{"id":123839,"date":"2018-02-12T06:30:15","date_gmt":"2018-02-11T22:30:15","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=123839"},"modified":"2018-02-11T17:05:44","modified_gmt":"2018-02-11T09:05:44","slug":"adv-funct-mater-%e7%94%b5%e5%8c%96%e5%ad%a6%e6%80%a7%e8%83%bd%e5%8f%af%e8%b0%83%e7%9a%84cu-mofs%e6%9d%90%e6%96%99%e9%97%ae%e4%b8%96","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=123839","title":{"rendered":"Adv. Funct. Mater.: \u7535\u5316\u5b66\u6027\u80fd\u53ef\u8c03\u7684Cu-MOFs\u6750\u6599\u95ee\u4e16"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08\u7b80\u79f0MOFs\uff09\u662f\u4e00\u7c7b\u9ad8\u5ea6\u6709\u5e8f\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599\uff0c\u5177\u6709\u6bd4\u8868\u9762\u79ef\u5927\u3001\u5b54\u9699\u7387\u9ad8\u3001\u529f\u80fd\u53ef\u8c03\u3001\u4e3b-\u5ba2\u4f53\u76f8\u4e92\u4f5c\u7528\u3001\u7a33\u5b9a\u6027\u9ad8\u7b49\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5728\u6c14\u4f53\u5438\u9644\/\u5206\u79bb\u3001\u4f20\u611f\u3001\u50ac\u5316\u7b49\u9886\u57df\u663e\u793a\u51fa\u5de8\u5927\u7684\u5e94\u7528\u6f5c\u529b\u3002\u5728\u5404\u79cd\u5e94\u7528\u4e2d\uff0cMOFs\u7684\u7535\u5316\u5b66\u5e94\u7528\u4e00\u76f4\u975e\u5e38\u53d7\u5173\u6ce8\uff0c\u4f46\u4e0d\u5e78\u7684\u662fMOFs\u9700\u8981\u96c6\u6210\u6216\u6d82\u8986\u5728\u5bfc\u7535\u886c\u5e95\u7684\u8868\u9762\u4e0a\uff0c\u624d\u80fd\u7528\u4e8e\u7535\u5316\u5b66\u53ca\u76f8\u5173\u5e94\u7528\u3002\u636e\u62a5\u9053\uff0c\u91c7\u7528MOF\u57fa\u78b3\u7cca\u6cd5\u5236\u4f5c\u7535\u6781\u867d\u7136\u7b80\u5355\uff0c\u4f46\u5176\u7a33\u5b9a\u6027\u548c\u51c6\u786e\u6027\u5dee\uff0c\u56e0\u800c\u96be\u4ee5\u5b9e\u7528\u3002\u4f5c\u4e3a\u4e00\u4e2a\u66ff\u4ee3\u65b9\u6cd5\uff0c\u5c31\u662f\u5c06\u6750\u6599\u76f4\u63a5\u6c89\u79ef\u5728\u5bfc\u7535\u57fa\u677f\u4e0a\u7528\u4e8e\u7535\u5316\u5b66\u6c27\u5316\u6216\u8fd8\u539f\u53cd\u5e94\uff0c\u4f46\u5173\u4e8e\u4e0d\u540c\u914d\u4f53\u5bf9\u5408\u6210\u6750\u6599\u5f62\u6001\u548c\u7535\u5316\u5b66\u6027\u80fd\u7684\u5f71\u54cd\u3001\u6750\u6599\u7684\u7a33\u5b9a\u6027\u7b49\u65b9\u9762\u5374\u9c9c\u6709\u62a5\u9053\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u5434\u5eb7\u5175\u6559\u6388<\/strong>\u548c\u5fb7\u56fd\u9521\u6839\u5927\u5b66\u6768\u5e74\u4fca\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u7814\u53d1\u56e2\u961f\u5728Adv. Funct. Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cTunable Electrochemistry of Electrosynthesized Copper Metal\u2013Organic Frameworks<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u4e2d\u7814\u7a76\u4eba\u5458\u4ee51,3,5-\u82ef\u4e09\u7532\u9178\uff08BTC\uff09\u30011,4-\u5bf9\u82ef\u4e8c\u7532\u9178\uff08BDC\uff09\u30011,2,4,5-\u82ef\u56db\u7532\u9178\uff08BTEC\uff09\u4e3a\u6709\u673a\u914d\u4f53\uff0c\u91c7\u7528\u7b80\u5355\u7684\u7535\u5316\u5b66\u8fd8\u539f\u6cd5\u5236\u5907\u51fa\u4e86Cu-MOFs\u65b0\u6750\u6599\uff0c\u5e76\u5bf9\u8be5\u6750\u6599\u8fdb\u884c\u7535\u5bb9\u3001\u7535\u89e3\u3001\u7535\u50ac\u5316\u884c\u4e3a\u3001\u7535\u5316\u5b66\u7a33\u5b9a\u6027\u7b49\u6d4b\u8bd5\uff0c\u7814\u7a76\u4eba\u5458\u53d1\u73b0Cu-MOFs\u6750\u6599\u7684\u7535\u5316\u5b66\u6027\u80fd\u4f9d\u8d56\u4e8e\u4f7f\u7528\u7684\u6709\u673a\u914d\u4f53\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u9009\u62e9\u6709\u673a\u914d\u4f53\u548c\u91d1\u5c5e\u79bb\u5b50\u8bbe\u8ba1MOFs\u6750\u6599\u6027\u80fd\u53ef\u7b80\u5316\u5408\u6210\u8fc7\u7a0b\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 <\/strong>\u91c7\u7528\u4e0d\u540c\u914d\u4f53\u5236\u5907\u7684<\/strong>Cu-MOFs<\/strong>\u7535\u955c\u53ca\u6b21\u7ea7\u6a21\u578b\u5bf9\u6bd4<\/strong><\/p>\n

\"\"<\/p>\n

(A\u3001D\u3001G) Cu-BTEC\u7684SEM\u3001TEM\u56fe\u53ca\u8be5\u6750\u6599\u6b21\u7ea7\u7ed3\u6784\u5355\u5143\u6a21\u578b\uff1b<\/p>\n

(B\u3001E\u3001H) Cu-BDC\u7684SEM\u3001TEM\u56fe\u53ca\u8be5\u6750\u6599\u6b21\u7ea7\u7ed3\u6784\u5355\u5143\u6a21\u578b\uff1b<\/p>\n

(C\u3001F\u3001I) Cu-BTC\u7684SEM\u3001TEM\u56fe\u53ca\u8be5\u6750\u6599\u6b21\u7ea7\u7ed3\u6784\u5355\u5143\u6a21\u578b\u3002<\/p>\n

\u56fe<\/strong>2 <\/strong>\u91c7\u7528\u4e0d\u540c\u914d\u4f53\u5236\u5907\u7684<\/strong>Cu-MOFs<\/strong>\u7535\u5316\u5b66\u6027\u80fd\u53ef\u8c03\u6027\u8003\u5bdf<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u57280.1M KCl\u6eb6\u6db2\u4e2d\u626b\u63cf\u901f\u7387100 mV s\u22121<\/sup>\u6761\u4ef6\u4e0b\u6d4b\u5f97\u7684(a) Cu-BTEC\u3001(b) Cu-BDC\u3001(c) Cu-BTC \u7535\u5bb9\u4f0f\u5b89\u56fe\uff0c\u5047\u5b9a\u8be5\u5408\u6210\u6750\u6599\u5177\u6709\u76f8\u540c\u7684\u5f52\u4e00\u5316\u7535\u5bb9\uff0c\u5219\u8868\u660e\u8be5\u6750\u6599\u5177\u6709\u76f8\u540c\u7684\u8868\u9762\u79ef\uff1b<\/p>\n

(B) \u57280.1M KCl\u6c34\u6eb6\u6db2\u4e2d\u8bb0\u5f55\u7684(a)\u3001(b)\u3001(c)\u6cd5\u62c9\u7b2c\u884c\u4e3a\u56fe\u3002<\/p>\n

\u56fe<\/strong>3 Cu-MOFs<\/strong>\u5728\u4f20\u611f\u9886\u57df\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u5728\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u6cd5\u8bb0\u5f55\u56fe\u4e2d\u53ef\u6e05\u6670\u770b\u5230\u5c16\u9510\u7684Cu-MOFs\u9634\u6781\u5cf0\uff1b<\/p>\n

(B) \u5b89\u57f9\u66f2\u7ebf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u5728\u8fd9\u9879\u5de5\u4f5c\u4e2d\uff0c\u5206\u522b\u91c7\u7528\u4e09\u79cd\u6709\u673a\u914d\u4f4d\u4f53\u5408\u6210Cu-MOFs\uff0c\u6d4b\u8bd5\u4e86\u5408\u6210\u6750\u6599\u5f62\u6001\u548c\u6750\u6599\u5f62\u6001\u5bf9\u5176\u7535\u5316\u5b66\u6027\u80fd\u53ca\u5e94\u7528\u6548\u679c\u7684\u5f71\u54cd\uff0c\u4f5c\u8005\u6307\u51fa\u5408\u6210\u6750\u6599\u7684\u7535\u5bb9\u3001\u6cd5\u62c9\u7b2c\u884c\u4e3a\u3001\u7535\u5316\u5b66\u54cd\u5e94\u7b49\u6027\u80fd\u4f9d\u8d56\u4e8e\u4e0e\u6750\u6599\u5f62\u6001\u548c\u66b4\u9732\u7684\u94dc\u6d3b\u6027\u4f4d\u70b9\u6570\u76ee\uff0c\u800c\u6750\u6599\u5f62\u6001\u548c\u91d1\u5c5e\u6d3b\u6027\u53d7\u914d\u4f53\u5f71\u54cd\u8f83\u5927\u3002\u91c7\u75281,3,5-\u82ef\u4e09\u7532\u9178\u5408\u6210\u7684Cu\u2013MOFs\u5728\u7535\u50ac\u5316H2<\/sub>O2<\/sub>\u8fd8\u539f\u53cd\u5e94\u4e2d\u5177\u6709\u6700\u4f73\u7684\u7535\u5316\u5b66\u6d3b\u6027\uff0c\u5229\u7528\u6b64\u4f18\u70b9\u53ef\u5236\u5907\u9ad8\u7075\u654f\u5ea6\u548c\u9ad8\u9009\u62e9\u6027\u7684H2<\/sub>O2<\/sub>\u7535\u5316\u5b66\u4f20\u611f\u68c0\u6d4b\u5668\u3002\u8fd9\u9879\u57fa\u7840\u5de5\u4f5c\u7684\u8fdb\u884c\uff0c\u5f00\u8f9f\u4e86MOFs\u5728\u7535\u5316\u5b66\u6027\u80fd\u53ef\u8c03\u65b9\u9762\u7684\u7814\u7a76\u65b9\u6cd5\uff0c\u4e3a\u8bbe\u8ba1\u65b0\u578bMOFs\u6750\u6599\u63d0\u4f9b\u4e86\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Tunable Electrochemistry of Electrosynthesized Copper Metal\u2013Organic Frameworks<\/a>\uff08Adv. Funct. Mater.\uff0c2018\uff0cDIO: 10.1002\/adfm.201706961\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u65b0\u4eba\u7ec4\u738b\u5065\u5eb7\u4f9b\u7a3f\uff0c\u8d75\u98de\u9f99\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u3002<\/a><\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c<\/strong>\u4e0a\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08\u7b80\u79f0MOFs\uff09\u662f\u4e00\u7c7b\u9ad8\u5ea6\u6709\u5e8f\u7684\u65b0\u578b\u591a\u5b54\u6750\u6599\uff0c\u5177\u6709\u6bd4\u8868\u9762\u79ef\u5927\u3001\u5b54\u9699\u7387\u9ad8\u3001\u529f\u80fd\u53ef\u8c03\u3001\u4e3b-\u5ba2\u4f53\u76f8\u4e92\u4f5c\u7528\u3001\u7a33\u5b9a\u6027\u9ad8\u7b49\u72ec\u7279\u7684\u7269\u7406\u5316\u5b66\u6027\u8d28\uff0c\u5728\u6c14\u4f53\u5438…<\/p>\n","protected":false},"author":230,"featured_media":123841,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[2789],"class_list":["post-123839","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-mofs"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/123839"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=123839"}],"version-history":[{"count":2,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/123839\/revisions"}],"predecessor-version":[{"id":123844,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/123839\/revisions\/123844"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/123841"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=123839"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=123839"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=123839"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}