{"id":131225,"date":"2018-03-22T06:30:00","date_gmt":"2018-03-21T22:30:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=131225"},"modified":"2018-03-21T23:15:34","modified_gmt":"2018-03-21T15:15:34","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e5%9c%a8%e8%be%83%e3%80%91%e4%b8%93%e9%a2%98%e6%8a%a5%e9%81%93%ef%bc%9aimide-orthoborate%e5%8f%8c%e7%9b%90%e7%94%b5%e8%a7%a3%e8%b4%a8%e4%bd%93%e7%b3%bb%e6%8a%91%e5%88%b6","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=131225","title":{"rendered":"\u4e13\u9898\u62a5\u9053\uff1aImide-Orthoborate\u53cc\u76d0\u7535\u89e3\u8d28\u4f53\u7cfb\u6291\u5236\u9502\u679d\u6676\u53ca\u63d0\u5347\u9502\u91d1\u5c5e\u5e93\u4ed1\u6548\u7387\u7684\u7814\u7a76"},"content":{"rendered":"

1\u3001\u5f15\u8a00<\/b><\/strong><\/p>\n

\u968f\u7740\u5148\u8fdb\u4fbf\u643a\u5f0f\u7535\u5b50\u4ea7\u54c1\u3001\u7535\u52a8\u6c7d\u8f66\u7b49\u7684\u5feb\u901f\u53d1\u5c55\uff0c\u5bf9\u4e8e\u7535\u6c60\u7684\u80fd\u91cf\u5bc6\u5ea6\u63d0\u51fa\u4e86\u66f4\u9ad8\u7684\u8981\u6c42\u3002\u91d1\u5c5e\u9502\u5177\u6709\u9ad8\u7684\u7406\u8bba\u6bd4\u5bb9\u91cf\uff083860 mAh\/g\uff09\u53ca-3.04 V \u7684\u8d85\u8d1f\u7535\u6781\u7535\u52bf\uff08\u76f8\u5bf9\u6807\u51c6\u6c22\u7535\u6781\uff09\uff0c\u662f\u7406\u60f3\u7684\u9ad8\u6bd4\u80fd\u91cf\u4e8c\u6b21\u7535\u6c60\u8d1f\u6781\u6750\u6599\u3002\u56e0\u6b64\uff0c\u5f00\u53d1\u57fa\u4e8e\u91d1\u5c5e\u9502\u8d1f\u6781\u7684\u9ad8\u6bd4\u80fd\u91cf\u4e8c\u6b21\u7535\u6c60\u5982\u9502\u91d1\u5c5e\u7535\u6c60\u3001\u9502\u7a7a\u6c14\u7535\u6c60\u53ca\u9502\u786b\u7535\u6c60\u7b49\u91cd\u65b0\u53d7\u5230\u5173\u6ce8\uff0c\u5e76\u6210\u4e3a\u8fd1\u5e74\u6765\u56fd\u5185\u5916\u5316\u5b66\u7535\u6e90\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u3002\u7136\u800c\uff0c\u91d1\u5c5e\u9502\u4f5c\u4e3a\u8d1f\u6781\u4f7f\u7528\u65f6\uff0c\u5728\u53cd\u590d\u5145\u653e\u7535\u8fc7\u7a0b\u4e2d\u5bb9\u6613\u51fa\u73b0\u7c89\u5316\u3001\u679d\u6676\u751f\u957f\u7b49\u95ee\u9898\uff0c\u5bfc\u81f4\u5bf9\u5e94\u4e8c\u6b21\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\u6781\u5dee\u3001\u5bb9\u91cf\u8870\u51cf\u8fc5\u901f\u3001\u5e93\u4ed1\u6548\u7387\u4f4e\u3001\u6781\u5316\u4e25\u91cd\uff1b\u66f4\u4e3a\u4e25\u91cd\u7684\u662f\uff0c\u9502\u679d\u6676\u751f\u957f\u8fd8\u4f1a\u523a\u7a7f\u9694\u819c\u5bfc\u81f4\u7535\u6c60\u77ed\u8def\u5e76\u53ef\u80fd\u5f15\u53d1\u4e25\u91cd\u7684\u5b89\u5168\u95ee\u9898\u3002<\/p>\n

\u56fd\u5185\u5916\u7814\u7a76\u73b0\u72b6\u8868\u660e\uff0c\u9502\u91d1\u5c5e\u8d1f\u6781\u6027\u80fd\u7684\u6539\u5584\u9014\u5f84\u4e3b\u8981\u5305\u62ec\uff1a\u9502\u91d1\u5c5e\u5408\u91d1\u5316\uff1b\u56fa\u4f53\u7535\u89e3\u8d28\uff1b\u9502\u91d1\u5c5e\u8868\u9762\u7ed3\u6784\u8bbe\u8ba1\uff1b\u6709\u673a\u7535\u89e3\u6db2\u4fc3\u8fdb\u9502\u91d1\u5c5e\/\u7535\u89e3\u8d28\u754c\u9762SEI\u819c\u7a33\u5b9a\u6027\u3002\u5176\u4e2d\uff0c\u901a\u8fc7\u4f18\u5316\u6709\u673a\u7535\u89e3\u6db2\u6210\u5206\u53ca\u6539\u6027\u6dfb\u52a0\u5242\u4fc3\u8fdb\u9502\u91d1\u5c5e\/\u7535\u89e3\u8d28\u754c\u9762SEI\u819c\u7a33\u5b9a\u6027\uff0c\u88ab\u8ba4\u4e3a\u662f\u6291\u5236\u9502\u679d\u6676\u751f\u957f\u3001\u63d0\u5347\u5e93\u4ed1\u6548\u7387\u7684\u6700\u7b80\u4fbf\u3001\u6709\u6548\u7684\u9014\u5f84\u4e4b\u4e00\u3002<\/p>\n

\u00a0<\/b><\/strong>2\u3001\u6210\u679c\u4ecb\u7ecd<\/b><\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u897f\u5357\u77f3\u6cb9\u5927\u5b66\u674e\u661f\u535a\u58eb\u4e0e\u7f8e\u56fd\u897f\u5317\u592a\u5e73\u6d0b\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u8bb8\u6b66\u535a\u58eb\u3001\u5f20\u7ee7\u5149\u535a\u58eb\u3001\u90d1\u5efa\u660e\u535a\u58eb\u7b49\u5728\u5229\u7528\u9170\u4e9a\u80fa-\u787c\u9178\u76d0\uff08Imide-Orthoborate\uff09\u53cc\u76d0\u7535\u89e3\u8d28\u4f53\u7cfb\u6291\u5236\u9502\u679d\u6676\u751f\u957f\u3001\u63d0\u5347\u9502\u91d1\u5c5e\u5e93\u4ed1\u6548\u7387\u65b9\u9762\u5f00\u5c55\u4e86\u8f83\u7cfb\u7edf\u7684\u7814\u7a76\u5de5\u4f5c\u3002<\/p>\n

\uff081\uff09\u9996\u5148\u91c7\u7528\u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\uff08DFT\uff09\u4e0e\u5b9e\u9a8c\u76f8\u7ed3\u5408\u7684\u65b9\u6cd5\uff0c\u6bd4\u8f83\u7814\u7a76\u4e86\u53cc\u4e09\u6c1f\u7532\u70f7\u78fa\u9170\u4e9a\u80fa\u9502–<\/b><\/strong>\u4e8c\u8349\u9178\u787c\u9178\u9502\uff08LiTFSI-LiBOB\uff09\u3001\u53cc\u4e09\u6c1f\u7532\u70f7\u78fa\u9170\u4e9a\u80fa–<\/b><\/strong>\u4e8c\u6c1f\u8349\u9178\u787c\u9178\u9502\uff08LiTFSI-LiDFOB\uff09\u3001\u53cc\u6c1f\u78fa\u9170\u4e9a\u80fa\u9502–<\/b><\/strong>\u4e8c\u8349\u9178\u787c\u9178\u9502\uff08LiFSI-LiBOB\uff09\u3001\u53cc\u6c1f\u78fa\u9170\u4e9a\u80fa\u9502–<\/b><\/strong>\u4e8c\u6c1f\u8349\u9178\u787c\u9178\u9502\uff08LiFSI-LiDFOB\uff09\u56db\u79cd\u9170\u4e9a\u80fa-\u787c\u9178\u76d0\u53cc\u76d0\u7535\u89e3\u8d28\u4f53\u7cfb\u5bf9\u6291\u5236\u9502\u679d\u6676\u751f\u957f\u3001\u63d0\u5347\u9502\u91d1\u5c5e\u5e93\u4ed1\u6548\u7387\u7684\u4f5c\u7528\u6548\u679c\u3002\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0cLiTFSI-LiBOB\u53cc\u76d0\u7535\u89e3\u8d28\u4f53\u7cfb\u80fd\u591f\u53d1\u6325\u6700\u4f18\u7684\u6548\u679c\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cEffects of Imide-Orthoborate Dual-Salt Mixtures in Organic Carbonate Electrolytes on the Stability of Lithium Metal Batteries\u201d\u4e3a\u9898\u53d1\u8868\u5728ACS Appl. Mater. Inter. 2018<\/i><\/b><\/em><\/strong>, 10, 2469-2479\uff08Xing Li, Jianming Zheng \uff08\u5171\u540c\u4e00\u4f5c\uff09, Mark H. Engelhard, Donghai Mei, Qiuyan Li, Shuhong Jiao, Ning Liu, \u00a0Wengao Zhao, Ji-Guang Zhang\uff08\u901a\u8baf\u4f5c\u8005\uff09, Wu Xu\uff08\u901a\u8baf\u4f5c\u8005\uff09\uff09\u3002\u6b64\u5916\uff0c\u4e3a\u4e86\u66f4\u51c6\u786e\u7684\u6d4b\u5b9a\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5e93\u4ed1\u6548\u7387\uff0c\u8fd8\u7cfb\u7edf\u7814\u7a76\u4e86\u9694\u819c\u7684\u5f71\u54cd\uff0c\u7814\u7a76\u7ed3\u679c\u8868\u660e\u805a\u4e59\u70ef\uff08PE\uff09\u819c\u662f\u76f8\u5bf9\u6700\u7a33\u5b9a\u7684\u9694\u819c\u4f53\u7cfb\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cStability of Polymeric Separators in Lithium Metal Battery under Low Voltage Environment\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728J. Mater. Chem. A\u00a02018<\/i><\/b><\/em><\/strong>, DOI: 10.1039\/c7ta11259a\uff08Xing Li, Jinhui Tao, Dehong Hu, Mark H. Engelhard, Wengao Zhao, Ji-Guang Zhang\uff08\u901a\u8baf\u4f5c\u8005\uff09, Wu Xu\uff08\u901a\u8baf\u4f5c\u8005\uff09\uff09\u3002<\/p>\n

\uff082\uff09\u57fa\u4e8e\u4e0a\u8ff0\u7814\u7a76\u57fa\u7840\uff0c\u53c8\u5f00\u5c55\u4e86LiPF6<\/sub>\u6dfb\u52a0\u5242\u6539\u6027LiTFSI-LiBOB\u53cc\u76d0\u7535\u89e3\u8d28\u7684\u7814\u7a76\u5de5\u4f5c\u3002\u7814\u7a76\u8868\u660e\uff0c\u9002\u91cf\u7684LiPF6<\/sub>\u6dfb\u52a0\u5242\u53ef\u4ee5\u8bf1\u5bfcEC\u6eb6\u5242\u5f00\u73af\u3001\u805a\u5408\uff0c\u4f7f\u751f\u6210\u7684SEI\u819c\u8868\u9762\u5bcc\u542bpoly(CO3<\/sub>)\u6210\u5206\uff0cSEI\u819c\u8868\u9762\u7531\u6b64\u53d8\u7684\u81f4\u5bc6\u3001\u5149\u6ed1\uff0c\u53ef\u4ee5\u6709\u6548\u6291\u5236\u9502\u679d\u6676\u7684\u751f\u957f\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cElectrolyte additive enabled fast charging and\u00a0stable cycling lithium metal batteries\u201d\u4e3a\u9898\uff0c\u53d1\u8868\u5728Nat. Energy\u00a02017<\/i><\/b><\/em><\/strong>, 2, 17012\uff08Jianming Zheng, Mark H. Engelhard, Donghai Mei, Shuhong Jiao, Bryant J. Polzin,\u00a0Ji-Guang Zhang\uff08\u901a\u8baf\u4f5c\u8005\uff09Wu Xu\uff08\u901a\u8baf\u4f5c\u8005\uff09\uff09\u3002\u4f46\u662f\uff0c\u8be5LiPF6<\/sub>\u6539\u6027Imide-Orthoborate\u53cc\u76d0\u7535\u89e3\u8d28\u4f53\u7cfb\u5bf9\u5e94\u7684\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5e93\u4ed1\u6548\u7387\u4ecd\u4e0d\u9ad8\uff0c\u53ea\u670990.6%\u5de6\u53f3\u3002<\/p>\n

\uff083\uff09\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63d0\u5347\u5bf9\u5e94\u9502\u91d1\u5c5e\u7684\u5e93\u4ed1\u6548\u7387\uff0c\u4f18\u5316\u4e86LiTFSI-LiBOB\u53cc\u76d0\u7535\u89e3\u8d28\u4f53\u7cfb\u4e2d\u7684\u6eb6\u5242\u6bd4\u4f8b\uff0c\u540c\u65f6\u4f7f\u7528\u4e86\u7ec4\u5408\u6dfb\u52a0\u5242\uff08LiPF6 <\/sub>+ VC + FEC\uff09\uff0c\u53d1\u73b0\u5bf9\u5e94\u9502\u91d1\u5c5e\u8d1f\u6781\u5e93\u4ed1\u6548\u7387\u53ef\u63d0\u5347\u81f398.1%\u3002\u8be5\u7814\u7a76\u6210\u679c\u4ee5\u201cDendrite-Free and\u00a0Performance-Enhanced Lithium Metal Batteries through Optimizing Solvent Compositions and Adding Combinational Additives\u201d\u4e3a\u9898\u53d1\u8868\u5728Adv. Energy Mater.\u00a02018<\/i><\/b><\/em><\/strong>, 1703022\uff08Xing Li, Jianming Zheng\uff08\u5171\u540c\u4e00\u4f5c\uff09, Xiaodi Ren, Mark H. Engelhard, Wengao Zhao, Qiuyan Li, Ji-Guang Zhang\uff08\u901a\u8baf\u4f5c\u8005\uff09, Wu Xu\uff08\u901a\u8baf\u4f5c\u8005\uff09\uff09\u3002<\/p>\n

\u00a0<\/b><\/strong>3\u3001\u56fe\u6587\u5bfc\u8bfb<\/b><\/strong><\/p>\n

\u88681 \u7b2c\u4e00\u6027\u539f\u7406\u8ba1\u7b97\u8868\u660e\uff0c\u5316\u5b66\u53ca\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff1aLiTFSI+LiBOB >Li\u00a0TFSI+LiDFOB > LiFSI+LiDFOB > LiFSI+LiBOB\uff08ACS Appl. Mater. Inter. 2018<\/i><\/em>, 10, 2469-2479\uff09\u3002<\/strong><\/p>\n\n\n\n\n\n\n\n\n
Types of \u00a0 \u00a0 dual-salts<\/td>\nDisproportionation reaction<\/td>\nReaction energies (kJ mol-1<\/sup>)<\/td>\n<\/tr>\n
Electrochemical
\n \u00a0(two radicals)<\/td>\n		Chemical
\n (two anions)<\/td>\n<\/tr>\n
TFSI+BOB<\/td>\nCF3<\/sub>SO2<\/sub>NSO2<\/sub>CF3 +<\/sub>(C2<\/sub>O4<\/sub>)B(O4<\/sub>C2<\/sub>)\u00a0\u2192 CF3<\/sub>SO2<\/sub>NSO2<\/sub>OC(=O)C(=O)O + CF3<\/sub>B(O4<\/sub>C2<\/sub>)<\/td>\n487.7<\/td>\n517.9<\/td>\n<\/tr>\n
TFSI+DFOB<\/td>\nCF3<\/sub>SO2<\/sub>NSO2<\/sub>CF3 <\/sub>+ \u00a0(C2<\/sub>O4<\/sub>)BF2<\/sub>\u00a0\u2192 CF3<\/sub>SO2<\/sub>NSO2<\/sub>OC(=O)C(=O)O + CF3<\/sub>BF2<\/sub><\/td>\n244.6<\/td>\n326.9<\/td>\n<\/tr>\n
FSI+BOB<\/td>\nFSO2<\/sub>NSO2<\/sub>F + (C2<\/sub>O4<\/sub>)B(O4<\/sub>C2<\/sub>)\u00a0\u2192 FSO2<\/sub>OC(=O)C(=O)O + FSO2<\/sub>NB(O4<\/sub>C2<\/sub>)<\/td>\n47.6<\/td>\n85.0<\/td>\n<\/tr>\n
FSI+DFOB<\/td>\n\n

FSO2<\/sub>NSO2<\/sub>F + (C2<\/sub>O4<\/sub>)BF2<\/sub>\u00a0\u2192 FSO2<\/sub>OC(=O)C(=O)O + FSO2<\/sub>NBF2<\/sub><\/p>\n<\/td>\n

97.1<\/td>\n204.8<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

 <\/p>\n

\u56fe1\u00a0\u5bf9\u5e94\u9502\u91d1\u5c5e\u4e8c\u6b21\u7535\u6c60\uff08NMC||Li\uff09\u5faa\u73af\u7a33\u5b9a\u6027\uff1aLiTFSI+LiBOB >Li\u00a0TFSI+LiDFOB > LiFSI+LiDFOB > LiFSI+LiBOB\uff08ACS Appl. Mater. Inter. 2018<\/i><\/em>, 10, 2469-2479\uff09\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe2 \u4e0d\u540c\u7c7b\u578b\u7684\u9694\u819c\u5728\u4e24\u79cd\u5178\u578b\u7535\u89e3\u6db2\u4e2d\u6d4b\u5b9a\u7684\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5e93\u4ed1\u6548\u7387\uff0c\u4ece\u4e2d\u53ef\u4ee5\u53d1\u73b0PE\u819c\u4f53\u73b0\u51fa\u76f8\u5bf9\u6700\u597d\u7684\u7a33\u5b9a\u6027\uff08J. Mater. Chem. A 2018<\/i><\/em>, DOI: 10.1039\/c7ta11259a\uff09\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe3\u00a0\u4f7f\u7528\u4e0d\u540c\u7535\u89e3\u6db2\u5bf9\u5e94\u7684\u9502\u91d1\u5c5e\u8d1f\u6781\u622a\u9762\uff08a-c\uff09\u53ca\u8868\u9762\uff08d-f\uff09\u7684SEM\u56fe\u7247\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a, d\uff08LiPF6<\/sub>\/EC-DEC\uff09\u3001b, e\uff08LiTFSI-LiBOB\/EC-DEC\uff09\u3001c, f\uff08LiTFSI-LiBOB+LiPF6<\/sub>\/EC-DEC\uff09\u3002\u4ece\u56fe\u4e2d\u53ef\u4ee5\u89c2\u5bdf\u5230\uff0c\u4f7f\u7528LiPF6<\/sub>\u6dfb\u52a0\u5242\u4fee\u9970\u7684LiTFSI-LiBOB\u53cc\u76d0\u7535\u89e3\u6db2\u53ef\u4ee5\u4fc3\u8fdb\u66f4\u7a33\u5b9a\u7684SEI\u751f\u957f\uff08Nat. Energy 2017<\/i><\/b><\/em><\/strong>, 2, 17012\uff09\u3002<\/p>\n

\u56fe4\u00a0\u4f7f\u7528\u5355\u4e00\u6dfb\u52a0\u5242\u4e0e\u4f7f\u7528\u7ec4\u5408\u6dfb\u52a0\u5242\u5bf9\u5e94\u7684\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5e93\u4ed1\u6548\u7387\u6bd4\u8f83\u3002<\/strong><\/p>\n

\"\"<\/p>\n

\u4ece\u56fe\u4e2d\u53ef\u4ee5\u89c2\u5bdf\u5230\uff0c\u4f7f\u7528\u7ec4\u5408\u6dfb\u52a0\u5242\uff08LiPF6<\/sub>+VC+FEC\uff09\u5bf9\u5e94\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5e93\u4ed1\u6548\u7387\u9ad8\u8fbe98.1%\uff08Adv. Energy Mater.\u00a02018<\/i><\/em>, 1703022\uff09\u3002<\/p>\n

\u56fe5 \u4f7f\u7528\u4e0d\u540c\u6dfb\u52a0\u5242\u5bf9\u5e94\u7684\u9502\u91d1\u5c5e\u8d1f\u6781\u5728100\u6b21\u5faa\u73af\u540e\u7684\u8868\u9762SEM\u3002<\/strong><\/p>\n

\"\"<\/p>\n

a. \u4f7f\u7528LiTFSI-LiBOB+LiPF6<\/sub>\/EC-EMC\u7535\u89e3\u6db2; b. \u4f7f\u7528LiTFSI-LiBOB+LiPF6<\/sub>+VC+FEC\/EC-EMC\uff084:6\uff09\u7535\u89e3\u6db2; c. \u4f7f\u7528LiTFSI-LiBOB+LiPF6<\/sub>+VC+FEC\/EC-EMC\uff087:3\uff09\u7535\u89e3\u6db2\u3002<\/p>\n

\u4ece\u56fe\u4e2d\u53ef\u4ee5\u89c2\u5bdf\u5230\uff0c\u4f7f\u7528\u7ec4\u5408\u6dfb\u52a0\u5242\uff08LiPF6<\/sub>+VC+FEC\uff09\u51e0\u4e4e\u4e0d\u4f1a\u5728\u9502\u91d1\u5c5e\u8868\u9762\u4ea7\u751f\u9502\u679d\u6676\uff0c\u6b64\u5916\uff0c\u4f7f\u7528\u7ec4\u5408\u6dfb\u52a0\u5242\u5bf9\u5e94\u7684\u9502\u91d1\u5c5e\u7535\u6c60\u7684\u5185\u963b\u4e5f\u660e\u663e\u5c0f\u4e8e\u4f7f\u7528\u5355\u4e00\u6dfb\u52a0\u5242\uff08Adv. Energy Mater.\u00a02018<\/i><\/b><\/em><\/strong>, 1703022\uff09\u3002<\/p>\n

\u00a0<\/b><\/strong>4\u3001\u5c0f\u7ed3<\/b><\/strong><\/p>\n

\u4e0a\u8ff0\u7814\u7a76\u7ed3\u679c\u8868\u660e\uff0c\u5728Imide-Orthoborate\u53cc\u76d0\u7535\u89e3\u8d28\u4f53\u7cfb\u4e2d\uff0cLiTFSI-LiBOB\u662f\u5316\u5b66\u53ca\u7535\u5316\u5b66\u76f8\u5bf9\u6700\u7a33\u5b9a\u7684\u53cc\u76d0\u7535\u89e3\u8d28\u4f53\u7cfb\u3001\u80fd\u591f\u5728\u9502\u91d1\u5c5e\u8868\u9762\u5f62\u6210\u65e0\u9502\u679d\u6676\u3001\u81f4\u5bc6\u3001\u7a33\u5b9a\u7684SEI\u819c\uff1b\u901a\u8fc7\u5229\u7528LiPF6<\/sub>\u4f5c\u4e3a\u6dfb\u52a0\u5242\u6539\u6027LiTFSI-LiBOB\u53cc\u76d0\u4f53\u7cfb\uff0c\u53ef\u4ee5\u4f7f\u751f\u6210\u7684SEI\u819c\u5c55\u73b0\u51fa\u66f4\u8584\u3001\u66f4\u81f4\u5bc6\u3001\u66f4\u7a33\u5b9a\u7b49\u7279\u6027\uff1b\u800c\u4f7f\u7528LiPF6<\/sub>\u00a0+ VC + FEC\u7ec4\u5408\u6dfb\u52a0\u5242\u6539\u6027\u7684LiTFSI-LiBOB\u53cc\u76d0\u4f53\u7cfb\uff0c\u8fd8\u53ef\u4ee5\u4f7f\u5bf9\u5e94\u7684\u9502\u91d1\u5c5e\u8d1f\u6781\u7684\u5e93\u4ed1\u6548\u7387\u63d0\u5347\u81f398.1%\u5de6\u53f3\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/b><\/strong><\/p>\n

    \n
  1. Effects of Imide-Orthoborate Dual-Salt Mixtures in Organic Carbonate Electrolytes on the Stability of Lithium Metal Batteries<\/a>, ACS Appl. Mater. Inter.,2018, 10, 2469-2479\uff1b<\/li>\n
  2. Stability of Polymeric Separators in Lithium Metal Battery under Low Voltage Environment<\/a>, J. Mater.Chem. A, DOI: 10.1039\/c7ta11259a\uff1b<\/li>\n
  3. Electrolyte additive enabled fast charging andstable cycling lithium metal batteries<\/a>\uff0cNat. Energy 2017, 2, 17012\uff1b<\/li>\n
  4. Dendrite-Free and Performance-Enhanced Lithium Metal Batteries through Optimizing Solvent Compositions and Adding Combinational Additives<\/a>, Adv. EnergyMater.2018, 1703022.<\/li>\n<\/ol>\n

    \u611f\u8c22\u897f\u5357\u77f3\u6cb9\u5927\u5b66\u674e\u8001\u5e08\u7684\u4f9b\u7a3f\uff01<\/p>\n

    \u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a><\/strong>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

    \u6750\u6599\u4eba\u91cd\u78c5\u63a8\u51fa\u6750\u6599\u8ba1\u7b97\u89e3\u51b3\u65b9\u6848\uff0c\u7ec4\u5efa\u4e86\u4e00\u652f\u6765\u81ea\u5168\u56fd\u77e5\u540d\u9ad8\u6821\u8001\u5e08\u53ca\u4f01\u4e1a\u5de5\u7a0b\u5e08\u7684\u79d1\u6280\u987e\u95ee\u56e2\u961f\uff0c\u4e13\u6ce8\u4e8e\u4e3a\u5927\u5bb6\u89e3\u51b3\u5404\u7c7b\u8ba1\u7b97\u6a21\u62df\u9700\u6c42\u3002\u5982\u679c\u60a8\u6709\u9700\u6c42\uff0c\u6b22\u8fce\u626b\u4ee5\u4e0b\u4e8c\u7ef4\u7801\u63d0\u4ea4\u60a8\u7684\u9700\u6c42\u3002\u6216\u70b9\u51fb\u94fe\u63a5\u63d0\u4ea4<\/a>\uff0c\u6216\u76f4\u63a5\u8054\u7cfb\u5fae\u4fe1\u5ba2\u670d\uff08\u5fae\u4fe1\u53f7\uff1aiceshigu\uff09<\/p>\n

    \"\"<\/p>\n","protected":false},"excerpt":{"rendered":"

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