f\u914d\u4f53\u7684\u957f\u5ea6\uff0c\u5c31\u5f62\u6210\u4e86\u4ecb\u5b54\u7ed3\u6784\u7684MOF-74\u62d3\u5c55\u7248\u672c\uff0c\u5b9e\u73b0\u6846\u67b6\u53d8\u5f62\u800c\u5c55\u73b0\u51fa\u67d4\u6027\u7279\u5f81\u3002\u6709\u7814\u7a76\u8868\u660e\uff0c\u5728MOF-74\u7684\u914d\u4f53\u9aa8\u5e72\u4e0a\u591a\u52a0\u4e00\u4e2a\u82ef\u73af\uff0c\u5c31\u8db3\u591f\u8bf1\u53d1\u6846\u67b6\u67d4\u6027\u3002<\/p>\n

\u6539\u53d8\u6709\u673a\u914d\u4f53\u7684\u6865\u8fde\u957f\u5ea6\u901a\u5e38\u88ab\u8ba4\u4e3a\u662f\u8bbe\u8ba1\u65b0MOF\u6750\u6599\u7684\u9014\u5f84\uff0c\u800c\u6539\u53d8\u975e\u914d\u4f4d\u7684\u4fa7\u57fa\u56e2\u5219\u66f4\u4fa7\u91cd\u5bf9\u5df2\u77e5MOF\u6750\u6599\u7684\u6539\u9020\u3002\u5bf9\u6846\u67b6\u67d4\u6027\u6765\u8bf4\uff0c\u975e\u914d\u4f4d\u7684\u4fa7\u57fa\u56e2\u8d77\u7740\u6392\u65a5\u3001\u5438\u5f15\u6216\u7535\u5b50\u4f5c\u7528\u3002Long\u7b49\u4eba\u62a5\u9053\u4e86\u4e00\u79cd\u9ad8\u5ea6\u67d4\u6027\u7684MOF\u6750\u6599\u2014\u2014[Co(bdp)]\uff0c\u5b83\u5728\u5ba4\u6e29\u4e0b\u5bf9CH4<\/sub>\u8868\u73b0\u51fa\u663e\u8457\u7684\u50a8\u5b58\u5bb9\u91cf\u3002\u6b64\u5916\uff0c\u4ed6\u4eec\u8fdb\u4e00\u6b65\u6bd4\u8f83\u4e86\u4e00\u7cfb\u5217\u540c\u578b[Co(bdp)]\u6846\u67b6\u7684\u6c14\u4f53\u5438\u9644\u6027\u80fd\u548c\u5bf9\u5e94\u7684\u6846\u67b6\u53d8\u5316\uff0c\u7ed3\u679c\u9a8c\u8bc1\u4e86\u975e\u914d\u4f4d\u4fa7\u57fa\u56e2\u7684\u7535\u5b50\u3001\u7a7a\u95f4\u548c\u4f4d\u7f6e\u6548\u5e94\u5bf9\u67d4\u6027\u53d8\u5316\u7684\u91cd\u8981\u4f5c\u7528\u3002<\/p>\n

\u53e6\u5916\uff0c\u975e\u914d\u4f4d\u7684\u4fa7\u57fa\u56e2\u5bf9\u4e3b\u4f53\u6750\u6599\u7684\u5438\u5f15\/\u6392\u65a5\u529b\u4e5f\u53ef\u7528\u6765\u8c03\u63a7\u6846\u67b6\u67d4\u6027\u3002\u6bd4\u5982\uff0c[Ag6<\/sub>X(Rtz)4<\/sub>]OH\u00b7nH2<\/sub>O\uff08X=Cl\u2212<\/sup>\u6216Br\u2212<\/sup>\uff0cR=NH3<\/sub>\u6216CH3<\/sub>\uff09\u4f1a\u51fa\u73b0\u7f51\u7edc\u7a7f\u63d2\u7684\u91cd\u6784\u73b0\u8c61\uff0c\u800c\u4e14\u5229\u7528\u6709\u673a\u4fa7\u57fa\u56e2\u7684\u4eb2\u6c34\u6027\/\u758f\u6c34\u6027\u53ef\u4ee5\u5b9e\u73b0\u6846\u67b6\u67d4\u6027\u7684\u8c03\u63a7\u3002\u5982\u679c\u5f15\u5165\u4eb2\u6c34\u7684\u6c28\u57fa\uff08R=NH2<\/sub>\uff09\uff0c\u5b83\u5141\u8bb8\u5ba2\u4f53OH–<\/sup>\/H2<\/sub>O\u653b\u51fb\u7ebf\u6027\u914d\u4f4d\u7684Ag+<\/sup>\uff0c\u5c31\u6709\u52a9\u4e8e\u540c\u65f6\u8868\u73b0\u51fa\u7a7f\u63d2\u91cd\u6784\u548c\u6846\u67b6\u53d8\u5f62\u884c\u4e3a\u3002\u5982\u679c\u5f15\u5165\u758f\u6c34\u7684\u7532\u57fa\uff08R=CH3<\/sub>\uff09\uff0c\u5219\u4f1a\u963b\u6b62\u8fd9\u6837\u7684\u653b\u51fb\uff0c\u7ed3\u679c\u4ec5\u4ec5\u8868\u73b0\u51fa\u5927\u7684\u6846\u67b6\u53d8\u5f62\u884c\u4e3a\u3002<\/p>\n

\"\"<\/p>\n

\u56fe4 [Ag6<\/sub>X(Rtz)4<\/sub>]OH\u00b7nH2<\/sub>O\u7684\u6846\u67b6\u547c\u5438\u548c\u91cd\u6784\u884c\u4e3a\u7684\u8c03\u63a7\u3002\u5de6\u56fe\uff1a\u540c\u65f6\u53d1\u751f\u6846\u67b6\u53d8\u5f62\u548c\u7a7f\u63d2\u91cd\u6784\uff0c\u5176\u4e2dR=NH2<\/sub>\uff1b\u53f3\u56fe\uff1a\u4ec5\u53d1\u751f\u6846\u67b6\u53d8\u5f62\uff0c\u6ca1\u6709\u7a7f\u63d2\u91cd\u6784\uff0c\u5176\u4e2dR=CH3<\/sub><\/strong><\/p>\n

3\u3001\u901a\u8fc7\u6539\u53d8\u5ba2\u4f53\u8d1f\u8f7d\uff0c\u8c03\u63a7\u6846\u67b6\u67d4\u6027<\/strong><\/p>\n

\u67d4\u6027MOF\u6750\u6599\u7684\u7ed3\u6784\u5f88\u5927\u7a0b\u5ea6\u4e0a\u4f9d\u8d56\u4e8e\u5438\u9644\u5ba2\u4f53\u7684\u79cd\u7c7b\u548c\u6570\u91cf\u3002MOF\u7ed3\u6784\u53d8\u5316\u7684\u65b9\u5f0f\u4e5f\u5e38\u5e38\u4f9d\u8d56\u4e8e\u5ba2\u4f53\u7684\u7c7b\u578b\uff0c\u4f46\u8fd9\u4e9b\u90fd\u4e0d\u7b97\u63a7\u5236MOF\u7684\u67d4\u6027\u3002\u4e0d\u8fc7\uff0c\u5ba2\u4f53\u4e0d\u4f46\u53ef\u7528\u4e8e\u8c03\u63a7\u7269\u7406\u6027\u80fd\uff08\u6bd4\u5982\u78c1\u6027\u3001\u53d1\u5149\u6027\u80fd\u7b49\uff09\uff0c\u8fd8\u53ef\u7528\u4e8e\u8c03\u63a7\u7531\u7269\u7406\u523a\u6fc0\uff08\u6e29\u5ea6\u548c\/\u6216\u538b\u529b\u53d8\u5316\u7b49\uff09\u8bf1\u53d1\u7684MOF\u67d4\u6027\u3002\u56e0\u6b64\uff0c\u6539\u53d8\u5ba2\u4f53\u8d1f\u8f7d\uff0c\u662f\u4e00\u79cd\u6539\u9020MOF\u6750\u6599\u7684\u7279\u6b8a\u5408\u6210\u540e\u4fee\u9970\u65b9\u6cd5\u3002<\/p>\n

\u5229\u7528\u5ba2\u4f53\u8c03\u63a7MOF\u7684\u70ed\u81a8\u80c0\u6027\u80fd\u5df2\u7ecf\u5f97\u5230\u4e86\u5f88\u597d\u7684\u9a8c\u8bc1\u3002\u901a\u5e38\uff0c\u5ba2\u4f53\u5206\u5b50\u7684\u4f4d\u963b\u6548\u5e94\u548c\u4e3b\u5ba2\u4f53\u4e4b\u95f4\u7684\u5438\u5f15\u529b\u4f1a\u963b\u788d\u6216\u8005\u4fc3\u8fdb\u4e3b\u4f53\u6846\u67b6\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u7684\u6536\u7f29\uff0c\u4ece\u800c\u662fMOF\u8868\u793a\u51fa\u66f4\u5c0f\u6216\u8005\u66f4\u5927\u7684\u70ed\u81a8\u80c0\u7cfb\u6570\u3002<\/p>\n

\"\"<\/p>\n

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\"\"<\/p>\n

\u56fe7 MAF-2\u4e2d\u67d4\u6027\u4e59\u57fa\u5728\u6e29\u5ea6\u76f8\u5173\u7684\u52a8\u529b\u5b66\u56e0\u7d20\u4e0b\u5bf9\u5b54\u5f84\u8fdb\u884c\u8c03\u63a7<\/strong><\/p>\n

\u3010\u603b\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1aControlling flexibility of metal-organic frameworks<\/a>\uff08Natl. Sci. Rev., 2017, DOI: 10.1093\/nsr\/nwx127\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u5b66\u672f\u7ec4maggie\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u3002<\/p>\n

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