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\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

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\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8be5\u7814\u7a76\u5df2\u4e8e\u8fd1\u65e5\u53d1\u8868\u5728Advanced Materials<\/em>\u671f\u520a\u4e0a\uff0c\u201cAn Unprecedented Stimuli\u2010Controlled Single\u2010Crystal Reversible Phase Transition of a Metal\u2013Organic Framework and Its Application to a Novel Method of Guest Encapsulation\u201d \u4f5c\u8005\u4e3aDr. Jose Giner\u548c\u5176\u535a\u58eb\u7814\u7a76\u751f\u8c2d\u6609\u7545\uff0c\u8be5\u8bfe\u9898\u7ec4\u96b6\u5c5e\u4e8e\u5df4\u585e\u7f57\u90a3\u6750\u6599\u79d1\u5b66\u7814\u7a76\u6240\u7684\u65e0\u673a\u6750\u6599\u50ac\u5316\u5b9e\u9a8c\u5ba4\u3002\u4ed6\u4eec\u5c06\u5177\u6709\u67d4\u6027\u4e14\u5bcc\u542b\u787c\u5143\u7d20\u7684\u4e8c\u5341\u9762\u4f53\u7403\u5f62\u6709\u673a\u7269\u4f5c\u4e3a\u914d\u4f53\uff0c\u5408\u6210\u51fa\u8be5\u53ef\u8f6c\u53d8\u6750\u6599\u3002\u201c\u76f8\u5bf9\u4e8e\u4f20\u7edf\u7684\u4e8c\u7ef4\u7fa7\u9178\u914d\u4f53\uff0c\u8fd9\u79cd\u65b0\u578b\u4e09\u7ef4\u7403\u5f62\u914d\u4f53\u662f\u5b9e\u73b0\u7ed3\u6784\u8f6c\u53d8\u56de\u521d\u59cb\u7684\u72b6\u6001\u5173\u952e\uff0c\u5b83\u4f7f\u9aa8\u67b6\u5404\u90e8\u5206\u91cd\u7ec4\u7684\u540c\u65f6\u8fd8\u80fd\u4fdd\u6301\u7ed3\u6784\u7684\u7a33\u5b9a\u3002\u201d<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011
\n <\/strong>
\n \u56fe\u4e00\u6839\u636e\u5355\u6676\u884d\u5c04\u7ed8\u5236\u7684MOF\u6676\u4f53\u7ed3\u6784<\/p>\n

\"\"<\/a><\/p>\n

a \u6676\u4f53\u5177\u6709\u6cbf\u7740b\u8f74\u7684\u5b54\u9053\uff0c \u8be5\u5b54\u9053\u80fd\u5bb9\u7eb3\u4e0d\u540c\u7684\u6eb6\u5242\u5206\u5b50<\/p>\n

b \u914d\u4f53H3<\/sub>BTB\u7684\u5206\u5b50\u5f0f1,3,5-tris(4-carboxyphenyl)benzene<\/p>\n

c \u78b3\u787c\u70f7\u914d\u4f53\uff0c\u5176\u4e2dm<\/em>eta-carborane fragment, C2<\/sub>B10<\/sub>H10<\/sub> \u95f4\u4f4d\u78b3\u787c\u70f7\u7528\u6a59\u8272\u7684\u4e8c\u5341\u9762\u4f53\u8868\u793a\uff0c\u9ed1\u70b9\u4ee3\u8868\u78b3\u539f\u5b50\u3002<\/p>\n

\u56fe\u4e8c MOF 1 \u4e0eMOF 2\u53ef\u9006\u8f6c\u53d8\u7684\u53cd\u5e94\u6761\u4ef6\u53ca\u5176\u5bf9\u5bcc\u52d2\u70ef\u7684\u5305\u8986\uff0c\u5176\u4e2dMOF 1 \u548cMOF 2 \u7684\u7ed3\u6784\u6839\u636e\u5355\u6676\u884d\u5c04\u6570\u636e\u7ed8\u5236\uff0cMOF 1\u5305\u8986\u5bcc\u52d2\u70ef\u7ed3\u6784\u6839\u636eDFT\u7ed3\u679c\u4f18\u5316\u5f97\u5230\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

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\u6587\u732e\u94fe\u63a5\uff1a<\/strong>\u201cAn Unprecedented Stimuli\u2010Controlled Single\u2010Crystal Reversible Phase Transition of a Metal\u2013Organic Framework and Its Application to a Novel Method of Guest Encapsulation\u201d https:\/\/onlinelibrary.wiley.com\/doi\/abs\/10.1002\/adma.201800726<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com.<\/p>\n

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