{"id":134600,"date":"2018-04-13T06:30:59","date_gmt":"2018-04-12T22:30:59","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=134600"},"modified":"2018-04-12T11:39:34","modified_gmt":"2018-04-12T03:39:34","slug":"%e3%80%90%e6%8a%95%e7%a8%bf%e5%be%85%e5%ae%9a%e3%80%91%e6%9a%a8%e5%8d%97%e5%a4%a7%e5%ad%a6-%e5%94%90%e7%be%a4%e5%a7%94-chemsuschem%ef%bc%9a%e5%90%88%e9%87%91%e8%b0%83%e6%8e%a7%e7%a2%b3%e7%94%b5","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=134600","title":{"rendered":"\u66a8\u5357\u5927\u5b66 \u5510\u7fa4\u59d4 ChemSusChem\uff1a\u5408\u91d1\u8c03\u63a7\u78b3\u7535\u6781\u529f\u51fd\u6570\u6539\u5584\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u7684\u7535\u8377\u63d0\u53d6"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8fd1\u5e74\u6765\uff0c\u57fa\u4e8eCsPbBr3<\/sub>\u5438\u5149\u5c42\u7684\u5168\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u4f4e\u6210\u672c\u5f97\u5230\u4e86\u7814\u7a76\u8005\u7684\u5bc6\u5207\u5173\u6ce8\uff0c\u5176\u5149\u7535\u8f6c\u6362\u6548\u7387\u4e5f\u6301\u7eed\u8d70\u9ad8\uff0c\u4e0d\u65ad\u5237\u65b0\u7eaa\u5f55\u3002\u7814\u7a76\u53d1\u73b0\uff0c\u65e0\u673aPSC\u5668\u4ef6\u7684\u7535\u8377\u63d0\u53d6\u80fd\u529b\u5bf9\u5149\u7535\u8f6c\u6362\u6548\u7387\u7684\u63d0\u5347\u5177\u6709\u5173\u952e\u4f5c\u7528\u3002\u7ecf\u5178\u65e0\u673aPSC\u5668\u4ef6\u91c7\u7528CsPbBr3<\/sub>\u8584\u819c\u4e3a\u5438\u5149\u5c42\uff0c\u5176\u4ef7\u5e26\u80fd\u7ea7\u4e3a-5.6 eV\uff0c\u4e0e\u78b3\u7535\u6781\u7684\u529f\u51fd\u6570-5.0 eV\u4ea7\u751f\u76840.6 eV\u7684\u80fd\u91cf\u5dee\u81f4\u4f7f\u7535\u8377\u63d0\u53d6\u56f0\u96be\u5e76\u9650\u5236\u5149\u4f0f\u6027\u80fd\u7684\u63d0\u5347\u3002\u56e0\u6b64\uff0c\u5982\u4f55\u5b9e\u73b0\u9ad8\u6548\u7535\u8377\u63d0\u53d6\u662f\u5168\u65e0\u673aPSC\u9886\u57df\u7684\u7814\u7a76\u70ed\u70b9\u4e4b\u4e00\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u66a8\u5357\u5927\u5b66\u65b0\u80fd\u6e90\u6280\u672f\u7814\u7a76\u9662\u5510\u7fa4\u59d4\u6559\u6388\uff08\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8bbe\u8ba1\u4e86\u4e00\u79cdPtNi\u5408\u91d1\u8c03\u63a7\u78b3\u80cc\u7535\u6781\u529f\u51fd\u6570\u7684\u5168\u65e0\u673aPSC\u5668\u4ef6\uff0c\u5229\u7528PtNi\u5408\u91d1\u63ba\u6742\u6bd4\u4f8b\u8c03\u63a7\u80cc\u7535\u6781\u529f\u51fd\u6570\u4e0eCsPbBr3<\/sub>\u4ef7\u5e26\u80fd\u7ea7\u7684\u5339\u914d\u5ea6\uff0c\u6709\u6548\u63d0\u9ad8\u4e86\u7535\u5b50-\u7a7a\u7a74\u7684\u5206\u79bb\u6548\u7387\uff0c\u5e76\u6700\u7ec8\u83b7\u5f97\u4e867.85%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u6b64\u5916\uff0c\u5668\u4ef6\u572825\u2103\u7684\u5ba4\u6e29\u548c80%\u7684\u76f8\u5bf9\u6e7f\u5ea6\u4e0b\u4fdd\u5b5820\u4f59\u5929\uff0c\u5149\u4f0f\u6027\u80fd\u4ecd\u80fd\u4fdd\u6301\u7a33\u5b9a\u3002\u901a\u8fc7\u8c03\u63a7\u80cc\u7535\u6781\u529f\u51fd\u6570\u6539\u5584\u7535\u8377\u63d0\u53d6\u4e3a\u6781\u5927\u63d0\u5347\u65e0\u673aPSC\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201cAlloy-Controlled Work Function for Enhanced Charge Extraction in All-Inorganic CsPbBr3<\/sub> Perovskite Solar Cells\u201d\u4e3a\u6807\u9898\u53d1\u8868\u5728ChemSusChem\u6742\u5fd7\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1.<\/strong>\u5168\u65e0\u673a<\/strong>PSC<\/strong>\u7684\u5668\u4ef6\u7ed3\u6784\u548c<\/strong>PtNi<\/strong>\u5408\u91d1\u7684\u5f62\u8c8c<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u5168\u65e0\u673aPSC\u7684\u5668\u4ef6\u7ed3\u6784\u793a\u610f\u56fe\u3002<\/p>\n

(b) \u5168\u65e0\u673aPSC\u7684SEM\u65ad\u9762\u56fe\u3002<\/p>\n

(c) \u65e0\u673aCsPbBr3<\/sub>\u7684\u6676\u4f53\u7ed3\u6784\u3002<\/p>\n

(d)-(e) PtNi\u5408\u91d1\u7684\u5f62\u8c8c\u3002<\/p>\n

\u56fe<\/strong>2. <\/strong>\u5168\u65e0\u673a<\/strong>PSC<\/strong>\u5668\u4ef6\u7684\u5149\u4f0f\u6027\u80fd\u53ca<\/strong>PtNi<\/strong>\u5408\u91d1\u7684\u529f\u51fd\u6570<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u4e0d\u540cPtNi\u5408\u91d1\u4fee\u9970\u7684\u5168\u65e0\u673aPSC\u5668\u4ef6\u7684J-V\u66f2\u7ebf\u3002<\/p>\n

(b) \u5168\u65e0\u673aPSC\u7684IPCE\u56fe\u8c31\u3002<\/p>\n

(c)-(f) PtNi\u5408\u91d1\u63ba\u6742\u78b3\u7535\u6781\u7684\u529f\u51fd\u6570\u56fe\u8c31\u3002<\/p>\n

(g) \u5168\u65e0\u673aPSC\u7684\u80fd\u7ea7\u7ed3\u6784\u548c\u7535\u8377\u4f20\u8f93\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong>3. <\/strong>\u5168\u65e0\u673a<\/strong>PSC<\/strong>\u7684\u7535\u8377\u63d0\u53d6\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a)-(b) \u5168\u65e0\u673aPSC\u5668\u4ef6\u7684\u590d\u5408\u7535\u6d41\u548c\u590d\u5408\u7535\u538b\u3002<\/p>\n

(c) \u7535\u6c60\u5668\u4ef6\u7684PL\u56fe\u8c31\u3002<\/p>\n

(d) \u7535\u6c60\u5668\u4ef6\u7684\u77ac\u6001\u8367\u5149\u5149\u8c31\u3002<\/p>\n

\u56fe<\/strong>4. <\/strong>\u7535\u6c60\u6027\u80fd\u53ca\u7a33\u5b9a\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(a) \u78b3\u91cf\u5b50\u70b9\u754c\u9762\u4fee\u9970\u7684\u5168\u65e0\u673aPSC\u7684J-V\u66f2\u7ebf\u3002<\/p>\n

(b) \u78b3\u91cf\u5b50\u70b9\u754c\u9762\u4fee\u9970\u7684\u5168\u65e0\u673aPSC\u7684IPCE\u3002<\/p>\n

(c) \u5168\u65e0\u673aPSC\u768420\u5929\u7a33\u5b9a\u6027\uff0880% RH, 25\u00baC\uff09\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u5229\u7528\u5408\u91d1\u8c03\u63a7\u78b3\u80cc\u7535\u6781\u7684\u529f\u51fd\u6570\u6539\u5584\u4e86\u5168\u65e0\u673aPSC\u5668\u4ef6\u7684\u7535\u5b50-\u7a7a\u7a74\u63d0\u53d6\u8fc7\u7a0b\uff0c\u901a\u8fc7\u4f18\u5316\u80fd\u7ea7\u7ed3\u6784\uff0c\u83b7\u5f97\u4e867.85%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\uff0c\u5e76\u63a2\u8ba8\u4e0d\u540c\u5408\u91d1\u6bd4\u4f8b\u5bf9\u7535\u6c60\u6027\u80fd\u7684\u5f71\u54cd\u3002\u8fd9\u9879\u5de5\u4f5c\u5bf9\u4e8e\u8fdb\u4e00\u6b65\u8c03\u9ad8\u7535\u8377\u63d0\u53d6\u80fd\u529b\u63d0\u4f9b\u4e86\u65b0\u601d\u8def\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aAlloy-Controlled Work Function for Enhanced Charge Extraction in All-Inorganic CsPbBr3 Perovskite Solar Cells <\/a><\/strong>(ChemSusChem, 2018, DOI: 10.1002\/cssc.201800060)<\/p>\n

\u672c\u6587\u7531\u66a8\u5357\u5927\u5b66\u65b0\u80fd\u6e90\u6280\u672f\u7814\u7a76\u9662\u4f9b\u7a3f\uff0c\u7279\u6b64\u611f\u8c22\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002\u5982\u679c\u4f60\u5bf9\u7535\u5b50\u6750\u6599\u611f\u5174\u8da3\uff0c\u613f\u610f\u4e0e\u7535\u5b50\u7535\u5de5\u9886\u57df\u4eba\u624d\u4ea4\u6d41\uff0c\u8bf7\u52a0\u5165\u6750\u6599\u4eba\u7535\u5b50\u7535\u5de5\u6750\u6599\u5b66\u4e60\u5c0f\u7ec4\uff08QQ\u7fa4\uff1a482842474\uff09\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1aRDD-2011-CHERISH , \u4efb\u4e39\u4e39\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a\u6d4b\u8bd5\u8c37<\/a><\/strong>\uff01<\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8fd1\u5e74\u6765\uff0c\u57fa\u4e8eCsPbBr3\u5438\u5149\u5c42\u7684\u5168\u65e0\u673a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff08PSC\uff09\u7531\u4e8e\u5176\u4f18\u5f02\u7684\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u4f4e\u6210\u672c\u5f97\u5230\u4e86\u7814\u7a76\u8005\u7684\u5bc6\u5207\u5173\u6ce8\uff0c\u5176\u5149\u7535\u8f6c\u6362\u6548\u7387\u4e5f\u6301\u7eed\u8d70\u9ad8\uff0c\u4e0d\u65ad…<\/p>\n","protected":false},"author":99,"featured_media":134601,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215,2],"tags":[3059,3060,1029],"class_list":["post-134600","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","category-keji","tag-3059","tag-3060","tag-1029"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/134600"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/99"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=134600"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/134600\/revisions"}],"predecessor-version":[{"id":134657,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/134600\/revisions\/134657"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/134601"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=134600"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=134600"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=134600"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}