{"id":127830,"date":"2018-03-06T06:30:36","date_gmt":"2018-03-05T22:30:36","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=127830"},"modified":"2018-03-04T22:14:42","modified_gmt":"2018-03-04T14:14:42","slug":"%e5%8d%8e%e4%b8%9c%e7%90%86%e5%b7%a5angew-chem-int-ed-%ef%bc%9a%e4%bb%a5%e8%a1%a8%e9%9d%a2%e6%b4%bb%e6%80%a7%e5%89%82%e4%b8%ba%e6%a8%a1%e6%9d%bf%e6%b0%b4%e7%9b%b8%e4%b8%ad%e5%88%b6%e5%a4%87","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=127830","title":{"rendered":"\u534e\u4e1c\u7406\u5de5Angew. Chem. Int. Ed.\uff1a\u4ee5\u8868\u9762\u6d3b\u6027\u5242\u4e3a\u6a21\u677f\u6c34\u76f8\u4e2d\u5236\u5907\u4ecb\u5b54Zr\u57faMOFs"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/span><\/p>\n

\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOFs\uff09\u6750\u6599\u5177\u6709\u6bd4\u8868\u9762\u79ef\u9ad8\u3001\u5b54\u5f84\u53ef\u8c03\u3001\u7ec4\u5206\u591a\u6837\u3001\u8868\u9762\u6613\u529f\u80fd\u5316\u7b49\u8bf8\u591a\u4f18\u70b9\uff0c\u662f\u5177\u6709\u5e7f\u9614\u5e94\u7528\u524d\u666f\u7684\u591a\u529f\u80fd\u6750\u6599\u3002\u7136\u800c\uff0c\u5927\u591aMOFs\u6750\u6599\u53ea\u5177\u6709\u5fae\u5b54\u7ed3\u6784\uff0c\u4e0d\u5229\u4e8e\u7269\u8d28\u4f20\u8f93\u548c\u5927\u5206\u5b50\u5ba2\u4f53\u7684\u8fdb\u5165\uff0c\u9650\u5236\u4e86\u8be5\u6750\u6599\u5728\u5927\u5206\u5b50\u5206\u79bb\u3001\u4f20\u611f\u3001\u91ca\u653e\u7b49\u8bf8\u591a\u9886\u57df\u7684\u5e94\u7528\u3002\u5728MOFs\u9aa8\u67b6\u4e2d\u5f15\u5165\u4ecb\u5b54\u5b54\u9053\u5e76\u5236\u5907\u5fae\u5b54-\u4ecb\u5b54\u5206\u89e3\u7ed3\u6784\u662f\u89e3\u51b3\u8fd9\u4e00\u96be\u9898\u7684\u53ef\u884c\u65b9\u6cd5\u4e4b\u4e00\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/span><\/p>\n

\u00a0<\/strong>\u8fd1\u65e5\uff0c\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u987e\u91d1\u697c\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u4e0e\u674e\u53ef\uff08\u7b2c\u4e00\u4f5c\u8005\uff09\u5728Angew. Chem. Int. Ed.<\/strong>\u53d1\u8868\u4e86\u9898\u4e3a\u201cAqueous-Phase Synthesis of Mesoporous Zr-Based MOFs Templated by Amphoteric Surfactants<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u7814\u7a76\u4ee5\u4e24\u6027\u8868\u9762\u6d3b\u6027\u5242\u4e3a\u6a21\u677f\uff0c\u5728\u6c34\u76f8\u4e2d\u6210\u529f\u5408\u6210\u4e86\u6709\u5e8f\u4ecb\u5b54\u7ed3\u6784\u7684Zr\u57faMOFs\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/span><\/p>\n

\u00a0<\/strong>\u56fe\u4e00. \u8868\u9762\u6d3b\u6027\u5242\u5316\u5b66\u7ed3\u6784\u5f0f<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\u56fe\u4e8c. \u6837\u54c1\u7684XRD\u548cBET\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u65e0\u6a21\u677f\u5242\u5236\u5907\u7684UiO-66-NH2<\/sub>\uff1b<\/p>\n

\uff08b\uff09CAPB\u4e3a\u6a21\u677f\u5236\u5907UiO-66-NH2<\/sub>\uff1b<\/p>\n

\uff08c\uff09OAPB\u4e3a\u6a21\u677f\u5236\u5907UiO-66-NH2<\/sub>\u3002<\/p>\n

\u56fe\u4e09. \u4ecb\u5b54UiO-66-NH2<\/sub>\u7684TEM\u8868\u5f81<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\uff08a\uff09\u548c\uff08b\uff09CAPB\u4e3a\u6a21\u677f\u5236\u5907UiO-66-NH2<\/sub>\u7684TEM\u8868\u5f81\uff1b<\/p>\n

\uff08c\uff09\u548c\uff08d\uff09OAPB\u4e3a\u6a21\u677f\u5236\u5907UiO-66-NH2<\/sub>\u7684TEM\u8868\u5f81\u3002<\/p>\n

\u56fe\u56db. \u516d\u65b9\u4ecb\u5b54UiO-66-NH2<\/sub>MOFs\u7684\u5f62\u6210\u673a\u7406<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\u56fe\u4e94. OAPB\u4e3a\u6a21\u677f\u5236\u5907\u7684\u4ecb\u5b54UiO-66-(OH)2<\/sub>\u7684\u7ed3\u679c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u516d. \u4e0d\u540c\u6a21\u677f\u5242\u5236\u5907\u7684UiO-66-NH2 <\/sub>MOFs\u5bf9\u7ec6\u80de\u8272\u7d20c\u7684\u5438\u9644\u91cf\u6bd4\u8f83<\/strong><\/p>\n

\"\"<\/p>\n

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\u3010\u5c0f\u7ed3\u3011<\/strong><\/span><\/p>\n

\u00a0<\/strong>\u8be5\u5de5\u4f5c\u4ee5\u7b80\u5355\u7684\u6c34\u76f8\u6a21\u677f\u6cd5\u5236\u5907\u4e86\u5fae\/\u4ecb\u5b54Zr\u57faMOFs\u6750\u6599\u3002\u8868\u9762\u6d3b\u6027\u5242\u4e0d\u4ec5\u8d77\u5230\u6a21\u677f\u4f5c\u7528\uff0c\u8fd8\u4e3a\u91d1\u5c5e\u524d\u9a71\u4f53\u63d0\u4f9b\u4e86\u951a\u5b9a\u4f4d\u70b9\u5e76\u5f15\u5bfc\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u5b9a\u5411\u7ec4\u88c5\u3002\u4ecb\u5b54UiO-66-NH2<\/sub>\u5c55\u73b0\u51fa\u4ecb\u5b54\u7684\u53ef\u8c03\u8282\u6027\u53ca\u6709\u673a\u6846\u67b6\u7684\u7a33\u5b9a\u6027\u3002\u4ecb\u5b54\u58c1\u7531\u89c4\u5219\u7684\u5fae\u5b54\u7ed3\u6676MOFs\u6784\u6210\u3002\u8fd9\u4e00\u5236\u5907\u65b9\u6cd5\u4e3a\u5236\u5907\u65b0\u578b\u4ecb\u5b54MOFs\u6750\u6599\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Aqueous-Phase Synthesis of Mesoporous Zr-Based MOFs Templated by Amphoteric Surfactants<\/a>\uff08Angew. Chem. Int. Ed., 2018 DOI: 10.1002\/anie.201800619\uff09<\/p>\n

\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong><\/p>\n

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\u8fd1\u5e74\u6765\uff0c\u5728Advanced Materials, Angewandte Chemie International Edition, Journal of the American Chemical Society, Advanced Functional Materials, Chemistry of Materials, Small, Journal of Physical Chemistry Letters, Chemical Communications, ACS Applied Materials & Interfaces\u7b49\u56fd\u9645\u77e5\u540d\u6742\u5fd7\u4e0a\u53d1\u8868SCI\u5b66\u672f\u8bba\u658790<\/strong>\u4f59\u7bc7\uff0c\u5355\u7bc7\u6700\u9ad8\u5f71\u54cd\u56e0\u5b5019.79<\/strong>\uff0c\u8bba\u6587\u4ed6\u5f15\u603b\u8ba13000<\/strong>\u4f59\u6b21\uff0cH\u56e0\u5b50\u8fbe\u523027<\/strong>\u3002\u53d1\u660e\u4e13\u5229\u591a\u9879\uff0c\u5176\u4e2d\u516c\u5f00\u53f7\u4e3aJP-2008-28019<\/strong>\u7684\u4e13\u5229\u6743\u5c5e\u5df2\u8f6c\u8ba9\u4e8e\u65e5\u672c\u677e\u4e0b\u7535\u5668\u516c\u53f8\u3002\u76ee\u524d\u4e3b\u6301\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\uff0c\u4e0a\u6d77\u5e02\u7eb3\u7c73\u6280\u672f\u4e13\u9879\u57fa\u91d1\uff0c\u4e0a\u6d77\u5e02\u6559\u59d4\u91cd\u70b9\u57fa\u91d1\uff0c\u6559\u80b2\u90e8\u535a\u58eb\u70b9\u57fa\u91d1\u7b49\u3002<\/p>\n

\u6559\u5b66\u65b9\u9762\u83b7\u5f97\uff1a\u5b9d\u94a2\u6559\u80b2\u5956\u3001\u4e0a\u6d77\u5e02\u5316\u5de5\u533a\u6559\u5b66\u5956\u3001\u4e0a\u6d77\u5e02\u4f18\u79c0\u7814\u7a76\u751f\u8bba\u6587\u6307\u5bfc\u8001\u5e08\u3001\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u6559\u5b66\u7ade\u8d5b\u4e00\u7b49\u5956\u3001\u6700\u4f73\u6559\u6848\u7f16\u5199\u5956\uff0c\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u6559\u5b66\u65b0\u661f\u3001\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u4f18\u79c0\u7814\u7a76\u751f\u8bba\u6587\u6307\u5bfc\u8001\u5e08\u7b49\u3002<\/p>\n

\u53c2\u4e0e\u7ffb\u8bd1\u4e13\u8457\u300a\u751f\u7269\u7cfb\u7edf\u7eb3\u7c73\u6280\u672f\u300b\u4e00\u90e8\u3002<\/p>\n

\u90e8\u5206\u7814\u7a76\u6210\u679c\uff1a<\/strong><\/p>\n

    \n
  1. Ke Li, Shaoliang Lin, Yongsheng Li, Qixin Zhuang and Jinlou Gu,* <\/strong>Aqueous phase synthesis of mesoporous Zr-based MOFs templated by amphoteric surfactant, Angewandte Chemie International Edition,<\/strong> 2018<\/strong>, In Press.<\/li>\n
  2. Zhe Wang, Shuanggang Hu, Jian Yang, Ajuan Liang, Yongsheng Li, Qixin Zhuang and Jinlou Gu,*<\/strong> Nanoscale Zr-based MOFs with tailorable size and introduced mesopore for protein delivery, Advanced Functional Materials<\/strong>, 2018<\/strong>, 201707356.<\/li>\n
  3. Pengfei Yang, Fangxin Mao, Yongsheng Li, Qixin Zhuang and Jinlou Gu,*<\/strong> Hierarchical\u00a0porous Zr-based MOFs synthesized by a facile monocarboxylic acid etching strategy, Chemistry-A European Journal<\/strong>, 2018<\/strong>, 2962-2970.<\/li>\n
  4. Zhe Wang, Jian Yang, Yongsheng Li, Qixin Zhuang and Jinlou Gu,*<\/strong> In situ carbothermal synthesis of nZVI functionalized porous carbon from Fe-MOFs for efficient detoxification of Cr(VI), European Journal of Inorganic Chemistry,<\/strong> 2018<\/strong>, 23-30.<\/li>\n
  5. Jian Yang, Xiaojing Chen, Yongsheng Li, Qixin Zhuang, Peifeng Liu, and Jinlou Gu,*<\/strong> Zr-based MOFs shielded with phospholipid bilayers: improved biostability and cell uptake for biological applications, Chemistry of Materials<\/strong>,\u00a02017<\/strong>,\u00a029, 4580-4589.<\/li>\n
  6. Zhe Wang, Jian Yang, Yongsheng Li, Qixin Zhuang, and Jinlou Gu,*<\/strong> Simultaneous degradation and removal of Cr(VI) from aqueous solution with Zr-Based MOFs bearing inherent reductive sites, Chemistry-A European Journal<\/strong>, 2017<\/strong>, 15415-15423.<\/li>\n
  7. Chao Wu,\u00a0Xiangyang Zhu,\u00a0Zhe Wang,\u00a0Jian Yang,\u00a0Yongsheng Li, and\u00a0Jinlou Gu,*<\/strong> Specific recovery and in situ reduction of precious metal from waste to create MOF composites with immobilized nanoclusters, Industrial & Engineering Chemistry Research, 2017, <\/strong>56, 13975-13982.<\/li>\n
  8. Zhe Wang, Ying Huang, Jian Yang, Yongsheng Li, Qixin Zhuang, and Jinlou Gu,* Water-based synthesis of chemically stable Zr-based MOFs using pyridine-containing ligands and their exceptionally high adsorption capacity for iodine, Dalton Transactions, 2017<\/strong>, 46, 7412-7420.<\/li>\n
  9. Jian Yang, Zhe Wang, Yongsheng Li, Qixin Zhuang, and Jinlou Gu<\/strong>,* Real-time monitoring of dissolved oxygen with inherent oxygen sensitive centers in metal\u2212organic frameworks, Chemistry of Materials<\/strong>, 2016<\/strong>, 28, 2652-58.<\/li>\n
  10. Bing Li, Xiangyang Zhu, Kaili Hu, Yongsheng Li, Jianfang Feng, Jianlin Shi, and Jinlou Gu<\/strong>,* Defect creation in metal-organic frameworks for rapid and controllable decontamination of roxarsone from aqueous solution, Journal of Hazardous Materials<\/strong>, 2016<\/strong>, 302, 57-64.<\/li>\n
  11. Jian Yang, Zhe Wang, Yongsheng, Li, Qixin Zhuang, Wenru, Zhao, and Jinlou Gu,*<\/strong> Porphyrinic MOFs for reversible fluorescent and colorimetric sensing of mercury(II) ions in aqueous phase, RSC Advances, 2016<\/strong>, 6, 69807-69814.<\/li>\n<\/ol>\n

    \u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u5b66\u672f\u7ec4Mr_PSP[\u5f6d\u80dc\u6500]\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

    \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a><\/span>\u3002<\/p>\n

    \u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/span>\u3002<\/p>\n

    \u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

    \u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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