{"id":144517,"date":"2018-07-04T06:30:00","date_gmt":"2018-07-03T22:30:00","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=144517"},"modified":"2018-07-02T14:53:59","modified_gmt":"2018-07-02T06:53:59","slug":"%e5%a4%a9%e6%b4%a5%e5%a4%a7%e5%ad%a6%e5%b7%a9%e9%87%91%e9%be%99angew%ef%bc%9a%e8%b6%85%e8%96%84%e9%92%af%e7%ba%b3%e7%b1%b3%e7%89%87%e7%9a%84%e4%bd%8e%e9%85%8d%e4%bd%8d%e8%be%b9%e7%bc%98%e4%bd%8d","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=144517","title":{"rendered":"\u5929\u6d25\u5927\u5b66\u5de9\u91d1\u9f99Angew\uff1a\u8d85\u8584\u94af\u7eb3\u7c73\u7247\u7684\u4f4e\u914d\u4f4d\u8fb9\u7f18\u4f4d\u70b9\u6539\u5584CO2\u7535\u8fd8\u539f\u6027\u80fd"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u89e3\u51b3\u4e8c\u6c27\u5316\u78b3\uff08CO2<\/sub>\uff09\u6392\u653e\u95ee\u9898\u7684\u6709\u6548\u65b9\u6cd5\u4e4b\u4e00\u662f\u5c06CO2<\/sub>\u7535\u5316\u5b66\u8f6c\u5316\u4e3a\u589e\u503c\u4ea7\u54c1\u3002\u94af\uff08Pd\uff09\u51ed\u501f\u826f\u597d\u7684\u5bfc\u7535\u6027\u548c\u5bf9\u4e2d\u95f4\u4f53\u5408\u9002\u7684\u5438\u9644\u6027\uff0c\u6210\u4e3a\u7535\u8fd8\u539f\u4e8c\u6c27\u5316\u78b3\uff08CO2<\/sub>ER\uff09\u7684\u6709\u6548\u50ac\u5316\u5242\u3002\u7136\u800c\uff0cPd\u7eb3\u7c73\u50ac\u5316\u5242\u901a\u5e38\u9700\u8981\u8f83\u5927\u7684\u8fc7\u7535\u4f4d\u3002\u901a\u5e38\uff0c\u6539\u5584\u7eb3\u7c73\u7ed3\u6784\u80fd\u6709\u6548\u8c03\u8282\u4e2d\u95f4\u4ea7\u7269\u7684\u5438\u9644\u80fd\uff0c\u4ece\u800c\u63d0\u9ad8\u50ac\u5316\u5242\u6d3b\u6027\u3002\u7814\u7a76\u8868\u660e\u91d1\u5c5e\u50ac\u5316\u5242\u8fb9\u7f18\u4f4d\u70b9\u5bf9\u4e8e\u63d0\u5347\u50ac\u5316\u6548\u679c\u6709\u91cd\u8981\u4f5c\u7528\u3002\u56e0\u6b64\uff0c\u672c\u6587\u901a\u8fc7\u6784\u5efa\u5177\u6709\u4e30\u5bcc\u8fb9\u7f18\u4f4d\u70b9\u539f\u5b50\u7684Pd\u7eb3\u7c73\u7247\uff0c\u7edf\u8ba1\u4e0d\u540c\u4f4d\u70b9\u539f\u5b50\u7684\u666e\u904d\u5316\u5e73\u5747\u914d\u4f4d\u6570(GCN)\uff0c\u7814\u7a76\u4e86\u8fb9\u7f18\u4f4d\u70b9\u4e0a\u5177\u6709\u4e0d\u540cGCN\u7684\u539f\u5b50\u5bf9\u4e2d\u95f4\u4ea7\u7269\u5438\u9644\u80fd\u548c\u50ac\u5316\u6027\u80fd\u7684\u5f71\u54cd\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u5929\u6d25\u5927\u5b66\u5316\u5de5\u5b66\u9662<\/strong>\u7684\u5de9\u91d1\u9f99\u6559\u6388<\/strong>\uff08\u901a\u8baf\u4f5c\u8005\uff09\u7b49\u4eba\uff0c\u53d1\u73b0\u8d85\u8584\u94af\u7eb3\u7c73\u7247\u66b4\u9732\u5927\u91cf\u7684\u8fb9\u7f18\u4f4d\u70b9\u539f\u5b50\uff0c\u80fd\u591f\u6709\u6548\u51cf\u5c11CO\u4ea7\u751f\u7684\u8fc7\u7535\u52bf\u3002\u5728-0.5V\u4e0b\uff0c 5\u4e2a\u539f\u5b50\u539a\u5ea6\u548c5.1 nm\u8fb9\u7f18\u957f\u5ea6\u7684\u516d\u65b9\u5f62Pd\u7eb3\u7c73\u7247\u7684CO\u6cd5\u62c9\u7b2c\u6548\u7387\u8fbe\u523094\uff05\uff0c\u57288\u5c0f\u65f6\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u540e\uff0c\u6ca1\u6709\u4efb\u4f55\u8870\u51cf\u3002\u8fd9\u662f\u76ee\u524dPd\u50ac\u5316\u5242\u4e2d\uff0cCO\u6d3b\u6027\u6700\u597d\u7684\u50ac\u5316\u5242\u3002\u5747\u5300\u7684\u516d\u89d2\u5f62\u6001\u4fbf\u4e8e\u6a21\u578b\u6784\u5efa\u548c\u6e05\u6670\u5408\u7406\u7684DFT\u8ba1\u7b97\u3002\u5b9e\u9a8c\u548c\u7406\u8bba\u63a2\u7d22\u8868\u660e\uff0cPd\u7eb3\u7c73\u7247\u6d3b\u6027\u589e\u5f3a\u7684\u6765\u6e90\u662f\u8fb9\u7f18\u4f4d\u70b9\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Low-Coordinated Edge Sites on Ultrathin Palladium Nanosheets Boosting CO2<\/sub> Electroreduction Performance<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Angewandte Chemie-International Edition<\/strong>\u4e0a\u3002\u8be5\u8bba\u6587\u7b2c\u4e00\u4f5c\u8005\u4e3a2016\u7ea7\u7855\u58eb\u751f\u6731\u6587\u9526\u540c\u5b66\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 Pd<\/strong>\u7eb3\u7c73\u7247\u7684\u5f62\u6210\u793a\u610f\u56fe\u3001<\/strong>TEM<\/strong>\u56fe\u50cf\u53ca\u70ad\u9ed1\u4e0a\u7684\u8d1f\u8f7d\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

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\uff08b\uff095.1 nm\u539aPd\u7eb3\u7c73\u7247\u7684TEM\u56fe\u50cf\uff1b<\/p>\n

\uff08c\uff09\u6d3b\u6027\u70ad\u9ed1\u4e0a\u76845.1 nm\u539a\u7684Pd\u7eb3\u7c73\u7247\u8d1f\u8f7d\u56fe\u50cf\u3002<\/p>\n

\u56fe<\/strong> 2 Pd<\/strong>\u7eb3\u7c73\u7247\u7684\u50ac\u5316\u6027\u80fd\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u7ebf\u6027\u626b\u63cf\u4f0f\u5b89\u56fe\uff1b<\/p>\n

\uff08b\uff09CO\u7684\u6cd5\u62c9\u7b2c\u6548\u7387\u56fe\uff1b<\/p>\n

\uff08c\uff09\u4e0d\u540c\u8fb9\u7f18\u957f\u5ea6Pd\u7eb3\u7c73\u7247\u7684CO\u7535\u6d41\u5bc6\u5ea6\u56fe\uff1b<\/p>\n

\uff08d\uff09\u5728-0.5 V. vs RHE\u4e0b\uff0c5.1 nm Pd\u7eb3\u7c73\u7247\u7684\u7a33\u5b9a\u6027\u6d4b\u8bd5\u56fe\u3002<\/p>\n

\u56fe<\/strong> 3 <\/strong>\u5728<\/strong>Pd<\/strong>\u7eb3\u7c73\u7247\u4e0a\uff0c<\/strong>CO2<\/sub>ER<\/strong>\u7684\u53cd\u5e94\u793a\u610f\u56fe\u53ca\u5176\u81ea\u7531\u80fd\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u5728Pd\u7eb3\u7c73\u7247\u4e0a\uff0cCO2<\/sub>ER\u53cd\u5e94\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u4e0d\u540c\u4f4d\u7f6e\u4e0a\uff0cCO2<\/sub>ER\u53cd\u5e94\u7684\u81ea\u7531\u80fd\u56fe\uff1b<\/p>\n

\uff08c\uff09\u4e0d\u540c\u4f4d\u7f6e\u4e0a\uff0cHER\u53cd\u5e94\u7684\u81ea\u7531\u80fd\u56fe\u3002<\/p>\n

\u56fe<\/strong> 4 CO2<\/sub>ER<\/strong>\u7684\u53cd\u5e94\u8fc7\u7a0b\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09*CO\u8fc1\u79fb\u8fc7\u6e21\u6001\u7684\u6a21\u578b\u56fe\uff1b<\/p>\n

\uff08b\uff09-0.5 V\u7684CO\u6cd5\u62c9\u7b2c\u6548\u7387\u4e0e\u5e7f\u4e49\u914d\u4f4d\u6570\u7ea6\u4e3a5\u548c6.5\u7684\u539f\u5b50\u6bd4\u7387\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n

\uff08c\uff09Pd\u7eb3\u7c73\u7247\u7684Tafel\u659c\u7387\u56fe\uff1b<\/p>\n

\uff08d\uff09\u5728Pd\u7eb3\u7c73\u7247\u4e0a\uff0cCO2<\/sub>ER\u7684\u53cd\u5e94\u8def\u5f84\u793a\u610f\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u672c\u6587\u6210\u529f\u5408\u6210\u4e86\u4e0d\u540c\u8fb9\u957f\u7684\u8d85\u8584Pd\u7eb3\u7c73\u7247\uff0c\u7814\u7a76\u4e86\u57280.1 M KHCO3<\/sub>\u6eb6\u6db2\u4e2d\uff0c CO2<\/sub>\u8f6c\u5316\u4e3aCO\u7684\u6027\u80fd\u3002\u5728\u4f4e\u7684\u8fc7\u7535\u52bf\u4e0b\uff0c\u8fb9\u7f18\u957f\u5ea6\u6700\u5c0f\u7684Pd\u7eb3\u7c73\u7247\u53ef\u4ee5\u5b9e\u73b0\u9ad8\u7684CO\u6cd5\u62c9\u7b2c\u6548\u7387\u3002\u5728-0.9 V\u4e0b\uff0c5.1 nm\u7684Pd\u7eb3\u7c73\u7247\u4e0e\u76f8\u8fd1\u5c3a\u5bf8\u7684Pd\u7eb3\u7c73\u9897\u7c92\u76f8\u6bd4\uff0c\u5177\u6709\u8d85\u8fc75\u500d\u7684\u8d28\u91cf\u6d3b\u6027\uff0c\u4e3a140 A\/g\u3002\u7ecf\u8fc78\u5c0f\u65f6\u7684\u6d4b\u8bd5\u540e\uff0c\u5f62\u8c8c\u548c\u7535\u50ac\u5316\u6027\u80fd\u90fd\u4fdd\u6301\u7a33\u5b9a\u3002\u7531DFT\u8ba1\u7b97\u53ef\u77e5\uff0c\u6027\u80fd\u63d0\u9ad8\u7684\u4e3b\u8981\u539f\u56e0\u662f\u4e30\u5bcc\u7684\u8fb9\u7f18\u4f4d\u70b9\uff0c\u66b4\u9732\u66f4\u9ad8\u914d\u4f4d\u6570\u7ea6\u4e3a5\u7684\u539f\u5b50\uff0c\u4fc3\u8fdb*COOH\u5438\u9644\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Low-Coordinated Edge Sites on Ultrathin Palladium Nanosheets Boosting CO2<\/sub> Electroreduction Performance<\/strong><\/a>\uff08Angew. Chem. Int. Ed., 2018, DOI: 10.1002\/anie.201806432\uff09\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1<\/strong>tougao@cailiaoren.com<\/strong><\/a>\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/strong>\u3002<\/p>\n

\u6750\u6599\u725b\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/strong><\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

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