{"id":128002,"date":"2018-03-05T06:30:45","date_gmt":"2018-03-04T22:30:45","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=128002"},"modified":"2018-03-04T22:10:55","modified_gmt":"2018-03-04T14:10:55","slug":"%e5%8d%8e%e4%b8%9c%e7%90%86%e5%b7%a5%e8%b4%ba%e6%99%93%e9%b9%8f%e4%b8%8a%e4%ba%a4%e9%ba%a6%e4%ba%a6%e5%8b%87-angew-chem-int-ed%ef%bc%9a%e6%b0%b4%e7%9b%b8%e4%b8%ad%e7%9f%b3%e5%a2%a8%e7%83%af","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=128002","title":{"rendered":"\u534e\u4e1c\u7406\u5de5\u8d3a\u6653\u9e4f&amp;\u4e0a\u4ea4\u9ea6\u4ea6\u52c7 Angew. Chem. Int. Ed\uff1a\u6c34\u76f8\u4e2d\u77f3\u58a8\u70ef\u7eb3\u7c73\u5e26\u7684\u8d85\u5206\u5b50\u7eb3\u7c73\u7ed3\u6784\u7814\u7a76"},"content":{"rendered":"<p>\u3010<strong>\u5f15\u8a00<\/strong>\u3011<\/p>\n<p>\u77f3\u58a8\u70ef\u7eb3\u7c73\u5e26(GNR) \u7531\u4e8e\u5176\u72ec\u7279\u7684\u5149\u5b66\uff0c\u7535\u5b50\u548c\u78c1\u5b66\u7279\u6027\uff0c\u5f15\u8d77\u4e86\u79d1\u7814\u4eba\u5458\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5728\u5176\u4f17\u591a\u7684\u5408\u6210\u65b9\u6cd5\u4e2d\uff0c\u81ea\u4e0b\u800c\u4e0a\u7684\u6db2\u76f8\u5408\u6210\u6cd5\u5728\u5728\u6db2\u76f8\u5206\u6563\u7684GNR\u5927\u89c4\u6a21\u751f\u4ea7\u4e2d\u5177\u6709\u4f17\u591a\u4f18\u70b9\uff0c\u4f8b\u5982\u660e\u786e\u7684\u7ed3\u6784\uff0c\u53ef\u63a7\u7684\u957f\u5ea6\uff0c\u5bbd\u5ea6\u548c\u8fb9\u7f18\u7ed3\u6784\u3002\u5c3d\u7ba1\u5b9e\u73b0\u4e86\u6db2\u76f8\u53ef\u5206\u6563\u7684GNRs\uff0c\u4f46\u7531\u4e8e\u7f3a\u5c11\u5408\u9002\u7684\u63a5\u679d\u90e8\u5206\uff0c\u96be\u4ee5\u514b\u670dGNR\u7684p-p\u5806\u53e0\u3002\u56e0\u6b64\uff0c\u6db2\u76f8\u4e2dGNR\u7684\u7814\u7a76\u53d7\u5230\u963b\u788d\uff0c\u8d85\u5206\u5b50\u81ea\u7ec4\u88c5\u548c\u6709\u5e8f\u8d85\u7ed3\u6784\u7684\u5e94\u7528\u9700\u8981\u8fdb\u4e00\u6b65\u7814\u7a76\u3002\u6700\u8fd1\u6709\u5b66\u8005\u7814\u7a76\u4e86GNRs\u63a5\u679d\u4eb2\u6c34\u67d4\u6027\u805a\u4e59\u70ef\u6c27\u5316\u7269\uff0c\u4e3a\u8d85\u5206\u5b50\u81ea\u7ec4\u88c5GNR\u7684\u57fa\u7840\u7814\u7a76\u5f00\u8f9f\u4e86\u9053\u8def\uff0c\u5e76\u5c06\u7ed3\u6784\u5b9a\u4e49GNR\u7684\u7814\u7a76\u6269\u5c55\u5230\u6c34\u76f8\u57fa\u9886\u57df\u3002<\/p>\n<p>\u3010<strong>\u6210\u679c\u7b80\u4ecb<\/strong>\u3011<\/p>\n<p>\u8fd1\u65e5\uff0c<strong>\u534e\u4e1c\u7406\u5de5\u5927\u5b66\u7684\u8d3a\u6653\u9e4f\u6559\u6388\u548c\u4e0a\u6d77\u4ea4\u901a\u5927\u5b66\u7684\u9ea6\u4ea6\u52c7\u6559\u6388(\u901a\u8baf\u4f5c\u8005)<\/strong>\u7b49\u4eba\u5728<strong>Angew. Chem. Int. Ed<\/strong>\u4e0a\u53d1\u5e03\u4e86\u4e00\u7bc7\u5173\u4e8es\u77f3\u58a8\u70ef\u7eb3\u7c73\u5e26\u7684\u6587\u7ae0\uff0c\u9898\u4e3a\u201c<strong>Supramolecular Nanostructures of Structurally Defined Graphene Nanoribbons in the Aqueous Phase<\/strong>\u201d\u3002\u4f5c\u8005\u901a\u8fc7\u6db2\u76f8\u5408\u6210\u6cd5\u5408\u6210\u4e86GNR\u63a5\u679d\u4eb2\u6c34\u67d4\u6027\u805a\u4e59\u70ef\u6c27\u5316\u7269(GNR-PEO), PEO\u63a5\u679d\u7387\u4e3a42-51\uff05\uff0c\u5728GNR\u6d53\u5ea6\u9ad8\u8fbe0.5 mg mL-1\u6eb6\u6db2\u4e2d\u4e2d\u5177\u6709\u4f18\u5f02\u7684\u5206\u6563\u6027\u3002GNR-PEO\u7684\u5237\u72b6\u7ed3\u6784\u5728\u6c34\u76f8\u4e2d\u5bfc\u81f4\u4e861D\u5206\u5c42\u81ea\u7ec4\u88c5\u884c\u4e3a\uff0c\u5f62\u6210\u4e86\u8d85\u957f\u7eb3\u7c73\u5e26\u6216\u5177\u6709\u53ef\u8c03\u5e73\u5747\u76f4\u5f84\u548c\u95f4\u8ddd\u7684\u5f39\u7c27\u72b6\u87ba\u65cb\u7ed3\u6784\u3002\u5728\u6c34\u5206\u6563\u4f53\u4e2d\uff0c\u8d85\u7ed3\u6784\u7684\u5149\u8c31\u5728\u8fd1\u7ea2\u5916\u8303\u56f4\u5185\u5438\u6536\uff0c\u8bf4\u660e\u5149\u5b50\u80fd\u91cf\u8f6c\u5316\u4e3a\u70ed\u80fd\u3002<\/p>\n<p>\u3010<strong>\u56fe\u7247\u5bfc\u8bfb<\/strong>\u3011<\/p>\n<p><strong>\u56fe1 GNR-PEO\u7684\u5206\u5b50\u7ed3\u6784\u53ca\u5176\u5728\u6c34\u4e2d\u53ef\u80fd\u7684\u5206\u5c42\u81ea\u7ec4\u88c5\u673a\u7406\u56fe\u89e3<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-128006\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/1-3.png\" alt=\"\" width=\"600\" height=\"240\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/1-3.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/1-3-300x120.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n\u7531\u4e8e\u53d1\u751f\u5e94\u529b\u8bf1\u53d1\u7684\u9a6c\u6c0f\u4f53\u8f6c\u53d8(SIM)\uff0c\u53ef\u4ee5\u6e05\u695a\u5730\u89c2\u5bdf\u5230\u6ede\u540e\u56de\u7ebf\u30023\uff05\u5e94\u53d8\u540e\uff0c\u9a6c\u6c0f\u4f53\u03b1\u201c\u76f8\u5f00\u59cb\u53d1\u751f\u5f39\u6027\u53d8\u5f62\uff0c\u7136\u540e\u53d1\u751f\u5851\u6027\u53d8\u5f62\u3002<\/p>\n<p><strong>\u56fe2 GNR-PEO\u5728\u6c34\u76f8\u4e2d\u7684\u5206\u6563\u548c\u8d85\u5206\u5b50\u7eb3\u7c73\u7ed3\u6784<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-128007\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/2-4.png\" alt=\"\" width=\"600\" height=\"496\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/2-4.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/2-4-300x248.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n(<strong>a<\/strong>) \u5177\u6709\u4e0d\u540c\u6700\u5927\u9aa8\u67b6\u6d53\u5ea6\u7684GNR-PEO\u7684\u6c34\u5206\u6563\u4f53\uff1b<\/p>\n<p>(<strong>b<\/strong>) GNR-PEO\u5206\u6563\u4f53\u7684\u6d53\u5ea6\u4e0ePEO\u7684\u5206\u5b50\u91cf\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n<p>(<strong>c<\/strong>) GNR-PEO1000\u5728THF\u548c\u6c34\u4e2d\u7684UV\/Vis\u5149\u8c31\uff1b<\/p>\n<p>(<strong>d-f<\/strong>) \u6c34\u4e2dGNR-PEO\u7684\u4e0a\u5c42\u7ed3\u6784\u5178\u578bTEM\u56fe\u50cf\u3002<\/p>\n<p><strong>\u56fe3 GNR-PEO\u7684TEM\u548cAFM\u56fe\u50cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-128008\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/3-4.png\" alt=\"\" width=\"600\" height=\"515\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/3-4.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/3-4-300x258.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n(<strong>a-b<\/strong>) \u87ba\u65cb\u72b6\u7ed3\u6784\u7684\u4f4e\u500d\u653e\u5927TEM\u56fe\u50cf\uff1b<\/p>\n<p>(<strong>c<\/strong>) \u6807\u6709\u76f8\u5e94\u5c3a\u5bf8\u7684\u5f39\u7c27\u72b6\u87ba\u65cb\u7684\u9ad8\u500d\u7387TEM\u56fe\u50cf\uff1b<\/p>\n<p>(<strong>d<\/strong>) \u771f\u5b9e\u7684\u5f26\u7ed3\u6784\uff1b<\/p>\n<p>(<strong>e<\/strong>) \u975e\u87ba\u65cb\u90e8\u5206\u7684\u9ad8\u653e\u5927\u7387TEM\u56fe\u50cf\uff1b<\/p>\n<p>(<strong>f-g<\/strong>) \u53cc\u94fe\u87ba\u65cb\u7ed3\u6784\u7684AFM\u9ad8\u5ea6\u5206\u5e03\u56fe\uff1b<\/p>\n<p>(<strong>h<\/strong>) \u975e\u87ba\u65cb\u90e8\u5206\u7684AFM\u9ad8\u5ea6\u56fe\u50cf\uff1b<\/p>\n<p>(<strong>i<\/strong>) \u6cbf\u7740\u767d\u8272\u865a\u7ebf\u7a7f\u8fc7\u6761\u72b6\u7ed3\u6784\u7684\u7ebf\u8f6e\u5ed3\u3002<\/p>\n<p><strong>\u56fe4 \u6837\u54c1\u7684\u70ed\u56fe\u50cf<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-128005\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/4-4.png\" alt=\"\" width=\"600\" height=\"353\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/4-4.png 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/03\/4-4-300x177.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><br \/>\n(<strong>a<\/strong>) GNR-PEO\u6c34\u5206\u6563\u4f53\u548c\u4e0d\u540c\u4f4e\u7ef4\u6750\u6599\u7684\u6e29\u5ea6\u968f\u7740\u65f6\u95f4\u800c\u589e\u52a0\uff1b<\/p>\n<p><strong>(b)<\/strong> GNR-PEO\u6c34\u5206\u6563\u4f53\u7684\u70ed\u56fe\u50cf\uff1b<\/p>\n<p>(<strong>c<\/strong>) \u4e0d\u540c\u4f4e\u7ef4\u6750\u6599\u6c34\u5206\u6563\u4f53\u7684\u70ed\u56fe\u50cf\u3002<\/p>\n<p>\u3010<strong>\u5c0f\u7ed3<\/strong>\u3011<\/p>\n<p>\u4f5c\u8005\u5408\u6210\u4e86\u4e00\u7cfb\u5217\u7ed3\u6784\u826f\u597d\u7684GNR\u63a5\u679d\u6709\u4e0d\u540c\u957f\u5ea6\u7684PEO\u7ebf\u5708\u3002GNR-PEO\u6837\u54c1\u5177\u670942-51\uff05\u7684\u63a5\u679d\u7387\uff0c\u5e76\u6839\u636ePEO\u957f\u5ea6\u663e\u793a\u51fa\u9ad8\u8fbe0.5mg\/mL\u7684\u9ad8\u6d53\u5ea6\u6c34\u5206\u6563\u6027\u3002GNR-PEO\u5f97\u76ca\u4e8e\u72ec\u7279\u7684\u6746\u72b6\u7ebf\u5708\u5237\u7ed3\u6784\uff0c\u5177\u6709\u660e\u786e\u800c\u575a\u786c\u7684\u9aa8\u67b6\u51e0\u4f55\u7ed3\u6784\uff0c\u5728\u6c34\u4e2d\u8868\u73b0\u51fa\u4e00\u7ef4\u5206\u5c42\u81ea\u7ec4\u88c5\u884c\u4e3a\uff0c\u6839\u636ePEO\u957f\u5ea6\u751f\u6210\u4e86\u53ef\u8c03\u8282\u76f4\u5f84\u548c\u95f4\u8ddd\u7684\u7eb3\u7c73\u5e26\u6216\u5f39\u7c27\u72b6\u87ba\u65cb\u3002\u6c34\u4e2d\u7684GNR-PEO\u8d85\u7ed3\u6784\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5149\u70ed\u8f6c\u5316\u6027\u80fd\u548c\u9ad8\u6548\u7387\u3002\u8fd9\u7bc7\u6587\u7ae0\u4e0d\u4ec5\u4e3aGNR\u81ea\u7ec4\u88c5\u7684\u57fa\u7840\u7814\u7a76\u5f00\u8f9f\u4e86\u9053\u8def\uff0c\u540c\u65f6\u8fd8\u5c06GNR\u7814\u7a76\u6269\u5c55\u5230\u5e7f\u6cdb\u7684\u6c34\u57fa\u9886\u57df\u5982\u6c34\u51dd\u80f6\u6216\u5149\u70ed\u80bf\u7624\u6cbb\u7597\u3002<\/p>\n<p><strong>\u6587\u732e\u94fe\u63a5<\/strong>\uff1a<a href=\"http:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.201712637\/full\" target=\"_blank\" rel=\"noopener\">Supramolecular Nanostructures of Structurally Defined GrapheneNanoribbons in the Aqueous Phase<\/a> (Angew. Chem. Int. Ed, 22 February, 2018 , DOI: 10.1002\/anie.201712637\uff09<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u7eb3\u7c73\u5b66\u672f\u7ec4jcfxs01\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener\">\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002<\/p>\n<p>\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong>\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\">\u6d4b\u8bd5\u8c37<\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 \u77f3\u58a8\u70ef\u7eb3\u7c73\u5e26(GNR) \u7531\u4e8e\u5176\u72ec\u7279\u7684\u5149\u5b66\uff0c\u7535\u5b50\u548c\u78c1\u5b66\u7279\u6027\uff0c\u5f15\u8d77\u4e86\u79d1\u7814\u4eba\u5458\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u5728\u5176\u4f17\u591a\u7684\u5408\u6210\u65b9\u6cd5\u4e2d\uff0c\u81ea\u4e0b\u800c\u4e0a\u7684\u6db2\u76f8\u5408\u6210\u6cd5\u5728\u5728\u6db2\u76f8\u5206\u6563\u7684GNR\u5927\u89c4&#8230;<\/p>\n","protected":false},"author":4915,"featured_media":128006,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[46,33],"class_list":["post-128002","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-graphene","tag-nano"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/128002"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/4915"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=128002"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/128002\/revisions"}],"predecessor-version":[{"id":128458,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/128002\/revisions\/128458"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/128006"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=128002"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=128002"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=128002"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}