{"id":134829,"date":"2018-04-21T14:00:53","date_gmt":"2018-04-21T06:00:53","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=134829"},"modified":"2018-04-17T12:08:05","modified_gmt":"2018-04-17T04:08:05","slug":"%e5%8e%a6%e9%97%a8%e5%a4%a7%e5%ad%a6nat-commun-%e4%b8%89%e7%a7%8d%e7%a2%b1%e9%87%91%e5%b1%9e%e8%a1%a8%e9%9d%a2%e7%9a%84%e7%94%b5%e5%8c%96%e5%ad%a6%e8%b0%83%e6%8e%a7%e5%8f%8asei%e8%86%9c%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=134829","title":{"rendered":"\u53a6\u95e8\u5927\u5b66Nat. Commun: 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ultra-smooth ultra-thin solid-electrolyteinterphases of three alkali metal anodes<\/strong><strong>\u201d<\/strong>\u4e3a\u9898\u53d1\u8868\u5728<strong>Nature Communications<\/strong>\u4e0a\u3002<\/p>\n<p><strong>\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n<p><strong>\u56fe\u4e00\u4e0d\u540cMA\u8868\u9762\u679d\u6676\u751f\u957f\u7684\u793a\u610f\u56fe\u548c\u629b\u5149MA\u8868\u9762\u7684\u7535\u5316\u5b66\u629b\u5149\u65b9\u6cd5<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134913\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/1-37.jpg\" alt=\"\" width=\"600\" height=\"294\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/1-37.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/1-37-300x147.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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LiTFSI \/ DME-DOL\u7535\u89e3\u6db2\u4e2d\u629b\u5149\u4e4b\u524d\uff08a\uff09\u548c\u629b\u5149\u4e4b\u540e\uff08b-d\uff09\u7684AFM\u56fe\u50cf<\/p>\n<p>\uff08e\uff0cf\uff09Na\u5728NaOTf \/diglyme\u7535\u89e3\u6db2\u4e2d\u629b\u5149\u540e\u7684AFM\u56fe\u50cf<\/p>\n<p>\uff08g\uff0ch\uff09K\u5728KTFSI \/ DME\u7535\u89e3\u6db2\u4e2d\u629b\u5149\u540e\u7684AFM\u56fe\u50cf<\/p>\n<p><strong>\u56fe\u4e09<\/strong><strong>AFM<\/strong><strong>\u8868\u5f81<\/strong><strong>SEI<\/strong><strong>\u5c42\u7684\u673a\u68b0\u6027\u80fd<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134915\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/3-33.jpg\" alt=\"\" width=\"600\" height=\"472\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/3-33.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/3-33-300x236.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" 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loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134916\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/4-32.jpg\" alt=\"\" width=\"600\" height=\"355\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/4-32.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/4-32-300x178.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a-f\uff09\u6d78\u6ce1Li\u7535\u6781\uff08a\uff0cb\uff09\u548c\u5177\u6709O-I\uff08c\uff0cd\uff09\u548cI-O-I\uff08e\uff0cf\uff09\u7ed3\u6784SEI\u7684Li\u7535\u6781\u7684XPS\u6df1\u5ea6\u5256\u6790\u56fe<\/p>\n<p>\uff08g\uff09\u5404\u79cd\u6761\u4ef6\u4e0b\u9502\u7535\u6781\u7684FTIR\u56fe<\/p>\n<p>\uff08h\uff09\u5faa\u73af5\u6b21\u4e4b\u540e\u6d78\u6ce1\u548c\u629b\u5149Li\u7535\u6781\u7684EIS\u56fe<\/p>\n<p><strong>\u56fe\u4e94\u629b\u5149\u548c\u6d78\u6ce1\u9502\u9633\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134917\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/5-26.jpg\" alt=\"\" width=\"600\" height=\"461\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/5-26.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/5-26-300x231.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a\uff0cc\uff0ce\uff09\u6d78\u6ce1\u6216\u629b\u5149Li\u7535\u6781\u5206\u522b\u7ec4\u6210\u8584\u819cLi\u5bf9\u79f0\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n<p>\uff08b\uff0cd\uff0cf\uff09\u4e0d\u540c\u8584\u819cLi\u5bf9\u79f0\u7535\u6c60\u5faa\u73af\u540e\u7684Li\u8868\u9762\u5f62\u8c8c<\/p>\n<p>\uff08g-i\uff09\u6d78\u6ce1\u6216\u629b\u5149Li\u7535\u6781\u5206\u522b\u7ec4\u6210Cu || Li\u7535\u6c60\u7684\u5e93\u4f26\u6548\u7387\u53ca\u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n<p><strong>\u56fe\u516d\u629b\u5149<\/strong><strong>Na<\/strong><strong>\u548c<\/strong><strong>K<\/strong><strong>\u9633\u6781\u7684\u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter size-full wp-image-134918\" src=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/6-19.jpg\" alt=\"\" width=\"600\" height=\"357\" srcset=\"http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/6-19.jpg 600w, http:\/\/www.cailiaoniu.com\/wp-content\/uploads\/2018\/04\/6-19-300x179.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>\uff08a-c\uff09\u6d78\u6ce1\u6216\u629b\u5149Na\u7535\u6781\u5206\u522b\u7ec4\u6210Na\u5bf9\u79f0\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n<p>\uff08d\uff0ce\uff09\u6ce1\u6216\u629b\u5149Li\u7535\u6781\u5206\u522b\u7ec4\u6210Cu || Li\u7535\u6c60\u7684\u5e93\u4f26\u6548\u7387\u53ca\u5faa\u73af\u7a33\u5b9a\u6027<\/p>\n<p>\uff08f\uff09\u5728400\u6b21\u5faa\u73af\u540e\u6d78\u6ce1\u548c\u629b\u5149\u7684Na\u7b94\u7684\u5149\u5b66\u56fe\u50cf<\/p>\n<p><strong>\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n<p>\u672c\u6587\u5efa\u7acb\u4e86\u4e00\u79cd\u7b80\u5355\u7684\u57fa\u4e8e\u6052\u7535\u52bf-\u6052\u7535\u6d41\u8054\u5408\u63a7\u5236\u7b56\u7565\u7684\u7535\u5316\u5b66\u629b\u5149\u65b9\u6cd5\uff0c\u5b9e\u73b0\u5bf9\u78b1\u91d1\u5c5e\u8868\u9762\u7684\u7535\u5316\u5b66\u8c03\u63a7\u548cSEI\u819c\u7684\u539f\u4f4d\u6210\u819c\u3002\u7814\u7a76\u8868\u660e\uff0c\u629b\u5149\u540e\u7684\u9502\u7535\u6781\u5177\u6709\u5927\u8303\u56f4\u5e73\u6574\u7684\u8868\u9762\u53ca\u5747\u5300\u5149\u6ed1\u7684SEI\u819c\uff0c\u8be5SEI\u819c\u5448\u73b0\u51fa\u65e0\u673a\u7269\u5d4c\u5165\u3001\u6709\u673a\u7269\u4ea4\u8054\u7684\u8f6f\u786c\u76f8\u95f4\u7684\u591a\u5c42\u819c\u7ed3\u6784\u7279\u5f81\u548c\u660e\u663e\u63d0\u5347\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u8fd9\u79cd\u5fae\u89c2\u5e73\u6574\u5149\u6ed1\u4e14\u517c\u5177\u521a\u6027\u548c\u5f39\u6027\u7684SEI\u819c\u7684\u9502\u8d1f\u6781\uff0c\u5177\u6709\u4f18\u8d8a\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5bf9\u9502\u679d\u6676\u6709\u5f88\u597d\u7684\u6291\u5236\u6548\u679c\uff0c\u8868\u73b0\u51fa\u660e\u663e\u52a0\u957f\u7684\u7a33\u5b9a\u6027\u53ca\u5bf9\u7535\u6c60\u7535\u89e3\u6db2\u7684\u666e\u9002\u6027\uff0c\u9502\u5e73\u9762\u7535\u6781\u53ef\u57282 mA cm<sup>\u20132<\/sup>\uff081 mAh cm<sup>\u20132<\/sup>\uff09\u3001100% Li \u653e\u7535\u6df1\u5ea6\uff08DOD\uff09\u4e0b\u7a33\u5b9a\u5faa\u73af\u81f3\u5c11200\u5468\u4e14\u5e93\u4f26\u6548\u7387\u9ad8\u8fbe99%\uff1b\u4e0e\u786b\u6216\u8005\u94b4\u9178\u9502\u6b63\u6781\u6750\u6599\u6784\u6210\u7684\u5168\u7535\u6c60\u4e5f\u540c\u6837\u5c55\u73b0\u51fa\u4f18\u8d8a\u7684\u5145-\u653e\u7535\u5faa\u73af\u6027\u80fd\u3002\u5c06\u7535\u5316\u5b66\u8c03\u63a7\u65b9\u6cd5\u8fdb\u4e00\u6b65\u62d3\u5c55\u5230\u94a0\u3001\u94be\u78b1\u91d1\u5c5e\u8d1f\u6781\u4e0a\uff0c\u4f9d\u7136\u53ef\u4ee5\u5f62\u6210\u5927\u8303\u56f4\u5e73\u6574\u7684\u94a0\u3001\u94be\u8868\u9762\u548c\u8d85\u8584\u8d85\u5149\u6ed1\u7684SEI\u819c\u3002\u7279\u522b\u662f\uff0c\u91d1\u5c5e\u94a0\u5e73\u9762\u7535\u6781\u53ef\u57282 mA cm<sup>\u20132<\/sup>\uff081 mAh cm<sup>\u20132<\/sup>\uff09100% Na DOD\u4e0b\u7a33\u5b9a\u5faa\u73af550\u5468\u4ee5\u4e0a\u4e14\u5e93\u4f26\u6548\u7387\u8fd1100%\u3002\u8fd9\u4e00\u57fa\u4e8e\u7535\u5316\u5b66\u8c03\u63a7\u7684\u78b1\u91d1\u5c5e\u8868\u9762\u629b\u5149\u548cSEI\u819c\u6784\u7b51\u7684\u65b9\u6cd5\u53ca\u591a\u5c3a\u5ea6\u8054\u5408\u8868\u5f81\uff0c\u4e3a\u89e3\u51b3\u78b1\u91d1\u5c5e\u8d1f\u6781\u95ee\u9898\u63d0\u4f9b\u4e86\u65b0\u7684\u601d\u8def\uff0c\u4e5f\u4e3a\u5f00\u5c55\u8868\u9762\u79d1\u5b66\u57fa\u7840\u7814\u7a76\u63d0\u4f9b\u9ad8\u8d28\u91cf\u7684\u78b1\u91d1\u5c5e\u8868\u9762\u3002<\/p>\n<p><strong>\u00a0<\/strong><strong>\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/strong><a href=\"https:\/\/www.nature.com\/articles\/s41467-018-03466-8\" target=\"_blank\" rel=\"noopener\"><strong>Designable ultra-smooth ultra-thin solid-electrolyte interphases of three alkali metal anodes<\/strong><\/a><strong>\u201d(Nat. Commun. 2018.<\/strong>DOI: 10.1038\/s41467-018-03466-8)<\/p>\n<p>\u8be5\u7814\u7a76\u662f\u5728\u6bdb\u79c9\u4f1f\u6559\u6388\u548c\u8463\u5168\u5cf0\u6559\u6388\u5171\u540c\u6307\u5bfc\u4e0b\uff0c\u75312014\u7ea7\u535a\u58eb\u751f\u8c37\u5b87\u30012016\u7ea7\u535a\u58eb\u751f\u738b\u536b\u4f1f\u30012013\u7ea7\u535a\u58eb\u751f\u674e\u827a\u5a1f\u7b49\u540c\u5b66\u901a\u529b\u5408\u4f5c\u7684\u6210\u679c\u3002\u6cc9\u5dde\u5e08\u8303\u5b66\u9662\u5434\u542f\u8f89\u6559\u6388\u548c\u4e0a\u6d77\u5e94\u7528\u7269\u7406\u7814\u7a76\u6240\u6a0a\u6625\u6d77\u7814\u7a76\u5458\u5206\u522b\u5728X\u5c04\u7ebf\u5149\u7535\u5b50\u80fd\u8c31\u8868\u5f81\u548c\u540c\u6b65\u8f90\u5c04\u8868\u5f81\u4e2d\u63d0\u4f9b\u4e86\u5927\u529b\u652f\u6301\u3002\u6211\u9662\u90d1\u660e\u68ee\u526f\u6559\u6388\u3001\u989c\u4f73\u4f1f\u6559\u6388\u3001\u5434\u5fb7\u5370\u6559\u6388\u3001iChEM\u7814\u7a76\u5458\u4e01\u677e\u56ed\u535a\u58eb\u5728\u5b9e\u9a8c\u548c\u7406\u8bba\u8ba1\u7b97\u65b9\u9762\u7ed9\u4e88\u4e86\u5927\u529b\u5e2e\u52a9\uff1b\u7530\u4e2d\u7fa4\u6559\u6388\u548c\u90d1\u5357\u5cf0\u6559\u6388\u7b49\u5bf9\u6b64\u5de5\u4f5c\u63d0\u51fa\u4e86\u5b9d\u8d35\u610f\u89c1\u3002\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u79d1\u6280\u90e8973\u8ba1\u5212\uff08\u9879\u76ee\u6279\u51c6\u53f7\uff1a2015CB251102\u30012012CB932902\uff09\uff0c\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\uff08\u9879\u76ee\u6279\u51c6\u53f7\uff1aU1305246\u300121621091\u300121473147\u300121533006\u300121673193\uff09\u7b49\u9879\u76ee\u7684\u8d44\u52a9\u3002<\/p>\n<p>\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u5fae\u89c2\u4e16\u754c\u7f16\u8bd1\u4f9b\u7a3f\uff0c\u8bba\u6587\u901a\u8baf\u4f5c\u8005<strong>\u8463\u5168\u5cf0\u6559\u6388<\/strong>\u6574\u7406\u7f16\u8f91\u3002<\/p>\n<p>\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c<a href=\"http:\/\/www.cailiaoniu.com\/25127.html\" target=\"_blank\" rel=\"noopener\"><strong>\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/strong><\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n<p><strong>\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong><a href=\"http:\/\/www.ceshigu.com\/\" target=\"_blank\" rel=\"noopener\"><strong>\u6d4b\u8bd5\u8c37<\/strong><\/a><strong>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u3010\u5f15\u8a00\u3011 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