{"id":139931,"date":"2018-05-24T14:00:17","date_gmt":"2018-05-24T06:00:17","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=139931"},"modified":"2018-05-23T14:10:34","modified_gmt":"2018-05-23T06:10:34","slug":"%e5%91%a8%e5%ae%8f%e6%89%8djacs-%e7%89%b9%e5%88%b6%e7%9a%84%e5%90%a1%e5%94%91%e5%8d%9f%e5%95%89%e7%b1%bb%e9%87%91%e5%b1%9e%e6%9c%89%e6%9c%ba%e9%aa%a8%e6%9e%b6%e9%80%89%e6%8b%a9%e6%80%a7%e5%82%ac","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=139931","title":{"rendered":"\u5468\u5b8f\u624dJACS: \u7279\u5236\u7684\u5421\u5511\u535f\u5549\u7c7b\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\u9009\u62e9\u6027\u50ac\u5316"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

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\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u3001PCN-602\u7684\u5236\u5907\u548c\u6676\u4f53\u7ed3\u6784<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09 \u5c06Oh<\/sub>\u548cD4h<\/sub>\u8282\u70b9\u88c5\u914d\u5230ftw-a<\/em>\u62d3\u6251\u7f51\u7edc\u7ed3\u6784\u4e0a\uff1b<\/p>\n

\uff08b\uff09 \u91c7\u7528[Ni8<\/sub>]\uff08[Ni8<\/sub>(OH)4<\/sub>(H2<\/sub>O)2<\/sub>Pz12<\/sub>]\uff09\u96c6\u7fa4\u548cH4<\/sub>TPPP\u914d\u4f53\u7684PCN-602\u7684\u7f51\u72b6\u7ed3\u6784\u8bbe\u8ba1\uff1b<\/p>\n

\uff08c\uff09 TTFPPP\u548c\u918b\u9178\u954d\u5408\u6210PCN-602\uff1b<\/p>\n

\uff08d\uff09 PCN-602\u7684\u6676\u4f53\u7ed3\u6784\u91c7\u7528\u7a7a\u95f4\u586b\u5145\u89c6\u56fe\uff08Ni,\u9ec4\u8272\uff1bN,\u84dd\u8272\uff1bC,\u7070\u8272\uff1bO,\u7ea2\u8272\uff1bF,\u7eff\u8272\uff1bH,\u767d\u8272\uff09\u3002<\/p>\n

\u56fe\u4e8c\u3001TTFPPP\u7684\u5408\u6210\u8def\u7ebf<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\u00a0\u56fe\u4e09\u3001PCN-624\u7684\u7406\u5316\u8868\u5f81<\/strong><\/p>\n

\"\"<\/strong>
\n \uff08a\uff09 PCN-624\u7684PXRD\u5256\u9762\u56fe\uff1b<\/p>\n

\uff08b\uff09 PCN-602\u572877K\u65f6\u7684N-\u5438\u9644\u7b49\u6e29\u7ebf\u56fe\uff1b<\/p>\n

\uff08c\uff09 PCN-624\u7684\u5b54\u5f84\u5206\u5e03\u5256\u9762\uff1b<\/p>\n

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\uff08e\uff09 \u5728\u4e0d\u540c\u6eb6\u5242\u4e2d\u5904\u740624\u5c0f\u65f6\u540e\u7684PCN-624\u7684\u6b8b\u6e23\u91cd\u91cf\u767e\u5206\u6bd4\u56fe\uff1b<\/p>\n

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\u56fe\u56db\u3001PCN-624\u901a\u8fc7\u4e3b-\u5ba2\u4f53\u4f5c\u7528\u5c01\u88c5C60<\/sub>An2<\/sub>\u7684\u539f\u7406\u56fe<\/strong><\/p>\n

\"\"<\/strong><\/p>\n

\u00a0\u56fe\u4e94\u3001PCN-624\u7684\u50ac\u5316\u6027\u80fd\uff0c\u9009\u62e9\u6027\u50ac\u5316\u5bcc\u52d2\u70ef<\/strong>\u00a0<\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Tailor-Made Pyrazolide-Based Metal-Organic Frameworks for Selective Catalysis<\/a>\uff08JACS, 2018<\/strong>, DOI: 10.1021\/jacs.8b02710\uff09<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u751f\u7269\u6750\u6599\u7ec4\u5c0f\u80d6\u7eb8\u7f16\u8bd1\u3002<\/strong><\/p>\n

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