{"id":137867,"date":"2018-05-13T14:00:52","date_gmt":"2018-05-13T06:00:52","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=137867"},"modified":"2018-05-13T17:05:01","modified_gmt":"2018-05-13T09:05:01","slug":"%e9%bb%84%e5%8a%b2%e6%9d%benat-commun-%ef%bc%9a%e9%92%99%e9%92%9b%e7%9f%bf%e5%a4%aa%e9%98%b3%e8%83%bd%e7%94%b5%e6%b1%a0%e5%95%86%e4%b8%9a%e5%8c%96%e8%bf%9b%e7%a8%8b%e7%9a%84%e5%b7%a8%e5%a4%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=137867","title":{"rendered":"\u9ec4\u52b2\u677eNat. Commun. \uff1a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5546\u4e1a\u5316\u8fdb\u7a0b\u7684\u5de8\u5927\u8fdb\u6b65\u2014\u2014\u91cf\u4ea7\u7684\u3001\u4f4e\u5ec9\u7684\u3001\u6548\u7387\u9ad8\u8fbe20%\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u81ea\u4ece2009\u5e74\u9996\u6b21\u62a5\u9053\u4ee5\u6765\u5df2\u7ecf\u53d6\u5f97\u4e86\u5de8\u5927\u8fdb\u5c55\u3002\u5927\u90e8\u5206\u6eb6\u6db2\u6cd5\u5236\u5907\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5df2\u8ba4\u8bc1\u7684\u6548\u7387\u8fbe\u523020%\u4ee5\u4e0a\u3002\u7136\u800c\u51e0\u4e4e\u6240\u6709\u9ad8\u6548\u7387\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u90fd\u662f\u7528\u65cb\u6d82\u6cd5\u5236\u5907\u7684\uff0c\u8fd9\u79cd\u5236\u5907\u65b9\u6cd5\u65e0\u6cd5\u6ee1\u8db3\u5de5\u4e1a\u5316\u7684\u9ad8\u541e\u5410\u91cf\u4e0e\u89c4\u6a21\u5316\u5236\u5907\u7684\u8981\u6c42\u3002\u7814\u7a76\u8005\u7814\u53d1\u4e86\u51e0\u79cd\u9002\u7528\u4e8e\u89c4\u6a21\u5316\u751f\u4ea7\u7684\u9499\u949b\u77ff\u8584\u819c\u5236\u5907\u65b9\u6cd5\uff0c\u5982\uff1a\u522e\u5200\u6d82\u5e03\u6cd5\u3001\u55b7\u96fe\u6c89\u79ef\u6cd5\u3001\u55b7\u58a8\u6253\u5370\u6cd5\u548c\u7535\u6c89\u79ef\u7b49\u3002\u5176\u4e2d\uff0c\u7531\u4e8e\u522e\u5200\u6d82\u5e03\u6cd5\u7684\u57fa\u5e95\u6e29\u5ea6\u53ef\u63a7\uff0c\u56e0\u6b64\u5728\u89c4\u6a21\u5316\u5236\u5907\u9ad8\u8d28\u91cf\u3001\u5927\u6676\u7c92\u9499\u949b\u77ff\u8584\u819c\u65b9\u6cd5\u4e2d\u8131\u9896\u800c\u51fa\u3002\u503c\u5f97\u6b23\u6170\u7684\u662f\u522e\u5200\u6d82\u5e03\u6cd5\u5236\u5907\u7684\u9499\u949b\u77ff\u592a\u9633\u7535\u6c60\u6548\u7387\u4ee5\u53ca\u9ad8\u8fbe19%\uff0c\u5df2\u7ecf\u5341\u5206\u63a5\u8fd1\u65cb\u6d82\u6cd5\u5236\u5907\u7684\u5668\u4ef6\u3002<\/p>\n

\u5546\u4e1a\u5316\u751f\u4ea7\u4e0d\u4ec5\u8981\u6ee1\u8db3\u4e0e\u89c4\u6a21\u5316\u751f\u4ea7\uff0c\u8fd8\u8981\u6ee1\u8db3\u5236\u9020\u6210\u672c\u4f4e\u3002\u4f46\u662f\u73b0\u5728\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u90fd\u9700\u8981\u6602\u8d35\u7684\u7a7a\u7a74\u4f20\u8f93\u5c42\u6765\u5b9e\u73b0\u9ad8\u6548\u7387\uff0c\u5982spiro-OMeTAD\u7b49\u3002\u6b64\u5916\uff0c\u758f\u6c34\u6027\u7684\u7a7a\u7a74\u4f20\u8f93\u5c42\u7684\u5b58\u5728\u5bfc\u81f4\u5c06\u9499\u949b\u77ff\u8584\u819c\u5f88\u96be\u522e\u6d82\u4e0a\u53bb\u3002\u56e0\u6b64\u8003\u8651\u5c06\u7a7a\u7a74\u4f20\u8f93\u5c42\u53bb\u6389\u4e0d\u4ec5\u6709\u5229\u4e8e\u964d\u4f4e\u6750\u6599\u6210\u672c\uff0c\u8fd8\u6709\u5229\u4e8e\u964d\u4f4e\u5236\u9020\u6210\u672c\uff0c\u8282\u7ea6\u65f6\u95f4\u3002<\/p>\n

\u7136\u800c\u5728\u53bb\u6389\u7a7a\u7a74\u4f20\u8f93\u5c42\u540e\uff0c\u9499\u949b\u77ff\u8584\u819c\u4e0eITO\u7684\u529f\u51fd\u6570\u4e0d\u5339\u914d\u5bfc\u81f4\u7a7a\u7a74\u5f88\u96be\u4ece\u9499\u949b\u77ff\u4f20\u8f93\u81f3ITO\u5c42\uff0c\u56e0\u6b64\u5bfc\u81f4\u5668\u4ef6\u6548\u7387\u4f4e\u4e0b\u3002\u5982\u4f55\u89e3\u51b3\u529f\u51fd\u6570\u5339\u914d\u95ee\u9898\u662f\u5236\u5907\u65e0\u7a7a\u7a74\u5c42\u9ad8\u6548\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u9762\u4e34\u7684\u5de8\u5927\u6311\u6218\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u5317\u5361\u7f57\u7eb3\u5927\u5b66\u548c\u5185\u5e03\u62c9\u65af\u52a0\u5927\u5b66\u6797\u80af\u5206\u6821\u7684\u9ec4\u52b2\u677e\u6559\u6388\u5728<\/strong>Nat. Commun.<\/strong>\u4e0a\u53d1\u8868\u4e86\u4e00\u7bc7\u9898\u4e3a\u201cMolecular doping enabled scalable blading of efficient hole-transport-layer-free perovskite solar cells<\/strong>\u201d\u7684\u6587\u7ae0\u3002\u8be5\u6587\u7ae0\u62a5\u9053\u4e86\u4e00\u79cd\u5206\u5b50\u63ba\u6742\u7b56\u7565\u6210\u529f\u7684\u89e3\u51b3\u4e86\u9499\u949b\u77ff\u4e0eITO\u7684\u80fd\u5e26\u4e0d\u5339\u914d\u95ee\u9898\uff0c\u5b9e\u73b0\u4e86\u6548\u7387\u9ad8\u8fbe20%\u7684\u65e0\u7a7a\u7a74\u4f20\u8f93\u5c42\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\uff0c\u6b64\u5916\u8be5\u7814\u7a76\u914d\u5408\u522e\u5200\u6d82\u5e03\u6cd5\u6210\u529f\u5b9e\u73b0\u4e86\u9ad8\u6548\u592a\u9633\u80fd\u7535\u6c60\u7684\u91cf\u4ea7\u5316\u3002<\/p>\n

\u3010\u56fe\u6587\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u56fe1<\/strong>\uff1a\u522e\u5200\u6d82\u5e03\u6cd5\u548c\u63ba\u6742F4TCNQ<\/strong>\u5206\u5b50\u7684\u9499\u949b\u77ff\u8584\u819c<\/strong><\/p>\n

\"\"<\/p>\n

(a). \u522e\u5200\u6d82\u5e03\u9499\u949b\u77ff\u8584\u819c\u793a\u610f\u56fe\u548cF4TCNQ\u63ba\u6742\u5242\u7684\u5316\u5b66\u7ed3\u6784\u5f0f\uff1b<\/p>\n

(b). \u57fa\u5e95\u4e3a150\u6444\u6c0f\u5ea6\uff0c\u522e\u6d82\u5728ITO\u4e0a\u7684\u9499\u949b\u77ff\u8584\u819c\u7684\u4fa7\u9762SEM\u56fe\uff1b<\/p>\n

(c-h).\u65e0\u63ba\u6742\u9499\u949b\u77ff\u8584\u819c\u7684AFM\u56fe(c)\u548c\u8868\u9762\u52bf\u5792\u56fe(f)\uff1bF4TCNQ\u63ba\u6742\u9499\u949b\u77ff\u8584\u819c\u7684AFM\u56fe(d)\u548c\u8868\u9762\u52bf\u5792\u56feg)\uff1b\u5c06F4TCNQ\u9897\u7c92\u6d12\u5728\u6742\u9499\u949b\u77ff\u8584\u819c\u7684AFM\u56fe(e)\u548c\u8868\u9762\u52bf\u5792\u56fe(h)\uff1b<\/p>\n

(i). \u4e0d\u540c\u9499\u949b\u77ff\u819c\u8868\u9762\u7535\u4f4d\u5206\u5e03\uff1b<\/p>\n

(j). MAPbI3<\/sub>:F4TCNQ\u5171\u6df7\u7269\u80fd\u91cf\u56fe\u548c\u7535\u5b50\u8f6c\u79fb\u8fc7\u7a0b\u793a\u610f\u56fe\u3002\u00a0<\/strong><\/p>\n

\u56fe2<\/strong>\uff1a\u7eaf\u9499\u949b\u77ff\u8584\u819c\u548c\u63ba\u6742\u9499\u949b\u77ff\u8584\u819c\u7684\u7535\u5bfc\u7387\u548c\u5149\u81f4\u53d1\u5149\u5bff\u547d<\/strong><\/p>\n

\"\"<\/p>\n

(a). \u9499\u949b\u77ff\u8584\u819c\u6a2a\u5411\u7535\u5bfc\u7387\u7684\u6d4b\u8bd5\u6a21\u578b\uff1b<\/p>\n

(b). \u63ba\u6742\u4e0e\u65e0\u63ba\u6742\u9499\u949b\u77ff\u8584\u819c\u7684I-V\u66f2\u7ebf\uff1b<\/p>\n

(c). \u65f6\u95f4\u5206\u8fa8\u5149\u81f4\u53d1\u5149\u66f2\u7ebf\uff1b<\/p>\n

(d). \u5bfc\u7535\u539f\u5b50\u529b\u663e\u5fae\u955c\u6d4b\u8bd5\u65b9\u6cd5\uff1b<\/p>\n

(e-h). \u65e0\u63ba\u6742\u7684\u9499\u949b\u77ff\u8584\u819c\u7684\u6676\u7c92\u5f62\u8c8cAFM\u56fe(e)\u548c\u5728\u6676\u7c92\u4e0a\u4e0e\u6676\u754c\u4e0a\u7684C-V\u56fe(f)\uff1b\u63ba\u6742\u7684\u9499\u949b\u77ff\u8584\u819c\u7684\u6676\u7c92\u5f62\u8c8cAFM\u56fe(g)\u548c\u5728\u6676\u7c92\u4e0a\u4e0e\u6676\u754c\u4e0a\u7684C-V\u56fe(h)\u3002<\/p>\n

\u56fe3<\/strong>\uff1a\u9499\u949b\u77ff\u8584\u819c\u5f62\u8c8c\uff0c\u5668\u4ef6\u7ed3\u6784\u4e0e\u5149\u4f0f\u6027\u80fd<\/strong><\/p>\n

\"\"<\/p>\n

(a-b).\u63ba\u6742\u9499\u949b\u77ff\u8584\u819c\u7684\u4f4e\u5206\u8fa8\u7387\u4e0e\u9ad8\u5206\u8fa8\u7387SEM\u56fe\uff1b<\/p>\n

(c). \u65e0\u7a7a\u7a74\u5c42\u9499\u949b\u77ff\u7535\u6c60\u5668\u4ef6\u7ed3\u6784\u56fe\uff1b<\/p>\n

(d). J-V\u66f2\u7ebf\uff1b<\/p>\n

(e). \u7a33\u6001\u7535\u6d41\u548c\u7a33\u6001PCE\u6d4b\u8bd5\uff1b<\/p>\n

(f). EQE\u548c\u79ef\u5206\u7535\u6d41\uff1b<\/p>\n

(g). \u5668\u4ef6\u6548\u7387\u7684\u7edf\u8ba1\u5206\u5e03\u56fe\u3002<\/p>\n

\u56fe4<\/strong>\uff1a\u754c\u9762\u7a7a\u7a74\u8f6c\u79fb\u673a\u7406<\/strong><\/p>\n

\"\"<\/p>\n

(a). \u7a7a\u7a74\u5728ITO\/MAPbI3<\/sub>\u754c\u9762\u8f6c\u79fb\u793a\u610f\u56fe\uff1b<\/p>\n

(b). \u7a7a\u7a74\u5728ITO\/F4TCNQ-MAPbI3<\/sub>\u754c\u9762\u8f6c\u79fb\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u00a0 \u8be5\u7814\u7a76\u9996\u5148\u5229\u7528\u522e\u5200\u6d82\u5e03\u6cd5\u514b\u670d\u4e86\u5927\u89c4\u6a21\u5236\u5907\u9ad8\u8d28\u91cf\u9499\u949b\u77ff\u8584\u819c\u96be\u9898\uff0c\u7136\u540e\u901a\u8fc7\u5206\u5b50\u63ba\u6742\u6cd5\u89e3\u51b3\u4e86\u9ad8\u6548\u7387\u65e0\u7a7a\u7a74\u4f20\u8f93\u5c42\u9499\u949b\u77ff\u7535\u6c60\u7684\u96be\u9898\u3002\u6700\u540e\u5668\u4ef6\u6548\u7387\u9ad8\u8fbe20%,\u5e76\u4e14\u51e0\u4e4e\u65e0\u8fdf\u6ede\u6548\u5e94\u3002\u8be5\u7814\u7a76\u4e3a\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5546\u4e1a\u5316\u5e26\u6765\u4e86\u66d9\u5149\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Molecular doping enabled scalable blading of efficient hole-transport-layer-free perovskite solar cells<\/a> (Nature Communications, 2018, DOI:10.1038\/s41467-018-04028-8)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u65b0\u80fd\u6e90\u5b66\u672f\u7ec4\u91d1\u4e5f\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u7f16\u8f91\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u4eba\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1<\/strong>cailiaokefu<\/strong>\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/strong><\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u81ea\u4ece2009\u5e74\u9996\u6b21\u62a5\u9053\u4ee5\u6765\u5df2\u7ecf\u53d6\u5f97\u4e86\u5de8\u5927\u8fdb\u5c55\u3002\u5927\u90e8\u5206\u6eb6\u6db2\u6cd5\u5236\u5907\u7684\u9499\u949b\u77ff\u592a\u9633\u80fd\u7535\u6c60\u5df2\u8ba4\u8bc1\u7684\u6548\u7387\u8fbe\u523020%\u4ee5\u4e0a\u3002\u7136\u800c\u51e0\u4e4e\u6240\u6709\u9ad8\u6548\u7387\u7684\u9499\u949b\u77ff…<\/p>\n","protected":false},"author":2114,"featured_media":137868,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3169,78,1029],"class_list":["post-137867","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-3169","tag-photovoltaic","tag-1029"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/137867"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/2114"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=137867"}],"version-history":[{"count":8,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/137867\/revisions"}],"predecessor-version":[{"id":138611,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/137867\/revisions\/138611"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/137868"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=137867"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=137867"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=137867"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}