{"id":142223,"date":"2018-06-14T14:00:04","date_gmt":"2018-06-14T06:00:04","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=142223"},"modified":"2018-06-12T09:15:26","modified_gmt":"2018-06-12T01:15:26","slug":"%e5%a4%aa%e5%b9%b3%e6%b4%8b%e8%a5%bf%e5%8c%97%e5%9b%bd%e5%ae%b6%e5%ae%9e%e9%aa%8c%e5%ae%a4nat-energy%ef%bc%9a%e4%bb%bf%e7%94%9f%e9%ab%98%e5%ae%b9%e9%87%8f%e5%90%a9%e5%97%aa%e5%9f%ba%e8%b4%9f%e6%9e%81","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=142223","title":{"rendered":"\u592a\u5e73\u6d0b\u897f\u5317\u56fd\u5bb6\u5b9e\u9a8c\u5ba4Nat. Energy\uff1a\u4eff\u751f\u9ad8\u5bb9\u91cf\u5429\u55ea\u57fa\u8d1f\u6781\u7535\u6781\u6db2\u7684\u6c34\u6027\u6709\u673a\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u6027\u80fd"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u6db2\u6d41\u7535\u6c60\u662f\u5229\u7528\u6b63\u8d1f\u6781\u7535\u89e3\u6db2\u5206\u5f00\uff0c\u5404\u81ea\u5faa\u73af\u7684\u4e00\u79cd\u9ad8\u6027\u80fd\u84c4\u7535\u6c60\uff0c\u5177\u6709\u5bb9\u91cf\u9ad8\u3001\u4f7f\u7528\u9886\u57df\u5e7f\u3001\u5faa\u73af\u4f7f\u7528\u5bff\u547d\u957f\u7684\u7279\u70b9\u3002\u5176\u4e2d\uff0c\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u662f\u4e00\u79cd\u6b63\u5728\u79ef\u6781\u7814\u5236\u5f00\u53d1\u7684\u65b0\u578b\u5927\u5bb9\u91cf\u7535\u5316\u5b66\u50a8\u80fd\u88c5\u7f6e\uff0c\u5176\u6d3b\u6027\u7269\u8d28\u662f\u6d41\u52a8\u7684\u7535\u89e3\u8d28\u6eb6\u6db2\u3002\u8fd1\u5e74\u6765\uff0c\u6c34\u6eb6\u6027\u6709\u673a\uff08ASO\uff09\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u6750\u6599\u5e38\u4f5c\u4e3a\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\uff08RFB\uff09\u4e2d\u4f20\u7edf\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u7684\u66ff\u4ee3\u54c1\u3002\u7136\u800c\uff0c\u6587\u732e\u4e2d\u5df2\u62a5\u9053ASO\u7684\u53ef\u9006\u5bb9\u91cf\uff0c\u901a\u5e38\u4f4e\u4e8e\u5176\u7406\u8bba\u503c\u3002\u672c\u6587\u627e\u5230\u4e86\u4e00\u79cd\u89e3\u51b3\u8fd9\u4e00\u95ee\u9898\u7684\u65b9\u6cd5\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u592a\u5e73\u6d0b\u897f\u5317\u56fd\u5bb6\u5b9e\u9a8c\u5ba4<\/strong>\u7684Xiaoliang Wei<\/strong>\u548cWei Wang<\/strong>\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u4f5c\u8005\u7b49\u4eba\uff0c\u83b7\u5f97\u4e86\u4e00\u79cd\u5429\u55ea\u7684ASO\u5316\u5408\u7269\uff0c\u5176\u53ef\u9006\u5bb9\u91cf\u6781\u9ad8\uff0c\u8d85\u8fc7\u5176\u7406\u8bba\u503c\u768490\uff05\u3002\u6587\u4e2d\u901a\u8fc7\u5bf9\u5429\u55ea\u5206\u5b50\u7ed3\u6784\u8fdb\u884c\u4fee\u6539\uff0c\u4f7f\u539f\u5429\u55ea\u7684\u6eb6\u89e3\u5ea6\u63d0\u9ad8\u52301.8 M\uff0c\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\u8d85\u8fc7400 mV\u3002\u90bb\u8fd1\u9971\u548c\u7684\u5429\u55ea\u884d\u751f\u7269\uff087,8-\u4e8c\u7f9f\u57fa\u5429\u55ea-2-\u78fa\u9178\uff09RFB\u7684\u64cd\u4f5c\u7535\u538b\u53ef\u8fbe1.4 V\uff0c\u53ef\u9006\u9633\u6781\u7535\u89e3\u6db2\u5bb9\u91cf\u4e3a67 Ah L-1<\/sup>\uff0c500\u5708\u4e2d\u7684\u6bcf\u5708\u7684\u5faa\u73af\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a99.98\uff05\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>A biomimetic high-capacity phenazine-based anolyte for aqueous organic redox flow batteries<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Nature Energy<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1\u00a0<\/strong>\u5429\u55ea\u884d\u751f\u7269\u7684\u5206\u5b50\u7ed3\u6784\u548c\u6027\u8d28\u9884\u6d4b\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5429\u55ea\u5206\u5b50\u7ed3\u6784\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5728ADF 2017\u5305\u88c5\u7684\u6742\u5408\u529f\u80fdB3LYP-D3\u548c\u589e\u5f3a\u578bTZ2P\u5168\u7535\u5b50\u57fa\u7840\u4e0a\uff0c\u5429\u55ea\u53ca\u5176\u884d\u751f\u7269\u7684\u80fd\u91cf\u548c\u52bf\u80fd\u56fe\u3002<\/p>\n

\u56fe<\/strong> 2 <\/strong>\u5429\u55ea\u548c\u6700\u9ad8\u8ba1\u7b97\u6eb6\u5242\u80fd\u6750\u6599\u7684\u5e93\u4ed1\u7535\u4f4d\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong> 3 <\/strong>\u4f4e\u6d53\u5ea6\u548c\u9ad8\u6d53\u5ea6<\/strong>DHPS<\/strong>\u7684<\/strong>NMR<\/strong>\u8c31\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728D2<\/sub>O\u548c1M NaOH\u4e2d\uff0c0.1 M\u548c1.4 M DHPS\u76841 H-NMR\u8c31\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5728D2<\/sub>O\u548c1M NaOH\u4e2d\uff0c0.1 M\u548c1.4 M DHPS\u7684Na-NMR\u8c31\u56fe\u3002<\/p>\n

\u56fe<\/strong> 4\u00a0<\/strong>\u5429\u55ea\u884d\u751f\u7269\u7684\u5faa\u73af\u4f0f\u5b89\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/strong> 5\u00a0<\/strong>\u4f4e\u6d53\u5ea6\u6db2\u6d41\u7535\u6c60\u6027\u80fd\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u572820~100 mA cm-2<\/sup>\u4e0b\uff0c\u57280.1M DHPS\u6eb6\u89e3\u4e8e10 mL 1M NaOH\u548c0.133 M K4<\/sub>Fe(CN)6<\/sub>\/0.067 M K3<\/sub>Fe(CN)6<\/sub>\u6eb6\u89e3\u572815 mL 1M NaOH\u7684\u7535\u6c60\u7684\u5bb9\u91cf\u548c\u6548\u7387\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5728100 mA cm-2<\/sup>\u4e0b\uff0c1.4 M DHPS\u7535\u6c60\u7684\u5faa\u73af\u5bb9\u91cf\u548c\u6548\u7387\u56fe\u3002<\/p>\n

\u56fe<\/strong> 6\u00a0<\/strong>\u9ad8\u6d53\u5ea6\u6db2\u6d41\u7535\u6c60\u6027\u80fd\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u572820~100 mA cm-2<\/sup>\u4e0b\uff0c\u75311.4 M DHPS\u6eb6\u89e3\u4e8e5 mL 1 M NaOH\u548c0.31 M K4<\/sub>Fe(CN)6<\/sub>\/0.31 M K3<\/sub>Fe(CN)6<\/sub>\u6eb6\u89e3\u4e8e45 mL 2 M NaOH\u7ec4\u6210\u7684\u7535\u6c60\u7684\u5bb9\u91cf\u548c\u6548\u7387\u56fe\uff1b<\/p>\n

\uff08b\uff09\u5728100 mA cm-2<\/sup>\u4e0b\uff0c1.4 M DHPS\u7535\u6c60\u7684\u5faa\u73af\u5bb9\u91cf\u548c\u6548\u7387\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u57fa\u4e8e\u5429\u55ea\u5206\u5b50\u8bbe\u8ba1\u7684\u9ad8\u53ef\u9006\u5bb9\u91cfASO RFB\u5177\u6709\u5353\u8d8a\u7684\u6027\u80fd\u3002\u5429\u55ea\u884d\u751f\u7269\u7684\u5408\u6210\u65b9\u6cd5\u4e3b\u8981\u4f9d\u8d56\u4e8e\u4f4e\u6210\u672c\u7684\u6750\u6599\u548c\u8bd5\u5242\uff0c\u56e0\u6b64\u78b1\u6027RFB\u662f\u6709\u524d\u666f\u7684\u548c\u6210\u672c\u6548\u76ca\u7684ASO\u9633\u6781\u7535\u89e3\u6db2\u3002\u5728DHPS\u4e2d\uff0c\u672c\u6587\u901a\u8fc7NMR\u548cDFT\u7814\u7a76\u5429\u55ea\u529f\u80fd\u5316\uff0c\u8c03\u8282\u9ad8\u6eb6\u89e3\u5ea6\u548c\u4f4e\u6c27\u5316\u8fd8\u539f\u7535\u4f4d\uff0c\u8c03\u6574\u5176\u6838\u5fc3\u7ed3\u6784\uff0c\u83b7\u5f97\u80fd\u91cf\u5bc6\u96c6\u7684ASO\u6750\u6599\u3002DHPS\u9633\u6781\u7535\u89e3\u6db2\u5177\u6709\u5f88\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\uff0c\u5728\u6700\u592790\uff05\u7684\u6eb6\u89e3\u5ea6\u4e0b\uff0c\u53ef\u9006\u9633\u6781\u7535\u89e3\u6db2\u5bb9\u91cf\u4e3a67 Ah L-1<\/sup>\uff1b\u64cd\u4f5c\u7535\u6d41\u5bc6\u5ea6\u9ad8\u8fbe100 mA cm-2<\/sup>\uff1b\u80fd\u91cf\u6548\u7387>75\uff05\uff1b\u5faa\u73af500\u6b21\u540e\uff0c\u5bb9\u91cf\u4fdd\u6301\u7387\u4e3a99.98\uff05\uff0c\u8fd9\u5df2\u7ecf\u8d85\u8fc7\u5df2\u62a5\u9053\u7684RFB\u7684ASO\u6d3b\u6027\u6750\u6599\u7684\u6027\u80fd\u3002\u4f46\u662f\uff0cASO\u9634\u6781\u7535\u89e3\u6db2\u6750\u6599\u7684\u66ff\u4ee3\u7269\u5f88\u5c11\uff0c\u800c\u5728\u9ad8pH\u503c\u7cfb\u7edf\u4e2d\u5219\u66f4\u5c11\u3002\u672c\u6587\u83b7\u5f97\u5206\u5b50\u7ed3\u6784\u529f\u80fd\u5316\u65b9\u6cd5\uff0c\u63d0\u51fa\u4e86\u4e00\u79cd\u52a0\u901f\u8bbe\u8ba1\u5177\u6709\u9ad8\u5bb9\u91cf\uff0c\u7a33\u5b9a\u6027\u548c\u6301\u7eed\u6027\u7684\u9633\u6781\u7535\u89e3\u6db2\u548c\u9633\u6781\u7535\u89e3\u6db2\u7684ASO\u5316\u5408\u7269\u7684\u65b9\u6cd5\uff0c\u8fd9\u4e3a\u672a\u6765RFB\u6280\u672f\u63d0\u4f9b\u6709\u524d\u666f\u7684\u6c27\u5316\u8fd8\u539f\u6d3b\u6027\u6750\u6599\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>A biomimetic high-capacity phenazine-based anolyte for aqueous organic redox flow batteries<\/a><\/strong>\uff08Nat. Energy, 2018, DOI: 10.1038\/s41560-018-0167-3\uff09<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com<\/a>\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\u3002<\/p>\n

\u6750\u6599\u725b\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u6db2\u6d41\u7535\u6c60\u662f\u5229\u7528\u6b63\u8d1f\u6781\u7535\u89e3\u6db2\u5206\u5f00\uff0c\u5404\u81ea\u5faa\u73af\u7684\u4e00\u79cd\u9ad8\u6027\u80fd\u84c4\u7535\u6c60\uff0c\u5177\u6709\u5bb9\u91cf\u9ad8\u3001\u4f7f\u7528\u9886\u57df\u5e7f\u3001\u5faa\u73af\u4f7f\u7528\u5bff\u547d\u957f\u7684\u7279\u70b9\u3002\u5176\u4e2d\uff0c\u6c27\u5316\u8fd8\u539f\u6db2\u6d41\u7535\u6c60\u662f\u4e00\u79cd\u6b63\u5728\u79ef\u6781\u7814\u5236\u5f00\u53d1…<\/p>\n","protected":false},"author":7035,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3309,2861],"class_list":["post-142223","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-3309","tag-2861"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/142223"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7035"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=142223"}],"version-history":[{"count":4,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/142223\/revisions"}],"predecessor-version":[{"id":142331,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/142223\/revisions\/142331"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=142223"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=142223"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=142223"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}