{"id":130549,"date":"2018-03-17T06:30:28","date_gmt":"2018-03-16T22:30:28","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=130549"},"modified":"2018-03-16T20:52:00","modified_gmt":"2018-03-16T12:52:00","slug":"%e5%8c%97%e7%a7%91%e5%a4%a7%e8%8c%83%e4%b8%bd%e7%8f%8dacs-ami%ef%bc%9a%e5%9b%ba%e6%80%81%e9%94%82%e7%94%b5%e6%b1%a0%e7%94%a8%e4%b8%89%e7%bb%b4%e5%8f%8c%e7%9b%b8%e5%af%bc%e9%94%82%e5%a4%8d%e5%90%88","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=130549","title":{"rendered":"\u5317\u79d1\u5927\u8303\u4e3d\u73cdACS AMI\uff1a\u56fa\u6001\u9502\u7535\u6c60\u7528\u4e09\u7ef4\u53cc\u76f8\u5bfc\u9502\u590d\u5408\u56fa\u4f53\u7535\u89e3\u8d28"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u56fa\u6001\u9502\u7535\u6c60\u56e0\u5176\u56fa\u4f53\u7535\u89e3\u8d28\u5177\u6709\u4e0d\u6325\u53d1\u3001\u4e0d\u53ef\u71c3\u3001\u7535\u5316\u5b66\u7a97\u53e3\u5bbd\u7b49\u4f18\u70b9\uff0c\u6210\u4e3a\u9502\u7535\u6c60\u53d1\u5c55\u7684\u91cd\u8981\u65b9\u5411\u3002\u56fa\u6001\u9502\u7535\u6c60\u7684\u5f00\u53d1\u4ecd\u5b58\u5728\u56fa\u4f53\u7535\u89e3\u8d28\u79bb\u5b50\u7535\u5bfc\u7387\u4f4e\u3001\u7535\u89e3\u8d28\/\u7535\u6781\u754c\u9762\u7a33\u5b9a\u6027\u5dee\u7b49\u95ee\u9898\u3002\u65e0\u673a\u56fa\u4f53\u7535\u89e3\u8d28\u5177\u6709\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3001\u5bbd\u7684\u7535\u538b\u7a97\u53e3\uff0c\u4f46\u662f\u4ecd\u5b58\u5728\u4e00\u4e9b\u7f3a\u70b9\uff0c\u5982\u9676\u74f7\u7535\u89e3\u8d28\u4e0e\u7535\u6781\u754c\u9762\u7684\u521a\u6027\u754c\u9762\u6da6\u6e7f\u6027\u5dee\uff0c\u5bfc\u81f4\u754c\u9762\u963b\u6297\u8f83\u5927\uff1b\u91d1\u5c5e\u9502\u8d1f\u6781\u6613\u88ab\u6c27\u5316\u7269\u9676\u74f7\u8fd8\u539f\u7b49\u3002\u78f7\u9178\u949b\u94dd\u9502\uff08LATP\uff09\u4f5c\u4e3a\u4e00\u79cd\u6613\u5236\u5907\u3001\u4f4e\u6210\u672c\u3001\u9ad8\u7535\u5bfc\u7387\u3001\u5bf9\u7a7a\u6c14\u7a33\u5b9a\u7684\u9676\u74f7\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u5f15\u8d77\u4e86\u5e7f\u6cdb\u5173\u6ce8\uff0c\u4f46\u5176\u4e0e\u91d1\u5c5e\u9502\u63a5\u89e6\u65f6\u4f1a\u53d1\u751f\u53cd\u5e94\uff0c\u9650\u5236\u4e86\u5176\u5728\u91d1\u5c5e\u9502\u4e3a\u8d1f\u6781\u7684\u56fa\u6001\u9502\u7535\u6c60\u4e2d\u7684\u5e94\u7528\u3002\u805a\u5408\u7269\u7535\u89e3\u8d28\u5177\u6709\u8f83\u9ad8\u7684\u67d4\u6027\uff0c\u4e0e\u7535\u6781\u4e4b\u95f4\u6613\u5f62\u6210\u201c\u8f6f\u754c\u9762\u201d\uff0c\u589e\u52a0\u7535\u89e3\u8d28\/\u7535\u6781\u7684\u56fa-\u56fa\u754c\u9762\u7684\u63a5\u89e6\u9762\u79ef\uff0c\u8d77\u5230\u63d0\u9ad8\u754c\u9762\u7a33\u5b9a\u6027\u7684\u4f5c\u7528\uff0c\u4f46\u805a\u5408\u7269\u7535\u89e3\u8d28\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u8f83\u4f4e\uff0c\u4e14\u673a\u68b0\u5f3a\u5ea6\u4f4e\u6613\u88ab\u9502\u679d\u6676\u523a\u7a7f\u3002\u5c06\u805a\u5408\u7269\u4e0e\u65e0\u673a\u7535\u89e3\u8d28\u6709\u6548\u590d\u5408\uff0c\u6709\u671b\u83b7\u5f97\u517c\u5177\u4e8c\u8005\u4f18\u70b9\u7684\u590d\u5408\u56fa\u4f53\u7535\u89e3\u8d28\u3002<\/p>\n

\u3010\u6210\u679c\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6765\u81ea\u5317\u4eac\u79d1\u6280\u5927\u5b66\u8303\u4e3d\u73cd\u6559\u6388\u7814\u7a76\u56e2\u961f\u7ed3\u5408\u9759\u7535\u7eba\u4e1d\u548c\u6eb6\u6db2\u6d47\u94f8\u6280\u672f\u5236\u5907\u4e86\u4e00\u79cd\u4ee5\u805a\u4e19\u70ef\u8148\uff08<\/strong>PAN<\/strong>\uff09<\/strong>\/<\/strong>\u78f7\u9178\u949b\u94dd\u9502\uff08<\/strong>LATP<\/strong>\uff09\u7eb3\u7c73\u590d\u5408\u7ea4\u7ef4\u4e3a\u4e09\u7ef4\u9aa8\u67b6\uff0c\u805a\u6c27\u4e59\u70ef\uff08<\/strong>PEO<\/strong>\uff09\u57fa\u805a\u5408\u7269\u7535\u89e3\u8d28\u4e3a\u586b\u5145\u7684\u53cc\u76f8\u5bfc\u9502\u590d\u5408\u56fa\u4f53\u7535\u89e3\u8d28\u819c\uff08<\/strong>FCSE<\/strong>\uff09<\/strong>\u3002\u7531\u4e8e\u805a\u5408\u7269\u7ea4\u7ef4\u7684\u5b58\u5728\uff0c\u53ef\u4ee5\u5c06LATP\u4e0e\u91d1\u5c5e\u9502\u9694\u7edd\uff0c\u89e3\u51b3\u4e24\u8005\u4e4b\u95f4\u7684\u63a5\u89e6\u53cd\u5e94\u95ee\u9898\uff0c\u5b9e\u73b0\u5177\u6709\u9ad8\u7a33\u5b9a\u6027\u7684\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u3002\u7531\u4e8e\u4e09\u7ef4\u590d\u5408\u7ea4\u7ef4\u7f51\u7edc\u9aa8\u67b6\u7684\u5f15\u5165\uff0c\u590d\u5408\u7535\u89e3\u8d28\u819c\u76f8\u6bd4\u7eaf\u805a\u5408\u7269\u7535\u89e3\u8d28\uff0c\u5176\u62c9\u4f38\u5f3a\u5ea6\u3001\u7535\u5316\u5b66\u7a97\u53e3\u548c\u70ed\u7a33\u5b9a\u6027\u5747\u5f97\u5230\u4e86\u6709\u6548\u63d0\u5347\u3002\u805a\u5408\u7269\u7eb3\u7c73\u7ea4\u7ef4\u5bf9LATP\u7684\u4fdd\u62a4\u4f5c\u7528\uff0c\u4f7f\u8be5\u590d\u5408\u7535\u89e3\u8d28\u5bf9\u9502\u5177\u6709\u5f88\u9ad8\u7684\u754c\u9762\u7a33\u5b9a\u6027\u3002\u5bf9\u6bd4LATP\u9676\u74f7\u7247\u7ec4\u88c5\u7684Li|LATP|Li\u7535\u6c60\uff0cLi|FCSE|Li\u5177\u6709\u66f4\u7a33\u5b9a\u7684\u754c\u9762\uff0c\u4e14\u754c\u9762\u963b\u6297\u66f4\u4f4e\u3002\u91c7\u7528FCSE\u4e3a\u7535\u89e3\u8d28\u7ec4\u88c5\u7684\u5168\u56fa\u6001\u7535\u6c60\u5177\u6709\u4f18\u5f02\u7684\u5faa\u73af\u6027\u80fd\u548c\u500d\u7387\u6027\u80fd\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201c3D fiber-network reinforced bicontinuous composite solid electrolyte for dendrite-free lithium metal batteries<\/em><\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728\u671f\u520aACS Appl. Mater. Interfaces 2018, 10, 7069\u22127078<\/em>\uff08\u5f71\u54cd\u56e0\u5b50\uff1a7.504\uff09\u3002<\/em><\/p>\n

\"\"<\/p>\n

TOC\u56fe<\/strong><\/p>\n

 <\/p>\n

\u00a0<\/em>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 FCSE<\/strong>\u590d\u5408\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u5236\u5907\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u6eb6\u80f6\u51dd\u80f6\u6cd5\u5236\u5907\u7684Li1.5<\/sub>Al0.5<\/sub>Ti1.5<\/sub>(PO4<\/sub>)3<\/sub> \u7eb3\u7c73\u7c89\u4f53<\/p>\n

(b) PAN\u548cLATP\u7c89\u4f53\u5728DMF\u4e2d\u6df7\u5408\u5236\u5907\u7535\u7eba\u4e1d\u524d\u9a71\u4f53\u6eb6\u6db2<\/p>\n

(c) \u9759\u7535\u7eba\u4e1d\u6cd5\u5f97\u5230\u7684 LATP\/PAN \u7f51\u7edc<\/p>\n

(d) PEO-LiTFSI\u6eb6\u6db2\u6d47\u94f8\u5236\u5907\u7ea4\u7ef4\u589e\u5f3a\u7684\u590d\u5408\u7535\u89e3\u8d28<\/p>\n

\u00a0\u56fe2 FCSE\u7684\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

(a) LATP\u7eb3\u7c73\u7c89\u4f53\u7684XRD\u548cSEM\u56fe<\/p>\n

(b) 2LATP\/PAN \u7eb3\u7c73\u590d\u5408\u7ea4\u7ef4\u819c\u7684SEM\u56fe\u548c\u5149\u5b66\u7167\u7247<\/p>\n

(c) FCSE\u7684SEM\u56fe\u548c\u5149\u5b66\u7167\u7247<\/p>\n

\u00a0\u56fe3 FCSE\u7684\u7535\u5bfc\u7387\u548c\u70ed\u5206\u6790\u66f2\u7ebf<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u4e0d\u540c\u6210\u5206\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u968f\u6e29\u5ea6\u53d8\u5316\u66f2\u7ebf<\/p>\n

(b) FCSE\u548cPEO-LiTFSI\u7684DSC\u66f2\u7ebf<\/p>\n

\u00a0\u56fe4 FCSE\u7684\u7535\u5316\u5b66\u7a97\u53e3\u3001\u70ed\u7a33\u5b9a\u6027\u53ca\u529b\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a) FCSE\u548cPEO-LiTFSI\u572860 o<\/sup>C\u6d4b\u8bd5\u7684CV\u66f2\u7ebf<\/p>\n

(b) Li|FCSE|SS\u548cLi|PEO-LiTFSI|SS\u572860 o<\/sup>C\u65bd\u52a04.5V\u504f\u538b\u4e0d\u540c\u65f6\u95f4\u7684\u963b\u6297\u8c31<\/p>\n

(c) FCSE\u548c\u5546\u7528Celgard\u9694\u819c\u7684\u70ed\u7a33\u5b9a\u6027\u5bf9\u6bd4\u56fe<\/p>\n

(d) FCSE\u548cPEO-LiTFSI\u7684\u529b\u5b66\u62c9\u4f38\u6027\u80fd\u66f2\u7ebf<\/p>\n

\u00a0\u56fe5 FCSE\u3001PEO-LiTFSI\u5bf9\u91d1\u5c5e\u9502\u5316\u5b66\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(a) LATP\u9676\u74f7\u7247\u4e0e\u91d1\u5c5e\u9502\u8d1f\u6781\u63a5\u89e6\u524d\u540e\u7684\u989c\u8272\u5bf9\u6bd4<\/p>\n

(b) Li|LATP|Li\u5bf9\u79f0\u7535\u6c60\u572860o<\/sup>C\u653e\u7f6e\u4e0d\u540c\u65f6\u95f4\u540e\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\u56fe<\/p>\n

(c) \u7eb3\u7c73\u7ea4\u7ef4\u819c\u548cFCSE\u4e0e\u91d1\u5c5e\u9502\u63a5\u89e67\u5929\u540e\u7684\u5149\u5b66\u7167\u7247<\/p>\n

(d) Li|FCSE|Li\u53caLi|PEO-LiTFSI|Li\u5bf9\u79f0\u7535\u6c60\u572860o<\/sup>C\u9759\u7f6e\u4e0d\u540c\u65f6\u95f4\u540e\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\u56fe<\/p>\n

\u00a0\u56fe6 FCSE\u3001PEO-LiTFSI\u5bf9\u91d1\u5c5e\u9502\u7535\u5316\u5b66\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u4ee5FCSE\u4e0ePEO-LiTFSI\u7ec4\u88c5\u7684\u9502\u5bf9\u79f0\u7535\u6c60\u572860 o<\/sup>C\u4ee50.3 mA\/cm2<\/sup>\u5145\u653e\u7535\u66f2\u7ebf\u5bf9\u6bd4\u56fe<\/p>\n

(b) \u5145\u653e\u4e0d\u540c\u65f6\u95f4\u4e0b\u7684\u5bf9\u79f0\u7535\u6c60\u963b\u6297\u8c31\u5bf9\u6bd4\u56fe<\/p>\n

(c) Li|FCSE|Li\u5faa\u73af400 h\u540eFCSE\u7535\u89e3\u8d28\u8868\u9762SEM\u56fe<\/p>\n

(d) Li|FCSE|Li\u5faa\u73af400h\u540e\u7684\u9502\u7247\u8868\u9762SEM\u56fe<\/p>\n

(e) Li|PEO-LiTFSI|Li\u5faa\u73af400h\u540e\u7684\u9502\u7247\u8868\u9762SEM\u56fe<\/p>\n

\u00a0\u56fe7 Li|FCSE|LiFePO4<\/sub> \u572860o<\/sup>C\u6d4b\u8bd5\u7684\u5168\u56fa\u6001\u7535\u6c60\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a)\u4e0d\u540c\u500d\u7387\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf<\/p>\n

(b)\u4e0d\u540c\u500d\u7387\u4e0b\u7684\u5faa\u73af\u6027\u80fd<\/p>\n

(c) \u6052\u6d41\u5145\u653e100\u6b21\u7684\u5bb9\u91cf\u548c\u5e93\u4f26\u6548\u7387\u5bf9\u6bd4\u56fe<\/p>\n

(d) \u5faa\u73af\u4e0d\u540c\u6b21\u6570\u540e\u7684\u7535\u5316\u5b66\u963b\u6297\u8c31\u56fe<\/p>\n

(e) Li|PEO8<\/sub>-LiTFSI|LiFePO4<\/sub>\u7535\u6c60\u9502\u6c89\u79ef\u5265\u79bb\u793a\u610f\u56fe<\/p>\n

(f) Li|FCSE|LiFePO4<\/sub>\u7535\u6c60\u9502\u6c89\u79ef\u5265\u79bb\u793a\u610f\u56fe<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u5de5\u4f5c\u5229\u7528\u9759\u7535\u7eba\u4e1d\u548c\u6eb6\u6db2\u6d47\u94f8\u6280\u672f\u6210\u529f\u5236\u5907\u4e86\u4e00\u79cd\u53cc\u76f8\u5bfc\u9502\u4e09\u7ef4\u7f51\u7edc\u7ed3\u6784\u590d\u5408\u56fa\u4f53\u7535\u89e3\u8d28\u3002\u8be5\u590d\u5408\u56fa\u4f53\u7535\u89e3\u8d28\u5b9e\u73b0\u4e86\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3001\u5bbd\u7535\u538b\u7a97\u53e3\u4ee5\u53ca\u7a33\u5b9a\u7684\u7535\u6781\/\u7535\u89e3\u8d28\u754c\u9762\u3002\u7531\u4e8eLATP\u7eb3\u7c73\u9897\u7c92\u88ab\u5851\u5c01\u5728\u805a\u5408\u7269\u7eb3\u7c73\u7ea4\u7ef4\u7ed3\u6784\u4e2d\uff0c\u6709\u6548\u9694\u7edd\u4e86LATP\u4e0e\u91d1\u5c5e\u9502\u4e4b\u95f4\u7684\u5316\u5b66\u53cd\u5e94\u3002PEO\u7535\u89e3\u8d28\u5bf9\u8be5\u4e09\u7ef4\u7f51\u7edc\u7ed3\u6784\u7684\u586b\u5145\uff0c\u8fdb\u4e00\u6b65\u5b8c\u5584\u4e86\u9502\u79bb\u5b50\u5bfc\u7535\u7f51\u7edc\u7ed3\u6784\uff0c\u5e76\u589e\u52a0\u4e86\u7535\u89e3\u8d28\u819c\u7684\u67d4\u97e7\u6027\u548c\u673a\u68b0\u5f3a\u5ea6\u3002\u4e0e\u7eaf\u7684LATP\u9676\u74f7\u7247\u76f8\u6bd4\uff0cFCSE\u4e0e\u91d1\u5c5e\u9502\u7684\u754c\u9762\u963b\u6297\u66f4\u5c0f\u4e14\u968f\u65f6\u95f4\u65e0\u660e\u663e\u53d8\u5316\uff1b\u4e0e\u7eaf\u7684PEO\u57fa\u805a\u5408\u7269\u7535\u89e3\u8d28\u76f8\u6bd4\uff0cFCSE\u7684\u62c9\u4f38\u5f3a\u5ea6\u589e\u957f\u8fd112\u500d\u3002\u4ee5\u8be5\u590d\u5408\u7535\u89e3\u8d28\u7ec4\u88c5\u7684\u9502\u5bf9\u79f0\u7535\u6c60\u548c\u5168\u7535\u6c60\u5177\u6709\u4f18\u826f\u7684\u7a33\u5b9a\u6027\u3001\u754c\u9762\u517c\u5bb9\u6027\u548c\u6709\u6548\u6291\u5236\u9502\u679d\u6676\u7684\u80fd\u529b\u3002<\/p>\n

\u672c\u6210\u679c\u662f\u5728\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u91cd\u70b9\u9879\u76ee(51532002)\u3001\u5317\u4eac\u5e02\u81ea\u7136\u57fa\u91d1-\u6d77\u6dc0\u8054\u5408\u539f\u59cb\u521b\u65b0\u57fa\u91d1\u91cd\u70b9\u9879\u76ee\uff08L172023\uff09\u548c\u79d1\u6280\u90e8\u91cd\u5927\u7814\u53d1\u8ba1\u5212\uff082015CB932500\uff09\u7684\u8d44\u52a9\u4e0b\u5b8c\u6210\u3002\u672c\u7814\u7a76\u5de5\u4f5c\u7684\u4f5c\u8005\u4f9d\u6b21\u4e3a\u674e\u4e39\u3001\u9648\u9f99\u3001\u738b\u5929\u77f3\u3001\u8303\u4e3d\u73cd\u3002\u901a\u8baf\u4f5c\u8005\u4e3a\u8303\u4e3d\u73cd\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a3D fiber-network reinforced bicontinuous composite solid electrolyte for dendrite-free lithium metal batteries<\/a><\/strong>\uff08<\/em>ACS Applied Materials & Interface, 2018, DOI: 10.1021\/acsami.7b18123.<\/em>\uff09<\/em><\/p>\n

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