{"id":142622,"date":"2018-06-19T14:00:49","date_gmt":"2018-06-19T06:00:49","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=142622"},"modified":"2018-06-17T15:10:56","modified_gmt":"2018-06-17T07:10:56","slug":"%e5%8c%97%e4%ba%ac%e5%a4%a7%e5%ad%a6%e9%99%88%e5%b0%94%e5%bc%ba%e6%95%99%e6%8e%88macromolecules-%e5%9f%ba%e4%ba%8e%e5%a4%9a%e9%9d%a2%e4%bd%93%e4%bd%8e%e8%81%9a%e5%80%8d%e5%8d%8a%e7%a1%85%e6%b0%a7","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=142622","title":{"rendered":"\u5317\u4eac\u5927\u5b66\u9648\u5c14\u5f3a\u6559\u6388Macromolecules: \u57fa\u4e8e\u591a\u9762\u4f53\u4f4e\u805a\u500d\u534a\u7845\u6c27\u70f7\u4fa7\u94fe\u7684\u5747\u805a\u548c\u65e0\u89c4\u5171\u805a\u805a\u964d\u51b0\u7247\u70ef\u2014\u2014\u67d4\u6027\u94fe\u6548\u5e94\u548c\u7ec4\u4efd\u4f9d\u8d56"},"content":{"rendered":"

\u3010\u5f15\u8a00<\/b><\/strong>\u3011<\/p>\n

\u5411\u805a\u5408\u7269\u57fa\u4f53\u4e2d\u5f15\u5165\u65e0\u673a\u7ec4\u4efd\u662f\u7528\u6765\u5b9a\u5411\u6539\u8fdb\u805a\u5408\u7269\u6750\u6599\u6027\u8d28\u7684\u4e00\u79cd\u91cd\u8981\u7684\u65b9\u6cd5\u3002\u901a\u8fc7\u8c03\u8282\u805a\u5408\u7269\u57fa\u4f53\u548c\u65e0\u673a\u90e8\u5206\u7684\u4f5c\u7528\u529b\u548c\u5f62\u8c8c\uff0c\u53ef\u4ee5\u83b7\u5f97\u5177\u6709\u4f18\u5f02\u529b\u5b66\u3001\u5149\u5b66\u3001\u70ed\u3001\u7535\u78c1\u548c\u751f\u7269\u6027\u8d28\u7684\u590d\u5408\u6750\u6599\u3002\u5728\u8fc7\u53bb\u7684\u51e0\u5341\u5e74\u95f4\uff0c\u805a\u5408\u7269\u5728\u5206\u5b50\u6c34\u5e73\u7684\u65e0\u673a-\u6709\u673a\u6742\u5316\u5438\u5f15\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\u5174\u8da3\uff0c\u56e0\u800c\u8bb8\u591a\u5de5\u4f5c\u90fd\u96c6\u4e2d\u5728\u591a\u9762\u4f53\u4f4e\u805a\u500d\u534a\u7845\u6c27\u70f7\u65e0\u673a\u7eb3\u7c73\u7c92\u5b50\u4e0a\u3002\u591a\u9762\u4f53\u4f4e\u805a\u500d\u534a\u7845\u6c27\u70f7\u662f\u4e00\u7c7b\u7b3c\u72b6\u5206\u5b50\uff0c\u901a\u8fc7\u5316\u5b66\u5408\u6210\uff0c\u53ef\u5728\u7b3c\u5b50\u7684\u89d2\u843d\u5f15\u5165\u4e0d\u540c\u7684\u5b98\u80fd\u56e2\u3002\u56e0\u6b64\uff0c\u591a\u9762\u4f53\u4f4e\u805a\u500d\u534a\u7845\u6c27\u70f7\u53ef\u901a\u8fc7\u5316\u5b66\u53cd\u5e94\u5f15\u5165\u805a\u5408\u7269\u4fa7\u94fe\uff0c\u5f97\u5230\u57fa\u4e8e\u805a\u5408\u7269\u7684\u590d\u5408\u6750\u6599\u3002\u901a\u8fc7\u5f15\u5165\u591a\u9762\u4f53\u4f4e\u805a\u500d\u534a\u7845\u6c27\u70f7\uff0c\u53ef\u4ee5\u6539\u53d8\u5206\u5b50\u94fe\u7684\u8fd0\u52a8\u548c\u5206\u5b50\u5806\u79ef\uff0c\u56e0\u6b64\u8fbe\u5230\u6539\u53d8\u6750\u6599\u6027\u8d28\u7684\u76ee\u7684\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb<\/b><\/strong>\u3011<\/p>\n

\u8fd1\u65e5\uff0c\u5317\u4eac\u5927\u5b66<\/b><\/strong>\u7684\u9648\u5c14\u5f3a\u6559\u6388<\/b><\/strong>\u901a\u8fc7\u5f00\u73af\u805a\u5408\u5236\u5907\u4e86\u57fa\u4e8e\u591a\u9762\u4f53\u4f4e\u805a\u500d\u534a\u7845\u6c27\u70f7\u4fa7\u94fe\u7684\u5747\u805a\u548c\u65e0\u89c4\u5171\u805a\u805a\u964d\u51b0\u7247\u70ef\u3002\u5bf9\u4e8e\u5747\u805a\u7269P-z-POSS(z\u4ee3\u8868\u94fe\u957f)\uff0cPOSS\u57fa\u56e2\u901a\u8fc7\u4e0d\u540c\u94fe\u957f\u7684\u78b3\u94fe\u5f15\u5165\u805a\u964d\u51b0\u7247\u70ef\u9aa8\u67b6\uff1b\u5bf9\u4e8e\u65e0\u89c4\u5171\u805a\u7684\u805a\u964d\u51b0\u7247\u70ef\uff0cP-6-co17\u3002\u7ec4\u4efd\u7684\u8c03\u8282\u662f\u901a\u8fc7\u8c03\u8282\u4e01\u916f\u57fa\u53d6\u4ee3\u7684\u964d\u51b0\u7247\u70ef\u5355\u4f53\u548c\u542b\u6709\u591a\u9762\u4f53\u4f4e\u805a\u500d\u534a\u7845\u6c27\u70f7\u7684\u964d\u51b0\u7247\u70ef\u5355\u4f53\u7684\u6295\u6599\u6bd4\u5b9e\u73b0\u7684\u3002\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u7814\u7a76\u4e86\u4e0d\u540c\u78b3\u94fe\u957f\u5ea6\u5bf9\u591a\u9762\u4f53\u4f4e\u805a\u500d\u534a\u7845\u6c27\u70f7\u7684\u964d\u51b0\u7247\u70ef\u9f50\u805a\u7269\u7ed3\u6676\u5ea6\u7684\u5f71\u54cd\uff0c\u548c\u5747\u805a\u7269\u7269\u7406\u6027\u8d28\u7684\u7ec4\u4efd\u4f9d\u8d56\u3002\u8be5\u6210\u679c\u4ee5\u9898\u4e3a”Homopolymer and Random Copolymer of Polyhedral Oligomeric Silsesquioxane (POSS)-Based Side-Chain Polynorbornenes: Flexible Spacer Effect and Composition Dependence<\/b><\/strong>“\u53d1\u8868\u5728Macromolecules<\/b><\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>1<\/b><\/strong>.<\/b><\/strong>\u00a0<\/b><\/strong>M-6, M-17-POSS\u548cP-6-co-17\u7684\u6838\u78c1\u6c22\u8c31<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>2<\/b><\/strong>. <\/b><\/strong>P-z-POSS\u7684DSC\u56fe<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>3<\/b><\/strong>. <\/b><\/strong>P-z-POSS\u7684\u4e00\u7ef4XRD\u56fe<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>4<\/b><\/strong>. <\/b><\/strong>P-17-POSS\u7684\u4e8c\u7ef4XRD\u56fe<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>5<\/b><\/strong>. <\/b><\/strong>P-6-co-17\u7684DSC\u56fe<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

\u56fe<\/b><\/strong>6<\/b><\/strong>. <\/b><\/strong>P-6-co-17\u7684\u4e00\u7ef4XRD\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

(a).P-6-co-17\u5728\u5ba4\u6e29\u7684\u4e00\u7ef4XRD\u8868\u5f81<\/p>\n

(b).P-6-co-17\u5728\u5728\u4e0d\u540c\u6e29\u5ea6\u4e0b\u7684\u4e00\u7ef4XRD\u8868\u5f81<\/p>\n

\u56fe<\/b><\/strong>7<\/b><\/strong>. <\/b><\/strong>P-6-co-17\u7684\u7cfb\u5217\u8868\u5f81<\/b><\/strong><\/p>\n

\"\"<\/b><\/strong><\/p>\n

(a).P-6-co-17\u5728\u5ba4\u6e29\u7684\u5c0f\u89d2\u5149\u6563\u5c04<\/p>\n

(b).P-6-co-17\u7684TEM\u56fe<\/p>\n

(c).1\/Lposs-fposs\u56fe<\/p>\n

\u56fe<\/b><\/strong>8<\/b><\/strong>. <\/b><\/strong>P-6-co-17\u7684\u56fe\u793a<\/b><\/strong><\/p>\n

\"\"<\/p>\n

(a).POSS\u5806\u79ef\u548c\u5f62\u8c8c\u5206\u79bb<\/p>\n

(b).\u5355\u5411\u5ef6\u4f38\u540e\u7684\u5f62\u8c8c\u53d8\u5316<\/p>\n

\u56fe<\/b><\/strong>9<\/b><\/strong>. <\/b><\/strong>P-6-co-17\u7684\u6d41\u53d8\u6e29\u5ea6\u8303\u56f4\u66f2\u7ebf<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>10<\/b><\/strong>. <\/b><\/strong>P-6-co-17\u7684\u5ba4\u6e29\u538b\u529b-\u5e94\u53d8\u66f2\u7ebf<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u56fe<\/b><\/strong>11<\/b><\/strong>. <\/b><\/strong>P-6-co-17\u7684\u4e8c\u7ef4XRD\u548c\u5c0f\u89d2\u5149\u6563\u5c04\u56fe<\/b><\/strong><\/p>\n

\"\"<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/b><\/strong><\/p>\n

\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u901a\u8fc7\u5f00\u73af\u805a\u5408\u5236\u5907\u4e86\u57fa\u4e8e\u591a\u9762\u4f53\u4f4e\u805a\u500d\u534a\u7845\u6c27\u70f7\u4fa7\u94fe\u7684\u5747\u805a\u548c\u65e0\u89c4\u5171\u805a\u805a\u964d\u51b0\u7247\u70ef\u3002\u5bf9\u4e8e\u5747\u805a\u7269P-z-POSS(z\u4ee3\u8868\u94fe\u957f)\uff0cPOSS\u57fa\u56e2\u901a\u8fc7\u4e0d\u540c\u94fe\u957f\u7684\u78b3\u94fe\u5f15\u5165\u805a\u964d\u51b0\u7247\u70ef\u9aa8\u67b6\uff1b\u5bf9\u4e8e\u65e0\u89c4\u5171\u805a\u7684\u805a\u964d\u51b0\u7247\u70ef\uff0cP-6-co17\u3002\u7ec4\u4efd\u7684\u8c03\u8282\u662f\u901a\u8fc7\u8c03\u8282\u4e01\u916f\u57fa\u53d6\u4ee3\u7684\u964d\u51b0\u7247\u70ef\u5355\u4f53\u548c\u542b\u6709\u591a\u9762\u4f53\u4f4e\u805a\u500d\u534a\u7845\u6c27\u70f7\u7684\u964d\u51b0\u7247\u70ef\u5355\u4f53\u7684\u6295\u6599\u6bd4\u5b9e\u73b0\u7684\u3002\u5728\u8fd9\u4e2a\u5de5\u4f5c\u4e2d\uff0c\u4f5c\u8005\u7814\u7a76\u4e86\u4e0d\u540c\u78b3\u94fe\u957f\u5ea6\u5bf9\u591a\u9762\u4f53\u4f4e\u805a\u500d\u534a\u7845\u6c27\u70f7\u7684\u964d\u51b0\u7247\u70ef\u9f50\u805a\u7269\u7ed3\u6676\u5ea6\u7684\u5f71\u54cd\uff0c\u548c\u5747\u805a\u7269\u7269\u7406\u6027\u8d28\u7684\u7ec4\u4efd\u4f9d\u8d56\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1aHomopolymer and Random Copolymer of Polyhedral Oligomeric Silsesquioxane (POSS)-Based Side-Chain Polynorbornenes: Flexible Spacer Effect and Composition Dependence<\/a><\/strong>\u00a0(Macromolecules, 2018, DOI: 10. 1021\/acs.macromol.8b00302)<\/p>\n

\u672c\u6587\u7531\u6750\u6599\u4eba\u5b66\u672f\u7ec4gaxy\u4f9b\u7a3f\uff0c\u6750\u6599\u725b\u6574\u7406\u7f16\u8f91\u3002 \u00a0<\/p>\n

\u6750\u6599\u725b\u7f51\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u7f16\u8f91\u90e8\u5927\u5bb6\u5ead<\/a>\u3002 \u00a0<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1tougao@cailiaoren.com\u3002<\/p>\n

\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu\uff0c\u6211\u4eec\u4f1a\u9080\u8bf7\u5404\u4f4d\u8001\u5e08\u52a0\u5165\u4e13\u5bb6\u7fa4\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\u3001\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/b><\/strong>\u6d4b\u8bd5\u8c37<\/b><\/u><\/strong><\/a>\uff01<\/b><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u5411\u805a\u5408\u7269\u57fa\u4f53\u4e2d\u5f15\u5165\u65e0\u673a\u7ec4\u4efd\u662f\u7528\u6765\u5b9a\u5411\u6539\u8fdb\u805a\u5408\u7269\u6750\u6599\u6027\u8d28\u7684\u4e00\u79cd\u91cd\u8981\u7684\u65b9\u6cd5\u3002\u901a\u8fc7\u8c03\u8282\u805a\u5408\u7269\u57fa\u4f53\u548c\u65e0\u673a\u90e8\u5206\u7684\u4f5c\u7528\u529b\u548c\u5f62\u8c8c\uff0c\u53ef\u4ee5\u83b7\u5f97\u5177\u6709\u4f18\u5f02\u529b\u5b66\u3001\u5149\u5b66\u3001\u70ed\u3001\u7535…<\/p>\n","protected":false},"author":7336,"featured_media":142634,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[42],"class_list":["post-142622","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-jiedu","tag-gaofenzi"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/142622"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7336"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=142622"}],"version-history":[{"count":5,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/142622\/revisions"}],"predecessor-version":[{"id":142907,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/142622\/revisions\/142907"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/media\/142634"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=142622"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=142622"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=142622"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}