{"id":130744,"date":"2018-03-18T06:30:11","date_gmt":"2018-03-17T22:30:11","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=130744"},"modified":"2018-03-18T11:44:58","modified_gmt":"2018-03-18T03:44:58","slug":"%e5%8d%97%e6%b4%8b%e7%90%86%e5%b7%a5%e7%8e%8b%e6%98%95adv-mater-%e9%94%82%e5%8c%96%e8%84%b1%e9%94%82%e5%88%b6%e5%a4%87%e5%af%a1%e5%b1%82%e7%a1%85%e7%83%af%e7%8a%b6%e7%ba%b3%e7%b1%b3%e7%89%87","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=130744","title":{"rendered":"\u5357\u6d0b\u7406\u5de5\u738b\u6615Adv. Mater. : \u9502\u5316\/\u8131\u9502\u5236\u5907\u5be1\u5c42\u7845\u70ef\u72b6\u7eb3\u7c73\u7247\u7528\u4e8e\u53ef\u5145\u9502\u6c27\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong>
\n \u7845\u70ef\u662f\u4e00\u79cd\u7c7b\u4f3c\u77f3\u58a8\u70ef\u3001\u5177\u6709\u5f2f\u66f2\u8702\u7a9d\u7ed3\u6784\u7684\u5355\u5c42\u7845\u539f\u5b50\u3002\u7845\u70ef\u7684\u672c\u5f81\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u9884\u8ba1\u4ec5\u7565\u4f4e\u4e8e\u77f3\u58a8\u70ef\u4f46\u4ecd\u5728\u540c\u4e00\u4e2a\u6570\u91cf\u7ea7\u3002\u6b64\u5916\uff0c\u7845\u70ef\u7684\u6027\u80fd\u6613\u4e8e\u901a\u8fc7\u5f62\u6210\u5408\u91d1\u3001\u63ba\u6742\u3001\u529f\u80fd\u5316\u4ee5\u53ca\u673a\u68b0\u5e94\u53d8\u7b49\u624b\u6bb5\u8fdb\u884c\u8c03\u8282\uff0c\u8fd9\u5728\u5f88\u5927\u7a0b\u5ea6\u4e0a\u6269\u5c55\u4e86\u5176\u5e94\u7528\u3002\u6700\u540e\u4f46\u540c\u6837\u91cd\u8981\u7684\u662f\uff0c\u7845\u7684\u4e30\u5ea6\u548c\u4f4e\u6210\u672c\u589e\u52a0\u4e86\u7845\u70ef\u57fa\u6750\u6599\u5b9e\u9645\u5e94\u7528\u7684\u5438\u5f15\u529b\u3002\u7136\u800c\uff0c\u7845\u70ef\u57fa\u6750\u6599\u76ee\u524d\u7684\u5408\u6210\u65b9\u6cd5\u4ecd\u5b58\u5728\u660e\u663e\u7684\u7f3a\u70b9\u3002\u4f8b\u5982\uff0c\u5916\u5ef6\u751f\u957f\u5236\u5907\u6548\u7387\u4f4e\uff0c\u800c\u57fa\u4e8e\u8d77\u59cb\u539f\u6599\u7684\u5316\u5b66\u5265\u79bb\u4e5f\u5b58\u5728\u4ea7\u91cf\u4f4e\u7684\u95ee\u9898\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u4e00\u79cd\u540c\u65f6\u5177\u6709\u9ad8\u4ea7\u7387\u548c\u9ad8\u6536\u76ca\u7684\u65b9\u6cd5\u662f\u7845\u70ef\u57fa\u6750\u6599\u5b9e\u9645\u5e94\u7528\u9762\u4e34\u7684\u5173\u952e\u6311\u6218\u4e4b\u4e00\u3002\u7535\u5316\u5b66\u9502\u5316\/\u8131\u9502\u8fc7\u7a0b(LDP)\u57282D\u8fc7\u6e21\u91d1\u5c5e\u786b\u5316\u7269\u7684\u5236\u5907\u5df2\u7ecf\u5f97\u5230\u5e94\u7528\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong>
\n \u8fd1\u65e5\uff0c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u738b\u6615\u6559\u6388(\u901a\u8baf\u4f5c\u8005)\u7b49<\/strong>\u4ee5\u7403\u78e8\u7eb3\u7c73\u7845\u7c89\u4e3a\u539f\u6599\uff0c\u901a\u8fc7\u81ea\u4e0a\u800c\u4e0b\u9502\u5316\/\u8131\u9502\u8fc7\u7a0b\u5236\u5907\u5be1\u5c42\u7845\u70ef\u72b6\u7eb3\u7c73\u7247\uff0c\u5e76\u5728Adv. Mater.<\/strong>\u4e0a\u53d1\u8868\u4e86\u9898\u4e3a\u201cLithiation\/Delithiation Synthesis of Few Layer Silicene Nanosheets for Rechargeable Li-O2<\/sub> Batteries<\/strong>\u201d\u7684\u7814\u7a76\u8bba\u6587\u3002\u7814\u7a76\u53d1\u73b0\u8131\u9502\u6eb6\u5242\u5bf9\u4e8e\u6700\u7ec8\u4ea7\u7269\u7684\u7ed3\u6784\u8d77\u5230\u4e86\u5173\u952e\u4f5c\u7528\uff0c\u4f7f\u7528\u5f02\u4e19\u9187\u80fd\u591f\u5f97\u523030-100 nm\u957f\u3001\u7ea62.4 nm\u539a\u76842D \u7845\u70ef\u72b6\u4ea7\u7269\u3002\u7535\u5316\u5b66\u7279\u6027\u5206\u6790\u8868\u660e\uff0c\u6240\u5f97\u4ea7\u7269\u7528\u4e8e\u53ef\u7528\u4e8e\u53ef\u5145Li-O2<\/sub>\u7535\u6c60\u4e2d\uff0c\u5e76\u663e\u793a\u51fa\u8f83\u9ad8\u6027\u80fd\uff0c\u5177\u670973%\u7684\u80fd\u6e90\u6548\u7387\u548c\u8f83\u9ad8\u7a33\u5b9a\u6027\u3002\u8be5\u5de5\u4f5c\u63d0\u51fa\u7684\u81ea\u4e0a\u5411\u4e0b\u7684\u5408\u6210\u7b56\u7565\u4e0d\u4ec5\u4e3a\u89e3\u51b3\u5177\u6709\u5236\u5907\u5be1\u5c42\u7845\u70ef\u7684\u6311\u6218\u6027\u95ee\u9898\u63d0\u4f9b\u4e86\u65b9\u6848\uff0c\u8fd8\u8bc1\u5b9e\u4e86\u5229\u7528\u975e\u5c42\u72b6\u7ed3\u6784\u5236\u5907\u4e8c\u7ef4\u6750\u6599\u7684\u53ef\u884c\u6027\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong>
\n \u56fe1 \u9502\u5316\/\u8131\u9502\u8fc7\u7a0b\u5236\u5907\u7845\u70ef\u6750\u6599<\/strong><\/p>\n

\"\"<\/p>\n

\u5728\u4e0d\u540c\u60c5\u51b5\u4e0b\u8fdb\u884c\u9502\u5316\/\u8131\u9502\u8fc7\u7a0b\u7684\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe2 \u7845\u70ef\u57fa\u6750\u6599\u7684\u5f62\u8c8c\u548c\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a,b) \u7845\u7eb3\u7c73\u6d77\u80c6\u7684TEM\u56fe\u50cf\uff1b
\n c) \u7845\u77f3\u58a8\u7684SEM\u56fe\u50cf\uff1b
\n d) \u5be1\u5c42\u7845\u70ef\u7684TEM\u56fe\u50cf\uff1b
\n e) \u5be1\u5c42\u7845\u70ef\u7684HRTEM\u56fe\u50cf\uff1b
\n f) \u5be1\u5c42\u7845\u70ef\u7684AFM\u56fe\u50cf\uff0c\u5185\u63d2\u4e3a\u56fe\u4e2d\u9ed1\u7ebf\u7684\u9ad8\u5ea6\u66f2\u7ebf\uff1b
\n g) \u4ea7\u7269\u7684XRD\u56fe\u8c31\u3002<\/p>\n

\u56fe3 \u7845\u70ef\u57fa\u6750\u6599\u7684\u8868\u9762\u5b98\u80fd\u56e2<\/strong><\/p>\n

\"\"<\/p>\n

a) \u7845\u7eb3\u7c73\u6d77\u80c6\u7684O 1s XPS\u8c31\u56fe\uff1b
\n b) \u7845\u7eb3\u7c73\u6d77\u80c6\u7684Si 2p XPS\u8c31\u56fe\uff1b
\n c) \u7845\u77f3\u58a8\u7684O 1s XPS\u8c31\u56fe\uff1b
\n d) \u7845\u77f3\u58a8\u7684Si 2p XPS\u8c31\u56fe\uff1b
\n e) \u5be1\u5c42\u7845\u70ef\u7684O 1s XPS\u8c31\u56fe\uff1b
\n f) \u5be1\u5c42\u7845\u70ef\u7684Si 2p XPS\u8c31\u56fe\u3002<\/p>\n

\u56fe4 \u5be1\u5c42\u7845\u70ef\u7684\u7535\u5316\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a) 100 mAh\u00b7g-1<\/sup>\u4e0bLi-O2<\/sub>\u7535\u6c60\u4e2d\u4e0d\u540c\u7535\u6781\u7684\u5178\u578b\u7535\u538b\u66f2\u7ebf\uff1b
\n b) SL\u7535\u6781\u5728\u4e0d\u540c\u7535\u6d41\u5bc6\u5ea6\u4e0b\u7684\u5178\u578b\u7535\u538b\u66f2\u7ebf\uff1b
\n c,d) 100\u548c200 mAh\u00b7g-1<\/sup>\u4e0bSL\u7535\u6781\u7684\u9009\u5b9a\u7535\u538b\u66f2\u7ebf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong>
\n \u57fa\u4e8e\u8be5\u5de5\u4f5c\uff0cLDP\u6cd5\u4e3a\u5408\u62102D \u7845\u70ef\u72b6\u6750\u6599\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u89e3\u51b3\u65b9\u6848\u3002\u6839\u636e\u6750\u6599\u8868\u5f81\u7ed3\u679c\u7684\u5206\u6790\uff0c\u53d1\u73b0SL\u4e3a\u7845\u7684\u4e00\u79cd\u540c\u5206\u5f02\u6784\u4f53\uff0c\u5176\u8868\u9762\u9644\u7740\u591a\u79cd\u5b98\u80fd\u56e2\uff0c\u5982Si(-O)2<\/sub>\u3001Si(-OH)x<\/sub>\u548cSi(-O)4<\/sub>\u3002\u7528\u4e8eLi-O2<\/sub>\u7535\u6c60(LOB)\u7684SL\u7535\u6781\u5177\u6709\u9ad8\u80fd\u6e90\u6548\u7387\u548c\u9ad8\u7a33\u5b9a\u6027\u3002\u8be5\u5de5\u4f5c\u6210\u679c\u53ef\u80fd\u9610\u660e\u7845\u70ef\u57fa\u6750\u6599\u672a\u6765\u7684\u7814\u7a76\u65b9\u5411\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a Lithiation\/Delithiation Synthesis of Few Layer Silicene Nanosheets for Rechargeable Li\u2013O2<\/sub> Batteries<\/a><\/strong> (Adv. Mater.<\/strong>, 2018, DOI: 10.1002\/adma.201705523)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5c0f\u7ec4abc940504\u3010\u8096\u6770\u3011\u7f16\u8bd1\u6574\u7406\uff0c\u53c2\u4e0e\u65b0\u80fd\u6e90\u8bdd\u9898\u8ba8\u8bba\u8bf7\u52a0\u5165\u201c\u6750\u6599\u4eba\u65b0\u80fd\u6e90\u6750\u6599\u4ea4\u6d41\u7fa4 422065953\u201d\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH\uff0c\u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba\u3001\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7845\u70ef\u662f\u4e00\u79cd\u7c7b\u4f3c\u77f3\u58a8\u70ef\u3001\u5177\u6709\u5f2f\u66f2\u8702\u7a9d\u7ed3\u6784\u7684\u5355\u5c42\u7845\u539f\u5b50\u3002\u7845\u70ef\u7684\u672c\u5f81\u8f7d\u6d41\u5b50\u8fc1\u79fb\u7387\u9884\u8ba1\u4ec5\u7565\u4f4e\u4e8e\u77f3\u58a8\u70ef\u4f46\u4ecd\u5728\u540c\u4e00\u4e2a\u6570\u91cf\u7ea7\u3002\u6b64\u5916\uff0c\u7845\u70ef\u7684\u6027\u80fd\u6613\u4e8e\u901a\u8fc7\u5f62\u6210\u5408\u91d1\u3001\u63ba\u6742…<\/p>\n","protected":false},"author":4931,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[],"class_list":["post-130744","post","type-post","status-publish","format-standard","hentry","category-jiedu"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/130744"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/4931"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=130744"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/130744\/revisions"}],"predecessor-version":[{"id":130815,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/130744\/revisions\/130815"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=130744"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=130744"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=130744"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}