{"id":139647,"date":"2018-05-24T14:00:05","date_gmt":"2018-05-24T06:00:05","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=139647"},"modified":"2018-05-23T14:12:35","modified_gmt":"2018-05-23T06:12:35","slug":"adv-mater-%ef%bc%9a%e7%a2%97%e7%83%af%e6%8e%ba%e6%9d%82%e7%9a%84aie%e7%ba%b3%e7%b1%b3%e7%82%b9%e5%8f%af%e9%ab%98%e5%ba%a6%e6%8a%91%e5%88%b6%e9%9d%9e%e8%be%90%e5%b0%84%e8%a1%b0%e5%87%8f%e4%bf%83","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=139647","title":{"rendered":"Adv. Mater.\uff1a\u7897\u70ef\u63ba\u6742\u7684AIE\u7eb3\u7c73\u70b9\u53ef\u9ad8\u5ea6\u6291\u5236\u975e\u8f90\u5c04\u8870\u51cf\u4fc3\u8fdb\u4f53\u5185\u764c\u75c7\u5149\u6cbb\u7597"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u764c\u75c7\u5149\u6cbb\u7597\u7684\u5149\u5b66\u8bd5\u5242\u591f\u5b9e\u73b0\u5b9e\u65f6\u5206\u5b50\u8bca\u65ad\u548c\u540c\u65f6\u5149\u6cbb\u7597\u3002\u5728\u591a\u79cd\u764c\u75c7\u5149\u6cbb\u7597\u836f\u7269\u4e2d\uff0c\u8367\u5149\u7eb3\u7c73\u7c92\u5b50\u5728\u6210\u50cf\u6280\u672f\u7684\u9ad8\u7075\u654f\u5ea6\u3001\u65f6\u95f4\u5206\u8fa8\u7387\u3001\u539f\u4f4d\u6807\u8bb0\u3001\u589e\u5f3a\u7684\u6e17\u900f\u6027\u4ee5\u53caEPR\u6548\u5e94\u4fdd\u6301\u7b49\u65b9\u9762\u5177\u6709\u663e\u8457\u4f18\u52bf\uff0c\u56e0\u800c\u8fd1\u5e74\u6765\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002\u4e3a\u4e86\u6ee1\u8db3\u764c\u75c7\u5149\u6cbb\u7597\u7684\u9700\u6c42\uff0c\u8367\u5149\u7eb3\u7c73\u7c92\u5b50\u8fd8\u5e94\u5177\u5907\u8db3\u591f\u9ad8\u7684\u8fd1\u7ea2\u5916\u53d1\u5c04\u548c\u6d3b\u6027\u6c27\u4ea7\u751f\u6548\u7387\u3001\u9ad8\u7a33\u5b9a\u6027\u3001\u53ef\u5ffd\u7565\u7684\u7ec6\u80de\u6bd2\u6027\u4ee5\u53ca\u5408\u9002\u7684\u7c92\u5b50\u5c3a\u5bf8\u548c\u8868\u9762\u5316\u5b66\u6027\u8d28\u7b49\u3002\u76ee\u524d\u6709\u673a\u8367\u5149\u56e2\u63ba\u6742\u7684\u7eb3\u7c73\u7c92\u5b50\u5bb9\u6613\u805a\u96c6\u4ea7\u751f\u8367\u5149\u6dec\u706d\u548c\u6d3b\u6027\u6c27\u4ea7\u751f\u6548\u7387\u7684\u964d\u4f4e\u3002\u56e0\u6b64\uff0c\u53d1\u5c55\u5177\u6709\u9ad8\u6548\u8367\u5149\u548c\u6d3b\u6027\u6c27\u4ea7\u751f\u6548\u7387\u7684\u8367\u5149\u7eb3\u7c73\u7c92\u5b50\u7528\u4e8e\u764c\u75c7\u5149\u6cbb\u7597\u662f\u8feb\u5207\u9700\u8981\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u9999\u6e2f\u79d1\u6280\u5927\u5b66\u5510\u672c\u5fe0\u9662\u58eb<\/strong>\u8bfe\u9898\u7ec4\u4e0e\u5357\u5f00\u5927\u5b66\u4e01\u4e39\u6559\u6388<\/strong>\u8bfe\u9898\u7ec4\uff0c\u56f4\u7ed5\u63a7\u5236\u548c\u4f18\u5316AIE\u7eb3\u7c73\u70b9\u7684\u8367\u5149\u548c\u6d3b\u6027\u6c27\u4ea7\u751f\u6548\u7387\uff0c\u5236\u5907\u4e86\u4e24\u79cdAIE\u590d\u5408\u7eb3\u7c73\u70b9\uff0c\u5176\u4e2d\u7897\u70ef\u7ed3\u5408\u7684AIE\u7eb3\u7c73\u70b9\u5177\u6709\u66f4\u597d\u7684\u8367\u5149\u91cf\u5b50\u4ea7\u7387\u548c\u6d3b\u6027\u6c27\u4ea7\u751f\u6548\u7387\uff0c\u6781\u5927\u5730\u63d0\u9ad8\u4e86\u764c\u75c7\u5149\u6cbb\u7597\u6548\u679c\u3002\u7814\u7a76\u8868\u660e\uff0c\u7897\u70ef\u4e0eAIE\u5206\u5b50\u4e4b\u95f4\u7684\u5f3a\u76f8\u4e92\u4f5c\u7528\u9650\u5236\u4e86AIE\u5206\u5b50\u7684\u5206\u5b50\u5185\u65cb\u8f6c\uff0c\u4ece\u800c\u6291\u5236\u975e\u8f90\u5c04\u8870\u51cf\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a”Corannulene-Incorporated AIE Nanodots with Highly Suppressed Nonradiative Decay for Boosted Cancer Phototheranostics In Vivo<\/strong>“\u53d1\u8868\u5728Advanced Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong>1 TPP-TPA<\/strong>\u5206\u5b50\u5408\u6210\u53ca\u8367\u5149\u6027\u8d28<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u8fd1\u7ea2\u5916\u53d1\u5c04TPP-TPA\u5206\u5b50\u7684\u5408\u6210\u8def\u7ebf\uff1b<\/p>\n

(B) DMSO-H2<\/sub>O\u6eb6\u5242\u4f53\u7cfb\u4e2d\u4e0d\u540cH2<\/sub>O\u542b\u91cf\u6761\u4ef6\u4e0bTPP-TPA\u5206\u5b50\u7684\u8367\u5149\u8c31\u56fe\uff1b<\/p>\n

(C) TPP-TPA\u5206\u5b50680\u7eb3\u7c73\u5904\u76f8\u5bf9\u8367\u5149\u5f3a\u5ea6\u4e0e\u6eb6\u5242\u4e2dH2<\/sub>O\u542b\u91cf\u7684\u5173\u7cfb\u66f2\u7ebf\u56fe\uff1b<\/p>\n

(D) \u57fa\u4e8e\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8bba\u8ba1\u7b97\u5f97\u5230\u7684TPP-TPA\u5206\u5b50\u57fa\u6001\u4e0bHOMO\u548cLUMO\u7684\u5206\u5b50\u8f68\u9053\u632f\u5e45\u56fe\u3002<\/p>\n

\u56fe2 Cor-AIE\u548cDSPE-AIE\u7eb3\u7c73\u70b9\u7684\u5149\u5b66\u6027\u8d28\u7814\u7a76<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u7eb3\u7c73\u6c89\u6dc0\u6cd5\u5236\u5907Cor-AIE\u548cDSPE-AIE\u7eb3\u7c73\u70b9\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

(B) Cor-AIE\u548cDSPE-AIE\u7eb3\u7c73\u70b9\u7684\u8367\u5149\u8c31\u56fe\uff1b<\/p>\n

(C) Cor-AIE\u548cDSPE-AIE\u7eb3\u7c73\u70b9\u7684\u8367\u5149\u5bff\u547d\u8c31\u56fe\uff1b<\/p>\n

(D) \u767d\u5149\u7167\u5c04\u6761\u4ef6\u4e0bCor-AIE\u548cDSPE-AIE\u7eb3\u7c73\u70b9\u7684\u5438\u6536\u5149\u8c31\uff1b<\/p>\n

(E) \u767d\u5149\u7167\u5c04\u6761\u4ef6\u4e0bCor-AIE\u548cDSPE-AIE\u7eb3\u7c73\u70b9\u5bf9ABDA\u7684\u964d\u89e3\u901f\u7387\uff1b<\/p>\n

(F) AIEgens\u5728DSPE-AIE \u7eb3\u7c73\u70b9\u6a21\u578b\u4e2d\u7684\u975e\u8f90\u5c04\u3001\u8f90\u5c04\u548c\u7cfb\u7edf\u95f4\u8de8\u8d8a\u8fc7\u7a0b\u7684Jablonski \u56fe\uff1b<\/p>\n

(G) AIEgens\u5728Cor-AIE \u7eb3\u7c73\u70b9\u6a21\u578b\u4e2d\u7684\u975e\u8f90\u5c04\u3001\u8f90\u5c04\u548c\u7cfb\u7edf\u95f4\u8de8\u8d8a\u8fc7\u7a0b\u7684Jablonski \u56fe\u3002<\/p>\n

\u56fe3 \u7897\u70ef\u6ef4\u52a0\u5230TPP-TPA\u6eb6\u6db2\u4e2d\u76841<\/sup>H \u6838\u78c1\u6ef4\u5b9a<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u7897\u70ef\u4e0eTPP-TPA\u5206\u5b50\u7ed3\u6784\uff1b<\/p>\n

(B) TPP-TPA\u4e0e\u7897\u70ef\u6ef4\u5b9a\u65f6TPP-TPA\u4e0aHa<\/sub>\u5316\u5b66\u4f4d\u79fb\u53d8\u5316\uff1b<\/p>\n

(C) TPP-TPA\u4e0e\u7897\u70ef\u6ef4\u5b9a\u65f6\u7897\u70ef\u4e0aHe<\/sub>\u5316\u5b66\u4f4d\u79fb\u53d8\u5316\uff1b<\/p>\n

(D) TPP-TPA\u4e0e\u7897\u70ef\u6ef4\u5b9a\u65f6TPP-TPA\u4e0aHb<\/sub>\u5316\u5b66\u4f4d\u79fb\u53d8\u5316\uff1b<\/p>\n

(E) TPP-TPA\u4e0e\u7897\u70ef\u6ef4\u5b9a\u65f6TPP-TPA\u4e0aHc<\/sub>\u548cHd<\/sub>\u5316\u5b66\u4f4d\u79fb\u53d8\u5316\u3002<\/p>\n

\u56fe<\/strong>4 <\/strong>\u8179\u819c\u764c\u75c7\u5c0f\u9f20\u9759\u8109\u6ce8\u5c04<\/strong>Cor-AIE<\/strong>\u7eb3\u7c73\u70b9<\/strong>24<\/strong>\u5c0f\u65f6\u540e\u624b\u672f<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u8179\u819c\u764c\u75c7\u5c0f\u9f20\u9759\u8109\u6ce8\u5c04Cor-AIE\u7eb3\u7c73\u70b924\u5c0f\u65f6\u540e\u8179\u8154\u5185\u80a0\u8868\u9762\u4e0a\u80bf\u7624\u7ed3\u8282\u7684\u660e\u573a\u3001\u8367\u5149\u3001\u751f\u7269\u53d1\u5149\u4ee5\u53caH&E \u67d3\u8272\u7167\u7247\uff1b<\/p>\n

(B) \u8179\u819c\u764c\u75c7\u5c0f\u9f20\u9759\u8109\u6ce8\u5c04Cor-AIE\u7eb3\u7c73\u70b924\u5c0f\u65f6\u540e\u8179\u819c\u8868\u9762\u4e0a\u80bf\u7624\u7ed3\u8282\u7684\u660e\u573a\u3001\u8367\u5149\u3001\u751f\u7269\u53d1\u5149\u4ee5\u53caH&E \u67d3\u8272\u7167\u7247\uff1b<\/p>\n

(C) \u624b\u672f\u5207\u9664\u524d\u80bf\u7624\u8367\u5149\u56fe\u50cf\uff1b<\/p>\n

(D) \u65e0Cor-AIE\u7eb3\u7c73\u70b9\u8367\u5149\u5f15\u5bfc\u624b\u672f\u7684\u80bf\u7624\u8367\u5149\u56fe\u50cf\uff1b<\/p>\n

(E) Cor-AIE\u7eb3\u7c73\u70b9\u8367\u5149\u5f15\u5bfc\u624b\u672f\u7684\u80bf\u7624\u8367\u5149\u56fe\u50cf\uff1b<\/p>\n

(F) \u8367\u5149\u6210\u50cf\u7cfb\u7edf\u548c\u751f\u7269\u53d1\u5149\u6210\u50cf\u7cfb\u7edf\u68c0\u9a8c\u6709\u65e0Cor-AIE\u7eb3\u7c73\u70b9\u8367\u5149\u5f15\u5bfc\u624b\u672f\u7684\u80bf\u7624\u7ed3\u8282\uff1b<\/p>\n

(G) \u6709\u65e0Cor-AIE\u7eb3\u7c73\u70b9\u8367\u5149\u5f15\u5bfc\u624b\u672f\u7684\u80bf\u7624\u7ed3\u8282\u7684\u76f4\u5f84\u76f4\u65b9\u56fe\u3002<\/p>\n

\u56fe5 Cor-AIE\u7eb3\u7c73\u70b9\u5728\u5149\u52a8\u529b\u80bf\u7624\u6cbb\u7597\u4e2d\u7684\u53ef\u884c\u6027<\/strong><\/p>\n

\"\"<\/p>\n

(A) \u8179\u819c\u764c\u75c5\u5c0f\u9f20\u5728\u751f\u7406\u76d0\u6c34\u3001\u201cDSPE-AIE dots + L\u201d\u548c\u201cCor-AIE dots + L\u201d\u5904\u7406\u6761\u4ef6\u4e0b\u7684\u65f6\u95f4\u4f9d\u8d56\u751f\u7269\u53d1\u5149\u6210\u50cf\uff1b<\/p>\n

(B) \u4e0d\u540c\u7ec4\u57280\u30011\u30013\u30015\u548c9\u5929\u65f6\u8179\u8154\u5185\u80bf\u7624\u7684\u5f3a\u5ea6\uff1b<\/p>\n

(C) \u4e0d\u540c\u5904\u7406\u540e\u7684\u5c0f\u9f20\u5b58\u6d3b\u7387\u66f2\u7ebf\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u9996\u6b21\u62a5\u9053\u4e86\u901a\u8fc7\u4f18\u5316\u8367\u5149\u7eb3\u7c73\u7c92\u5b50\u95f4\u7684\u9650\u57df\u5fae\u73af\u5883\u80fd\u591f\u5f00\u53d1\u51fa\u5177\u6709\u9ad8\u6548\u8367\u5149\u548c\u6d3b\u6027\u6c27\u4ea7\u751f\u6548\u7387\u7684AIE\u7eb3\u7c73\u70b9\u3002\u9650\u57df\u5fae\u73af\u5883\u8fdb\u4e00\u6b65\u9650\u5236\u4e86AIE\u5206\u5b50\u7684\u5206\u5b50\u5185\u65cb\u8f6c\uff0c\u4ece\u800c\u6291\u5236\u4e86\u975e\u8f90\u5c04\u8870\u51cf\u3002\u5728\u8179\u819c\u764c\u75c5\u7684\u5c0f\u9f20\u6a21\u578b\u5b9e\u9a8c\u4e2d\uff0c\u8fd9\u79cdAIE\u7eb3\u7c73\u70b9\u6781\u5927\u5730\u63d0\u9ad8\u4e86\u5149\u6cbb\u7597\u6548\u679c\u3002\u672c\u6587\u7814\u7a76\u7ed3\u679c\u5bf9\u5176\u4ed6\u8367\u5149\u7eb3\u7c73\u7c92\u5b50\u4f53\u7cfb\u63d0\u5347\u764c\u75c7\u5149\u6cbb\u7597\u6548\u679c\u5177\u6709\u501f\u9274\u610f\u4e49\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aCorannulene\u2010Incorporated AIE Nanodots with Highly Suppressed Nonradiative Decay for Boosted Cancer Phototheranostics In Vivo\u00a0<\/a>\u00a0(Adv. Mater. 2018, DOI: 10.1002\/adma.201801065)<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u9ad8\u5206\u5b50\u548c\u751f\u7269\u5b66\u672f\u7ec4Gaxy\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u5ba1\u6838\u6574\u7406\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u7ad9\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u53ca\u884c\u4e1a\u4ece\u4e1a\u5458\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

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