{"id":121116,"date":"2018-01-18T06:30:32","date_gmt":"2018-01-17T22:30:32","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=121116"},"modified":"2018-01-16T10:31:14","modified_gmt":"2018-01-16T02:31:14","slug":"angew-chem-int-ed-%e7%a2%b1%e5%bc%8f%e7%a2%b3%e9%85%b8%e7%9b%90%e4%b8%ba%e6%a8%a1%e6%9d%bf%e7%9a%84%e6%99%ae%e9%b2%81%e5%a3%ab%e8%93%9d%e7%b1%bb%e4%bc%bc%e7%89%a9%e5%88%b6%e5%a4%87%e5%8f%8a","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=121116","title":{"rendered":"Angew. Chem. Int. Ed. : \u78b1\u5f0f\u78b3\u9178\u76d0\u4e3a\u6a21\u677f\u7684\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\u5236\u5907\u53ca\u5176\u5f3a\u52b2\u6c34\u6c27\u5316\u6027\u80fd"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u4ea7\u6c27\u53cd\u5e94(OER)\u662f\u4e00\u4e2a\u70ed\u529b\u5b66\u4e0a\u5761\u53cd\u5e94(237 kJ\u00b7mol-1<\/sup>)\uff0c\u6d89\u53ca\u5230\u591a\u79cd\u9ad8\u80fd\u4e2d\u95f4\u4f53\u7684\u53c2\u4e0e\u3002\u867d\u7136\u8d35\u91d1\u5c5e\u50ac\u5316\u5242IrO2<\/sub>\u548cRuO2<\/sub>\u5177\u6709\u826f\u597d\u7684OER\u6d3b\u6027\uff0c\u50a8\u91cf\u4f4e\u4ee5\u53ca\u9ad8\u6210\u672c\u9650\u5236\u4e86\u5176\u5927\u89c4\u6a21\u7684\u5e94\u7528\u3002\u5c31\u8fd9\u4e00\u70b9\u6765\u8bf4\uff0c\u7531\u50a8\u91cf\u4e30\u5bcc\u5143\u7d20\u7ec4\u6210\u7684\u9ad8\u6548\u6c34\u6c27\u5316\u50ac\u5316\u5242\u8fd1\u5e74\u6765\u53d7\u5230\u7279\u522b\u5173\u6ce8\u3002\u7279\u522b\u662f\u91d1\u5c5e\u6709\u673a\u6846\u67b6(MOFs)\u884d\u751f\u50ac\u5316\u5242\u4f53\u7cfb\uff0c\u7531\u4e8e\u5176\u6d3b\u6027\u4f4d\u70b9\u6570\u91cf\u589e\u52a0\uff0c\u5176\u7535\u5316\u5b66\u6d3b\u6027\u4ea6\u6709\u63d0\u5347\u3002\u6700\u8fd1\uff0c\u666e\u9c81\u58eb\u84dd\u884d\u751f\u7269(PBAs) \u4f5c\u4e3a\u4e00\u7c7b\u7528\u4e8e\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u3001\u6c27\u8fd8\u539f\u53cd\u5e94\u7b49\u80fd\u6e90\u76f8\u5173\u9886\u57df\u7684\u65b0\u578b\u6750\u6599\uff0c\u7814\u7a76\u4eba\u5458\u5df2\u8fdb\u884c\u4e86\u5e7f\u6cdb\u7814\u7a76\u3002\u867d\u7136PBAs\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u7684\u591a\u529f\u80fd\u6027\u548c\u7a33\u5b9a\u6027\u5df2\u8fdb\u884c\u4e86\u7814\u7a76\uff0c\u5176\u5728\u6c34\u6c27\u5316\u9886\u57df\u7684\u5e94\u7528\u5374\u5be5\u5be5\u65e0\u51e0\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u97e9\u56fd\u5cad\u5357\u5927\u5b66\u5b8b\u6cf0\u71ee\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u4ee5\u78b1\u5f0f\u78b3\u9178\u76d0\u4e3a\u6a21\u677f\u7684\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269(PBAs)\u7684\u5408\u6210\u53ca\u5176\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u826f\u597d\u7684\u6c34\u6c27\u5316\u6d3b\u6027\uff0c\u5e76\u5728Angew. Chem. Int. Ed.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cBoosting Electrochemical Water Oxidation with Metal Hydroxide Carbonate Templated Prussian Blue Analogues<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u4ee5\u78b1\u5f0f\u78b3\u9178\u94b4\u4e3a\u6a21\u677f\u7684t-CoII<\/sup>-CoIII<\/sup>\u6700\u4f18\u7684\u6c34\u6c27\u5316\u6d3b\u6027\u4e3a\u8fbe\u523010 mA\u00b7cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u65f6\u8fc7\u7535\u538b\u4f4e\u81f3240 mV\u3002\u5728\u8d85\u8fc750 h\u7684\u8ba1\u65f6\u6d4b\u91cf\u4e2d\u4ecd\u80fd\u4ea7\u751f\u6052\u5b9a\u7535\u6d41\u3002\u6b64\u5916\uff0c\u4e0a\u8ff0\u50ac\u5316\u5242\u6d3b\u6027\u4f18\u4e8e\u65e0\u6a21\u677f\u5236\u5907\u7684PBAs\u751a\u81f3\u8d35\u91d1\u5c5e\u50ac\u5316\u5242RuO2<\/sub>\u3002\u5149\u8c31\u548c\u5fae\u89c2\u7814\u7a76\u8868\u660e\uff0cPBAs\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u5c06\u8f6c\u5316\u4e3a\u5c42\u72b6\u6c22\u6c27\u5316\u7269\u7ed3\u6784\u5e76\u63d0\u4f9b\u6c34\u6c27\u5316\u7684\u6d3b\u6027\u4f4d\u70b9\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 \u6750\u6599\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u4ee5\u78b1\u5f0f\u78b3\u9178\u76d0\u4e3a\u6a21\u677f\u5408\u6210\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\u4ee5\u53ca\u78b1\u6027\u4ecb\u8d28\u4e0b\u7535\u5316\u5b66\u5236\u6c27\u8fc7\u7a0b\u4e2d\u8f6c\u5316\u4e3a\u5206\u5c42\u7ed3\u6784\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2 \u50ac\u5316\u5242\u7684\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

a) t-CoII<\/sup>-CoIII<\/sup>\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

b) \u5355\u4e2a\u7acb\u65b9\u4f53\u7684TEM\u56fe\u50cf<\/p>\n

c) t-CoII<\/sup>-CoIII<\/sup>\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

d) \u76f8\u5e94\u7684\u7535\u5b50\u884d\u5c04\u56fe\u50cf\u3002<\/p>\n

\u56fe3 \u50ac\u5316\u5242\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

1M KOH\u6eb6\u6db2\u4e2d\uff0ct-CoII<\/sup>-CoIII<\/sup>\u4e0e\u5176\u4ed6\u50ac\u5316\u5242\u7684OER\u6027\u80fd\u6bd4\u8f83\u3002(\u626b\u901f2 mV\u00b7s-1<\/sup>)<\/p>\n

\u56fe4 \u50ac\u5316\u5242\u5728\u7535\u5316\u5b66\u8fc7\u7a0b\u4e2d\u7684\u5f62\u6001\u8f6c\u5316<\/strong><\/p>\n

\"\"<\/p>\n

a) \u8d85\u8fc750 h\u7684\u8ba1\u65f6\u6d4b\u91cf\u540et-CoII<\/sup>-CoIII<\/sup>\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

b) t-CoII<\/sup>-CoIII<\/sup>\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

c) t-CoII<\/sup>-CoIII<\/sup>\u7684\u9009\u533a\u7535\u5b50\u884d\u5c04\u56fe\u50cf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u62a5\u9053\u4e86\u4e00\u79cd\u4ee5\u78b1\u5f0f\u78b3\u9178\u76d0\u4e3a\u6a21\u677f\u7684\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269(PBAs)\u7684\u5408\u6210\u53ca\u5176\u5728\u78b1\u6027\u4ecb\u8d28\u4e2d\u826f\u597d\u7684\u6c34\u6c27\u5316\u6d3b\u6027\u3002\u4e0a\u8ff0\u6a21\u677f\u6cd5\u4e3a\u81ea\u652f\u6491\u96c6\u6210\u4f53\u7cfb\u7684\u6784\u7b51\u63d0\u4f9b\u4e86\u6240\u9700\u7684\u673a\u68b0\u7a33\u5b9a\u6027\u3001\u7535\u5b50\u7535\u5bfc\u7387\u548c\u9ad8\u7535\u5316\u5b66\u8868\u9762\u79ef\u3002\u50ac\u5316\u5242\u8fbe\u523010 mA\u00b7cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u65f6\u8fc7\u7535\u538b\u4f4e\u81f3240 mV\u3002\u50ac\u5316\u5242\u7a33\u5b9a\u6027\u826f\u597d\uff0c\u5728\u8d85\u8fc750 h\u7684\u8ba1\u65f6\u6d4b\u91cf\u4e2d\u4ecd\u80fd\u4ea7\u751f\u6052\u5b9a\u7535\u6d41\u3002\u9ad8\u7535\u6d41\u5bc6\u5ea6\u3001\u7b80\u5355\u7684\u7535\u5b50\u4f20\u9012\u4ee5\u53ca\u826f\u597d\u7684\u5236\u6c27\u957f\u671f\u7a33\u5b9a\u6027\u4f7f\u6a21\u677f\u5316PBA\u8def\u7ebf\u9002\u5408\u5b9e\u9645\u5e94\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Boosting Electrochemical Water Oxidation with Metal Hydroxide Carbonate Templated Prussian Blue Analogues<\/a><\/strong>\u00a0(Angew. Chem. Int. Ed., 2018, DOI: 10.1002\/anie.201710809)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

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