{"id":133749,"date":"2018-04-08T06:30:59","date_gmt":"2018-04-07T22:30:59","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=133749"},"modified":"2018-04-07T14:56:48","modified_gmt":"2018-04-07T06:56:48","slug":"%e6%9a%a8%e5%8d%97%e5%a4%a7%e5%ad%a6%e5%94%90%e7%be%a4%e5%a7%94angew-chem-int-ed-%ef%bc%9a%e5%85%a8%e6%97%a0%e6%9c%ba%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=133749","title":{"rendered":"\u66a8\u5357\u5927\u5b66\u5510\u7fa4\u59d4Angew. Chem. Int. Ed.\uff1a\u5168\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u4e0e\u6c34\u84b8\u6c7d\u5316\u201c\u654c\u201d\u4e3a\u201c\u53cb\u201d"},"content":{"rendered":"

\u5f15\u8a00<\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u57fa\u4e8eCsPbBr3<\/sub>\u7684\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u7531\u4e8e\u5177\u6709\u4f18\u5f02\u7684\u70ed\u5b66\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u53d7\u5230\u4e86\u79d1\u7814\u4eba\u5458\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u4e0e\u6709\u673a-\u65e0\u673a\u6742\u5316PSC\u76f8\u6bd4\uff0c\u5168\u65e0\u673aCsPbBr3<\/sub>\u592a\u9633\u80fd\u7535\u6c60\u53ef\u4ee5\u5728\u76f8\u5bf9\u6e7f\u5ea690%\u4ee5\u4e0a\u7684\u7a7a\u6c14\u73af\u5883\u4e2d\u4fdd\u6301\u7a33\u5b9a\u3002\u5df2\u5f00\u53d1\u7684\u65e0\u673aPSC\u53ea\u80fd\u5c06\u592a\u9633\u80fd\u8f6c\u6362\u4e3a\u7535\u80fd\uff0c\u800c\u5bf9\u5468\u56f4\u73af\u5883\u4e2d\u7684\u6c34\u84b8\u6c7d\u80fd\u7b49\u5176\u5b83\u80fd\u91cf\u4e0d\u80fd\u5438\u6536\u5229\u7528\u3002\u6c34\u84b8\u53d1\u662f\u5b9e\u73b0\u6c34\u5faa\u73af\u7684\u5173\u952e\u8fc7\u7a0b\uff0c\u5728\u6b64\u671f\u95f4\u91ca\u653e\u51fa\u5de8\u5927\u7684\u6c34\u84b8\u6c7d\u80fd\u3002\u5982\u4f55\u5728\u4e0d\u589e\u52a0\u7535\u6c60\u6210\u672c\u7684\u524d\u63d0\u4e0b\uff0c\u5b9e\u73b0\u65e0\u673aPSC\u7684\u591a\u80fd\u96c6\u6210\u5e94\u7528\u662f\u5f53\u524d\u5149\u4f0f\u7814\u7a76\u9886\u57df\u7684\u524d\u6cbf\u79d1\u5b66\u95ee\u9898\u4e4b\u4e00\uff0c\u5c24\u5176\u4f7fPSC\u5668\u4ef6\u4e0e\u6c34\u84b8\u6c7d\u5316\u201c\u654c\u201d\u4e3a\u201c\u53cb\u201d\u66f4\u662f\u5b9e\u73b0\u6700\u5927\u80fd\u91cf\u6536\u96c6\u7684\u96be\u9898\u3002<\/p>\n

\u6210\u679c\u7b80\u4ecb<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u66a8\u5357\u5927\u5b66\u5510\u7fa4\u59d4\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09\u8bbe\u8ba1\u4e86\u4e00\u79cd\u57fa\u4e8e\u78b3\u7535\u6781\u7684\u65e0\u7a7a\u7a74\u5168\u65e0\u673aPSC\u5668\u4ef6\uff0c\u5229\u7528\u78b3\u7535\u6781\u5de7\u5999\u5730\u5b9e\u73b0\u5668\u4ef6\u540c\u65f6\u6355\u83b7\u592a\u9633\u80fd\u4e0e\u6c34\u84b8\u6c7d\u80fd\u3002\u5176\u57fa\u672c\u539f\u7406\u662f\uff1a\u5728\u592a\u9633\u5149\u7167\u65f6\uff0c\u78b3\u7535\u6781\u53ef\u4ee5\u63d0\u53d6CsPbBr3<\/sub>\u4ea7\u751f\u7684\u5149\u751f\u7a7a\u7a74\uff0c\u5b9e\u73b0\u7535\u5b50-\u7a7a\u7a74\u5bf9\u7684\u6709\u6548\u5206\u79bb\uff1b\u800c\u5728\u9ad8\u6e7f\u73af\u5883\u4e2d\uff0c\u78b3\u7535\u6781\u53c8\u4e0e\u6c34\u84b8\u6c7d\u95f4\u7684\u6c34\u4f0f\u6548\u5e94\u4ea7\u751f\u989d\u5916\u7684\u7535\u538b\u4e0e\u7535\u6d41\uff0c\u5b9e\u73b0\u6c34\u6c7d\u8bf1\u5bfc\u53d1\u7535\u3002\u901a\u8fc7\u4f18\u5316\u7535\u6c60\u7684\u80fd\u7ea7\u7ed3\u6784\u4ee5\u53ca\u78b3\u7535\u6781\u7684\u8868\u9762\u7ed3\u6784\uff0c\u8be5\u5168\u65e0\u673aPSC\u5728\u6807\u51c6\u592a\u9633\u5149\u7167\u6761\u4ef6\u4e0b\u83b7\u5f979.43%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\uff0c\u540c\u65f6\u572880%\u7684\u76f8\u5bf9\u6e7f\u5ea6\u4e0b\u53ef\u4ee5\u83b7\u5f970.35 V\u7535\u538b\u548c0.45 \u03bcA\u7535\u6d41\u3002\u7531\u4e8e\u65e0\u673a\u9499\u949b\u77ffCsPbBr3<\/sub>\u5177\u6709\u975e\u5e38\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\uff0c\u56e0\u6b64\u8be5\u7535\u6c60\u4ecd\u53ef\u4ee5\u5728\u8be5\u6e7f\u5ea6\u4e0b\u4fdd\u6301\u975e\u5e38\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\uff0c\u5bf9\u591a\u80fd\u96c6\u6210\u5149\u4f0f\u7535\u6c60\u7684\u53d1\u5c55\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cCarbon Electrode Tailored All-Inorganic Perovskite Solar Cells To Harvest Solar And Water-Stream Energies<\/strong>\u201d\u4e3a\u6807\u9898\u53d1\u8868\u5728Angewandte Chemie International Edition<\/strong>\u6742\u5fd7\u4e0a\u3002<\/p>\n

\u56fe\u6587\u7b80\u4ecb<\/strong><\/p>\n

\u56fe<\/strong>1. <\/strong>\u80fd\u540c\u65f6\u6355\u83b7\u592a\u9633\u80fd\u548c\u6c34\u84b8\u6c7d\u80fd\u7684\u5168\u65e0\u673a<\/strong>PSC<\/strong>\u5668\u4ef6\u7ed3\u6784\u548c\u7535\u8377\u4f20\u8f93\u793a\u610f\u56fe<\/strong><\/p>\n

\u00a0\"\"<\/strong><\/p>\n

\u56fe<\/strong>2. <\/strong>\u65e0\u673a<\/strong>CsPbBr3<\/sub><\/strong>\u8584\u819c\u7684\u5f62\u8c8c\u3001\u5168\u65e0\u673a<\/strong>PSC<\/strong>\u7684\u5149\u4f0f\u6027\u80fd\u4ee5\u53ca\u6c34\u84b8\u6c7d\u53d1\u7535\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09CsPbBr3<\/sub>\u548c\uff08b\uff09\u78b3\u7535\u6781\u7684\u8868\u9762SEM\u56fe\u3002<\/p>\n

\uff08c\uff09\u5168\u65e0\u673aPSC\u7684SEM\u65ad\u9762\u56fe\u3002<\/p>\n

\uff08d\uff09\u5168\u65e0\u673aPSC\u7684J-V<\/em>\u66f2\u7ebf\u3002<\/p>\n

\uff08e\uff09\u5168\u65e0\u673aPSC\u7684\u6548\u7387\u5206\u5e03\u3002<\/p>\n

\uff08f\uff09\u78b3\u7535\u6781\u7ecf\u4e0d\u540c\u7b49\u79bb\u5b50\u5904\u7406\u65f6\u95f4\u540e\u7684\u6c34\u84b8\u6c7d\u8bf1\u5bfc\u7535\u538b\u4fe1\u53f7\u3002<\/p>\n

\uff08g\uff09\u78b3\u7535\u6781\u7ecf\u4e0d\u540c\u7b49\u79bb\u5b50\u5904\u7406\u65f6\u95f4\u540e\u7684\u6c34\u84b8\u6c7d\u8bf1\u5bfc\u7535\u6d41\u4fe1\u53f7\u3002<\/p>\n

\u56fe<\/strong>3. <\/strong>\u78b3\u7535\u6781\u5728\u4e0d\u540c\u6e7f\u5ea6\u73af\u5883\u4e0b\u7684\u53d1\u7535\u80fd\u529b\u548c\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u7535\u538b\u548c\uff08b\uff09\u7535\u6d41\u968f\u6e7f\u5ea6\u7684\u53d8\u5316\u66f2\u7ebf\uff1b<\/p>\n

\uff08c\uff09\u7535\u538b\u548c\uff08d\uff09\u7535\u6d41\u5728RH<\/em> = 80%\u7684\u957f\u671f\u7a33\u5b9a\u6027\u3002<\/p>\n

\u56fe<\/strong>4. <\/strong>\u5168\u65e0\u673a<\/strong>PSC<\/strong>\u5668\u4ef6\u7684\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09CsPbBr3<\/sub>\u8584\u819c\u5728RH<\/em> = 80%\u4e0b\u7684\u7d2b\u5916-\u53ef\u89c1\u5438\u6536\u5149\u8c31\u66f2\u7ebf\uff0c\u4ee5\u53ca\uff08b\uff09515nm\u5904\u7684\u5438\u6536\u5cf0\u5f3a\u5ea6\u968f\u65f6\u95f4\u7684\u53d8\u5316\u3002<\/p>\n

\uff08c\uff09~\uff08f\uff09\u5149\u4f0f\u53c2\u6570\u5728RH<\/em> = 80%\u4e0b\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

\u6750\u6599\u4eba\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/strong><\/a>\u3001\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u5f15\u8a00 \u8fd1\u5e74\u6765\uff0c\u57fa\u4e8eCsPbBr3\u7684\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u7531\u4e8e\u5177\u6709\u4f18\u5f02\u7684\u70ed\u5b66\u548c\u5316\u5b66\u7a33\u5b9a\u6027\u53d7\u5230\u4e86\u79d1\u7814\u4eba\u5458\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u4e0e\u6709\u673a-\u65e0\u673a\u6742\u5316PSC\u76f8\u6bd4\uff0c\u5168…<\/p>\n","protected":false},"author":272,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[3041],"class_list":["post-133749","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-3041"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/133749"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/272"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=133749"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/133749\/revisions"}],"predecessor-version":[{"id":133776,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/133749\/revisions\/133776"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=133749"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=133749"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=133749"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}