{"id":131857,"date":"2018-03-28T06:30:15","date_gmt":"2018-03-27T22:30:15","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=131857"},"modified":"2018-03-26T20:01:27","modified_gmt":"2018-03-26T12:01:27","slug":"%e5%8d%8e%e4%b8%ad%e7%a7%91%e5%a4%a7%e8%92%8b%e5%87%af%e7%8e%8b%e5%ba%b7%e4%b8%bdenergy-storage-mater-%e5%9f%ba%e4%ba%8ena3v2po42f3%e6%ad%a3%e6%9e%81%e7%9a%84%e9%95%bf%e5%af%bf%e5%91%bd","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=131857","title":{"rendered":"\u534e\u4e2d\u79d1\u5927\u848b\u51ef&\u738b\u5eb7\u4e3dEnergy Storage Mater. : \u57fa\u4e8eNa3V2(PO4)2F3\u6b63\u6781\u7684\u957f\u5bff\u547d\u6c34\u6eb6\u6db2\u950c\u79bb\u5b50\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u53ef\u518d\u5145\u7535\u7684\u201c\u6447\u6905\u578b\u201d\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u5177\u6709\u6210\u672c\u4f4e\u5ec9\u3001\u5b89\u5168\u6027\u9ad8\u3001\u73af\u5883\u53cb\u597d\u3001\u7ec4\u88c5\u65b9\u4fbf\u7b49\u4f18\u70b9\uff0c\u662f\u4e00\u7c7b\u6f5c\u5728\u7684\u50a8\u80fd\u6280\u672f\u3002\u7136\u800c\uff0c\u4e00\u822c\u7684\u6b63\u6781\u6750\u6599\u5728\u4e8c\u4ef7\u950c\u79bb\u5b50\u5d4c\u8131\u8fc7\u7a0b\u5b58\u5728\u7ed3\u6784\u4e0d\u7a33\u5b9a\u548c\u6269\u6563\u7f13\u6162\u7684\u95ee\u9898\uff1b\u540c\u65f6\uff0c\u950c\u8d1f\u6781\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u6781\u6613\u5f62\u6210\u679d\u6676\uff0c\u5bfc\u81f4\u7535\u6c60\u77ed\u8def\u3002\u56e0\u6b64\uff0c\u5bfb\u627e\u5408\u9002\u7684\u6b63\u6781\u6750\u6599\u548c\u6709\u6548\u6291\u5236\u950c\u679d\u6676\u7684\u65b9\u6cd5\uff0c\u662f\u4e00\u4e2a\u5de8\u5927\u7684\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u534e\u4e2d\u79d1\u6280\u5927\u5b66\u848b\u51ef\u548c\u738b\u5eb7\u4e3d\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\uff0c\u6210\u529f\u5f00\u53d1\u4e86Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub>\u6b63\u6781\u6750\u6599(N3<\/sub>VPF@C)\uff0c\u540c\u65f6\u901a\u8fc7\u4fee\u9970\u91d1\u5c5eZn\u8d1f\u6781\uff08CFF-Zn\uff09\uff0c\u7ec4\u88c5\u4e86CFF-Zn\/\/ N3<\/sub>VPF@C\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u3002\u8be5\u7535\u6c60\u4f53\u7cfb\u5177\u67091.62V\u7535\u538b\uff0c97.5Wh\/kg\u7684\u80fd\u91cf\u5bc6\u5ea6\u548c\u957f\u8fbe4000\u5708\u7684\u5faa\u73af\u5bff\u547d(95%\u5bb9\u91cf\u4fdd\u6301\u7387)\u3002\u4f5c\u8005\u901a\u8fc7\u975e\u539f\u4f4dXPS\u3001XRD\u548cSEM mapping\u7b49\u8868\u5f81\u4e86\u7535\u6c60\u7684\u673a\u7406\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u57fa\u4e8eCFF-Zn\/\/N3<\/sub>VPF@C<\/strong>\u7684\u8f6f\u5305\u7535\u6c60\u540c\u6837<\/strong>\u5177\u6709\u826f\u597d\u7684\u5faa\u73af\u6027\u80fd\u3002\u76f8\u5173\u6210\u679c\u4ee5\u9898\u4e3a\u201cA long-life aqueous Zn-ion battery based on Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub> cathode<\/strong>\u201d\u53d1\u8868\u5728\u4e86Energy Storage Materials<\/strong>\u00a0<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1<\/strong>\u00a0<\/strong>\u6750\u6599\u7ed3\u6784\u548c\u7535\u6c60\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09N3<\/sub>VPF@C\u7684XRD\u56fe\u8c31\uff1b\u63d2\u56fe\u4e3aN3<\/sub>VPF@C\u7684SEM\u56fe\uff1b<\/p>\n

b\uff09CFF-Zn\/\/N3<\/sub>VPF@C\u7535\u6c60\u7684CV\u66f2\u7ebf\uff1b<\/p>\n

c\uff09CFF-Zn\/\/N3<\/sub>VPF@C\u7535\u6c60\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

d\uff09CFF-Zn\/\/N3<\/sub>VPF@C\u7535\u6c60\u7ed3\u6784\u548c\u673a\u7406\u793a\u610f\u56fe\uff1b<\/p>\n

\u56fe<\/strong>2\u00a0<\/strong>\u7535\u6c60\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09CFF-Zn\/\/N3<\/sub>VPF@C\u7535\u6c60\u7684\u500d\u7387\u5bb9\u91cf\u6027\u80fd\uff1b<\/p>\n

b\uff09CFF-Zn\/\/N3<\/sub>VPF@C\u7535\u6c60\u7684\u4e0d\u540c\u500d\u7387\u4e0b\u7684\u5145\u653e\u7535\u66f2\u7ebf\uff1b<\/p>\n

c\uff09CFF-Zn\/\/N3<\/sub>VPF@C\u7535\u6c60\u5728200mA\/g\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

d\uff09Zn\/\/N3<\/sub>VPF@C\u7535\u6c60\u5728200mA\/g\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

e\uff09CFF-Zn\/\/N3<\/sub>VPF@C\u7535\u6c60\u57281000mA\/g\u7535\u6d41\u5bc6\u5ea6\u4e0b\u5faa\u73af\u6027\u80fd\uff1b<\/p>\n

\u56fe<\/strong>3\u00a0 Zn <\/strong>\u548c<\/strong>CFF-Zn<\/strong>\u5f62\u8c8c\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u539f\u59cbZn\u7684SEM\u7167\u7247\uff1b<\/p>\n

b\uff09\u5faa\u73af\u540eZn\u7684SEM\u7167\u7247\uff1b<\/p>\n

c\uff09\u539f\u59cbCFF-Zn\u7684SEM\u7167\u7247\uff1b<\/p>\n

d\uff09\u5faa\u73af\u540eCFF-Zn\u7684SEM\u7167\u7247\uff1b<\/p>\n

\u56fe<\/strong>4\u00a0<\/strong>\u5faa\u73af\u524d\u540e<\/strong>N3<\/sub>VPF@C<\/strong>\u7535\u6781\u7684\u8868\u9762\u7ed3\u6784\u53d8\u5316<\/strong><\/p>\n

\"\"<\/p>\n

a\uff09\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0bZn2p\u7684XPS\u56fe\u8c31\uff1b<\/p>\n

b\uff09\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0bV2p\u7684XPS\u56fe\u8c31\uff1b<\/p>\n

c\uff09\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0bC1s\u7684XPS\u56fe\u8c31\uff1b<\/p>\n

d\uff09\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0bF1s\u7684XPS\u56fe\u8c31\uff1b<\/p>\n

\u56fe<\/strong>5\u00a0\u00a0 N3<\/sub>VPF@C<\/strong>\u7535\u6781\u4e0d\u540c\u5145\u653e\u7535\u72b6\u6001\u4e0b\u7684\u7ed3\u6784\u53d8\u5316<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong>6\u00a0\u00a0CFF-Zn\/\/N3<\/sub>VPF@C<\/strong>\u8f6f\u5305\u7535\u6c60\u7684\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

a-e\uff09\u00a0CFF-Zn\/\/N3<\/sub>VPF@C<\/strong>\u8f6f\u5305\u7535\u6c60\u7684\u6570\u7801\u7167\u7247<\/strong>\uff1b\u00a0<\/strong><\/p>\n

f\uff09\u00a0CFF-Zn\/\/N3<\/sub>VPF@C<\/strong>\u8f6f\u5305\u7535\u6c60\u7684\u5faa\u73af\u6027\u80fd\uff1b<\/strong><\/p>\n

\u3010\u5c0f\u7ed3<\/strong>\u3011<\/p>\n

\u8be5\u7814\u7a76\u5c55\u793a\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u950c\u79bb\u5b50\u7535\u6c60\u6b63\u6781\u6750\u6599\u548c\u6291\u5236\u950c\u679d\u6676\u7684\u65b9\u6cd5\uff0c\u5e76\u6784\u5efa\u4e86\u9ad8\u7535\u538b\u3001\u957f\u5bff\u547d\u7684\u201c\u6447\u6905\u578b\u201dCFF-Zn\/\/ N3<\/sub>VPF@C\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u3002\u53d1\u73b0\uff0cN3<\/sub>VPF@C\u6b63\u6781\u6750\u6599\u7684\u7a33\u5b9a\u6027\u4e3b\u8981\u6765\u6e90\u4e8e\u5176\u9ad8\u5ea6\u53ef\u9006\u7684V3+<\/sup> \u2194 V4+<\/sup>\u7535\u5bf9\u3001\u6b63\u6781\u8868\u9762\u5f62\u6210\u7684SEI\u819c\u548c\u6b63\u6781\u5ffd\u7565\u4e0d\u8ba1\u7684\u4f53\u79ef\u53d8\u5316\uff080.22%\uff09\u3002\u800cZn\u8d1f\u6781\u901a\u8fc7\u7b80\u5355\u7684\u78b3\u819c\u4fee\u9970\uff0c\u53ef\u4ee5\u6709\u6548\u6291\u5236\u950c\u679d\u6676\u7684\u751f\u6210\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u548c\u7b56\u7565\uff0c\u6709\u671b\u4e3a\u6c34\u7cfb\u950c\u57fa\u7535\u6c60\u63d0\u4f9b\u65b0\u7684\u601d\u8def\u548c\u65b9\u6cd5\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>A long-life aqueous Zn-ion battery based on Na3<\/sub>V2<\/sub>(PO4<\/sub>)2<\/sub>F3<\/sub> cathode<\/a> \uff08Energy Storage Mater.,\u00a02018\uff0cDOI\uff1a10.1016\/j.ensm.2018.03.003\uff09<\/p>\n

\u611f\u8c22\u534e\u4e2d\u79d1\u5927\u848b\u51ef\u548c\u738b\u5eb7\u4e3d\u6559\u6388\u8bfe\u9898\u7ec4\u7684\u4f9b\u7a3f\uff01<\/p>\n

\u6750\u6599\u4eba\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u53ef\u518d\u5145\u7535\u7684\u201c\u6447\u6905\u578b\u201d\u6c34\u7cfb\u950c\u79bb\u5b50\u7535\u6c60\u5177\u6709\u6210\u672c\u4f4e\u5ec9\u3001\u5b89\u5168\u6027\u9ad8\u3001\u73af\u5883\u53cb\u597d\u3001\u7ec4\u88c5\u65b9\u4fbf\u7b49\u4f18\u70b9\uff0c\u662f\u4e00\u7c7b\u6f5c\u5728\u7684\u50a8\u80fd\u6280\u672f\u3002\u7136\u800c\uff0c\u4e00\u822c\u7684\u6b63\u6781\u6750\u6599\u5728\u4e8c\u4ef7\u950c\u79bb\u5b50\u5d4c\u8131\u8fc7\u7a0b\u5b58\u5728…<\/p>\n","protected":false},"author":2219,"featured_media":131862,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[2984],"class_list":["post-131857","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-2984"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/131857"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2219"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=131857"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/131857\/revisions"}],"predecessor-version":[{"id":132219,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/131857\/revisions\/132219"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/131862"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=131857"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=131857"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=131857"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}