{"id":138419,"date":"2018-05-15T14:00:25","date_gmt":"2018-05-15T06:00:25","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=138419"},"modified":"2018-05-15T16:35:21","modified_gmt":"2018-05-15T08:35:21","slug":"%e5%b7%b2%e6%a0%a1%e7%a8%bf%e5%a4%8d%e6%97%a6%e5%a4%a7%e5%ad%a6adv-energy-mater-%e5%b0%86%e6%b0%a2%e6%b0%a7%e5%8c%96%e9%95%8d%e8%bd%ac%e5%8c%96%e4%b8%ba%e4%b8%89%e7%bb%b4%e6%99%ae%e9%b2%81%e5%a3%ab","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=138419","title":{"rendered":"\u590d\u65e6\u5927\u5b66Adv Energy Mater: \u5c06\u6c22\u6c27\u5316\u954d\u8f6c\u5316\u4e3a\u4e09\u7ef4\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\u9635\u5217\u4ee5\u83b7\u5f97Ni2P\/Fe2P\u8fdb\u884c\u6c22\u9ad8\u6548\u6790\u51fa\u53cd\u5e94"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u968f\u7740\u79d1\u5b66\u7684\u4e0d\u65ad\u8fdb\u6b65\u548c\u53d1\u5c55\uff0c\u5bf9\u6e05\u6d01\u548c\u53ef\u56de\u6536\u71c3\u6599\u7684\u9700\u6c42\u4e0d\u65ad\u589e\u957f\uff0c\u6c22\u6c14\u5df2\u7136\u6210\u4e3a\u6700\u7406\u60f3\u7684\u80fd\u6e90\u8f7d\u4f53\u3002\u8fd1\u5e74\u6765\uff0c\u9488\u5bf9\u7535\u5316\u5b66\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u6765\u9ad8\u6548\u5236\u5907\u6c22\u6c14\u5df2\u7ecf\u53d6\u5f97\u4e86\u5f88\u5927\u7684\u8fdb\u6b65\u3002\u7136\u800c\uff0c\u7531\u4e8e\u8d35\u91d1\u5c5e\u94c2\u7684\u9ad8\u6210\u672c\u548c\u8d44\u6e90\u532e\u4e4f\u6027\uff0c\u5927\u591a\u6570\u94c2\u57fa\u50ac\u5316\u5242\u4e0d\u80fd\u5f97\u5230\u5e7f\u6cdb\u7684\u5b9e\u9645\u5e94\u7528\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u76ee\u524d\u8bb8\u591a\u7814\u7a76\u5df2\u7ecf\u8bc1\u660e\uff0c\u5404\u79cd\u91d1\u5c5e\u786b\u5316\u7269\u548c\u91d1\u5c5e\u78f7\u5316\u7269\u662f\u91d1\u5c5e\u94c2\u50ac\u5316\u5242\u7684\u7406\u60f3\u66ff\u4ee3\u54c1\u3002\u5177\u6709\u591a\u5b54\u548c\u6709\u5e8f\u7ed3\u6784\u7684\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08MOFs\uff09\u53ef\u4ee5\u7528\u4e8e\u5236\u5907\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\uff0c\u91d1\u5c5e\u786b\u5316\u7269\u548c\u91d1\u5c5e\u78f7\u5316\u7269\uff0c\u7528\u4f5c\u5206\u89e3\u6c34\u7684\u50ac\u5316\u5242\u3002\u8bb8\u591a\u7814\u7a76\u8868\u660e\u901a\u8fc7\u4f7f\u7528\u542b\u954d\u548c\u94b4\u7684\u666e\u9c81\u58eb\u84dd\u7c7b\u4f3c\u7269\uff08PBA\uff09\uff0c\u53ef\u4ee5\u5f97\u5230\u5177\u6709\u5f88\u597dHER\u6027\u80fd\u7684\u50ac\u5316\u5242\u3002\u5c3d\u7ba1\u5982\u6b64\uff0c\u57fa\u4e8e\u8be5\u7c7bMOF\u7684\u50ac\u5316\u5242\u7531\u4e8e\u70e7\u7ed3\u540e\u7ed3\u5757\u4e25\u91cd\uff0c\u5206\u6563\u6027\u8f83\u5dee\uff0c\u4e0e\u4e0d\u540c\u5e95\u7269\u4e0a\u751f\u957f\u7684\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u663e\u793a\u7684\u8868\u89c2\u6548\u7387\u662f\u4e0d\u5982\u540e\u8005\u7684\u3002\u901a\u5e38\uff0c\u76f4\u63a5\u751f\u957f\u5728\u57fa\u5e95\u4e0a\u7684\u50ac\u5316\u5242\u53ef\u4ee5\u8fbe\u5230\u8f83\u9ad8\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u5177\u6709\u8f83\u4f4e\u7684\u7535\u8377\u963b\u6297\u548c\u8f83\u5927\u7684\u6d3b\u6027\u9762\u79ef\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u00ad\u00ad\u00ad\u00ad\u8fd1\u65e5\uff0c\u590d\u65e6\u5927\u5b66\u7684\u53f6\u660e\u65b0\u6559\u6388\u548c\u6c88\u5251\u950b\u6559\u6388\u56e2\u961f<\/strong>\u901a\u8fc7\u5728\u5728\u949b\u7b94\u4e0a\u5236\u5907\u6c22\u6c27\u5316\u954d\u9635\u5217\uff0c\u5e76\u4e14\u7528K3<\/sub>[Fe(CN)6<\/sub>]\u5904\u7406\u6c22\u6c27\u5316\u954d(Nickel hydroxide)\u9635\u5217\u4ee5\u9996\u6b21\u83b7\u5f973D PBA(NHPBA)\u9635\u5217\u3002\u6c22\u6c27\u5316\u954d\u7684\u677f\u72b6\u5f62\u6001\u88ab\u5b8c\u7f8e\u5730\u4fdd\u7559\u4e0b\u6765\u5e76\u4e0ePBA\u7eb3\u7c73\u7acb\u65b9\u4f53\u7ed3\u5408\u3002\u7136\u540e\u5728350\u2103\u4e0b\u7528\u6b21\u78f7\u9178\u94a0\u5c06NHPBA\u78f7\u5316\uff0c\u5f97\u5230\u7684NHPBA\u78f7\u5316\u7269\uff08NHPBAP\uff09\u6837\u54c1\u5728\u9178\u6027\u548c\u78b1\u6027\u6eb6\u6db2\u4e2d\u90fd\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u6d3b\u6027\uff0c\u53ef\u4ee5\u8fbe\u523010mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\uff0c\u4ec5\u65bd\u52a070 (\u9178\u6027\u7535\u89e3\u6db2)\u548c121mV(\u78b1\u6027\u7535\u89e3\u6db2)\u7684\u8fc7\u7535\u4f4d\u3002\u8fc7\u7535\u4f4d\u4e3a266 mV\u65f6\uff0cNHPBA\u78f7\u5316\u7269\u53ef\u4ee5\u5728\u9178\u4e2d\u8fbe\u5230500 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u3002\u5728100 mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u4e0b\u8fdb\u884c20 h\u7684\u957f\u671f\u7a33\u5b9a\u6027\u8bd5\u9a8c\u540e\uff0c\u5728\u78b1\u6027\u6eb6\u6db2\u4e2d\u89c2\u5bdf\u5230\u22489mV\u7684\u5c0f\u91cf\u8fc7\u7535\u52bf\u589e\u91cf\u3002\u8be5\u6837\u54c1\u7684\u9ad8\u6548HER\u6d3b\u6027\uff0c\u4e3b\u8981\u5f52\u56e0\u4e8e\u591a\u7ea7\u7ed3\u6784\u4e0e\u4e30\u5bcc\u7684\u91d1\u5c5e\u4f4d\u70b9\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u201cTransforming Nickel Hydroxide into 3D Prussian Blue Analogue Array to Obtain Ni2P\/Fe2P for Efficient Hydrogen Evolution Reaction<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Energy Materials<\/strong>\u4e0a\u3002\u00ad\u00ad\u00ad\u00ad<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u00a0<\/strong>\u6c22\u6c27\u5316\u954d\u7684<\/strong>SEM<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u539f\u59cb\u6c22\u6c27\u5316\u954d<\/p>\n

\uff08b\uff0cg\uff09\u4e0e\u516d\u6c30\u5408\u94c1\u9178\u94be\u572890\u2103\u53cd\u5e94\u4e0b0.5\u5c0f\u65f6b\uff09\uff0c2\u5c0f\u65f6c\uff09\uff0c4\u5c0f\u65f6d\uff09\uff0c8\u5c0f\u65f6e\uff09\uff0c16\u5c0f\u65f6f\uff09\u548c24\u5c0f\u65f6g\uff09\u53cd\u5e94\u7684SEM\u56fe\u50cf<\/p>\n

\u56fe\u4e8c\u00a0<\/strong>\u6c22\u6c27\u5316\u954d\u7684\u7269\u76f8\u8868\u5f81\u4ee5\u53ca<\/strong>NHPBA <\/strong>\u5f62\u6210\u8fc7\u7a0b\u7684\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\uff08a\uff09\u539f\u59cb\u6c22\u6c27\u5316\u954d\u548c\u572890\u2103\u4e0b\u4e0e\u516d\u6c30\u5408\u94c1\u9178\u94be\u53cd\u5e94\u4e0d\u540c\u65f6\u95f4\u7684XRD\u56fe\u8c31<\/p>\n

\uff08b\uff09NHPBA \u5f62\u6210\u8fc7\u7a0b\u7684\u793a\u610f\u56fe<\/p>\n

\u56fe\u4e09\u00a0NHPBA\u7684\u50ac\u5316\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cd\uff090.5 m H 2 SO 4 a\uff09\u548c\u76f8\u5e94\u5854\u83f2\u5c14\u659c\u7387b\uff09\uff0c1 m KOH c\uff09LSV\u66f2\u7ebf\u548c\u76f8\u5e94Tafel\u659c\u7387d\uff09\u7684LSV\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u56db \u7535\u5316\u5b66\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09NHPBA\uff0cPBAP NP\uff0cNHPBAP\u548cNi5<\/sub>P4<\/sub>\u9635\u5217\u7684EIS<\/p>\n

\uff08b\uff09\u57280.5m H2<\/sub>SO4<\/sub>\u4e2d\u8ba1\u7b97\u7684Cdl<\/sub><\/p>\n

\uff08c\uff09NHPBA\u7684\u7535\u6d41\u5bc6\u5ea6\u4e3a100mA cm-2<\/sup>\u7684\u8ba1\u65f6\u7535\u4f4d\u6ef4\u5b9a\u66f2\u7ebf<\/p>\n

\uff08d\uff09NHPBA\u5728\uff08\u865a\u7ebf\uff09\u548c\u4e4b\u524d\uff08\u5b9e\u7ebf\uff09\u957f\u671f\u6d4b\u8bd5\u7684LSV\u66f2\u7ebf\u3002<\/p>\n

\u56fe\u4e94\u00a0<\/strong>DFT<\/strong>\u8ba1\u7b97<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff0cb\uff09Fe2P\u548cNi2P a\u7684\uff08100\uff09\u8868\u9762\u4ee5\u53ca\u4e0d\u540c\u4f4d\u7f6e\u4e0a\u6c22\u5438\u9644\u80fd\u7684DFT\u8ba1\u7b97<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u901a\u8fc7\u7b80\u5355\u7684\u65b9\u6cd5\uff0c\u7528\u6c22\u6c27\u5316\u954d\u524d\u4f53\u5236\u5907\u5177\u6709\u89c4\u5219\u805a\u96c6\u7ed3\u6784\u76843D MOFs\u3002\u7cfb\u7edf\u5730\u7814\u7a76\u4e0d\u540c\u7684\u53cd\u5e94\u65f6\u95f4\uff0c\u53cd\u5e94\u6e29\u5ea6\u548c\u4e0d\u540c\u7684\u6eb6\u6db2\u6d53\u5ea6\u3002\u6700\u540e\uff0c\u6d4b\u8bd5\u4e86NHPBAP\u4f18\u5f02\u7684HER\u6027\u80fd\uff0c\u57280.5m H2<\/sub> SO4<\/sub>\u4e2d\u5728266mV\u7684\u8fc7\u7535\u52bf\u4e0b\uff0c\u53ef\u4ee5\u8fbe\u5230500mA cm-2<\/sup>\u7684\u7535\u6d41\u5bc6\u5ea6\u3002\u5f53\u5c06\u5e38\u89c4\u7684\u6c22\u6c27\u5316\u954d\u4e0e\u591a\u5b54PBA\u4f5c\u4e3a\u524d\u4f53\u7ed3\u5408\u65f6\uff0c\u5176\u4f18\u5f02\u7684HER\u6027\u80fd\u53ef\u5f52\u56e0\u4e8e\u591a\u7ea7\u7ed3\u6784\u3002\u6b64\u5916\uff0c\u83b7\u5f97\u7684\u91d1\u5c5e\u78f7\u5316\u7269\uff0c\u5305\u62ec\u78b3\u5305\u88f9\u7684Fe2<\/sub>P\u548cNi2 <\/sub>P\uff0c\u53ef\u4ee5\u901a\u8fc7\u534f\u540c\u6548\u5e94\u63d0\u9ad8HER\u6d3b\u6027\u3002\u7531\u4e8e\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\u548cMOFs\u6750\u6599\u79cd\u7c7b\u7684\u591a\u6837\u6027\uff0c\u6211\u4eec\u7684\u5de5\u4f5c\u53ef\u4ee5\u8fdb\u4e00\u6b65\u62d3\u5bbd\uff0c\u4ee5\u6fc0\u53d1\u66f4\u591a\u7684\u7814\u7a76\u6765\u8f6c\u5316\u4e0d\u540c\u7684\u91d1\u5c5e\u6c22\u6c27\u5316\u7269\u548cMOFs\u3002\u6211\u4eec\u8ba4\u4e3a\u8fd9\u79cd\u5236\u5907\u5177\u6709\u590d\u6742\u7ec4\u5206\u548c\u72ec\u7279\u7ed3\u6784\u7684MOFs\u7684\u7b56\u7565\u5c06\u5728\u5404\u4e2a\u9886\u57df\u4e2d\u83b7\u5f97\u826f\u597d\u7684\u5e94\u7528\u524d\u666f\uff0c\u7279\u522b\u662f\u5728\u6c14\u4f53\u50a8\u5b58\uff0c\u7535\u5316\u5b66\u88c5\u7f6e\u548c\u78c1\u6027\u9886\u57df\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>\u201c<\/strong>Transforming Nickel Hydroxide into 3D Prussian Blue Analogue Array to Obtain Ni2P\/Fe2P for Efficient Hydrogen Evolution Reaction<\/strong><\/a>\u201d(Adv. Energy Mater. DOI: 10.1002\/aenm.201800484)<\/strong>\u00a0<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u5fae\u89c2\u4e16\u754c\u7f16\u8bd1\uff0c\u8bba\u6587\u901a\u8baf\u4f5c\u8005\u6c88\u5251\u950b\u6559\u6388\u4fee\u6b63\u4f9b\u7a3f\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/strong><\/a>\u3002\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u968f\u7740\u79d1\u5b66\u7684\u4e0d\u65ad\u8fdb\u6b65\u548c\u53d1\u5c55\uff0c\u5bf9\u6e05\u6d01\u548c\u53ef\u56de\u6536\u71c3\u6599\u7684\u9700\u6c42\u4e0d\u65ad\u589e\u957f\uff0c\u6c22\u6c14\u5df2\u7136\u6210\u4e3a\u6700\u7406\u60f3\u7684\u80fd\u6e90\u8f7d\u4f53\u3002\u8fd1\u5e74\u6765\uff0c\u9488\u5bf9\u7535\u5316\u5b66\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u6765\u9ad8\u6548\u5236\u5907\u6c22\u6c14\u5df2\u7ecf\u53d6\u5f97\u4e86…<\/p>\n","protected":false},"author":7084,"featured_media":139082,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[116],"class_list":["post-138419","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-catalyst"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/138419"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7084"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=138419"}],"version-history":[{"count":6,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/138419\/revisions"}],"predecessor-version":[{"id":139083,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/138419\/revisions\/139083"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/139082"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=138419"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=138419"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=138419"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}