{"id":137298,"date":"2018-05-06T06:30:17","date_gmt":"2018-05-05T22:30:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=137298"},"modified":"2018-05-06T05:10:44","modified_gmt":"2018-05-05T21:10:44","slug":"%e6%b4%9b%e6%a1%91%e8%81%94%e9%82%a6%e7%90%86%e5%b7%a5gratzel%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9fjoule-%e5%8f%af%e5%ae%9e%e7%8e%b0%e9%ab%98%e6%95%88%e5%88%86%e5%ad%90%e5%85%89%e4%bc%8f%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=137298","title":{"rendered":"\u6d1b\u6851\u8054\u90a6\u7406\u5de5Gr\u00e4tzel\u6559\u6388\u56e2\u961fJoule: \u53ef\u5b9e\u73b0\u9ad8\u6548\u5206\u5b50\u5149\u4f0f\u7684\u76f4\u63a5\u63a5\u89e6\u578b\u7535\u8377\u9009\u62e9\u6027\u63d0\u53d6\u5c42"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u56e0\u539f\u6750\u6599\u4e30\u5bcc\u3001\u5236\u9020\u6210\u672c\u4f4e\u548c\u5de5\u827a\u6280\u672f\u76f8\u5bf9\u7b80\u5355\u800c\u53d7\u5230\u6781\u5927\u5173\u6ce8\u30021991\u5e74\u7531\u6d1b\u6851\u8054\u90a6\u7406\u5de5\u5b66\u9662(EPFL)\u7684Michael Gr\u00e4tzel\u6559\u6388\u9996\u6b21\u53d1\u660e\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u5728\u6a21\u62df\u592a\u9633\u5149(AM1.5G, 83 W m-2<\/sup>)\u4e0b\u4fbf\u83b7\u5f97\u4e867.9%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u76ee\u524d\uff0c\u5df2\u62a5\u9053\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u7684\u6548\u7387\u4e3a14.3%\uff0c\u548c\u9762\u79ef\u4e3a1 cm2<\/sup>\u7684\u8bd5\u6837\u4e0a\u7684\u8ba4\u8bc1\u6548\u7387\u5df2\u7ecf\u8fbe\u523011.9%\uff0c\u4ee5\u53ca\u5728\u4eba\u9020\u5ba4\u5185\u5149(Osram 930 \u6696\u767d\u8272\u8367\u5149\u706f\u7ba1)\u7167\u5c04\u4e0b\u7535\u6c60\u7684\u6548\u7387\u5df2\u7a81\u783428.9%\u3002\u4f20\u7edf\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u7535\u6c60\u4e3b\u8981\u7531\u5bfc\u7535\u57fa\u5e95(FTO)\u3001\u5bf9\u7535\u6781(Pt)\u3001\u591a\u5b54\u534a\u5bfc\u4f53\u8584\u819c(TiO2<\/sub>)\u3001\u6c27\u5316\u8fd8\u539f\u7535\u89e3\u8d28\u548c\u67d3\u6599\u654f\u5316\u5242\u7ec4\u6210\u3002\u5176\u7ed3\u6784\u662f\u7528\u963b\u6321\u5c42(10-30 \u03bcm) \u5c06\u4ecb\u5b54\u4e8c\u6c27\u5316\u949b(TiO2<\/sub>)\u8584\u819c\u4e0e\u50ac\u5316\u5bf9\u7535\u6781\u5206\u5f00\u907f\u514d\u7535\u6781\u95f4\u7535\u5206\u6d41\u6f0f\u7535\u3002\u8fd9\u79cd\u7ed3\u6784\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u4e0d\u4ec5\u9700\u8981\u67d3\u6599\u6fc0\u53d1\u6001\u53ef\u4ee5\u5728\u4ecb\u5b54TiO2<\/sub>\u8584\u819c\u5b9e\u73b0\u4f20\u8f93\uff0c\u8fd8\u9700\u8981\u5176\u53ef\u4ee5\u5728\u7535\u89e3\u8d28\u6216\u963b\u6321\u5c42\u4e2d\u5b9e\u73b0\u4f20\u8f93\u3002\u7136\u800c\u7531\u4e8e\u67d3\u6599\u6fc0\u53d1\u6001\u7684\u5bff\u547d\u5f88\u77ed\uff0c\u5c31\u5f88\u5bb9\u6613\u9020\u6210\u6fc0\u5b50\u7684\u590d\u5408\u800c\u51cf\u5c11\u8f7d\u6d41\u5b50\u7684\u6536\u96c6\u3002\u5c3d\u7ba1\u62a5\u9053\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u6548\u7387\u9010\u6e10\u5f97\u5230\u63d0\u9ad8\uff0c\u4f46\u662f\u5728\u5bf9\u8fd9\u4e2a\u95ee\u9898\u7684\u6539\u8fdb\u4e0a\u9c9c\u6709\u62a5\u9053\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u6d1b\u6851\u8054\u90a6\u7406\u5de5\u5b66\u9662<\/strong>Michael Gr\u00e4tzel<\/strong>\u6559\u6388<\/strong>(<\/strong>\u901a\u8baf\u4f5c\u8005<\/strong>)<\/strong>\u56e2\u961f<\/strong>\u63d0\u51fa\u4e86\u4e00\u79cd\u57fa\u4e8e\u7531n\u578b\u65e0\u673a\u534a\u5bfc\u4f53\u4ecb\u5b54TiO2<\/sub>\u548cp\u578b\u6709\u673a\u534a\u5bfc\u4f53PEDOT\u76f4\u63a5\u63a5\u89e6\u6784\u6210II\u578b\u7ed3\u6982\u5ff5\u7684\u65b0\u578b\u7ed3\u6784\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u3002\u8fd9\u79cd\u907f\u514d\u7535\u6781\u95f4\u7535\u5206\u6d41\u65e0\u963b\u6321\u5c42\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u662f\u901a\u8fc7\u673a\u68b0\u5730\u5c06\u4e24\u5757\u7535\u6781\u538b\u5236\u800c\u6210\uff0c\u5176\u5b9e\u73b0\u4e86\u67d3\u6599\u6fc0\u53d1\u6001\u53ef\u4ee5\u53ea\u5728\u4ecb\u5b54\u4e8c\u6c27\u5316\u949b\u8584\u819c\u800c\u4e0d\u9700\u8981\u5728\u7535\u89e3\u8d28\u6216\u963b\u6321\u5c42\u4f20\u8f93\u4e0b\u9ad8\u6548\u7684\u592a\u9633\u80fd\u7535\u6c60\u3002\u4ee5\u4ecb\u5b54\u4e8c\u6c27\u5316\u949b, XY1b\/Y123\u4f5c\u4e3a\u5171\u654f\u5316\u5242\u548cCu(II)\/Cu(I)\u57fa\u7684\u6c27\u5316\u8fd8\u539f\u7535\u89e3\u8d28\u7684\u65b0\u578b\u7ed3\u6784\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\uff0c\u5728\u6807\u51c6\u7684AM1.5G, 100 mW cm-2<\/sup>\u5149\u7167\u4e0b\u83b7\u5f97\u4e8613.1%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\uff0c\u540c\u65f6\u57281000 lux \u5f3a\u5ea6\u4e0b\u7684\u73af\u5883\u5ba4\u5185\u5149\u7ebf\u7167\u5c04\u4e0b\u83b7\u5f97\u4e86\u521b\u7eaa\u5f55\u768432\uff05\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u4ee5\u201cDirect Contact of Selective Charge Extraction Layers Enables High-Efficiency Molecular Photovoltaics<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Joule<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1. <\/strong>\u65b0\u578b\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u7ed3\u6784\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u4f20\u7edf(\u5de6)\u548c\u65b0\u578b(\u53f3)\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u7684\u7ed3\u6784\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(B) \u00a0n\u578b\u4e8c\u6c27\u5316\u949b\u4e0ep\u578b\u534a\u5bfc\u4f53\u80fd\u5e26\u8fb9\u7f18\u7684II\u578b\u7ed3\u793a\u610f\u56fe\uff1b<\/p>\n

(C) \u00a0\u57fa\u4e8e\u673a\u68b0\u6324\u538b\u7684\u7535\u6781\u76f4\u63a5\u63a5\u89e6\u7684\u65b0\u578b\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u793a\u610f\u56fe\uff1b<\/p>\n

(D \u00a0\u6c27\u5316\u8fd8\u539f\u5bf9\u4ec5\u901a\u8fc7\u4ecb\u5b54TiO2<\/sub>\u8584\u819c\u6269\u6563\u7684\u65b0\u578b\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u3002<\/p>\n

\u56fe<\/strong>2. <\/strong>\u65b0\u578b\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u7684\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(A) TiO2<\/sub>, PEDOT\u548cAu\u7684\u80fd\u7ea7\u56fe\uff1b<\/p>\n

(B) \u654f\u5316\u5242\u548c\u7535\u89e3\u8d28\u7684\u5206\u5b50\u7ed3\u6784\uff1b<\/p>\n

(C) \u57fa\u4e8en\u578bTiO2<\/sub>\u4e0ep\u578bPEDOT\u63a5\u89e6\uff0cTiO2<\/sub>\u4e0eAu\u76f4\u63a5\u63a5\u89e6\uff0c\u548c\u5206\u5f00\u7684TiO2<\/sub>\u4e0ePEDOT\u7535\u6781\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u7684J-V<\/em>\u66f2\u7ebf\uff1b<\/p>\n

(D) \u7535\u6c60\u7684\u963b\u6297\u56fe\u8c31\uff1b<\/p>\n

(E) \u57fa\u4e8eY123\uff0c XY1b\/Y123\u654f\u5316\u5242\u7684\u7535\u6c60\u7684J-V<\/em>\u66f2\u7ebf\uff1b<\/p>\n

(F) \u57fa\u4e8eY123\uff0c XY1b\/Y123\u654f\u5316\u5242\u7684\u7535\u6c60\u7684IPCE\u548c\u79ef\u5206\u7535\u6d41\u3002<\/p>\n

\u56fe<\/strong>3. <\/strong>\u592a\u9633\u7535\u6c60\u5728\u4eba\u9020\u5ba4\u5185\u5149\u6e90\u4e0b\u7684\u9ad8\u6548\u80fd\u91cf\u8f6c\u6362<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u5149\u654f\u9762\u79ef\u4e3a2.80\u548c20.25 cm2<\/sup>\u7684\u592a\u9633\u7535\u6c60\u7167\u7247\uff1b<\/p>\n

(B) \u53d1\u5c04\u529f\u7387\u5bc6\u5ea6\u56fe\u8c31\u4e0e\u5438\u6536\u56fe\u8c31\u3002\u9ed1\u8272\u5b9e\u66f2\u7ebf\u662fOsram 930 \u6696\u767d\u8272\u8367\u5149\u706f\u7ba1\u7684\u53d1\u5c04\u529f\u7387\u5bc6\u5ea6\u56fe\u8c31\uff1b\u9ed1\u8272\u865a\u66f2\u7ebf\u662f\u6574\u5408\u529f\u7387\u5bc6\u5ea6\uff1b\u7ea2\u8272\u5b9e\u66f2\u7ebf\u662f\u4ecb\u5b54\u4e8c\u6c27\u5316\u949b, XY1b\/Y123\u4f5c\u4e3a\u5171\u654f\u5316\u5242\u8584\u819c\u7684\u7d2b\u5916\u53ef\u89c1\u5438\u6536\u56fe\uff1b<\/p>\n

(C) \u4e0d\u540c\u5f3a\u5ea6\u5ba4\u5185\u5149\u7167\u5c04\u4e0b\uff0c\u5149\u654f\u9762\u79ef\u4e3a2.80 cm2<\/sup>\u7684\u7535\u6c60\u7684I-V<\/em>\u66f2\u7ebf\uff1b<\/p>\n

(D) \u4e0d\u540c\u5f3a\u5ea6\u5ba4\u5185\u5149\u7167\u5c04\u4e0b\uff0c\u5149\u654f\u9762\u79ef\u4e3a20.25 cm2<\/sup>\u7684\u7535\u6c60\u7684I-V<\/em>\u66f2\u7ebf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u7814\u7a76\u4eba\u5458\u6210\u529f\u7814\u5236\u51fa\u4e86\u4e00\u79cd\u57fa\u4e8e\u7531n\u578b\u65e0\u673a\u534a\u5bfc\u4f53\u4ecb\u5b54TiO2<\/sub>\u548cp\u578b\u6709\u673a\u534a\u5bfc\u4f53PEDOT\u76f4\u63a5\u63a5\u89e6\u7684\u65b0\u578b\u7ed3\u6784\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u3002\u8be5\u65b0\u578b\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u5728\u5168\u592a\u9633\u5149\u7167\u4e0b\u83b7\u5f97\u4e8613.1%\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\uff0c\u5728\u4eba\u9020\u5ba4\u5185\u5149\u6e90\u7167\u5c04\u4e0b\u8fbe\u5230\u521b\u7eaa\u5f55\u768432\uff05\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002\u8be5\u7814\u7a76\u63d0\u51fa\u4e86\u4e00\u79cd\u65b0\u578b\u7ed3\u6784\u7684\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\uff0c\u907f\u514d\u4e86\u4f20\u7edf\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u56e0\u963b\u6321\u5c42\u7684\u5b58\u5728\u800c\u5bfc\u81f4\u7684\u6fc0\u5b50\u590d\u5408\uff0c\u6709\u6548\u63d0\u9ad8\u4e86\u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u7684\u5149\u7535\u8f6c\u6362\u6548\u7387\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong> Direct Contact of Selective Charge Extraction Layers Enables High-Efficiency Molecular Photovoltaics<\/a> (Joule, 2018, DOI: 10.1016\/j.joule.2018.03.017<\/a>)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u4eba\u7ec4xuwz\u7f16\u8f91\uff0c\u5f20\u6770\u5ba1\u6838\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>!<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u67d3\u6599\u654f\u5316\u592a\u9633\u80fd\u7535\u6c60\u56e0\u539f\u6750\u6599\u4e30\u5bcc\u3001\u5236\u9020\u6210\u672c\u4f4e\u548c\u5de5\u827a\u6280\u672f\u76f8\u5bf9\u7b80\u5355\u800c\u53d7\u5230\u6781\u5927\u5173\u6ce8\u30021991\u5e74\u7531\u6d1b\u6851\u8054\u90a6\u7406\u5de5\u5b66\u9662(EPFL)\u7684Michael Gr\u00e4tzel\u6559…<\/p>\n","protected":false},"author":230,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[2],"tags":[],"class_list":["post-137298","post","type-post","status-publish","format-standard","hentry","category-keji"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/137298"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/230"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=137298"}],"version-history":[{"count":7,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/137298\/revisions"}],"predecessor-version":[{"id":137567,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/137298\/revisions\/137567"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=137298"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=137298"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=137298"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}