{"id":144874,"date":"2018-07-08T06:00:45","date_gmt":"2018-07-07T22:00:45","guid":{"rendered":"http:\/\/www.cailiaoniu.com\/?p=144874"},"modified":"2018-07-06T17:05:00","modified_gmt":"2018-07-06T09:05:00","slug":"energ-environ-sci-%ef%bc%9a%e5%90%b8%e9%99%84%e8%81%9a%e7%94%b5%e8%a7%a3%e8%b4%a8%e8%af%b1%e5%af%bc%e5%ae%9a%e5%90%91%e7%95%8c%e9%9d%a2%e7%94%b5%e8%8d%b7%e8%bd%ac%e7%a7%bb%e4%bf%83%e8%bf%9b%e6%97%a0","status":"publish","type":"post","link":"http:\/\/www.cailiaoniu.com\/?p=144874","title":{"rendered":"Energ. Environ. Sci.\uff1a\u5438\u9644\u805a\u7535\u89e3\u8d28\u8bf1\u5bfc\u5b9a\u5411\u754c\u9762\u7535\u8377\u8f6c\u79fb\u4fc3\u8fdb\u65e0\u91d1\u5c5e\u78b3\u7eb3\u7c73\u7ba1\u4e0a\u7684\u6c34\u6c27\u5316"},"content":{"rendered":"

\u3010\u5f15\u8a00\u3011<\/strong><\/p>\n

\u7535\u5316\u5b66\u6c34\u6c27\u5316\u53cd\u5e94\uff08WOR\uff09\u662f\u6c34\u5206\u89e3\u3001\u53ef\u518d\u751f\u71c3\u6599\u7535\u6c60\u548c\u53ef\u5145\u7535\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u7684\u6838\u5fc3\u7684\u80fd\u91cf\u8f6c\u6362\u8fc7\u7a0b\u3002\u7136\u800c\uff0cWOR\u52a8\u529b\u5b66\u8fdf\u7f13\uff0c\u9700\u8981\u5f88\u9ad8\u7684\u8fc7\u7535\u4f4d\u3002\u5e38\u7528IrO2<\/sub>\u6216RuO2<\/sub>\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u50ac\u5316\u6d3b\u6027\u9ad8\uff0c\u4f46\u662f\u8fd9\u4e9b\u8d35\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u6210\u672c\u8f83\u9ad8\u9650\u5236\u4e86\u5176\u5e7f\u6cdb\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u4e9f\u9700\u53d1\u5c55\u9ad8\u6548\u800c\u4f4e\u6210\u672c\u7684\u975e\u8d35\u91d1\u5c5eWOR\u50ac\u5316\u5242\u3002\u76ee\u524d\u78b3\u7eb3\u7c73\u6750\u6599\u6bd4\u5982\u78b3\u7eb3\u7c73\u7ba1\uff08CNTs\uff09\u662f\u4e00\u79cd\u975e\u5e38\u6709\u6f5c\u529b\u7684\u50ac\u5316\u6750\u6599\u3002\u4f46\u662f\u539f\u59cb\u7eb3\u7c73\u78b3\u6750\u6599\u7531\u4e8e\u5176\u50ac\u5316\u6d3b\u6027\u4f4d\u70b9\u5c11\uff0c\u5bfc\u81f4\u5176WOR\u50ac\u5316\u6027\u80fd\u5dee\u3002\u76ee\u524d\u8c03\u6574\u7eb3\u7c73\u78b3\u7684\u8868\u9762\u548c\u7535\u5b50\u7ed3\u6784\uff08\u5373\u7535\u8377\u5bc6\u5ea6\u6216\u81ea\u65cb\u5bc6\u5ea6\uff09\uff0c\u53ef\u4ee5\u8c03\u8282\u521d\u59cb\u53cd\u5e94\u7269\u548c\u53cd\u5e94\u4e2d\u95f4\u4f53\u7684\u5728\u50ac\u5316\u5242\u8868\u9762\u7684\u5438\u9644\uff0c\u88ab\u8ba4\u4e3a\u662f\u4e00\u79cd\u589e\u5f3a\u7eb3\u7c73\u78b3\u50ac\u5316\u6d3b\u6027\u7684\u6709\u6548\u7b56\u7565\u3002\u73b0\u5b58\u7684\u6700\u666e\u904d\u7684\u65b9\u6cd5\u662f\u5f15\u5165\u5f02\u8d28\u539f\u5b50\uff08\u6bd4\u5982N\u6216O\uff09\u5230\u7eb3\u7c73\u78b3\u4e2d\u8fdb\u884c\u5171\u4ef7\u63ba\u6742\u4ece\u800c\u8c03\u8282\u7eb3\u7c73\u78b3\u7684\u7535\u5b50\u7ed3\u6784\uff0c\u8fd9\u79cd\u7535\u8c03\u5236\u662f\u901a\u8fc7\u5206\u5b50\u5185\u7535\u8377\u8f6c\u79fb\u6765\u5b9e\u73b0\u7684\u3002\u7136\u800c\u8fd9\u7c7b\u65b9\u6cd5\u901a\u5e38\u7834\u574f\u539f\u59cb\u78b3\u7684\u6676\u683c\u7ed3\u6784\uff0c\u635f\u5bb3\u7535\u5b50\u4f20\u8f93\uff1b\u53e6\u5916\uff0c\u7531\u4e8e\u63ba\u6742\u539f\u5b50\u6d53\u5ea6\u7684\u9650\u5236\u548c\u63ba\u6742\u4f4d\u7f6e\u7684\u968f\u673a\u6027\uff0c\u5bfc\u81f4\u50ac\u5316\u6d3b\u6027\u7684\u589e\u5f3a\u5e76\u4e0d\u5c3d\u5982\u4eba\u610f\u3002\u7279\u522b\u662f\u5728\u76f8\u5bf9\u4f4e\u7684\u7535\u89e3\u8d28\u6d53\u5ea6\u4e0b\uff080.1 M KOH\uff09\uff0c\u7edd\u5927\u591a\u6570\u5f02\u8d28\u539f\u5b50\u63ba\u6742\u7684\u7eb3\u7c73\u78b3\u6750\u6599\u663e\u793a\u4e86\u8f83\u5dee\u7684WOR\u6027\u80fd\u3002\u672c\u6587\u9009\u53d6\u78b3\u7eb3\u7c73\u7ba1\uff08CNT\uff09\u4f5c\u4e3a\u6a21\u578b\u50ac\u5316\u5242\uff0c\u5229\u7528\u754c\u9762\u5206\u5b50\u95f4\u7535\u8377\u8f6c\u79fb\u7684\u6982\u5ff5\uff0c\u901a\u8fc7\u7b80\u5355\u7684\u805a\u7535\u89e3\u8d28\u5438\u9644\uff0c\u83b7\u5f97\u4e86\u9ad8\u6548\u7684\u65e0\u91d1\u5c5eWOR\u50ac\u5316\u5242\u3002\u8be5\u65b9\u6cd5\u5177\u6709\u666e\u9002\u6027\uff0c\u53ef\u9002\u7528\u4e8e\u5176\u4ed6\u7684\u78b3\u6750\u6599\u6765\u5236\u5907\u4e00\u7cfb\u5217\u9ad8\u6027\u80fdWOR\u50ac\u5316\u5242\uff0c\u66f4\u91cd\u8981\u7684\u662f\u63d0\u51fa\u7684\u65b9\u6cd5\u7b80\u4fbf\u3001\u73af\u4fdd\u3001\u53ef\u653e\u5927\u5236\u5907\u3002<\/p>\n

\u3010\u6210\u679c\u7b80\u4ecb\u3011<\/strong><\/p>\n

\u8fd1\u65e5\uff0c\u4e2d\u56fd\u4e2d\u5c71\u5927\u5b66<\/strong>\u7684\u4f59\u4e01\u5c71<\/strong>\u548c\u7f8e\u56fd\u51ef\u65af\u897f\u50a8\u5927\u5b66<\/strong>\u7684\u6234\u9ece\u660e\uff08\u5171\u540c\u901a\u8baf\uff09<\/strong>\u4f5c\u8005\u7b49\u4eba\uff0c\u9009\u53d6\u78b3\u7eb3\u7c73\u7ba1\uff08CNT\uff09\u4f5c\u4e3a\u6a21\u578b\u50ac\u5316\u5242\uff0c\u5229\u7528\u754c\u9762\u5206\u5b50\u95f4\u7535\u8377\u8f6c\u79fb\u7684\u6982\u5ff5\u6765\u8c03\u5236\u7eb3\u7c73\u78b3\u7684\u8868\u9762\u548c\u7535\u5b50\u7ed3\u6784\uff0c\u4ece\u800c\u6781\u5927\u589e\u5f3a\u78b3\u7eb3\u7c73\u7ba1\u7684WOR\u50ac\u5316\u6027\u80fd\u3002\u5c06\u5177\u6709\u5f3a\u5438\u7535\u5b50\u80fd\u529b\u7684\u805a\u4e8c\u70ef\u4e19\u57fa\u4e8c\u7532\u57fa\u6c2f\u5316\u94f5\uff08PDDA\u3001\u53d7\u4f53\uff09\u975e\u5171\u4ef7\u5438\u9644\u5230\u7eafCNT\uff08\u7ed9\u4f53\uff09\u4e0a\u5145\u5f53\u7f13\u51b2\u5c42\uff0c\u4e00\u65b9\u9762\u901a\u8fc7\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u4f7f\u53cd\u5e94\u7269\uff08OH–<\/sup>\uff09\u5bcc\u96c6\u5728\u8868\u9762\uff0c\u53e6\u4e00\u65b9\u9762\u901a\u8fc7\u5b9a\u5411\u5206\u5b50\u95f4\u7535\u8377\u8f6c\u79fb\u8bf1\u5bfc\u754c\u9762\u7535\u8377\u91cd\u65b0\u5206\u5e03\u3002\u8fd9\u4e0d\u4ec5\u6539\u5584\u4e86\u53cd\u5e94\u52a8\u529b\u5b66\uff0c\u800c\u4e14\u53ef\u4ee5\u5728\u78b3\u8868\u9762\u4ea7\u751f\u9ad8\u5bc6\u5ea6\u7684\u50ac\u5316\u4f4d\u70b9\uff0c\u6700\u7ec8\u5c06\u975e\u6d3b\u6027CNT\u8f6c\u5316\u4e3a\u6709\u6548\u7684\u65e0\u91d1\u5c5e\u6c34\u6c27\u5316\u50ac\u5316\u5242\u3002\u7814\u7a76\u7ed3\u679c\u663e\u793a\uff1a\u5373\u4f7f\u5728\u8f83\u4f4e\u7684\u7535\u89e3\u8d28\u6d53\u5ea6\uff080.1 M KOH\uff09\u60c5\u51b5\u4e0b\uff0c\u572810.0 mA cm-2<\/sup> WOR\u7535\u6d41\u5bc6\u5ea6\u4e0b\uff0cPDDA\u5438\u9644\u7684CNT\u50ac\u5316\u5242\u663e\u793a\u4e86\u4f4e\u7684\u8fc7\u7535\u4f4d\uff08370 mV\uff09\u548c\u5c0f\u7684\u5854\u83f2\u5c14\u659c\u7387\uff0876 mV dec-1<\/sup>\uff09\uff0c\u8be5\u50ac\u5316\u6027\u80fd\u5927\u5927\u4f18\u4e8e\u7eafCNT\uff08> 520 mV\uff0c166 mV dec-1<\/sup>\uff09\uff0c\u751a\u81f3\u4e0e\u5546\u4e1a\u7684\u8d35\u91d1\u5c5eRuO2<\/sub>\uff08360 mV\uff0c137 mV dec-1<\/sup>\uff09\u7684\u6027\u80fd\u76f8\u5ab2\u7f8e\u3002\u8be5\u65b9\u6cd5\u5177\u6709\u666e\u9002\u6027\uff0c\u53ef\u9002\u7528\u4e8e\u5176\u4ed6\u7684\u78b3\u6750\u6599\u4ece\u800c\u5236\u5907\u4e00\u7cfb\u5217\u9ad8\u6027\u80fd\u975e\u91d1\u5c5eWOR\u50ac\u5316\u5242\u3002\u76f8\u5173\u6210\u679c\u4ee5\u201c<\/strong>Boosting water oxidation on metal-free carbon nanotubes via directional interfacial charge-transfer induced by adsorbed polyelectrolyte<\/strong>\u201d\u4e3a\u9898\u53d1\u8868\u5728Energy & Environmental Science<\/strong>\u4e0a\u3002<\/p>\n

\u3010\u56fe\u6587\u5bfc\u8bfb\u3011<\/strong><\/p>\n

\u56fe<\/strong> 1 PDDA<\/strong>\u529f\u80fd\u5316<\/strong>CNTs<\/strong>\u590d\u5408\u819c\u5236\u5907\u548c\u7ed3\u6784\u8868\u5f81<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09PDDA\u529f\u80fd\u5316CNTs\u590d\u5408\u819c\uff0c\u5373\u67d4\u6027WOR\u50ac\u5316\u5242\u7684\u5f62\u6210\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u9762\u79ef\u4e3a12.56 cm2<\/sup>\u7684PDDA@CNTs93\u819c\u7684\u5b9e\u7269\u56fe\uff0c\uff1b<\/p>\n

\uff08c\uff09PDDA@CNTs93\u819c\u7684SEM\u56fe\u50cf\uff1b<\/p>\n

\uff08d\uff09\u7eafCNT\u7684TEM\u56fe\u50cf\uff08\u63d2\u56fe\uff1b\u6837\u54c1\u7684\u6c34\u63a5\u89e6\u89d2\uff09\uff1b<\/p>\n

\uff08e\uff09PDDA@CNTs93\u7684TEM\u56fe\u50cf\uff08\u63d2\u56fe\uff1b\u6837\u54c1\u7684\u6c34\u63a5\u89e6\u89d2\uff09\u3002<\/p>\n

\u56fe<\/strong> 2 PDDA@CNTs<\/strong>\u7684\u50ac\u5316\u6027\u80fd\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u57280.1 M KOH\u4e2d\uff0c\u7eafPDDA\u3001\u7eafCNT\u3001\u539f\u59cbCNT\u3001PDDA@CNTs95\u3001PDDA@CNTs93\u548cPDDA@CNTs90\u7684LSV\u66f2\u7ebf\uff0c\uff08b\uff09\u53ca\u5bf9\u5e94\u7684Tafel\u56fe\uff1b<\/p>\n

\uff08c\uff09PDDA@CNTs93\u7684RRDE\u6d4b\u8bd5\u68c0\u6d4b\u6c27\u6c14\u7684\u4ea7\u751f\uff08\u73af\u7535\u4f4d\uff1a0.4 V vs. RHE\uff09<\/p>\n

\uff08d\uff09PDDA@CNTs93\u7684RRDE\u66f2\u7ebf\uff08\u73af\u7535\u4f4d\uff1a1.5V vs. RHE\uff09\uff1b<\/p>\n

\uff08e\uff09PDDA@CNTs93\u5728\u6052\u538b\u4e0b\u7535\u6d41\u7a33\u5b9a\u6027\u6d4b\u8bd5\uff1b<\/p>\n

\uff08f\uff09PDDA@CNTs93\u548c\u7eafCNT\u7684\u7535\u5316\u5b66\u6d3b\u6027\u8868\u9762\u79ef\u5f52\u4e00\u5316\u7684\u6781\u5316\u66f2\u7ebf\u56fe\u3002<\/p>\n

\u56fe<\/strong> 3 <\/strong>\u7eaf<\/strong>CNT<\/strong>\u548c<\/strong>PDDA@CNTs93<\/strong>\u7684\u8868\u9762\u7535\u5b50\u7ed3\u6784\u5bf9\u6bd4\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09\u7eafPDDA\u548cPDDA@CNTs93\u7684\u9ad8\u5206\u8fa8\u7387XPS N 1s\u5149\u8c31\u56fe\uff1b<\/p>\n

\uff08b\uff09\u7eafCNT\u548cPDDA@CNTs93\u7684\u62c9\u66fc\u5149\u8c31\u56fe\uff1b<\/p>\n

\uff08c\uff09\u7eafCNT\u7684AFM\u5f62\u8c8c\u56fe\uff1b<\/p>\n

\uff08d\uff09\u7eafCNT\u7684AFM\u7684CPD\u56fe\uff1b<\/p>\n

\uff08e\uff09\u7eafCNT\u7684\u9ad8\u5ea6\u4e0eCPD\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08f\uff09PDDA@CNTs93\u7684AFM\u56fe\uff1b<\/p>\n

\uff08g\uff09PDDA@CNTs93\u7684CPD\u56fe\uff1b<\/p>\n

\uff08h\uff09PDDA@CNTs93\u7684\u9ad8\u5ea6\u4e0eCPD\u66f2\u7ebf\u56fe\u3002<\/p>\n

\u56fe<\/strong> 4 <\/strong>\u7eaf<\/strong>PEI<\/strong>\u3001\u7eaf<\/strong>CNT<\/strong>\u548c<\/strong>PEI@CNT<\/strong>\u7684\u50ac\u5316\u6027\u80fd\u56fe<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09PEI\u548cCNT\u4e4b\u95f4\u7535\u5b50\u76f8\u4e92\u4f5c\u7528\u7684\u793a\u610f\u56fe\uff1b<\/p>\n

\uff08b\uff09\u7eafPEI\u548cPEI@CNT\u7684\u9ad8\u5206\u8fa8\u7387XPS N 1s\u5149\u8c31\u56fe\uff1b<\/p>\n

\uff08c\uff09\u57280.1 M KOH\u4e2d\uff0c\u7eafPEI\u3001\u7eafCNT\u548cPEI@CNT\u7684WOR\u7684LSV\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08d\uff09\u57280.1 M KOH\u4e2d\uff0cPDDA@CNTs93\u3001PEI@CNTs\u548c\u7eafCNT\u7684\u7535\u5316\u5b66\u6d3b\u6027\u8868\u9762\u79ef\u5f52\u4e00\u5316\u7684\u6781\u5316\u66f2\u7ebf\u56fe\u3002<\/p>\n

\u56fe<\/strong> 5 PDDA@CNTs<\/strong>\u548c\u7eaf<\/strong>CNT<\/strong>\u7684\u50ac\u5316\u673a\u7406\u5206\u6790<\/strong><\/p>\n

\"\"<\/p>\n

\uff08a\uff09PDDA@CNTs93\u5728\u4e0d\u540cpH\u503c\u4e0b(12.5, 13, 13.5\u548c14)\u7684LSV\u6781\u5316\u66f2\u7ebf\u56fe\uff1b<\/p>\n

\uff08b\uff09log j<\/em>\u4e0ePDDA@CNTs93\u7684\u65bd\u52a0\u7535\u4f4d\u548cC[OH-]<\/sub>\u7684\u51fd\u6570\u5173\u7cfb\u56fe\uff1b<\/p>\n

\uff08c\uff09PDDA@CNTs93\u7684\u8fc7\u7535\u4f4d\u548cTafel\u659c\u7387\u4e0epH\u503c (12.5, 13, 13.5\u548c14)\u7684\u5173\u7cfb\u56fe\uff1b<\/p>\n

\uff08d\uff09\u57280.1 M KOH\u548c1 M KOH\u6eb6\u6db2\u4e2d\uff0cPDDA@CNTs93\u548c\u65e0\u91d1\u5c5eWOR\u50ac\u5316\u5242\u7684\u8fc7\u7535\u4f4d\u5dee\u5f02\u7684\u5bf9\u6bd4\u56fe\uff1b<\/p>\n

\uff08e\uff09PDDA@CNTs\u548c\u7eafCNT\u5bf9\u6c22\u6c27\u6839\u7684\u5438\u9644\u80fd\u5bf9\u6bd4\u56fe\uff1b<\/p>\n

\uff08f\uff09\u5206\u5b50\u52a8\u529b\u5b66\u6a21\u62df0.1 M KOH\u4e2d\uff0cOH–<\/sup>\u7684\u76f8\u5bf9\u5bc6\u5ea6\u4e0eCNT\u8868\u9762\u8ddd\u79bb\u7684\u51fd\u6570\u5173\u7cfb\u56fe\u3002<\/p>\n

\u3010\u5c0f\u7ed3\u3011<\/strong><\/p>\n

\u4e0d\u540c\u4e8e\u4f20\u7edf\u7684\u5171\u4ef7\u63ba\u6742\uff0c\u901a\u8fc7\u805a\u7535\u89e3\u8d28PDDA\u975e\u5171\u4ef7\u529f\u80fd\u5316\u7eb3\u7c73\u7ba1\uff0c\u5229\u7528\u754c\u9762\u5206\u5b50\u95f4\u7535\u8377\u8f6c\u79fb\u7684\u6982\u5ff5\u8c03\u5236\u7eb3\u7c73\u78b3\u7684\u8868\u9762\u548c\u7535\u5b50\u7ed3\u6784\uff0c\u4e00\u65b9\u9762\u901a\u8fc7\u5b9a\u5411\u5206\u5b50\u95f4\u7535\u8377\u8f6c\u79fb\u8bf1\u5bfc\u754c\u9762\u7535\u8377\u91cd\u65b0\u5206\u5e03\u4f7f\u78b3\u8868\u9762\u4ea7\u751f\u9ad8\u5bc6\u5ea6\u7684\u50ac\u5316\u4f4d\u70b9\uff0c\u53e6\u4e00\u65b9\u9762\u901a\u8fc7\u9759\u7535\u76f8\u4e92\u4f5c\u7528\u4f7f\u53cd\u5e94\u7269(OH–<\/sup>)\u5bcc\u96c6\u5728\u50ac\u5316\u5242\u8868\u9762\u6539\u5584\u4e86\u53cd\u5e94\u52a8\u529b\u5b66\u3002\u8fd9\u79cd\u754c\u9762\u8c03\u63a7\u7b56\u7565\u80fd\u591f\u5b9e\u73b0\u6d3b\u6027\u4f4d\u70b9\u548c\u53cd\u5e94\u52a8\u529b\u5b66\u7684\u534f\u540c\u8c03\u8282\uff0c\u6700\u7ec8\u5927\u5927\u63d0\u9ad8\u78b1\u6027\u4ecb\u8d28\u4e2dCNT\u7684WOR\u50ac\u5316\u6027\u80fd\u3002\u56e0\u6b64\uff0c\u5373\u4f7f\u5355\u72ec\u7684\u7eafCNT\u548c\u805a\u7535\u89e3\u8d28\u662f\u7535\u5316\u5b66\u60f0\u6027\u7684\uff0c\u4f18\u5316\u7684PDDA\u529f\u80fd\u5316\u7eb3\u7c73\u7ba1\u590d\u5408\u819c\u50ac\u5316\u5242\u4e5f\u663e\u793a\u51fa\u4f18\u5f02\u7684WOR\u50ac\u5316\u6027\u80fd\u3002\u751a\u81f3\u5728\u8f83\u4f4e\u7684\u7535\u89e3\u8d28\u6d53\u5ea6\u4e0b\uff080.1 M KOH\uff09\uff0c\u572810.0 mA cm-2<\/sup>\u65f6\uff0c\u4ecd\u5177\u6709370 mV\u7684\u4f4e\u8fc7\u7535\u4f4d\u548c\u8f83\u5c0f\u7684Tafel\u659c\u7387\uff0876 mV dec-1<\/sup>\uff09\uff0c\u5927\u5927\u4f18\u4e8e\u7eaf\u7684CNT\uff08> 520mV\uff0c166 mV dec-1<\/sup>\uff09\uff0c\u751a\u81f3\u4e0e\u5546\u4e1a\u7684\u8d35\u91d1\u5c5eRuO2<\/sub>\uff08360 mV\uff0c137 mV dec-1<\/sup>\uff09\u76f8\u5ab2\u7f8e\u3002\u6b64\u5916\uff0c\u5f53\u7535\u89e3\u8d28pH\u503c\u572813~14\u8303\u56f4\u5185\u53d8\u5316\u65f6\uff0cPDDA\u529f\u80fd\u5316\u7eb3\u7c73\u7ba1\u7684WOR\u6d3b\u6027\u51e0\u4e4e\u662f\u4e0epH\u503c\u65e0\u5173\u7684\uff0c\u4e0e\u4e4b\u622a\u7136\u4e0d\u540c\u7684\u662f\uff0c\u5927\u90e8\u5206\u62a5\u9053\u7684\u78b3\u57faWOR\u78b3\u50ac\u5316\u5242\u7684\u6d3b\u6027\u662f\u4e0epH\u503c\u76f8\u5173\u7684\uff0c\u5728pH\u503c\u4e3a13\u65f6WOR\u50ac\u5316\u6548\u679c\u8f83\u5dee\u3002\u6709\u8da3\u7684\u662f\uff0c\u7eb3\u7c73\u7ba1\u7684WOR\u50ac\u5316\u6027\u80fd\u53ef\u901a\u8fc7\u5438\u9644\u5177\u6709\u5438\/\u63a8\u7535\u5b50\u7279\u6027\u805a\u5408\u7269\u6765\u8c03\u63a7\u3002\u8fd9\u79cd\u72ec\u7279\u7684\u754c\u9762\u63a7\u5236\u7b56\u7565\u53ef\u4ee5\u6269\u5c55\u5230\u6d89\u53caOH–<\/sup>\u7684\u8bb8\u591a\u5176\u4ed6\u7535\u5316\u5b66\u53cd\u5e94\u3002\u66f4\u91cd\u8981\u7684\u662f\uff0c\u8fd9\u79cd\u65b9\u6cd5\u7b80\u4fbf\u3001\u73af\u4fdd\u548c\u53ef\u5927\u89c4\u6a21\u5236\u5907\uff0c\u4e14\u53ef\u9002\u7528\u4e8e\u5176\u4ed6\u78b3\u6750\u6599\u6765\u5236\u5907\u4e00\u7cfb\u5217\u65b0\u9896\u7684\u65e0\u91d1\u5c5eWOR\u50ac\u5316\u5242\u7528\u4e8e\u6c34\u5206\u89e3\u3001\u53ef\u5145\u7535\u950c\u7a7a\u6c14\u7535\u6c60\u548c\u518d\u751f\u71c3\u6599\u7535\u6c60\u3002<\/p>\n

\u6587\u732e\u94fe\u63a5\uff1a<\/strong>Boosting water oxidation on metal-free carbon nanotubes via directional interfacial charge-transfer induced by adsorbed polyelectrolyte<\/strong><\/a>\uff08Energ. Environ. Sci., 2018, DOI: 10.1039\/ C8EE01487F\uff09\u3002<\/p>\n

\u3010\u901a\u8baf\u4f5c\u8005\u7b80\u4ecb<\/strong>\u3011<\/p>\n

\u4f59\u4e01\u5c71\u535a\u58eb\u3001\u6559\u6388\u3001\u535a\u58eb\u751f\u5bfc\u5e08\uff0c2008\u5e74\u535a\u58eb\u6bd5\u4e1a\u4e8e\u4e2d\u5c71\u5927\u5b66\u3002\u56de\u56fd\u524d\uff0c\u5148\u540e\u5728\u7f8e\u56fd\u4ee3\u987f\u5927\u5b66\u3001\u7f8e\u56fd\u51ef\u601d\u897f\u50a8\u5927\u5b66\u548c\u65b0\u52a0\u5761\u5357\u6d0b\u7406\u5de5\u5927\u5b66\u4ece\u4e8b\u535a\u58eb\u540e\u7814\u7a76\uff0c2015\u5e742\u6708\u5165\u9009\u4e2d\u7ec4\u90e8\u201c\u9752\u5e74\u5343\u4eba\u8ba1\u5212\u201d\uff0c\u540c\u5e745\u6708\u52a0\u5165\u4e2d\u5c71\u5927\u5b66\u4efb\u5316\u5b66\u5b66\u9662\u6559\u6388\u3002\u7814\u7a76\u56e2\u961f\u4e3b\u8981\u81f4\u529b\u4e8e\u805a\u5408\u7269\u53ca\u78b3\u57fa\u529f\u80fd\u6750\u6599\u7684\u53ef\u63a7\u5408\u6210\u53ca\u5176\u5728\u5149\u7535\u5668\u4ef6\u548c\u80fd\u91cf\u5b58\u50a8\u4e0e\u8f6c\u5316\u5668\u4ef6\u4e2d\u7684\u5e94\u7528\u7814\u7a76\u3002\u8fc4\u4eca\u4e3a\u6b62\u5171\u53d1\u8868\u5b66\u672f\u8bba\u6587\u8fd190\u7bc7\uff0c\u5176\u4e2d\u4ee5\u7b2c\u4e00\u4f5c\u8005\u548c\u901a\u8baf\u4f5c\u8005\u5728Nature Nanotechnology, Chem. Soc. Rev, J. Am. Chem. Soc, Angew. Chem. Int. Ed, Energy Environ Science, Advanced Materials, Advanced Functional Materials, ACS Nano \u7b49\u56fd\u9645\u5b66\u672f\u671f\u520a\u4e0a\u53d1\u8868\u8bba\u658740\u4f59\u7bc7\uff0c\u5728Chem. Soc. Rev\u7b49\u671f\u520a\u4e0a\u53d1\u8868\u7efc\u8ff0\u8bba\u65874\u7bc7\u3002\u5176\u4e2d18\u7bc7\u8bba\u6587\u88abESI\u8bc4\u4e3a\u9ad8\u88ab\u5f15\u8bba\u6587\uff0c2\u7bc7\u8bba\u6587\u88abESI\u8bc4\u4e3a\u70ed\u70b9\u8bba\u6587\u3002\u8bba\u6587\u5df2\u88abSCI\u5f15\u7528\u8fd17000\u6b21\uff0cH\u56e0\u5b50\u4e3a31\u3002\u8fd1\u5e74\u6765\u4ee3\u8868\u4f5c\u5305\u62ecNature Nanotechnology 2014, 9, 555 (ESI\u70ed\u70b9\u8bba\u6587); Chem. Soc. Rev. 2015, 44, 647 (ESI\u9ad8\u88ab\u5f15\u8bba\u6587); Energy Environ. Sci. 2018, DOI: 10.1039\/C8EE01487F; Energy Environ. Sci. 2017, 10, 893 (back cover\uff0cESI\u70ed\u70b9\u8bba\u6587); Energy Environ. Sci. 2017, 10, 2312 (back cover); Adv. Funct. Mater. 2017, 27, 1701971 (front cover); Adv. Mater., 2015, 27, 4895; Adv. Mater. 2014, 26, 6790 (ESI\u9ad8\u88ab\u5f15\u8bba\u6587)\u3002<\/p>\n

\u6b22\u8fce\u5927\u5bb6\u5230\u6750\u6599\u4eba\u5ba3\u4f20\u79d1\u6280\u6210\u679c\u5e76\u5bf9\u6587\u732e\u8fdb\u884c\u6df1\u5165\u89e3\u8bfb\uff0c\u6295\u7a3f\u90ae\u7bb1<\/strong>tougao@cailiaoren.com<\/strong><\/a>\u3002<\/p>\n

\u6750\u6599\u4eba\u6295\u7a3f\u4ee5\u53ca\u5185\u5bb9\u5408\u4f5c\u53ef\u52a0\u7f16\u8f91\u5fae\u4fe1\uff1acailiaokefu<\/strong>\u3002<\/p>\n

\u6750\u6599\u725b\u4e13\u6ce8\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u53ca\u884c\u4e1a\u8fdb\u5c55\uff0c\u8fd9\u91cc\u6c47\u96c6\u4e86\u5404\u5927\u9ad8\u6821\u7855\u535a\u751f\u3001\u4e00\u7ebf\u79d1\u7814\u4eba\u5458\u4ee5\u53ca\u884c\u4e1a\u4ece\u4e1a\u8005\uff0c\u5982\u679c\u60a8\u5bf9\u4e8e\u8ddf\u8e2a\u6750\u6599\u9886\u57df\u79d1\u6280\u8fdb\u5c55\uff0c\u89e3\u8bfb\u9ad8\u6c34\u5e73\u6587\u7ae0\u6216\u662f\u8bc4\u8ff0\u884c\u4e1a\u6709\u5174\u8da3\uff0c\u70b9\u6211\u52a0\u5165\u6750\u6599\u4eba\u7f16\u8f91\u90e8<\/strong><\/a>\u3002<\/p>\n

\u6750\u6599\u6d4b\u8bd5\uff0c\u6570\u636e\u5206\u6790\uff0c\u4e0a<\/strong>\u6d4b\u8bd5\u8c37<\/strong><\/a>\uff01<\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"

\u3010\u5f15\u8a00\u3011 \u7535\u5316\u5b66\u6c34\u6c27\u5316\u53cd\u5e94\uff08WOR\uff09\u662f\u6c34\u5206\u89e3\u3001\u53ef\u518d\u751f\u71c3\u6599\u7535\u6c60\u548c\u53ef\u5145\u7535\u91d1\u5c5e\u7a7a\u6c14\u7535\u6c60\u7684\u6838\u5fc3\u7684\u80fd\u91cf\u8f6c\u6362\u8fc7\u7a0b\u3002\u7136\u800c\uff0cWOR\u52a8\u529b\u5b66\u8fdf\u7f13\uff0c\u9700\u8981\u5f88\u9ad8\u7684\u8fc7\u7535\u4f4d\u3002\u5e38\u7528IrO2\u6216R…<\/p>\n","protected":false},"author":7035,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[215],"tags":[3384,3386,3385],"class_list":["post-144874","post","type-post","status-publish","format-standard","hentry","category-jiedu","tag-3384","tag-3386","tag-3385"],"_links":{"self":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/144874"}],"collection":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/users\/7035"}],"replies":[{"embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=144874"}],"version-history":[{"count":3,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/144874\/revisions"}],"predecessor-version":[{"id":145113,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=\/wp\/v2\/posts\/144874\/revisions\/145113"}],"wp:attachment":[{"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=144874"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=144874"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.cailiaoniu.com\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=144874"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}