{"id":140234,"date":"2018-05-29T14:00:18","date_gmt":"2018-05-29T06:00:18","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=140234"},"modified":"2018-05-29T14:46:15","modified_gmt":"2018-05-29T06:46:15","slug":"%e4%b8%ad%e7%a7%91%e9%99%a2adv-mater-10%ef%bc%85%e6%95%88%e7%8e%87%ef%b9%91%e5%85%a8%e6%ba%b6%e6%b6%b2%e5%8a%a0%e5%b7%a5%e5%92%8c%e6%97%a0%e9%87%91%e5%b1%9e%e6%b0%a7%e5%8c%96%e7%89%a9%e7%9a%84","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=140234","title":{"rendered":"\u4e2d\u79d1\u9662Adv. Mater: >10\uff05\u6548\u7387\ufe51\u5168\u6eb6\u6db2\u52a0\u5de5\u548c\u65e0\u91d1\u5c5e\u6c27\u5316\u7269\u7684\u67d4\u6027\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7531\u4e8e\u9ad8\u67d4\u6027\uff0c\u91cd\u91cf\u8f7b\uff0c\u6210\u672c\u4f4e\u4ee5\u53ca\u53ef\u5370\u5237\u548c\u5377\u5bf9\u5377\u5f0f\u52a0\u5de5\u7684\u4f18\u52bf\uff0c\u6709\u673a\u592a\u9633\u80fd\u7535\u6c60\uff08OSC\uff09\u5df2\u7ecf\u5f15\u8d77\u4e86\u5de8\u5927\u7684\u5173\u6ce8\u3002\u5e38\u89c1\u7684\u67d4\u6027OSC\u662f\u4e00\u79cd\u7531\u67d4\u6027\u900f\u660e\u7535\u6781\uff08FTE\uff09\uff0c\u4f4e\u529f\u51fd\u91d1\u5c5e\u4fee\u9970\u7684\u9634\u6781\u548c\u6d3b\u6027\u5c42\u7ec4\u6210\u7684\u4e09\u660e\u6cbb\u7ed3\u6784\u3002\u8be5\u9886\u57df\u7684\u6700\u7ec8\u76ee\u6807\u662f\u901a\u8fc7\u5370\u5237\u548c\u5377\u5bf9\u5377\u7b49\u5de5\u827a\uff0c\u5236\u9020\u9ad8\u6548\u7387\u67d4\u6027\u548c\u4f4e\u6210\u672c\u7684\u5149\u4f0f\u7ec4\u4ef6\u3002\u5370\u5237\u7684\u67d4\u6027\u5668\u4ef6\u8981\u6c42\u5176\u7ec4\u6210\u6750\u6599\u53ef\u6db2\u4f53\u52a0\u5de5\uff0c\u4e14\u4e0e\u521a\u6027\u5668\u4ef6\u7684\u6548\u7387\u76f8\u5ab2\u7f8e\u3002\u56e0\u6b64\uff0c\u5e94\u8be5\u52aa\u529b\u63d0\u9ad8\u67d4\u6027\u5668\u4ef6\u7684\u6027\u80fd\uff0c\u5e76\u5347\u7ea7\u67d4\u6027OSC\u7684\u5236\u9020\u5de5\u827a\uff0c\u4ee5\u4fbf\u5b9e\u9645\u5e94\u7528\u3002\u4f4e\u6e29\u4e0b\u7684\u5168\u6eb6\u6db2\u5904\u7406\u65b9\u6848\u975e\u5e38\u9002\u5408\u5370\u5237\uff0c\u5377\u5bf9\u5377\u52a0\u5de5\u548c\u522e\u6d82\uff0c\u5e76\u4e14\u8fd8\u53ef\u4ee5\u964d\u4f4e\u5176\u6210\u672c\u3002\u5728OSC\u4e2d\uff0c\u6700\u5e38\u7528\u7684\u7535\u6781\u662f\u91d1\u5c5e\u63ba\u6742\u7684\u91d1\u5c5e\u6c27\u5316\u7269\uff08MMO\uff09\uff0c\u4f8b\u5982\u94df\u63ba\u6742\u7684\u6c27\u5316\u9521\uff08ITO\uff09\u3002\u7136\u800c\uff0cITO\u5728\u5851\u6599\u57fa\u677f\u4e0a\u9762\u4e34\u673a\u68b0\u8106\u6027\u548c\u5bfc\u7535\u6027\u95ee\u9898\u3002\u6b64\u5916\uff0c\u91d1\u5c5e\u6c27\u5316\u7269\u819c\u901a\u5e38\u5728\u9ad8\u6e29\u4e0b\u901a\u8fc7\u771f\u7a7a\u6e85\u5c04\u8fdb\u884c\u5904\u7406\uff0c\u8fd9\u4e9b\u95ee\u9898\u4f7f\u5f97MMO\u819c\u6210\u672c\u6602\u8d35\u4e14\u4e0e\u5370\u5237\u548c\u5377\u5bf9\u5377\u52a0\u5de5\u4e0d\u517c\u5bb9\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u79d1\u9662\u5b81\u6ce2\u6750\u6599\u6240\u65b0\u80fd\u6e90\u6280\u672f\u7814\u7a76\u6240\u845b\u5b50\u4e49\u7814\u7a76\u5458<\/strong>\u548c<\/strong>\u6a0a\u7ec6\u526f\u7814\u7a76\u5458\uff08\u5171\u540c\u901a\u8baf\u4f5c\u8005\uff09<\/strong>\u8054\u5408\u9999\u6e2f\u7406\u5de5\u5927\u5b66\u5f90\u5bbe\u521a\u6559\u6388\u548c\u4e25\u950b\u6559\u6388<\/strong>\u62a5\u9053\u4e86\u4e00\u79cd\u9ad8\u6548\u7684\u5168\u6eb6\u6db2\u52a0\u5de5\u7684\u65e0\u91d1\u5c5e\u6c27\u5316\u7269\u67d4\u6027OSC\uff0c\u5176\u4e2dPEDOT:PSS\/PET\u57fa\u6750\u5728\u5ba4\u6e29\uff08\u224820\u2103\uff09\u4e0b\u8fdb\u884c\u7532\u78fa\u9178\uff08CH4<\/sub>SO3<\/sub>\uff09\u5904\u7406\u3002\u8fd9\u79cd\u6e29\u548c\u9178\u5904\u7406\u8bf1\u5bfc\u51fa\u5149\u6ed1\u548c\u5747\u5300\u7684PEDOT:PSS\u8584\u819c\uff0c\u4e14\u5177\u6709\u9ad8\u5149\u5b66\u548c\u7535\u5b66\u7279\u6027\u3002\u4e0eH2<\/sub>SO4<\/sub>\u548cHNO3<\/sub>\u7684\u5904\u7406\u4e0d\u540c\uff0c\u5ba4\u6e29\u6e29\u548c\u7532\u78fa\u9178\u5904\u7406\u907f\u514d\u4e86\u7532\u78fa\u9178\u8150\u8680\u7834\u574f\u4e0b\u5c42\u7684\u5851\u6599\u57fa\u6750\uff0c\u56e0\u6b64\u5b83\u4e0e\u5851\u6599\u57fa\u6750\u76f8\u517c\u5bb9\u3002\u6b64\u5916\uff0c\u9664\u4e86\u5fc5\u987b\u70ed\u6c89\u79ef\u7684\u94dd\u9634\u6781\u4e4b\u5916\uff0c\u67d4\u6027OSC\u5668\u4ef6\u7684\u6240\u6709\u90e8\u4ef6\u90fd\u53ef\u4ee5\u5728\u4e0d\u8d85\u8fc7100\u2103\u7684\u6e29\u5ea6\u4e0b\u8fdb\u884c\u5168\u6eb6\u6db2\u52a0\u5de5\uff0c\u8fd9\u662f\u4e00\u79cd\u7b80\u6d01\u7684\u65b9\u6cd5\uff0c\u5e76\u4e0e\u5370\u5237\u548c\u5377\u5bf9\u5377\u52a0\u5de5\u517c\u5bb9\u3002\u5168\u6eb6\u6db2\u52a0\u5de5\u67d4\u6027\u5668\u4ef6\u7684V<\/em>OC<\/sub>\u4e3a0.93 V\uff0cJ<\/em>SC<\/sub>\u4e3a15.49 mA cm-2<\/sup>\uff0c\u586b\u5145\u56e0\u5b50\uff08FF\uff09\u4e3a70.27\uff05\uff0c\u5176\u6700\u9ad8\u80fd\u91cf\u8f6c\u6362\u6548\u7387\uff08PCE\uff09\u4e3a10.12\uff05\u3002\u7ecf\u8fc71000\u6b21\u5faa\u73af\u8fde\u7eed\u5f2f\u66f2\u8bd5\u9a8c\uff08\u5f2f\u66f2\u534a\u5f84r<\/em> = 5.6mm\uff09\u540e\uff0c\u67d4\u6027\u5668\u4ef6\u4fdd\u7559\u4e8694\uff05\u7684\u521d\u59cbPCE\u503c\u3002\u6b64\u5916\uff0c\u5f53\u5168\u6eb6\u6db2\u52a0\u5de5\u7684\u521a\u6027\u5668\u4ef6\uff08\u886c\u5e95\u4e3a\u73bb\u7483\u57fa\u677f\uff09\uff0c\u8868\u73b0\u4e86\u9ad8\u8fbe10.60\uff05\u7684\u6548\u7387\u3002\u76f8\u5173\u7814\u7a76\u6210\u679c\u201cAll<\/strong>\u2010<\/strong>Solution<\/strong>\u2010<\/strong>Processed Metal<\/strong>\u2010<\/strong>Oxide<\/strong>\u2010<\/strong>Free Flexible Organic Solar Cells with Over 10% Efficiency<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Advanced Materials<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe\u4e00\u00a0<\/strong>PEDOT:PSS<\/strong>\u7684\u5149\u7535\u6027\u80fd\u7684<\/strong>\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5ba4\u6e29\u9178\u5904\u7406\u6539\u6027PEDOT:PSS\u548cDMSO\u63ba\u6742PEDOT:PSS\u7684\u5bfc\u7535\u7387\u548c\u65b9\u5757\u7535\u963b<\/p>\n

\uff08b\uff09PET\uff08\u2248200\u03bcm\uff09\uff0cPEDOT:PSS\/PET\u548cITO (\u2248180 nm)\/PET\u7684\u900f\u5c04\u5149\u8c31<\/p>\n

\u56fe\u4e8c\u00a0<\/strong>PEDOT:PSS<\/strong>\u8584\u819c\u7684\u7269\u76f8\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u539f\u59cbPEDOT:PSS\u8584\u819c\u7684TEM\u56fe\u50cf<\/p>\n

\uff08b\uff09\u5ba4\u6e29\u6e29\u548c\u9178\u5904\u7406\u7684PEDOT:PSS\u8584\u819cTEM\u56fe\u50cf<\/p>\n

\uff08c\uff09\u539f\u59cb\u8584\u819c\u7684AFM\u56fe\u50cf<\/p>\n

\uff08d\uff09\u5ba4\u6e29\u6e29\u548c\u9178\u5904\u7406\u7684\u8584\u819cAFM\u56fe\u50cf<\/p>\n

\u56fe\u4e09\u00a0<\/strong>PEDOT:PSS<\/strong>\u8584\u819c\u7684\u6210\u5206\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u539f\u59cb\u819c\u548c\u5ba4\u6e29\u6e29\u548c\u9178\u5904\u7406\u7684PEDOT:PSS\u819c\u7684UPS\u8c31\u56fe<\/p>\n

\uff08b\uff09\u539f\u59cb\u8584\u819c\u7684S 2p XPS\u5149\u8c31<\/p>\n

\uff08c\uff09\u5ba4\u6e29\u6e29\u548c\u9178\u5904\u7406\u7684\u8584\u819c\u7684S 2p XPS\u5149\u8c31<\/p>\n

\uff08d\uff09\u4e24\u79cd\u8584\u819c\u7684XPS\u5168\u8c31<\/p>\n

\u56fe\u56db\u00a0<\/strong>\u67d4\u6027<\/strong>OSC<\/strong>\u7684\u7ed3\u6784\u548c\u6027\u80fd\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5168\u6eb6\u6db2\u52a0\u5de5\u7684\u67d4\u6027OSC\u7684\u7ed3\u6784\u793a\u610f\u56fe<\/p>\n

\uff08b\uff09\u7535\u6c60\u7684\u80fd\u7ea7\u793a\u610f\u56fe<\/p>\n

\uff08c\uff09\u57fa\u4e8eITO\u548cPEDOT:PSS\u7535\u6781\u7684\u521a\u6027\u7535\u6c60\u7684J-V<\/em>\u7279\u6027<\/p>\n

\uff08d\uff09\u5168\u6eb6\u6db2\u52a0\u5de5\u7684\u67d4\u6027\u5668\u4ef6\u7684J-V<\/em>\u7279\u6027<\/p>\n

\uff08e\uff09\u6bd4\u8f83\u67d4\u6027OSC\u7684PCE<\/p>\n

\uff08f\uff09\u8fde\u7eed\u5f2f\u66f2\u6d4b\u8bd5\u4e2d\u67d4\u6027\u5668\u4ef6\u7684\u5f52\u4e00\u5316\u7684PCE\u7684\u53d8\u5316<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u8be5\u65b9\u6cd5\u5168\u6eb6\u6db2\u52a0\u5de5\u7684\u67d4\u6027OSC\u662f\u5728\u5ba4\u6e29 CH4<\/sub>SO3<\/sub>\u5904\u7406\u7684PEDOT:PSS\/PET\u57fa\u5e95\u4e0a\u5236\u5907\u7684\u3002\u901a\u8fc7\u5ba4\u6e29\u548c\u7532\u78fa\u9178\u5904\u7406\uff0c\u4f7f\u5f97PEDOT:PSS\u8584\u819c\u8868\u73b0\u4e86\u826f\u597d\u7684\u5149\u5b66\u3001\u7535\u5b66\u7279\u6027\u548c\u5149\u6ed1\u7684\u8868\u9762\uff08RMS\uff1a2.14nm\uff09\uff0c\u53ef\u5f52\u56e0\u4e8e\u6e29\u548c\u9178\u5904\u7406\u53bb\u9664\u4e86\u90e8\u5206\u7edd\u7f18\u7269\u8d28PSS\u548c\u8bf1\u5bfc\u51fa\u66f4\u597d\u7684\u76f8\u5206\u79bb\u5f62\u8c8c\u3002\u6b64\u5916\uff0c\u6e29\u548c\u7684\u7532\u78fa\u9178\u5904\u7406\u907f\u514d\u4e86\u7834\u574f\u5851\u6599\u57fa\u677f\uff0c\u8fd9\u8981\u5f52\u56e0\u4e8e\u5ba4\u6e29\u4e0b\u6e29\u548c\u7532\u78fa\u9178\u7684\u5fae\u5f31\u7834\u574f\u7279\u6027\u3002\u5b9e\u9a8c\u53d1\u73b0\uff0c\u53cc\u5c42PEDOT:PSS \u7535\u6781\u548c\u53cc\u5c42PEDOT:PSS\uff084083\uff09\u754c\u9762\u5c42\u7684\u8bbe\u8ba1\u5bf9\u67d4\u6027\u5668\u4ef6\u975e\u5e38\u5173\u952e\uff0c\u56e0\u4e3a\u5b83\u6539\u5584\u4e86\u754c\u9762\u7684\u6da6\u6e7f\u6027\uff08\u03b8= 10.2\u00b0\uff09\uff0c\u63d0\u9ad8\u4e86\u7a7a\u7a74\u8fc1\u79fb\u7387\uff082.38\u00d710\u22124<\/sup>cm2<\/sup> V\u22121<\/sup> s\u22121<\/sup>\uff09\u4ee5\u53ca\u9ad8R<\/em>sq<\/sub>\uff08\u224840\u03a9sq-1<\/sup>\uff09\u3002\u6b64\u5916\uff0cPEDOT:PSS\u7535\u6781\u7684\u529f\u51fd\u6570\uff08-4.91 eV\uff09\u4e0ePEDOT:PSS\uff084083\uff09\u754c\u9762\u5c42\u7684\u529f\u51fd\u6570\uff08-5.05 eV\uff09\u76f8\u5339\u914d\uff0c\u6709\u5229\u4e8e\u7a7a\u7a74\u4f20\u8f93\u548c\u88ab\u6536\u96c6\uff0c\u63d0\u9ad8\u4e86\u592a\u9633\u80fd\u7535\u6c60\u7684V<\/em>OC<\/sub>\u3002\u56e0\u6b64\uff0c\u5168\u6eb6\u6db2\u52a0\u5de5\u7684\u67d4\u6027OSCs\u7684V<\/em>OC<\/sub>\u4e3a0.93 V\uff0cJ<\/em>SC<\/sub>\u4e3a15.49 mA cm\u2212<\/sup>2<\/sup>\uff0cFF\u4e3a70.27\uff05\uff0cPCE\u4e3a10.12\uff05\uff0c\u5e76\u4e14\u57281000\u6b21\u5faa\u73af\u5f2f\u6298\u4e2d\u4fdd\u6301\u6781\u9ad8\u7684\u6548\u7387\u503c\u3002\u5168\u6eb6\u6db2\u52a0\u5de5\u67d4\u6027\u7535\u6c60\uff08FTE\ufe51\u9633\u6781\/\u9634\u6781\u7f13\u51b2\u5c42\u4ee5\u53ca\u6d3b\u6027\u5c42\u5747\u4e3a\u6eb6\u6db2\u52a0\u5de5\uff09\u9002\u7528\u4e8e\u5370\u5237\ufe51\u5377\u5bf9\u5377\u548c\u522e\u6d82\u67d4\u6027\u5316OSCs\uff0c\u8fd9\u5c06\u63d0\u9ad8\u9ad8\u6548\u7387\u4f4e\u6210\u672c\u67d4\u6027OSC\u4ea7\u54c1\u7684\u5e02\u573a\u6e17\u900f\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a\u201c<\/strong>All<\/strong>\u2010<\/strong>Solution<\/strong>\u2010<\/strong>Processed Metal<\/strong>\u2010<\/strong>Oxide<\/strong>\u2010<\/strong>Free Flexible Organic Solar Cells with Over 10% Efficiency<\/strong><\/a>\u201d<\/strong>(<\/strong>Adv.mater.2018<\/strong> DOI: 10.1002\/adma.201800075<\/strong>)<\/strong><\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u7f16\u8f91\u90e8\u5b66\u672f\u7ec4\u5fae\u89c2\u4e16\u754c\u7f16\u8bd1\uff0c\u8bba\u6587\u901a\u8baf\u4f5c\u8005\u845b\u5b50\u4e49\u7814\u7a76\u5458\u3001\u6a0a\u7ec6\u526f\u7814\u7a76\u5458\u4fee\u6b63\u4f9b\u7a3f\u3002<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8<\/strong><\/a>\u3002<\/p>\n

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