{"id":133874,"date":"2018-04-09T06:30:24","date_gmt":"2018-04-08T22:30:24","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=133874"},"modified":"2018-04-08T15:23:07","modified_gmt":"2018-04-08T07:23:07","slug":"%e5%a4%a7%e8%bf%9e%e5%8c%96%e5%ad%a6%e7%89%a9%e7%90%86%e7%a0%94%e7%a9%b6%e6%89%80%e5%88%98%e7%94%9f%e5%bf%a0%e7%a0%94%e7%a9%b6%e5%91%98%e5%9b%a2%e9%98%9f-adv-mater-%e9%ab%98%e6%80%a7%e8%83%bd","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=133874","title":{"rendered":"\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u5218\u751f\u5fe0\u7814\u7a76\u5458\u56e2\u961f Adv. Mater: \u9ad8\u6027\u80fd\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684\u76f8\u53d8\u63a7\u5236"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u4e8c\u7ef4(2D) Ruddlesden-Popper (RP)\u578b\u6742\u5316\u9499\u949b\u77ff\u534a\u5bfc\u4f53\uff0c\u56e0\u4e3a\u5176\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u548c\u5149\u7535\u6027\u80fd\uff0c\u5df2\u7ecf\u5728\u79d1\u7814\u9886\u57df\u5438\u5f15\u4e86\u6781\u5927\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u4e8c\u7ef4\u9499\u949b\u77ff\u590d\u6742\u7684\u7ed3\u6676\u52a8\u529b\u5b66\u65b9\u9762\u7684\u7814\u7a76\u4ecd\u5b58\u5728\u7a7a\u767d\u3002<\/p>\n

\u00a0<\/strong>\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5927\u8fde\u5316\u5b66\u7269\u7406\u7814\u7a76\u6240\u535a\u58eb\u7814\u7a76\u751f\u5f20\u65ed\u540c\u5b66\u5728\u6d01\u51c0\u80fd\u6e90\u56fd\u5bb6\u5b9e\u9a8c\u5ba4\u592a\u9633\u80fd\u7814\u7a76\u90e8\u8584\u819c\u592a\u9633\u80fd\u7535\u6c60\u7814\u7a76\u7ec4\uff08DNL1606\uff09\u5218\u751f\u5fe0\u7814\u7a76\u5458\u548c\u9655\u897f\u5e08\u8303\u5927\u5b66\u8d75\u594e\u6559\u6388\u6307\u5bfc\u4e0b\uff0c\u7ee72017\u5e74\u5728\u80fd\u6e90\u7814\u7a76\u9876\u7ea7\u671f\u520a Energy & Environmental. Science<\/em><\/strong> \u4e0a\u62a5\u9053\u4e86\u4f4e\u7ef4\u9499\u949b\u77ff\u7535\u6c60\u6700\u9ad8\u6548\u7387\u4e4b\u540e\uff0c\u53c8\u5728\u4e8c\u7ef4\u9499\u949b\u77ff\u7ed3\u6676\u52a8\u529b\u5b66\u7814\u7a76\u4e0a\u53d6\u5f97\u65b0\u8fdb\u5c55\uff0c\u76f8\u5173\u7814\u7a76\u6210\u679c\u53d1\u8868\u5728Advanced Materials<\/em><\/strong>\u4e0a(DOI: 10.1002\/adma.201707166)\u3002<\/p>\n

\u8be5\u7814\u7a76\u5229\u7528\u9ad8\u80fd\u540c\u6b65\u8f90\u5c04\u6280\u672f\uff0c\u5b9e\u65f6\u8ffd\u8e2a\u4e8c\u7ef4\u9499\u949b\u77ff\u524d\u9a71\u4f53\u6eb6\u6db2\u53cd\u5e94\u5f62\u6210\u56fa\u6001\u8584\u819c\u7684\u76f8\u8f6c\u53d8\u884c\u4e3a\uff0c\u7814\u7a76\u4e86\u57fa\u5e95\u6e29\u5ea6\u548c\u6eb6\u5242\u6027\u8d28\u5982\u4f55\u5f71\u54cd\u4e8c\u7ef4\u9499\u949b\u77ff\u7ed3\u6676\u52a8\u529b\u5b66\u4ee5\u53ca\u8584\u819c\u76f8\u7eaf\u5ea6\u3001\u91cf\u5b50\u9631\u6392\u5217\u53d6\u5411\u548c\u5149\u4f0f\u6027\u80fd\u3002<\/p>\n

\u4e0a\u8ff0\u7814\u7a76\u5de5\u4f5c\u5206\u522b\u5f97\u5230\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u3001\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u3001\u4e2d\u592e\u9ad8\u6821\u57fa\u91d1\u3001\u6559\u80b2\u90e8\u201c111\u5f15\u667a\u8ba1\u5212\u201d\u3001\u201c\u5343\u4eba\u8ba1\u5212\u201d\u9879\u76ee\u7684\u8d44\u52a9\u4ee5\u53ca\u5eb7\u5948\u5c14\u5927\u5b66\u9ad8\u80fd\u540c\u6b65\u8f90\u5c04\u5149\u6e90\u7684\u5e2e\u52a9\u3002<\/p>\n

\u56fe\u4e00\uff1a\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684\u7535\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a). \u4e00\u6b65\u6cd5\u65cb\u6d82(BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u524d\u9a71\u4f53\u6eb6\u6db2\u548c\u7535\u6c60\u7ed3\u6784\u4ee5\u53ca\u8584\u819c\u6676\u4f53\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

(b). \u5bf9\u6bd4\u4e0d\u540c2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u592a\u9633\u7535\u6c60\u7684J-V\u66f2\u7ebf\u56fe<\/p>\n

(c). \u6700\u4f73\u6027\u80fd\u5668\u4ef6\u7684EQE\u548c\u79ef\u5206\u7535\u6d41\u66f2\u7ebf<\/p>\n

(d). 2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u592a\u9633\u7535\u6c60\u7684\u6b63\u53cd\u626bJ-V\u66f2\u7ebf<\/p>\n

\u8868\u4e00\uff1a\u4e8c\u7ef4\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u7684\u57fa\u672c\u53c2\u6570<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe\u4e8c\uff1a\u4e8c\u7ef4\u9499\u949b\u77ff\u7ed3\u6676\u52a8\u529b\u5b66\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

(a-c). \u539f\u4f4dGIWAXS\u6d4b\u8bd5\u5206\u6790\u4e0d\u540c2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u8584\u819c\u7684\u76f8\u53d8\u8fc7\u7a0b<\/p>\n

(d-f). \u4e0d\u540c2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u8584\u819c\u5f62\u6210\u7684\u52a8\u529b\u5b66\u6a21\u578b<\/p>\n

\u56fe\u4e09\uff1a\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u7684\u7ed3\u6676\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

(a-f). GIWAXS\u6d4b\u8bd5\u5206\u6790\u4e0d\u540c2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u8584\u819c\u7684\u7ed3\u6676\u6027\u8d28<\/p>\n

(g). \u5e73\u884c\u53d6\u5411\uff08\u5de6\uff09\u548c\u5782\u76f4\u53d6\u5411\uff08\u53f3\uff09\u7684TiO2<\/sub>\/(BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u754c\u9762<\/p>\n

\u56fe\u56db\uff1a\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u7684\u5f62\u8c8c\u7279\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(a). \u4e0d\u540c2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u8584\u819c\u7684\u626b\u63cf\u7535\u955c\u622a\u9762\u7167\u7247<\/p>\n

(b). \u4e0d\u540c2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u8584\u819c\u7684\u626b\u63cf\u7535\u955c\u5e73\u9762\u7167\u7247<\/p>\n

(c). \u4e0d\u540c2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u8584\u819c\u7684\u539f\u5b50\u529b\u663e\u5fae\u955c\u7167\u7247<\/p>\n

\u56fe\u4e94\uff1a\u4e8c\u7ef4\u9499\u949b\u77ff\u8584\u819c\u7684\u5149\u5b66\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a). \u4e0d\u540c2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u8584\u819c\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u548c\u5149\u5b66\u5e26\u9699\u8c31\u56fe<\/p>\n

(b). \u4e0d\u540c2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u8584\u819c\u7a33\u6001\u8367\u5149\u8c31\u56fe<\/p>\n

(c). \u4e0d\u540c2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u8584\u819c\u5149\u5b66\u5e26\u9699\u548c\u8367\u5149\u7ebf\u5bbd\u7684\u53d8\u5316\u8c31\u56fe<\/p>\n

(d). \u4e0d\u540c2D (BA)2<\/sub>(MA)3<\/sub>Pb4<\/sub>I13<\/sub>\u8584\u819c\u8367\u5149\u5bff\u547d\u8c31\u56fe<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/p>\n

\u7814\u7a76\u8868\u660e\uff0c\u5f53\u524d\u9a71\u4f53-\u6eb6\u5242\u4e2d\u95f4\u6001\u5f62\u6210\u65f6\uff0c\u9499\u949b\u77ff\u7684\u6210\u6838\u80fd\u5792\u589e\u52a0\uff0c\u5bfc\u81f4\u4e8c\u7ef4\u9499\u949b\u77ff\u76f8\u7eaf\u5ea6\u548c\u6676\u4f53\u53d6\u5411\u6709\u5e8f\u6027\u964d\u4f4e\u3002\u7814\u7a76\u8fdb\u4e00\u6b65\u8868\u660e\u57fa\u5e95\u8bf1\u5bfc\u4e8c\u7ef4\u9499\u949b\u77ff\u6210\u6838\u751f\u957f\u662f\u9ad8\u8d28\u91cf\u9499\u949b\u77ff\u8584\u819c\u7684\u5173\u952e\u3002\u901a\u8fc7\u57fa\u5e95\u8bf1\u5bfc\u7ed3\u6676\uff0c\u53ef\u4ee5\u6291\u5236\u524d\u9a71\u4f53-\u6eb6\u5242\u4e2d\u95f4\u6001\u7684\u5f62\u6210\uff0c\u4ece\u800c\u5b9e\u73b0\u9ad8\u8d28\u91cf\u4e8c\u7ef4\u9499\u949b\u77ff\u6676\u4f53\u7684\u751f\u957f\uff1a\u4e8c\u7ef4\u91cf\u5b50\u9631\u91c7\u53d6\u70ed\u529b\u5b66\u66f4\u7a33\u5b9a\u7684\u5782\u76f4\u53d6\u5411\uff1b\u6676\u4f53\u76f8\u7eaf\u5ea6\u6700\u9ad8\u3002\u57fa\u4e8e\u9ad8\u8d28\u91cf\u9499\u949b\u77ff\u8584\u819c\uff0c\u592a\u9633\u7535\u6c60\u7684\u5149\u7535\u8f6c\u5316\u6548\u7387\u5927\u5e45\u63d0\u5347\u3002\u8be5\u7814\u7a76\u7ed3\u679c\u5bf9\u5236\u5907\u9ad8\u8d28\u91cf\u4f4e\u7ef4\u9499\u949b\u77ff\u8584\u819c\u4ee5\u53ca\u9ad8\u6027\u80fd\u5149\u7535\u5668\u4ef6\u63d0\u4f9b\u4e86\u7406\u8bba\u6839\u636e\uff0c\u5c06\u6709\u52a9\u4e8e\u63a8\u52a8\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u8fdb\u4e00\u6b65\u8d70\u5411\u5546\u4e1a\u5e94\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Phase Transition Control for High Performance Ruddlesden\u2013Popper Perovskite Solar Cells <\/strong>(Adv. Mater. 2018, 1707166. DOI: 10.1002\/adma.201707166)<\/p>\n

\u3010\u56e2\u961f\u4ecb\u7ecd\u3011<\/strong><\/p>\n

\u5927\u8fde\u5316\u7269\u6240\u5218\u751f\u5fe0\u7814\u7a76\u5458\u548c\u9655\u897f\u5e08\u8303\u5927\u5b66\u8d75\u594e\u6559\u6388\u9886\u5bfc\u7684\u56e2\u961f\u6700\u8fd1\u5728\u9499\u949b\u77ff\u5668\u4ef6\u65b9\u9762\u53d6\u5f97\u4e86\u7cfb\u5217\u56fd\u9645\u9886\u5148\u7814\u7a76\u6210\u679c\uff0c\u5305\u62ec\uff1a2017\u5e74\u5236\u5907\u51fa\u4e16\u754c\u6700\u9ad8\u6548\u738713.7%\u7684\u4e8c\u7ef4\u9499\u949b\u77ff\u7535\u6c60\uff08Energy Environ. Sci., <\/em>2017, 10, 2095\uff09; 2018\u5e74\u91c7\u53d6\u6676\u754c\u949d\u5316\u6cd5\u5236\u5907\u7a33\u5b9a\u9ad8\u6548\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\uff08Adv. Mater., 2018, DOI:10.1002\/adma.201706576\uff09; 2018\u5e74\u901a\u8fc7\u5b9e\u65f6\u8ffd\u8e2a\u6280\u672f\u7814\u7a76\u4e09\u7ef4\u9499\u949b\u77ff\u4e2d\u95f4\u6001\u7684\u5f62\u6210(ACS Energy Lett., 2018, DOI: 10.1021\/acsenergylett.8b00428)\uff1b2018\u5e74\u5229\u7528\u522e\u6d82\u6280\u672f\u5236\u5907\u9ad8\u6548\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\uff08Joule, 2018, In press\uff09\u3002\u8fd9\u4e9b\u6210\u679c\u90fd\u8fbe\u5230\u4e86\u540c\u7c7b\u7814\u7a76\u7684\u56fd\u9645\u5148\u8fdb\u6c34\u5e73\u3002<\/p>\n

\u6750\u6599\u4eba\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u4eea\u5668\u8bbe\u5907\u3001\u8bd5\u5242\u8017\u6750\u3001\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u627e\u6750\u6599\u4eba<\/strong><\/a>\u3001\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u4e8c\u7ef4(2D) Ruddlesden-Popper (RP)\u578b\u6742\u5316\u9499\u949b\u77ff\u534a\u5bfc\u4f53\uff0c\u56e0\u4e3a\u5176\u4f18\u5f02\u7684\u7a33\u5b9a\u6027\u548c\u5149\u7535\u6027\u80fd\uff0c\u5df2\u7ecf\u5728\u79d1\u7814\u9886\u57df\u5438\u5f15\u4e86\u6781\u5927\u7684\u5173\u6ce8\u3002\u7136\u800c\uff0c\u4e8c\u7ef4…<\/p>\n","protected":false},"author":272,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[2630],"class_list":["post-133874","post","type-post","status-publish","format-standard","hentry","category-jiedu","category-keji","tag-2630"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/133874"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/272"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=133874"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/133874\/revisions"}],"predecessor-version":[{"id":133965,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/133874\/revisions\/133965"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=133874"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=133874"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=133874"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}