{"id":123934,"date":"2018-02-02T06:30:07","date_gmt":"2018-02-01T22:30:07","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=123934"},"modified":"2018-02-01T23:00:30","modified_gmt":"2018-02-01T15:00:30","slug":"adv-funct-mater-%ef%bc%9a%e5%90%84%e5%90%91%e5%bc%82%e6%80%a7ag2s-au%e4%b8%89%e8%a7%92%e7%ba%b3%e7%b1%b3%e6%a3%b1%e6%9f%b1%e7%94%a8%e4%ba%8e%e7%ad%89%e7%a6%bb%e5%ad%90%e4%bd%93%e5%8f%af%e8%a7%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=123934","title":{"rendered":"Adv. Funct. Mater. \uff1a\u5404\u5411\u5f02\u6027Ag2S-Au\u4e09\u89d2\u7eb3\u7c73\u68f1\u67f1\u7528\u4e8e\u7b49\u79bb\u5b50\u4f53\u53ef\u89c1\/\u8fd1\u7ea2\u5916\u5149\u50ac\u5316\u5236\u6c22"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u5177\u6709\u8868\u9762\u7b49\u79bb\u5b50\u4f53\u5171\u632f(SPR)\u7684\u8d35\u91d1\u5c5e\u7eb3\u7c73\u9897\u7c92(NPs)\u4e0e\u534a\u5bfc\u4f53\u590d\u5408\u5f62\u6210\u7684\u7b49\u79bb\u5b50\u4f53\u5149\u50ac\u5316\u5242\uff0c\u7531\u4e8e\u5176\u5f3a\u70c8\u7684\u53ef\u89c1\/\u8fd1\u7ea2\u5916\u5149\u54cd\u5e94\u548c\u9ad8\u6548\u7684\u7535\u8377\u5206\u79bb\uff0c\u5438\u5f15\u4e86\u4f17\u591a\u7814\u7a76\u4eba\u5458\u7684\u5173\u6ce8\u3002\u7b49\u79bb\u5b50\u4f53\u5149\u50ac\u5316\u673a\u7406\u4e00\u822c\u8ba4\u4e3a\u662f\u5165\u5c04\u5149\u6fc0\u53d1\u7b49\u79bb\u5b50\u4f53\u91d1\u5c5e\u7684\u81ea\u7531\u7535\u5b50\u5f62\u6210\u8f6c\u79fb\u5230\u534a\u5bfc\u4f53\u7684\u70ed\u7535\u5b50\u4ee5\u751f\u6210\u6c22\u6c14\uff0c\u800c\u7a7a\u7a74\u4fdd\u7559\u4e8e\u91d1\u5c5e\u8fdb\u884c\u6c27\u5316\u53cd\u5e94\u3002\u7b49\u79bb\u5b50\u4f53\u5149\u50ac\u5316\u5242\u7684\u6027\u80fd\u5f88\u5927\u7a0b\u5ea6\u4e0a\u53d6\u51b3\u4e8e\u91d1\u5c5e\u7c92\u5b50\u7684\u7ed3\u6784\u548c\u7ec4\u6210\u3002\u7531\u4e8eSPR\u8bf1\u5bfc\u7684\u7535\u5b50-\u7a7a\u7a74\u5bf9\u590d\u5408\u901f\u7387\u8f83\u5feb\uff0c\u6784\u7b51\u5f02\u8d28\u7ed3(\u534a\u5bfc\u4f53\/\u91d1\u5c5e)\u80fd\u591f\u4fc3\u8fdb\u534a\u5bfc\u4f53\u548c\u91d1\u5c5e\u4e4b\u95f4\u7684\u7b49\u79bb\u5b50\u4f53\u70ed\u7535\u5b50\u8f6c\u79fb\uff0c\u63d0\u5347\u5149\u50ac\u5316\u5236\u6c22\u6027\u80fd\u3002\u7136\u800c\uff0c\u534a\u5bfc\u4f53\u548c\u91d1\u5c5e\u4e4b\u95f4\u7684\u590d\u5408\u65b9\u5f0f\u5bf9\u4e8e\u7b49\u79bb\u5b50\u4f53\u5149\u50ac\u5316\u5242\u7684\u6027\u80fd\u81f3\u5173\u91cd\u8981\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u65e5\u672c\u5927\u962a\u5927\u5b66Tetsuro Majima\u6559\u6388\u3001\u66a8\u5357\u5927\u5b66\u674e\u5b9d\u519b\u6559\u6388(\u5171\u540c\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u901a\u8fc7\u63a7\u5236Ag2<\/sub>S\u7684\u9009\u62e9\u6027\u589e\u751f\uff0c\u5236\u5907\u4e86\u5404\u5411\u5f02\u6027\u7684Ag2<\/sub>S\u5916\u5ef6Au-\u4e09\u89d2\u7eb3\u7c73\u68f1\u67f1(TNPs)\u4f5c\u4e3a\u7b49\u79bb\u5b50\u4f53\u5149\u50ac\u5316\u5242\u7528\u4e8e\u5149\u50ac\u5316\u5236\u6c22\uff0c\u5e76\u5728Adv. Funct. Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cAnisotropic Ag2<\/sub>S\u2013Au Triangular Nanoprisms with Desired Configuration for Plasmonic Photocatalytic Hydrogen Generation in Visible\/Near-Infrared Region<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u5728\u53ef\u89c1\u5149\u548c\u8fd1\u7ea2\u5916\u5149\u7167\u5c04\u4e0b\uff0cAg2<\/sub>S\u5916\u5ef6Au-TNPs\u7684\u5236\u6c22\u901f\u7387(796 \u03bcmol\u00b7h-1<\/sup>\u00b7g-1<\/sup>)\u76f8\u6bd4Ag2<\/sub>S\u5305\u8986Au-TNPs(216 \u03bcmol\u00b7h-1<\/sup>\u00b7g-1<\/sup>)\u548c\u7eafAu-TNPs\u9ad8\u51fa\u8fd14\u500d\u3002\u5355\u7c92\u5b50\u5149\u81f4\u53d1\u5149\u7814\u7a76\u8868\u660e\u7b49\u79bb\u5b50\u4f53\u8bf1\u5bfc\u7684\u70ed\u7535\u5b50\u7531Au-TNPs\u5411Ag2<\/sub>S\u8f6c\u79fb\u8fdb\u800c\u7528\u4e8e\u4ea7\u6c22\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1 \u50ac\u5316\u5242\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a-c) Au\/Ag-TNPs(\u6838\/\u58f3)\u3001Ag2<\/sub>S\u5305\u8986Au-TNPs\u548cAg2<\/sub>S\u5916\u5ef6Au-TNPs\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

d) Au\/Ag-TNPs(\u6838\/\u58f3)\u3001Ag2<\/sub>S\u5305\u8986Au-TNPs\u548cAg2<\/sub>S\u5916\u5ef6Au-TNPs\u7684\u53ef\u89c1-\u8fd1\u7ea2\u5916\u5438\u6536\u5149\u8c31\u3002<\/p>\n

\u56fe2 Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u7684\u5f62\u8c8c\u548c\u5143\u7d20\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

a,f) Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

b) Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u7684HAABF-TEM\u56fe\u50cf\uff1b<\/p>\n

c) Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u7684HAADF-TEM\u56fe\u50cf\uff1b<\/p>\n

d,e) Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u7684HRTEM\u56fe\u50cf\uff1b<\/p>\n

g-i) Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u7684\u5143\u7d20\u5206\u5e03\uff1b<\/p>\n

j) \u5355\u9897\u7c92Ag2<\/sub>S\u5916\u5ef6Au-TNP\u7684EDS\u7ebf\u626b\u3002<\/p>\n

\u56fe3 \u785d\u9178\u94f6\u52a0\u5165\u91cf\u5bf9Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u5f62\u8c8c\u548c\u5149\u5438\u6536\u7684\u5f71\u54cd<\/strong><\/p>\n

\"\"<\/p>\n

a-c) \u4e0d\u540c\u785d\u9178\u94f6(20 \u00d7 10-3<\/sup> M)\u52a0\u5165\u91cf(10\u300120\u548c30 \u03bcL)\u7684Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u7684TEM\u56fe\u50cf\uff1b
\n d) \u4e0a\u8ff0\u6837\u54c1\u7684\u5438\u6536\u5149\u8c31\u3002<\/p>\n

\u56fe4 \u786b\u6e90\u53cd\u5e94\u65f6\u95f4\u5bf9Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u5f62\u8c8c\u548c\u5149\u5438\u6536\u7684\u5f71\u54cd<\/strong><\/p>\n

\"\"<\/p>\n

a-e) \u4e0e\u786b\u6e90\u53cd\u5e94\u4e0d\u540c\u65f6\u95f4(1-5 d)\u7684Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

f) \u4e0a\u8ff0\u6837\u54c1\u7684\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

g) Ag2<\/sub>S\u5728Au-TNPs\u4e0a\u5404\u5411\u5f02\u6027\u751f\u957f\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe5 Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u7684\u5149\u50ac\u5316\u5236\u6c22\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a,b) Ag2<\/sub>S\u5305\u8986\u3001Ag2<\/sub>S\u5916\u5ef6\u3001\u7eafAu-TNPs\u548cAg2<\/sub>S\u4f5c\u4e3a\u7b49\u79bb\u5b50\u4f53\u5149\u50ac\u5316\u5242\u5728\u53ef\u89c1-\u8fd1\u7ea2\u5916(\u03bb>420 nm)\u5149\u7167\u4e0b\u7684\u5236\u6c22\u6d3b\u6027\u548c\u901f\u7387\uff1b<\/p>\n

c) Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u7684\u5149\u50ac\u5316\u5236\u6c22\u8868\u89c2\u91cf\u5b50\u6548\u7387\u548c\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

d) \u4e0d\u540c\u751f\u957f\u65f6\u95f4Ag2<\/sub>S\u5916\u5ef6 Au-TNPs\u6837\u54c1\u7684\u5149\u50ac\u5316\u5236\u6c22\u901f\u7387\u3002<\/p>\n

\u56fe6 \u50ac\u5316\u5242\u7684\u5355\u9897\u7c92\u7a33\u6001\u8367\u5149<\/strong><\/p>\n

\"\"<\/p>\n

a,c) Au-TNP\u548cAg2<\/sub>S\u5916\u5ef6 Au-TNP\u7684\u5355\u9897\u7c92PL\u56fe\u50cf\uff1b<\/p>\n

b,d) Au-TNP\u548cAg2<\/sub>S\u5916\u5ef6 Au-TNP\u7684\u5355\u9897\u7c92PL\u5149\u8c31\u3002<\/p>\n

\u56fe7 Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u5149\u50ac\u5316\u5236\u6c22\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u5149\u50ac\u5316\u5236\u6c22\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u901a\u8fc7\u63a7\u5236Ag2<\/sub>S\u5728Au-TNP\u8fb9\u7f18\u7684\u9009\u62e9\u6027\u589e\u751f\uff0c\u5236\u5907\u4e86\u5404\u5411\u5f02\u6027\u7684Ag2<\/sub>S\u5916\u5ef6Au-TNPs\uff0c\u4f5c\u4e3a\u7b49\u79bb\u5b50\u4f53\u5149\u50ac\u5316\u5242\u7528\u4e8e\u8fd1\u7ea2\u5916\u5149\u50ac\u5316\u5236\u6c22\uff0c\u5176\u5236\u6c22\u901f\u7387\u662fAg2<\/sub>S\u5305\u8986Au-TNPs\u7684\u8fd14\u500d\u3002\u5355\u7c92\u5b50\u5149\u81f4\u53d1\u5149\u7814\u7a76\u8868\u660e\u7b49\u79bb\u5b50\u4f53\u8bf1\u5bfc\u7684\u70ed\u7535\u5b50\u7531Au-TNPs\u5411Ag2<\/sub>S\u8f6c\u79fb\u4e3a\u8fdb\u800c\u7528\u4e8e\u4ea7\u6c22\uff0c\u591a\u6781\u8868\u9762\u7b49\u79bb\u5b50\u4f53\u5171\u632f(MSPR)\u548c\u5076\u6781\u8868\u9762\u7b49\u79bb\u5b50\u4f53\u5171\u632f(DSPR)\u662fSPR PL\u6dec\u706d\u548c\u7535\u8377\u5206\u79bb\u7684\u6e20\u9053\u3002\u65f6\u57df\u6709\u9650\u5dee\u5206(FDTD)\u8ba1\u7b97\u548c\u5b9e\u9a8c\u7ed3\u679c\u8868\u660e\uff0c\u5404\u5411\u5f02\u6027Ag2<\/sub>S\u5916\u5ef6Au-TNPs\u80fd\u591f\u4fc3\u8fdbSPR\u8bf1\u5bfc\u70ed\u7535\u5b50\u8f6c\u79fb\u548c\u7535\u8377\u5206\u79bb\u4ee5\u8fdb\u884c\u9ad8\u6548\u5149\u50ac\u5316\u5236\u6c22\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Anisotropic Ag2<\/sub>S\u2013Au Triangular Nanoprisms with Desired Configuration for Plasmonic Photocatalytic Hydrogen Generation in Visible\/Near-Infrared Region<\/a><\/strong> (Adv. Funct. Mater., 2018, DOI: 10.1002\/adfm.201706969)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

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