{"id":140773,"date":"2018-06-01T14:00:00","date_gmt":"2018-06-01T06:00:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=140773"},"modified":"2018-05-29T19:41:58","modified_gmt":"2018-05-29T11:41:58","slug":"jacs%ef%bc%9a%e5%9f%ba%e4%ba%8e%e7%a6%bb%e6%95%a3%e9%87%91%e5%88%9a%e7%83%b7%e5%bd%a2ptii%e9%87%91%e5%b1%9e%e7%ac%bc%e6%9e%84%e7%ad%91%e7%9a%84%e9%92%bb%e7%9f%b3%e5%bd%a2%e8%b6%85%e5%88%86%e5%ad%90","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=140773","title":{"rendered":"JACS\uff1a\u57fa\u4e8e\u79bb\u6563\u91d1\u521a\u70f7\u5f62Pt(II)\u91d1\u5c5e\u7b3c\u6784\u7b51\u7684\u94bb\u77f3\u5f62\u8d85\u5206\u5b50\u914d\u4f4d\u6846\u67b6"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u8d85\u5206\u5b50\u914d\u4f4d\u56e0\u5176\u952e\u5408\u80fd\u529b\u5f3a\uff0c\u9ad8\u5ea6\u5b9a\u5411\u4ee5\u53ca\u52a8\u6001\u6027\u8d28\uff0c\u662f\u6784\u5efa\u5177\u6709\u5404\u79cd\u7ed3\u6784\u548c\u529f\u80fd\u8d85\u5206\u5b50\u914d\u4f4d\u5316\u5408\u7269\uff08Supramolecular Coordination Complexes, SCCs\uff09\u7684\u6709\u6548\u65b9\u6cd5\u3002\u7136\u800c\uff0c\u4e0e\u91d1\u5c5e\u6709\u673a\u6846\u67b6\uff08Metal-Organic Frameworks, MOFs\uff09\u7684\u65e0\u9650\u6846\u67b6\u7ed3\u6784\u76f8\u6bd4\uff0cSCCs\u5728\u8fc7\u53bb\u51e0\u5341\u591a\u5e74\u7684\u65f6\u95f4\u91cc\u4ec5\u7528\u4e8e\u6784\u5efa\u79bb\u6563\u7684\u8d85\u5206\u5b50\u7ec4\u88c5\u4f53\u3002\u56e0\u6b64\uff0c\u91c7\u7528\u914d\u4f4d\u76f8\u4e92\u4f5c\u7528\u3001\u53ef\u9006\u5171\u4ef7\u952e\u548c\u975e\u5171\u4ef7\u76f8\u4e92\u4f5c\u7528\u7b49\u65b9\u6cd5\uff0c\u6784\u5efa\u5404\u79cd\u7f51\u7edc\u578b\u7ed3\u6784\u7684\u591a\u5b54\u9aa8\u67b6\u6750\u6599\u662f\u975e\u5e38\u6709\u610f\u4e49\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u897f\u5317\u5927\u5b66\u5316\u5b66\u4e0e\u6750\u6599\u79d1\u5b66\u5b66\u9662<\/strong>\u7684\u66f9\u5229\u5e73\u6559\u6388<\/strong>\u548c\u7f8e\u56fd\u72b9\u4ed6\u5927\u5b66<\/strong>\u7684Peter J. Stang<\/strong>\u6559\u6388\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u4f5c\u8005\u7b49\u4eba\uff0c\u7ed3\u5408\u8d85\u5206\u5b50\u914d\u4f4d\u5316\u5408\u7269\uff08SCC\uff09\u548c\u91d1\u5c5e\u6709\u673a\u9aa8\u67b6\uff08MOF\uff09\u7684\u6982\u5ff5\uff0c\u5c06\u4e00\u79cd\u91d1\u521a\u70f7\u5f62\u914d\u4f4d\u7b3c\u5b50\u4f5c\u4e3a\u57fa\u672c\u5efa\u7b51\u5355\u5143\u5b9e\u73b0\u4e00\u79cd\u65b0\u578b\u94bb\u77f3\u5f62\u8d85\u5206\u5b50\u914d\u4f4d\u6846\u67b6\u7ed3\u6784\uff08Supramolecular Coordination Frameworks, SCFs\uff09\u3002\u91d1\u521a\u70f7\u8d85\u5206\u5b50\u914d\u4f4d\u7b3c\u5177\u6709\u56db\u4e2a\u672a\u914d\u4f4d\u7684\u5421\u5576\u57fa\uff0c\u5728\u94bb\u77f3\u5f62\u6846\u67b6\u4e2d\u4f5c\u4e3a\u56db\u9762\u4f53\u51e0\u4f55\u7684\u56db\u4e2a\u9876\u70b9\u3002\u56e0\u6b64\uff0c\u8fd9\u79cd\u7c7b\u91d1\u521a\u77f3SCF\u8868\u73b0\u51fa\u5177\u6709\u4e24\u7ec4\u5b54\u7684\u91d1\u521a\u70f7\u4e0e\u4e9a\u91d1\u521a\u70f7\u7c7b\u7ed3\u6784\uff0c\u5305\u62ec\u91d1\u521a\u70f7\u7c7b\u7b3c\u7684\u5185\u8154\u548c\u6846\u67b6\u4e2d\u5404\u4e2a\u7b3c\u4e4b\u95f4\u7684\u5ef6\u4f38\u7684\u91d1\u521a\u70f7\u7c7b\u7a7a\u95f4\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u5728DMSO\u4e2d\u52a0\u70ed\u84b8\u53d1\uff0c\u53ef\u89c2\u5bdf\u5230\u7eb3\u7c73\u5c3a\u5bf8\u7684\u94bb\u77f3\u5f62SCF\u7684\u5f62\u8c8c\u53ef\u63a7\u3001\u9ad8\u5ea6\u6392\u5217\u7684\u81ea\u7ec4\u88c5\u4e3a\u5fae\u7c73\u5c3a\u5bf8\u7684\u6b63\u516b\u9762\u4f53\u3002\u672c\u6587\u7814\u7a76\u8868\u660e\u8d85\u5206\u5b50\u914d\u4f4d\u5316\u5408\u7269\uff0c\u5728\u7cbe\u786e\u6784\u5efa\u9ad8\u5ea6\u8c03\u63a7\u7684\u591a\u5b54\u9aa8\u67b6\u6750\u6599\u4e2d\u7684\u5177\u6709\u5f88\u9ad8\u7684\u5e94\u7528\u6f5c\u529b\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728JACS<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 SCF-1<\/strong>\u7684\u6784\u5efa\u8fc7\u7a0b\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u91d1\u521a\u70f7\u9178\u8d85\u5206\u5b50\u914d\u4f4d\u7b3c3\uff0c\u94bb\u77f3\u5f62\u8d85\u5206\u5b50\u914d\u4f4d\u9aa8\u67b66\u548c\u5fae\u7c73\u516b\u9762\u4f53SCF-1\u7684\u6784\u5efa\u8fc7\u7a0b\u793a\u610f\u56fe\u3002<\/p>\n

\u56fe<\/strong> 2 <\/strong>\u4e0d\u540c\u7eb3\u7c73\u7b3c\u7684<\/strong>NMR<\/strong>\u8c31\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff091\uff0c2\uff0c3\uff0c4\u548c6\u7eb3\u7c73\u7b3c\u7684HNMR\u8c31\u56fe\uff1b<\/p>\n

\uff08b\uff091\uff0c2\uff0c3\u548c6\u7eb3\u7c73\u7b3c\u7684P{H}NMR\u8c31\u56fe\uff1b<\/p>\n

\uff08c\uff093[M-9OTf]9+<\/sup>\u7684ESI-TOF-MS\u5b9e\u9a8c\u548c\u8ba1\u7b97\u7ed3\u679c\u3002<\/p>\n

\u56fe<\/strong> 3 DMSO<\/strong>\u4e2d\uff0c<\/strong>3<\/strong>\u548c<\/strong>6<\/strong>\u53f7\u7eb3\u7c73\u7b3c\u7684<\/strong>DLS<\/strong>\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

DMSO\u4e2d\uff0c3\u548c6\u53f7\u7eb3\u7c73\u7b3c\u7684DLS\u56fe\u3002<\/p>\n

\u56fe<\/strong> 4 SCF-1<\/strong>\u7684\u5f62\u8c8c\u8868\u5f81\u548c\u5f62\u6210\u673a\u7406\u793a\u610f\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a-d\uff09SCF-1\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08e\uff09SCF-1\u7684\u5f62\u6210\u673a\u7406\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u7ed3\u5408\u79bb\u6563SCCs\u548c\u65e0\u9650MOFs\u7684\u4f18\u70b9\uff0c\u63d0\u4f9b\u4e86\u4e00\u79cd\u65b0\u7684\u7b56\u7565\uff0c\u9010\u6b65\u6784\u5efa\u65b0\u578b\u7684\u94bb\u77f3\u5f62\u8d85\u5206\u5b50\u6846\u67b6\uff08SCF\uff09\u3002SCF\u4e0eMOFs\u76f8\u6bd4\u5177\u6709MOFs\u548cSCCs\u7684\u57fa\u672c\u7279\u5f81\uff0c\u65e2\u53ef\u4ee5\u5177\u6709\u53ef\u9884\u6d4b\u7684\uff0c\u8bbe\u8ba1\u826f\u597d\u7684\u7ed3\u6784\uff0c\u4e5f\u53ef\u4ee5\u5177\u6709\u5f00\u653e\u7a7a\u95f4\u548c\u9ad8\u5ea6\u6709\u5e8f\u7684\u7ed3\u6784\u3002\u56e0\u6b64\uff0c\u8fd9\u9879\u5de5\u4f5c\u5c06\u5c06\u6846\u67b6\u7ed3\u6784\u548c\u8d85\u5206\u5b50\u914d\u4f4d\u5316\u5b66\u9886\u57df\u7d27\u5bc6\u5730\u8054\u7cfb\u5728\u4e00\u8d77\u3002\u91d1\u521a\u70f7\u8d85\u5206\u5b50\u914d\u4f4d\u7b3c\u4e3a\u7ed3\u70b9\u548c\u7ebf\u6027\u53cc\u5b98\u80fd\u56e2Pt\uff08II\uff09\u914d\u4f53\u4e3a\u57fa\u7840\u7684\u7c7b\u91d1\u521a\u5f62\u8d85\u5206\u5b50\u914d\u4f4d\u9aa8\u67b6\u7684\u9010\u6b65\u6784\u5efa\uff0c\u8fd9\u4e24\u4e2a\u8fde\u63a5\u5668\u90fd\u4fdd\u6301\u5177\u6709\u7279\u5b9a\u89d2\u5ea6\u548c\u5f62\u8c8c\u7684\u7279\u70b9\u3002\u6b64\u5916\uff0c\u8fd9\u4e9b\u81ea\u7ec4\u88c5\u7684\u7eb3\u7c73\u6b63\u516b\u9762\u4f53SCF\uff0c\u5177\u6709\u7ed3\u6784\u53ef\u63a7\u3001\u9ad8\u5ea6\u8c03\u8282\u7684\u7279\u70b9\u3002\u8fd9\u79cd\u65b9\u6cd5\u80fd\u591f\u8c03\u63a7\u5f62\u8c8c\u548c\u6709\u4ef7\u503c\u5c5e\u6027\uff08\u4f8b\u5982\u663e\u7740\u5b54\u9699\u7387\uff0c\u826f\u597d\u7ed3\u6784\uff0c\u4e3b\u5ba2\u4f53\u8bc6\u522b\uff0c\u5149\u5b66\u7ea4\u7ef4\u548c\u50ac\u5316\u6d3b\u6027\uff09\u7684\u65b0\u6846\u67b6\uff0c\u8fd9\u5bf9\u8bbe\u8ba1\u548c\u5236\u5907\u65b0\u529f\u80fd\u6750\u6599\u50a8\u80fd\uff0c\u6c14\u4f53\u5206\u79bb\uff0c\u836f\u7269\u8f93\u9001\uff0c\u4f20\u611f\uff0c\u591a\u76f8\u50ac\u5316\u7b49\u975e\u5e38\u6709\u7528\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Diamondoid supramolecular coordination frameworksfrom discrete adamantanoid platinum(II) cages<\/a>\uff08JACS, 2018, DOI: 10.1021\/jacs.8b03856\uff09\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a>\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<\/p>\n

\u6750\u6599\u725b\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u8d85\u5206\u5b50\u914d\u4f4d\u56e0\u5176\u952e\u5408\u80fd\u529b\u5f3a\uff0c\u9ad8\u5ea6\u5b9a\u5411\u4ee5\u53ca\u52a8\u6001\u6027\u8d28\uff0c\u662f\u6784\u5efa\u5177\u6709\u5404\u79cd\u7ed3\u6784\u548c\u529f\u80fd\u8d85\u5206\u5b50\u914d\u4f4d\u5316\u5408\u7269\uff08Supramolecular Coordination Co…<\/p>\n","protected":false},"author":7035,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3258,3259,3257],"class_list":["post-140773","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-3258","tag-3259","tag-3257"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/140773"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7035"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=140773"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/140773\/revisions"}],"predecessor-version":[{"id":140872,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/140773\/revisions\/140872"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=140773"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=140773"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=140773"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}